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diff --git a/.gitattributes b/.gitattributes new file mode 100644 index 0000000..6833f05 --- /dev/null +++ b/.gitattributes @@ -0,0 +1,3 @@ +* text=auto +*.txt text +*.md text diff --git a/15833-8.txt b/15833-8.txt new file mode 100644 index 0000000..948ca73 --- /dev/null +++ b/15833-8.txt @@ -0,0 +1,5041 @@ +The Project Gutenberg EBook of Scientific American Supplement, No. 441, +June 14, 1884., by Various + +This eBook is for the use of anyone anywhere at no cost and with +almost no restrictions whatsoever. You may copy it, give it away or +re-use it under the terms of the Project Gutenberg License included +with this eBook or online at www.gutenberg.org + + +Title: Scientific American Supplement, No. 441, June 14, 1884. + +Author: Various + +Release Date: May 16, 2005 [EBook #15833] + +Language: English + +Character set encoding: ISO-8859-1 + +*** START OF THIS PROJECT GUTENBERG EBOOK SCIENTIFIC AMERICAN *** + + + + +Produced by Juliet Sutherland and the Online Distributed +Proofreading Team at www.pgdp.net. + + + + + +[Illustration] + + + + +SCIENTIFIC AMERICAN SUPPLEMENT NO. 441 + + + + +NEW YORK, JUNE 14, 1884 + +Scientific American Supplement. Vol. XVII., No. 441. + +Scientific American established 1845 + +Scientific American Supplement, $5 a year. + +Scientific American and Supplement, $7 a year. + + * * * * * + + + + +TABLE OF CONTENTS. + + +I. CHEMISTRY AND METALLURGY.--On Electrolysis.--Precipitation + of lead, thallium, silver, bismuth, manganese, etc.--By H. + SCHUCHT + + The Electro-Chemical Equivalent of Silver + + Zircon.--How it can be rendered soluble.--By F. STOLBA + + A New Process for Making Wrought Iron Directly from the Ore. + --Comparison with other processes.--With descriptions and + engravings of the apparatus used + + Some Remarks on the Determination of Hardness in Water + + On the changes which Take Place in the Conversion of Hay + into Ensilage.--By F.J. Lloyd + +II. ENGINEERING AND MECHANICS.--Faure's Machine for + Decorticating Sugar Cane.--With full description + and 13 figures + + The Generation of Steam and the Thermodynamic Problems + Involved.--By WM. ANDERSON.--Apparatus used in the + experimental determination of the heat of combustion and + the laws which govern its development.--Ingredients of + fuel.--Potential energy of fuel.--With 7 figures and + several tables + + Planetary Wheel Trains.--Rotations of the wheels relatively + to the train arm.--By Prof. C.W. MACCORD + + The Pantanemone.--A New Windwheel.--1 engraving + + Relvas's New Life Boat.--With engraving + + Experiments with Double Barreled Guns and Rifles. + --Cause of the divergence of the charge.--4 figures + + Improved Ball Turning Machine.--1 figure + + Cooling Apparatus for Injection Water.--With engraving + + Corrugated Disk Pulleys.--1 engraving + +III. TECHNOLOGY.--A New Standard Light + + Dr. Feussner's New Polarizing Prism.--Points of difference + between the old and new prisms.--By P.R. SLEEMAN + + Density and Pressure of Detonating Gas + +IV. ELECTRICITY, LIGHT, ETC.--Early History of the Telegraph. + --Pyrsia, or the system of telegraphy among the Greeks. + --Communication by means of characters and the telescope. + --Introduction of the magnetic telegraph between Baltimore + and Washington + + The Kravogl Electro Motor and its Conversion Into a Dynamo + Electric Machine.--5 figures + + Bornhardt's Electric Machine for Blasting in Mines. + --15 figures + + Pritchett's Electric Fire Alarm.--1 figure + + A Standard Thermopile + + Telephonic Transmission without Receivers.--Some of the + apparatus exhibited at the annual meeting of the French + Society of Physics.--Telephonic transmission through a + chain of persons + + Diffraction Phenomena during Total Solar Eclipses.--By G.D. + Hiscox + +V. BOTANY AND HORTICULTURE.--Gum Diseases in Trees.-- + Cause and contagion of the same + + Drinkstone Park.--Trees and plants cultivated therein.-- + With 2 engravings + +VI. MEDICINE AND HYGIENE.--Miryachit.--A newly-discovered + disease of the nervous system, and its analogues.--By WM. A. + HAMMOND + +VII. MISCELLANEOUS.--Turkish Baths for Horses.--With + diagram. + + * * * * * + + + + +FAURE'S MACHINE FOR DECORTICATING SUGAR-CANE. + + +The object of the apparatus shown in the accompanying engraving is to +effect a separation of the tough epidermis of the sugar-cane from the +internal spongy pith which is to be pressed. Its function consists in +isolating and separating the cells from their cortex, and in putting +them in direct contact with the rollers or cylinders of the mill. +After their passage into the apparatus, which is naturally placed in a +line with the endless chain that carries them to the mill, the canes +arrive in less compact layers, pass through much narrower spaces, and +finally undergo a more efficient pressure, which is shown by an +abundant flow of juice. The first trials of the machine were made in +1879 at the Pointe Simon Works, at Martinique, with the small type +that was shown at the Paris Exhibition of 1878. These experiments, +which were applied to a work of 3,000 kilos of cane per hour, gave +entire satisfaction, and decided the owners of three of the colonial +works (Pointe Simon, Larcinty, and Marin) to adopt it for the season +of 1880. + +The apparatus is shown in longitudinal section in Fig. 1, and in plan +in Fig. 2. + +Fig. 3 gives a transverse section passing through the line 3-4, and +Fig. 4 an external view on the side whence the decorticated canes make +their exit from the apparatus. + +[Illustration: FAURE'S MACHINE FOR DECORTICATING SUGAR CANE.] + +The other figures relate to details that will be referred to further +along. + +_The Decorticating Cylinder._--The principal part of the apparatus is +a hollow drum, A, of cast iron, 430 mm. in internal diameter by 1.41 +m. in length, which is keyed at its two extremities to the shaft, a. +Externally, this drum (which is represented apart in transverse +section in Fig. 5) has the form of an octagonal prism with well +dressed projections between which are fixed the eight plates, C, that +constitute the decorticating cylinder. These plates, which are of +tempered cast iron, and one of which is shown in transverse section in +Fig. 7, when once in place form a cylindrical surface provided with 48 +helicoidal, dentate channels. The length of these plates is 470 mm. +There are three of them in the direction of the generatrices of the +cylinder, and this makes a total of 24. All are strengthened by ribs +(as shown in Fig. 8), and each is fixed by 4 bolts, _c_, 20mm. in +diameter. The pitch of the helices of each tooth is very elongated, +and reaches about 7.52 m. The depth of the toothing is 18 mm. + +_Frame and Endless Chain._--The cylinder thus constructed rotates with +a velocity of 50 revolutions per minute over a cylindrical vessel, B', +cast in a piece with the frame, B. This vessel is lined with two +series of tempered cast iron plates, D and D', called exit and +entrance plates, which rest thereon, through the intermedium of well +dressed pedicels, and which are held in place by six 20-millimeter +bolts. Their length is 708 mm. The entrance plates, D, are provided +with 6 spiral channels, whose pitch is equal to that of the channels +of the decorticating cylinder, C, and in the same direction. The depth +of the toothing is 10 mm. + +The exit plates, D', are provided with 7 spiral channels of the same +pitch and direction as those of the preceding, but the depth of which +increases from 2 to 10 mm. The axis of the decorticating cylinder does +not coincide with that of the vessel, B', so that the free interval +for the passage of the cane continues to diminish from the entrance to +the exit. + +The passage of the cane to the decorticator gives rise to a small +quantity of juice, which flows through two orifices, _b'_, into a sort +of cast iron trough, G, suspended beneath the vessel. The cane, which +is brought to the apparatus by an endless belt, empties in a conduit +formed of an inclined bottom, E, of plate iron, and two cast iron +sides provided with ribs. These sides rest upon the two ends of the +vessel, B', and are cross-braced by two flat bars, _e_, to which is +bolted the bottom, E. This conduit is prolonged beyond the +decorticating cylinder by an inclined chute, F, the bottom of which is +made of plate iron 7 mm. thick and the sides of the same material 9 +mm. thick. The hollow frame, B, whose general form is like that of a +saddle, carries the bearings, _b_, in which revolves the shaft, _a_. +One of these bearings is represented in detail in Figs. 9 and 10. It +will be seen that the cap is held by bolts with sunken heads, and that +the bearing on the bushes is through horizontal surfaces only. In a +piece with this frame are cast two similar brackets, Bē, which support +the axle, _h_, of the endless chain. To this axle, whose diameter is +100 mm., are keyed, toward the extremities, the pinions, H, to which +correspond the endless pitch chains, _i_. These latter are formed, as +may be seen in Figs. 11 and 12, of two series of links. The shorter of +these latter are only 100 mm. in length, while the longer are 210 mm., +and are hollowed out so as to receive the butts of the boards, I. The +chain thus formed passes over two pitch pinions, J, like the pinions, +H, that are mounted at the extremities of an axle, _j_, that revolves +in bearings, I', whose position with regard to the apparatus is +capable of being varied so as to slacken or tauten the chain, I. This +arrangement is shown in elevation in Fig. 13. + +_Transmission._--The driving shaft, _k_, revolves in a pillow block, +K, cast in a piece with the frame, B. It is usually actuated by a +special motor, and carries a fly-wheel (not shown in the figure for +want of space). It receives in addition a cog-wheel, L, which +transmits its motion to the decorticating cylinder through, the +intermedium of a large wooden-toothed gear wheel, L'. The shaft, _a_, +whose diameter is 228 mm., actuates in its turn, through the pinions, +M' and M, the pitch pinion, N, upon whose prolonged hub is keyed the +pinion, M. This latter is mounted loosely upon the intermediate axle, +_m_. Motion is transmitted to the driving shaft, _h_, of the endless +chain, I, by an ordinary pitch chain, through a gearing which is shown +in Fig. 12. The pitch pinion, N', is cast in a piece with a hollow +friction cone, Nē, which is mounted loosely upon the shaft, _h_, and +to which corresponds a second friction cone, O. This latter is +connected by a key to a socket, _o_, upon which it slides, and which +is itself keyed to the shaft, _h_. The hub of the cone, O, is +connected by a ring with a bronze nut, _p_, mounted at the threaded +end of the shaft, _h_, and carrying a hand-wheel, P. It is only +necessary to turn this latter in one direction or the other in order +to throw the two cones into or out of gear. + +If we allow that the motor has a velocity of 70 revolutions per +minute, the decorticating cylinder will run at the rate of 50, and the +sugar-cane will move forward at the rate of 12 meters per minute. + +This new machine is a very simple and powerful one. The decortication +is effected with wonderful rapidity, and the canes, opened throughout +their entire length and at all points of their circumference, leave +the apparatus in a state that allows of no doubt as to what the result +of the pressure will be that they have to undergo. There is no +tearing, no trituration, no loss of juice, but merely a simple +preparation for a rational pressure effected under most favorable +conditions. + +The apparatus, which is made in several sizes, has already received +numerous applications in Martinique, Trinidad, Cuba, Antigua, St. +Domingo, Peru, Australia, the Mauritius Islands, and +Brazil.--_Publication Industrielle._ + + * * * * * + + + + +MOVING A BRIDGE. + + +An interesting piece of engineering work has recently been +accomplished at Bristol, England, which consisted in the moving of a +foot-bridge 134 feet in length, bodily, down the river a considerable +distance. The pontoons by means of which the bridge was floated to its +new position consisted of four 80-ton barges, braced together so as to +form one solid structure 64 feet in width, and were placed in position +soon after the tide commenced to rise. At six o'clock A.M. the top of +the stages, which was 24 feet above the water, touched the under part +of the bridge, and in a quarter of an hour later both ends rose from +their foundations. When the tide had risen 4 ft. the stage and bridge +were floated to the new position, when at 8.30 the girders dropped on +to their beds. + + * * * * * + + + + +THE GENERATION OF STEAM, AND THE THERMODYNAMIC PROBLEMS +INVOLVED.[1] + + [Footnote 1: Lecture delivered at the Institution of Civil + Engineers, session 1883-84. For the illustrations we are indebted + to the courtesy of Mr. J. Forrest, the secretary.] + +By Mr. WILLIAM ANDERSON, M.I.C.E. + + +It will not be necessary to commence this lecture by explaining the +origin of fuel; it will be sufficient if I remind you that it is to +the action of the complex rays of the sun upon the foliage of plants +that we mainly owe our supply of combustibles. The tree trunks and +branches of our forests, as well as the subterranean deposits of coal +and naphtha, at one time formed portions of the atmosphere in the form +of carbonic acid gas; that gas was decomposed by the energy of the +solar rays, the carbon and the oxygen were placed in positions of +advantage with respect to each other--endowed with potential energy; +and it is my duty this evening to show how we can best make use of +these relations, and by once more combining the constituents of fuel +with the oxygen of the air, reverse the action which caused the growth +of the plants, that is to say, by destroying the plant reproduce the +heat and light which fostered it. The energy which can be set free by +this process cannot be greater than that derived originally from the +sun, and which, acting through the frail mechanism of green leaves, +tore asunder the strong bonds of chemical affinity wherein the carbon +and oxygen were hound, converting the former into the ligneous +portions of the plants and setting the latter free for other uses. The +power thus silently exerted is enormous; for every ton of carbon +separated in twelve hours necessitates an expenditure of energy +represented by at least 1,058 horse power, but the action is spread +over an enormous area of leaf surface, rendered necessary by the small +proportion of carbonic acid contained in the air, by measure only +1/2000 part, and hence the action is silent and imperceptible. It is +now conceded on all hands that what is termed heat is the energy of +molecular motion, and that this motion is convertible into various +kinds and obeys the general laws relating to motion. Two substances +brought within the range of chemical affinity unite with more or less +violence; the motion of transition of the particles is transformed, +wholly or in part, into a vibratory or rotary motion, either of the +particles themselves or the interatomic ether; and according to the +quality of the motions we are as a rule, besides other effects, made +conscious of heat or light, or of both. When these emanations come to +be examined they are found to be complex in the extreme, intimately +bound up together, and yet capable of being separated and analyzed. + +As soon as the law of definite chemical combination was firmly +established, the circumstance that changes of temperature accompanied +most chemical combinations was noticed, and chemists were not long in +suspecting that the amount of heat developed or absorbed by chemical +reaction should be as much a property of the substances entering into +combination as their atomic weights. Solid ground for this expectation +lies in the dynamic theory of heat. A body of water at a given height +is competent by its fall to produce a definite and invariable quantity +of heat or work, and in the same way two substances falling together +in chemical union acquire a definite amount of kinetic energy, which, +if not expended in the work of molecular changes, may also by suitable +arrangements be made to manifest a definite and invariable quantity of +heat. + +At the end of last century Lavoisier and Laplace, and after them, down +to our own time, Dulong, Desprez, Favre and Silbermann, Andrews, +Berthelot, Thomson, and others, devoted much time and labor to the +experimental determination of the heat of combustion and the laws +which governed its development. Messrs. Favre and Silbermann, in +particular, between the years 1845 and 1852, carried out a splendid +series of experiments by means of the apparatus partly represented in +Fig. 1 (opposite), which is a drawing one-third the natural size of +the calorimeter employed. It consisted essentially of a combustion +chamber formed of thin copper, gilt internally. The upper part of the +chamber was fitted with a cover through which the combustible could be +introduced, with a pipe for a gas jet, with a peep hole closed by +adiathermanous but transparent substances, alum and glass, and with a +branch leading to a thin copper coil surrounding the lower part of the +chamber and descending below it. The whole of this portion of the +apparatus was plunged into a thin copper vessel, silvered internally +and filled with water, which was kept thoroughly mixed by means of +agitators. This second vessel stood inside a third one, the sides and +bottom of which were covered with the skins of swans with the down on, +and the whole was immersed in a fourth vessel tilled with water, kept +at the average temperature of the laboratory. Suitable thermometers of +great delicacy were provided, and all manner of precautions were taken +to prevent loss of heat. + +[Illustration: THE GENERATION OF STEAM. Fig 1.] + +It is impossible not to admire the ingenuity and skill exhibited in +the details of the apparatus, in the various accessories for +generating and storing the gases used, and for absorbing and weighing +the products of combustion; but it is a matter of regret that the +experiments should have been carried out on so small a scale. For +example, the little cage which held the solid fuel tested was only 5/8 +inch diameter by barely 2 inches high, and held only 38 grains of +charcoal, the combustion occupying about sixteen minutes. Favre and +Silbermann adopted the plan of ascertaining the weight of the +substances consumed by calculation from the weight of the products of +combustion. Carbonic acid was absorbed by caustic potash, as also was +carbonic oxide, after having been oxidized to carbonic acid by heated +oxide of copper, and the vapor of water was absorbed by concentrated +sulphuric acid. The adoption of this system showed that it was in any +case necessary to analyze the products of combustion in order to +detect imperfect action. Thus, in the case of substances containing +carbon, carbonic oxide was always present to a variable extent with +the carbonic acid, and corrections were necessary in order to +determine the total heat due to the complete combination of the +substance with oxygen. Another advantage gained was that the +absorption of the products of combustion prevents any sensible +alteration in the volumes during the process, so that corrections for +the heat absorbed in the work of displacing the atmosphere were not +required. The experiments on various substances were repeated many +times. The mean results for those in which we are immediately +interested are given in Table I., next column. + +Comparison with later determinations have established their +substantial accuracy. The general conclusion arrived at is thus +stated: + +"As a rule there is an equality between the heat disengaged or +absorbed in the acts, respectively, of chemical combination or +decomposition of the same elements, so that the heat evolved during +the combination of two simple or com-pound substances is equal to the +heat absorbed at the time of their chemical segregation." + + TABLE I.--SUBSTANCES ENTERING INTO THE COMPOSITION OF FUEL. + + -----------------------+-------------+-----------+-------------------+ + | | Heat evolved in | + | Symbol and Atomic |the Combustion of | + | Weight. | 1 lb. of Fuel. | + +------------+------------+--------+----------+ + | | | |In Pounds | + | | | In | of Water | + | | |British |Evaporated| + | Before | After |Thermal | from and | + | Combustion | Combustion | Units. | at 212°. | + +------------+------------+--------+----------+ + Hydrogen burned | H 1 | H2O 18 | 62,032 | 64.21 | + in oxygen. | | | | | + -----------------------+------------+------------+--------+----------+ + Carbon burned to | C 12 | CO 28 | 4,451 | 4.61 | + carbonic oxide. | | | | | + -----------------------+------------+------------+--------+----------+ + Carbon burned to | C 12 | CO2 44 | 14,544 | 15.06 | + carbonic acid. | | | | | + -----------------------+------------+------------+--------+----------+ + Carbonic oxide burned | CO 28 | CO2 44 | 4,326 | 4.48 | + to carbonic acid. | | | | | + -----------------------+------------+------------+--------+----------+ + Olefiant gas (ethylene)| C2H4 28 | 2CO2 124 | 21,343 | 22.09 | + burnt in oxygen. | | 2H2O | | | + -----------------------+------------+------------+--------+----------+ + Marsh gas (methane) | CH4 16 | 2CO2 80 | 23,513 | 24.34 | + burnt in oxygen. | | 2H2O | | | + -----------------------+------------+------------+--------+----------+ + +Composition of air-- + + by volume 0.788 N + 0.197 O + 0.001 CO2 + 0.014 H2O + ---------------------------------------------------- + by weight 0.771 N + 0.218 O + 0.009 CO2 + 0.017 H2O + +This law is, however, subject to some apparent exceptions. Carbon +burned in protoxide of nitrogen, or laughing gas, N_{2}O, produces +about 38 per cent. more heat than the same substance burned in pure +oxygen, notwithstanding that the work of decomposing the protoxide of +nitrogen has to be performed. In marsh gas, or methane, CH_{4}, again, +the energy of combustion is considerably less than that due to the +burning of its carbon and hydrogen separately. These exceptions +probably arise from the circumstance that the energy of chemical +action is absorbed to a greater or less degree in effecting molecular +changes, as, for example, the combustion of 1 pound of nitrogen to +form protoxide of nitrogen results in the absorption of 1,157 units of +heat. Berthelot states, as one of the fundamental principles of +thermochemistry, "that the quantity of heat evolved is the measure of +the sum of the chemical and physical work accomplished in the +reaction"; and such a law will no doubt account for the phenomena +above noted. The equivalent heat of combustion of the compounds we +have practically to deal with has been experimentally determined, and +therefore constitutes a secure basis on which to establish +calculations of the caloric value of fuel; and in doing so, with +respect to substances composed of carbon, hydrogen, and oxygen, it is +convenient to reduce the hydrogen to its heat-producing equivalent of +carbon. The heat of combustion of hydrogen being 62,032 units, that of +carbon 14,544 units, it follows that 4.265 times the weight of +hydrogen will represent an equivalent amount of carbon. With respect +to the oxygen, it is found that it exists in combination with the +hydrogen in the form of water, and, being combined already, abstracts +its combining equivalent of hydrogen from the efficient ingredients of +the fuel; and hence hydrogen, to the extent of 1/8 of the weight of +the oxygen, must be deducted. The general formula then becomes: + + Heat of combustion = 14,544 {C + 4.265 (H-(O/8))}, + +and water evaporated from and at 212°, taking 966 units as the heat +necessary to evaporate 1 pound of water, + + lb. evaporated = 15.06 {C + 4.265 (H-(O/8))}, + +carbon, hydrogen, and oxygen being taken at their weight per cent. in +the fuel. Strictly speaking, marsh gas should be separately +determined. It often happens that available energy is not in a form in +which it can be applied directly to our needs. The water flowing down +from the mountains in the neighborhood of the Alpine tunnels was +competent to provide the power necessary for boring through them, but +it was not in a form in which it could be directly applied. The +kinetic energy of the water had first to be changed into the potential +energy of air under pressure, then, in that form, by suitable +mechanism, it was used with signal success to disintegrate and +excavate the hard rock of the tunnels. The energy resulting from +combustion is also incapable of being directly transformed into useful +motive power; it must first be converted into potential force of steam +or air at high temperature and pressure, and then applied by means of +suitable heat engines to produce the motions we require. It is +probably to this circumstance that we must attribute the slowness of +the human race to take advantage of the energy of combustion. The +history of the steam engine hardly dates back 200 years, a very small +fraction of the centuries during which man has existed, even since +historic times. + +The apparatus by means of which the potential energy of fuel with +respect to oxygen is converted into the potential energy of steam, we +call a steam boiler; and although it has neither cylinder nor piston, +crank nor fly wheel, I claim for it that it is a veritable heat +engine, because it transmits the undulations and vibrations caused by +the energy of chemical combination in the fuel to the water in the +boiler; these motions expend themselves in overcoming the liquid +cohesion of the water and imparting to its molecules that vigor of +motion which converts them into the molecules of a gas which, +impinging on the surfaces which confine it and form the steam space, +declare their presence and energy in the shape of pressure and +temperature. A steam pumping engine, which furnishes water under high +pressure to raise loads by means of hydraulic cranes, is not more +truly a heat engine than a simple boiler, for the latter converts the +latent energy of fuel into the latent energy of steam, just as the +pumping engine converts the latent energy of steam into the latent +energy of the pumped-up accumulator or the hoisted weight. + +If I am justified in taking this view, then I am justified in applying +to my heat engine the general principles laid down in 1824 by Sadi +Carnot, namely, that the proportion of work which can be obtained out +of any substance working between two temperatures depends entirely and +solely upon the difference between the temperatures at the beginning +and end of the operation; that is to say, if T be the higher +temperature at the beginning, and _t_ the lower temperature at the end +of the action, then the maximum possible work to be got out of the +substance will be a function of (T-_t_). The greatest range of +temperature possible or conceivable is from the absolute temperature +of the substance at the commencement of the operation down to absolute +zero of temperature, and the fraction of this which can be utilized is +the ratio which the range of temperature through which the substance +is working bears to the absolute temperature at the commencement of +the action. If W = the greatest amount of effect to be expected, T and +_t_ the absolute temperatures, and H the total quantity of heat +(expressed in foot pounds or in water evaporated, as the case may be) +potential in the substance at the higher temperature, T, at the +beginning of the operation, then Carnot's law is expressed by the +equation: + + / T - t \ + W = H( ------- ) + \ T / + +I will illustrate this important doctrine in the manner which Carnot +himself suggested. + +[Illustration: THE GENERATION OF STEAM. Fig 2.] + +Fig. 2 represents a hillside rising from the sea. Some distance up +there is a lake, L, fed by streams coming down from a still higher +level. Lower down on the slope is a millpond, P, the tail race from +which falls into the sea. At the millpond is established a factory, +the turbine driving which is supplied with water by a pipe descending +from the lake, L. Datum is the mean sea level; the level of the lake +is T, and of the millpond _t_. Q is the weight of water falling +through the turbine per minute. The mean sea level is the lowest level +to which the water can possibly fall; hence its greatest potential +energy, that of its position in the lake, = QT = H. The water is +working between the absolute levels, T and _t_; hence, according to +Carnot, the maximum effect, W, to be expected is-- + + / T - t \ + W = H( ------- ) + \ T / + / T - t \ +but H = QT [therefore] W = Q T( ------- ) + \ T / + + W = Q (T - t), + +that is to say, the greatest amount of work which can be expected is +found by multiplying the weight of water into the clear fall, which +is, of course, self-evident. + +Now, how can the quantity of work to be got out of a given weight of +water be increased without in any way improving the efficiency of the +turbine? In two ways: + +1. By collecting the water higher up the mountain, and by that means +increasing T. + +2. By placing the turbine lower down, nearer the sea, and by that +means reducing _t_. + +Now, the sea level corresponds to the absolute zero of temperature, +and the heights T and _t_ to the maximum and minimum temperatures +between which the substance is working; therefore similarly, the way +to increase the efficiency of a heat engine, such as a boiler, is to +raise the temperature of the furnace to the utmost, and reduce the +heat of the smoke to the lowest possible point. It should be noted, in +addition, that it is immaterial what liquid there may be in the lake; +whether water, oil, mercury, or what not, the law will equally apply, +and so in a heat engine, the nature of the working substance, provided +that it does not change its physical state during a cycle, does not +affect the question of efficiency with which the heat being expended +is so utilized. To make this matter clearer, and give it a practical +bearing, I will give the symbols a numerical value, and for this +purpose I will, for the sake of simplicity, suppose that the fuel used +is pure carbon, such as coke or charcoal, the heat of combustion of +which is 14,544 units, that the specific heat of air, and of the +products of combustion at constant pressure, is 0.238, that only +sufficient air is passed through the fire to supply the quantity of +oxygen theoretically required for the combustion of the carbon, and +that the temperature of the air is at 60° Fahrenheit = 520° absolute. +The symbol T represents the absolute temperature of the furnace, a +value which is easily calculated in the following manner: 1 lb. of +carbon requires 2-2/3 lb. of oxygen to convert it into carbonic acid, +and this quantity is furnished by 12.2 lb. of air, the result being +13.2 lb. of gases, heated by 14,544 units of heat due to the energy of +combustion; therefore: + + 14,544 units + T = 520° + ------------------ = 5,150° absolute. + 13.2 lb. X 0.238 + +The lower temperature, _t_, we may take as that of the feed water, say +at 100° or 560° absolute, for by means of artificial draught and +sufficiently extending the heating surface, the temperature of the +smoke may be reduced to very nearly that of the feed water. Under such +circumstances the proportion of heat which can be realized is + + 5,150° - 560° + = --------------- = 0.891; + 5,150° + +that is to say, under the extremely favorable if not impracticable +conditions assumed, there must be a loss of 11 per cent. Next, to give +a numerical value to the potential energy, H, to be derived from a +pound of carbon, calculating from absolute zero, the specific heat of +carbon being 0.25, and absolute temperature of air 520°: + + Units. + 1 lb. of carbon X 0.25 X 520 = 130 + 12.2 of air X 0.238 X 520 = 1,485 + Heat of combustion = 14,544 + ------ + 16,159 + Deduct heat equivalent to work of \ + displacing atmosphere by products of } + combustion raised from 60° to 100°, } 32 + or from 149.8 cubic feet to 161.3 } + cubic feet, / + ------ + Total units of heat available 16,127 + +Equal to 16.69 lb. of water evaporated from and at 212°. Hence the +greatest possible evaporation from and at 212° from a lb. of carbon-- + + 16,159 u. X 0.891 - 32 u. + W = --------------------------- = 14.87 lb. + 966 u. + +I will now take a definite case, and compare the potential energy of a +certain kind of fuel with the results actually obtained. For this +purpose the boiler of the eight-horse portable engine, which gained +the first prize at the Cardiff show of the Royal Agricultural Society +in 1872, will serve very well, because the trials, all the details of +which are set forth very fully in vol. ix. of the _Journal_ of the +Society, were carried out with great care and skill by Sir Frederick +Bramwell and the late Mr. Menelaus; indeed, the only fact left +undetermined was the temperature of the furnace, an omission due to +the want of a trustworthy pyrometer, a want which has not been +satisfied to this day.[2] + + [Footnote 2: In the fifty-second volume of the _Proceedings_ + (1887-78), page 154, will be found a remarkable experiment on the + evaporative power of a vertical boiler with internal circulating + pipes. The experiment was conducted by Sir Frederick Bramwell and + Dr. Russell, and is remarkable in this respect, that the quantity + of air admitted to the fuel, the loss by convection and + radiation, and the composition of the smoke were determined. The + facts observed were as follows: + + Steam pressure 53 lb................................... = 300.6° F. + lb. + Fuel--Water in coke and wood........................... 26.08 + Ash.............................................. 10.53 + Hydrogen, oxygen, nitrogen, and sulphur.......... 7.18 + ------ + Total non-combustible..................... 43.79 + Carbon, being useful combustible................. 194.46 + ------ + Total fuel................................ 238.25 + + Air per pound of carbon................................ 17-1/8 lb. + Time of experiment..................................... 4 h. 12 min. + Water evaporated from 60° into steam at 53 lb. pressure 1,620 lb. + Heat lost by radiation and convection.................. 70,430 units. + Mean temperature of chimney............................ 700° F. + " " " air................................ 70° F. + + No combustible gas was found in the chimney. + + I will apply Carnot's doctrine to this case. + + Potential energy of the fuel with respect to absolute zero: + Units. + 239.25 lb. Ũ 530° abs. Ũ 0.238 ...................... = 30,053 + 194.46 lb. Ũ 17-1/8 Ũ 530° Ũ 0.238, + the weight and heat of air....................... 420,660 + 194.46 Ũ 14,544 units heat of combustion of carbon... 2,828,200 + --------- + Total energy 3,278,813 + Heat absorbed in evaporating 26.08 lb. of water + in fuel............................................ -29,888 + --------- + Available energy.......................... 3,248,425 + + Temperature of furnace-- + + The whole of the fuel was heated up, but the heat absorbed in the + evaporation of the water lowered the temperature of the furnace, + and must be deducted from the heat of combustion. + + Units. + Heat of combustion................................... 2,828,200 + " " evaporation of 26.08 lb. water............... -29,888 + --------- + Available heat of combustion.............. 2,798,312 + + Dividing by 238.25 lb. gives the heat per 1 lb. + of fuel used................................... = 11,745 units. + And temperature of furnace: + 11,745 units/(18.125 lb. Ũ 0.238) + 530°......... = 3,253° + Temperature of chimney 700° + 460°............... = 1,160° + Maximum duty (3,253° - 1,160°)/3,253°............ = 0.643° + + Work of displacing atmosphere by smoke at 700°: + Cubic feet. + Volumes of gases at 70°........................ = 228.3 + " " " " 700°........................ = 499.8 + ----- + Increase of volume.................... 271.5 + + Units. + Work done= + (194.46 lb. Ũ 271.5 cub. ft. Ũ 144 sq. in. Ũ 15 lb.) + /722 units ..................................... = 147,720 + Maximum amount of work to be expected = + 3,248,425 Ũ 0.643.............................. = 2,101,700 + Deduct work of displacing atmosphere............. = 147,720 + --------- + Available work........................ 1,953,980 + + Actual work done: + Units. + 1,620 lb. of water raised from 60° and turned + into steam at 53 lb..... ...................... = 1,855,900 + Loss by radiation and convection................. 70,430 + 10-1/2 lb. ashes left, say at 500°............... 1,129 + --------- + Total work actually done.............. 1,927,459 + Unaccounted for.................................. 26,521 + --------- + Calculated available work........................ 1,953,980 + + The unaccounted-for work, therefore, amounts to only 1― per cent. + of the calculated available work. + + Sir Frederick Bramwell ingeniously arranged his data in the form + of a balance sheet, and showed 253,979 units unaccounted for; but + if from this we deduct the work lost in displacing the air, the + unaccounted-for heat falls to less than 4 per cent. of the total + heat of combustion. These results show how extremely accurate the + observations must have been, and that the loss mainly arises from + convection and radiation from the boiler.] + +The data necessary for our purpose are: + +Steam pressure 80 lb. temperature 324° = 784° absolute. +Mean temperature of smoke 389° = 849° " +Water evaporated per 1 lb of coal, from and at 212° 11.83 lb. +Temperature of the air 60° = 520° absolute. + " of feed water 209° = 669° " +Heating surface 220 square feet. +Grate surface 3.29 feet. +Coal burnt per hour 41 lb. + +The fuel used was a smokeless Welsh coal, from the Llangennech +colleries. It was analyzed by Mr. Snelus, of the Dowlais Ironworks, +and in Table II. are exhibited the details of its composition, and the +weight and volume of air required for its combustion. The total heat +of combustion in 1 lb of water evaporated: + + = 15.06 Ũ (0.8497 + 4.265 Ũ (0.426 - 0.035/8)) + = 15.24 lb. of water from and at 212° + = 14,727 units of heat. + + TABLE II.--PROPERTIES OF LLANGENNECH COAL. + + ---------------------+----------+------------+---------------------+ + | | | | + | | | Products of | + | | Oxygen | Combustion at 32° F.| + | Analyses | required +--------+------------+ + | of 1 lb. | for | | | + | of Coal. | Combustion.| Cubic | Volume | + | | Pounds. | feet. | per cent. | + ---------------------+----------+------------+--------+------------+ + Carbon........... | 0.8497 | 2.266 | 25.3 | 11.1 | + Hydrogen......... | 0.0426 | 0.309 | 7.6 | 3.4 | + Oxygen........... | 0.0350 | --- | --- | --- | + Sulphur.......... | 0.0042 | --- | --- | _ --- | + Nitrogen......... | 0.1045 | --- | 0.18 | | | + Ash.............. | 0.0540 | --- | --- | | | + +----------+------------+ | | 85.5 | + | | | | | | + Total........... | 1.0000 | 2.572 | --- | | | + 9-1/3.lb nitrogen | --- | --- | 118.9 | | | + 6 lb. excess of air. | --- | --- | 71.4 | _| | + +----------+------------+--------+------------+ + Total cubic feet of | | | | | + products per 1 lb. | | | | | + of coal........... | -- | -- | 226.4 | 100.0 | + ---------------------+----------+------------+--------+------------+ + +The temperature of the furnace not having been determined, we must +calculate it on the supposition, which will be justified later on, +that 50 per cent more air was admitted than was theoretically +necessary to supply the oxygen required for perfect combustion. This +would make 18 lb. of air per 1 lb. of coal; consequently 19 lb. of +gases would be heated by 14,727 units of heat. Hence: + + 14,727 u. + T = ---------------- = 3,257° + 19 lb. Ũ 0.238 + +above the temperatures of the air, or 3,777° absolute. The temperature +of the smoke, _t_, was 849° absolute; hence the maximum duty would be + + 3,777° - 849° + --------------- = 0.7752. + 3,777° + +The specific heat of coal is very nearly that of gases at constant +pressure, and may, without sensible error, be taken as such. The +potential energy of 1 lb. of coal, therefore, with reference to the +oxygen with which it will combine, and calculated from absolute zero, +is: + + Units. +19 lb. of coal and air at the temperature + of the air contained 19 lb. Ũ 520° Ũ 0.238 2,350 +Heat of combustion 14,727 + ------- + 17,078 +Deduct heat expended in displacing atmosphere 151 cubic feet - 422 + ------ + Total potential energy 16,656 + +Hence work to be expected from the boiler: + + / 3,777° - 849° \ + = 17,078 units X ( --------------- ) - 422 units + \ 3,777° / + ---------------------------------------------- = 13.27 lb. + 966 units + +of water evaporated from and at 212°, corresponding to 12,819 units. +The actual result obtained was 11.83 lb.; hence the efficiency of this +boiler was + + 11.83 + ------- = 0.892. + 13.27 + +I have already claimed for a boiler that it is a veritable heat +engine, and I have ventured to construct an indicator diagram to +illustrate its working. The rate of transfer of heat from the furnace +to the water in the boiler, at any given point, is some way +proportional to the difference of temperature, and the quantity of +heat in the gases is proportional to their temperatures. Draw a base +line representing -460° Fahr., the absolute zero of temperature. At +one end erect an ordinate, upon which set off T = 3,777°, the +temperature of the furnace. At 849° = _t_, on the scale of +temperature, draw a line parallel to the base, and mark on it a length +proportional to the heating surface of the boiler; join T by a +diagonal with the extremity of this line, and drop a perpendicular on +to the zero line. The temperature of the water in the boiler being +uniform, the ordinates bounded by the sloping line, and by the line, +_t_, will at any point be approximately proportional to the rate of +transmission of heat, and the shaded area above _t_ will be +proportional to the quantity of heat imparted to the water. Join T by +another diagonal with extremity of the heating surface on the zero +line, then the larger triangle, standing on the zero line, will +represent the whole of the heat of combustion, and the ratio of the +two triangles will be as the lengths of their respective bases, that +is, as (T - _t_) / T, which is the expression we have already used. The +heating surface was 220 square feet, and it was competent to transmit +the energy developed by 41 lb. of coal consumed per hour = 12,819 u. Ũ +41 u. = 525,572 units, equal to an average of 2,389 units per square +foot per hour; this value will correspond to the mean pressure in an +ordinary diagram, for it is a measure of the energy with which +molecular motion is transferred from the heated gases to the +boiler-plate, and so to the water. The mean rate of transmission, +multiplied by the area of heating surface, gives the area of the +shaded portion of the figure, which is the total work which should +have been done, that is to say, the work of evaporating 544 lb. of +water per hour. The actual work done, however, was only 485 lb. To +give the speculations we have indulged in a practical turn, it will be +necessary to examine in detail the terms of Carnot's formula. Carnot +labored under great disadvantages. He adhered to the emission theory +of heat; he was unacquainted with its dynamic equivalent; he did not +know the reason of the difference between the specific heat of air at +constant pressure and at constant volume, the idea of an absolute zero +of temperature had not been broached; but the genius of the man, while +it made him lament the want of knowledge which he felt must be +attainable, also enabled him to penetrate the gloom by which he was +surrounded, and enunciate propositions respecting the theory of heat +engines, which the knowledge we now possess enables us to admit as +true. His propositions are: + +1. The motive power of heat is independent of the agents employed to +develop it, and its quantity is determined solely by the temperature +of the bodies between which the final transfer of caloric takes place. + +2. The temperature of the agent must in the first instance be raised +to the highest degree possible in order to obtain a great fall of +caloric, and as a consequence a large production of motive power. + +3. For the same reason the cooling of the agent must be carried to as +low a degree as possible. + +4. Matters must be so arranged that the passage of the elastic agent +from the higher to the lower temperature must be due to an increase of +volume, that is to say, the cooling of the agent must be caused by its +rarefaction. + +This last proposition indicates the defective information which Carnot +possessed. He knew that expansion of the elastic agent was accompanied +by a fall of temperature, but he did not know that that fall was due +to the conversion of heat into work. We should state this clause more +correctly by saying that "the cooling of the agent must be caused by +the external work it performs." In accordance with these propositions, +it is immaterial what the heated gases or vapors in the furnace of a +boiler may be, provided that they cool by doing external work and, in +passing over the boiler surfaces, impart their heat energy to the +water. The temperature of the furnace, it follows, must be kept as +high as possible. The process of combustion is usually complex. First, +in the case of coal, close to the fire-bars complete combustion of the +red hot carbon takes place, and the heat so developed distills the +volatile hydrocarbons and moisture in the upper layers of the fuel. +The inflammable gases ignite on or near the surface of the fuel, if +there be a sufficient supply of air, and burn with a bright flame for +a considerable distance around the boiler. If the layer of fuel be +thin, the carbonic acid formed in the first instance passes through +the fuel and mixes with the other gases. If, however, the layer of +fuel be thick, and the supply of air through the bars insufficient, +the carbonic acid is decomposed by the red hot coke, and twice the +volume of carbonic oxide is produced, and this, making its way through +the fuel, burns with a pale blue flame on the surface, the result, as +far as evolution of heat is concerned, being the same as if the +intermediate decomposition of carbonic acid had not taken place. This +property of coal has been taken advantage of by the late Sir W. +Siemens in his gas producer, where the supply of air is purposely +limited, in order that neither the hydrocarbons separated by +distillation, nor the carbonic oxide formed in the thick layer of +fuel, may be consumed in the producer, but remain in the form of crude +gas, to be utilized in his regenerative furnaces. + +[Illustration: THE GENERATION OF STEAM. Fig 3.] + +[Illustration: THE GENERATION OF STEAM. Fig 4.] + +[Illustration: THE GENERATION OF STEAM. Fig 5.] + +[Illustration: THE GENERATION OF STEAM. Fig 6.] + +[Illustration: THE GENERATION OF STEAM. Fig 7.] + +_(To be continued.)_ + + * * * * * + +[Continued from SUPPLEMENT No. 437, page 6970.] + + + + +PLANETARY WHEEL-TRAINS. + +By Prof. C.W. MACCORD, Sc.D. + + +II. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 14] + +It has already been shown that the rotations of all the wheels of a +planetary train, relatively to the train-arm, are the same when the +arm is in motion as they would be if it were fixed. Now, in Fig. 14, +let A be the first and F the last wheel of an _incomplete_ train, that +is, one having but one sun-wheel. As before, let these be so connected +by intermediate gearing that, when T is stationary, a rotation of A +through _m_ degrees shall drive F through _n_ degrees: and also as +before, let T in the same time move through _a_ degrees. Then, if _m'_ +represent the total motion of A, we have again, + + m' = m + a, or m = m' - a. + +This is, clearly, the motion of A relatively to the fixed frame of the +machine; and is measured from a fixed vertical line through the +center of A. Now, if we wish to express the total motion of F +relatively to the same fixed frame, we must measure it from a vertical +line through the center of F, wherever that maybe; which gives in this +case: + + n' = n + a, or n = n' - a. + +but with respect to the train-arm when at rest, we have: + + ang. vel. A n + ------------ = ---, whence again + ang. vel. F m + + n' - a n + ------ = --- . + m' - a m + +This is the manner in which the equation is deduced by Prof. Willis, +who expressly states that it applies whether the last wheel F is or is +not concentric with the first wheel A, and also that the train may be +composed of any combinations which transmit rotation with both a +constant velocity ratio and a constant directional relation. He +designates the quantities _m'_, _n'_, _absolute revolutions_, as +distinguished from the _relative revolutions_ (that is, revolutions +relatively to the train-arm), indicated by the quantities _m_, _n_: +adding, "Hence it appears that the absolute revolutions of the wheels +of epicyclic trains are equal to the sum of their relative revolutions +to the arm, and of the arm itself, when they take place in the same +direction, and equal to the difference of these revolutions when in +the opposite direction." + +In this deduction of the formula, as in that of Prof. Rankine, all the +motions are supposed to have the same direction, corresponding to that +of the hands of the clock; and in its application to any given train, +the signs of the terms must be changed in case of any contrary motion, +as explained in the preceding article. + +And both the deduction and the application, in reference to these +incomplete trains in which the last wheel is carried by the +train-arm, clearly involve and depend upon the resolving of a motion +of revolution into the components of a circular translation and a +rotation, in the manner previously discussed. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 15] + +To illustrate: Take the simple case of two equal wheels, Fig. 15, of +which the central one A is fixed. Supposing first A for the moment +released and the arm to be fixed, we see that the two wheels will turn +in opposite directions with equal velocities, which gives _n_/_m_ = -1; +but when A is fixed and T revolves, we have _m'_ = 0, whence in the +general formula + + n' - a + ------ = -1, or n' = 2 a; + -a + +which means, being interpreted, that F makes two rotations about its +axis during one revolution of T, and in the same direction. Again, let +A and F be equal in the 3-wheel train, Fig. 16, the former being fixed +as before. In this case we have: + + n + --- = 1, m' = 0, which gives + m + + n' - a + ------- = 1, [therefore] n' = 0; + -a + +that is to say, the wheel F, which now evidently has a motion of +circular translation, does not rotate at all about its axis during the +revolution of the train-arm. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 16] + +All this is perfectly consistent, clearly, with the hypothesis that +the motion of circular translation is a simple one, and the motion of +revolution about a fixed axis is a compound one. + +Whether the hypothesis was made to substantiate the formula, or the +formula constructed to suit the hypothesis, is not a matter of +consequence. In either case, no difficulty will arise so long as the +equation is applied only to cases in which, as in those here +mentioned, that motion of revolution _can_ be resolved into those +components. + +When the definition of an epicyclic train is restricted as it is by +Prof. Rankine, the consideration of the hypothesis in question is +entirely eliminated, and whether it be accepted or rejected, the whole +matter is reduced to merely adding the motion of the train-arm to the +rotation of each sun-wheel. + +But in attempting to apply this formula in analyzing the action of an +incomplete train, we are required to add this motion of the train-arm, +not only to that of a sun-wheel, but to that of a planet-wheel. This +is evidently possible in the examples shown in Figs. 15 and 16, +because the motions to be added are in all respects similar: the +trains are composed of spur-wheels, and the motions, whether of +revolution, translation, or rotation, _take place in parallel planes +perpendicular to parallel axes_. This condition, which we have +emphasized, be it observed, must hold true with regard to the motions +of the first and last wheels and the train-arm, in order to make this +addition possible. It is not essential that spur-wheels should be used +exclusively or even at all; for instance, in Fig. 16, A and F may be +made bevel or screw-wheels, without affecting the action or the +analysis; but the train-arm in all cases revolves around the central +axis of the system, that is, about the axis of A, and to this the axis +of F _must_ be parallel, in order to render the deduction of the +formula, as made by Prof. Willis, and also by Prof. Goodeve, correct, +or even possible. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 17] + +This will be seen by an examination of Fig. 17; in which A and B are +two equal spur-wheels, E and F two equal bevel wheels, B and E being +secured to the same shaft, and A being fixed to the frame H. As the +arm T goes round, B will also turn in its bearings in the same +direction: let this direction be that of the clock, when the apparatus +is viewed from above, then the motion of F will also have the same +direction, when viewed from the central vertical axis, as shown at F': +and let these directions be considered as positive. It is perfectly +clear that F will turn in its bearings, in the direction indicated, at +a rate precisely equal to that of the train-arm. Let P be a pointer +carried by F, and R a dial fixed to T; and let the pointer be vertical +when OO is the plane containing the axes of A, B, and E. Then, when F +has gone through any angle a measured from OO, the pointer will have +turned from its original vertical position through an equal angle, as +shown also at F'. + +Now, there is no conceivable sense in which the motion of T can be +said to be added to the rotation of F about its axis, and the +expression "absolute revolution," as applied to the motion of the last +wheel in this train, is absolutely meaningless. + +Nevertheless, Prof. Goodeve states (Elements of Mechanism, p. 165) +that "We may of course apply the general formula in the case of bevel +wheels just as in that of spur wheels." Let us try the experiment; +when the train-arm is stationary, and A released and turned to the +right, F turns to the left at the same rate, whence: + + n + --- = -1; also m' = 0 when A is fixed, + m + +and the equation becomes + + n' - a + ------ = -1, [therefore] n' = 2a: + - a + +or in other words F turns _twice_ on its axis during one revolution of +T: a result too palpably absurd to require any comment. We have seen +that this identical result was obtained in the case of Fig. 15, and it +would, of course, be the same were the formula applied to Figs. 5 and +6; whereas it has never, so far as we are aware, been pretended that a +miter or a bevel wheel will make more than one rotation about its axis +in rolling once around an equal fixed one. + +Again, if the formula be general, it should apply equally well to a +train of screw wheels: let us take, for example, the single pair shown +in Fig. 8, of which, when T is fixed, the velocity ratio is unity. The +directional relation, however, depends upon the direction in which the +wheels are twisted: so that in applying the formula, we shall have +_n/m_ = +1, if the helices of both wheels are right handed, and +_n_/_m_ = -1, if they are both left handed. Thus the formula leads to +the surprising conclusion, that when A is fixed and T revolves, the +planet-wheel B will revolve about its axis twice as fast as T moves, +in one case, while in the other it will not revolve at all. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 18] + +A favorite illustration of the peculiarities of epicyclic mechanism, +introduced both by Prof. Willis and Prof. Goodeve, is found in the +contrivance known as Ferguson's Mechanical Paradox, shown in Fig. 18. +This consists of a fixed sun-wheel A, engaging with a planet-wheel B +of the same diameter. Upon the shaft of B are secured the three thin +wheels E, G, I, each having 20 teeth, and in gear with the three +others F, H, K, which turn freely upon a stud fixed in the train-arm, +and have respectively 19, 20, and 21 teeth. In applying the general +formula, we have the following results: + + n 20 n' - a 1 + For the wheel F, --- = ---- = ---------, [therefore] n' = - ---- a. + m 19 -a 19 + + n n' - a + " " " H, --- = 1 = --------, [therefore] n' = 0. + m -a + + n 20 n' - a 1 + " " " K, --- = ---- = ---------, [therefore] n' = + ---- a. + m 21 -a 21 + +The paradoxical appearance, then, consists in this, that although the +drivers of the three last wheels each have the same number of teeth, +yet the central one, H, having a motion of circular translation, +remains always parallel to itself, and relatively to it the upper one +seems to turn in the same direction as the train-arm, and the lower in +the contrary direction. And the appearance is accepted, too, as a +reality; being explained, agreeably to the analysis just given, by +saying that H has no absolute rotation about its axis, while the other +wheels have; that of F being positive and that of K negative. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 18] + +The Mechanical Paradox, it is clear, may be regarded as composed of +three separate trains, each of which is precisely like that of Fig. +16: and that, again, differs from the one of Fig. 15 only in the +addition of a third wheel. Now, we submit that the train shown in Fig. +17 is mechanically equivalent to that of Fig. 15; the velocity ratio +and the directional relation being the same in both. And if in Fig. 17 +we remove the index P, and fix upon its shaft three wheels like E, G, +and I of Fig. 18, we shall have a combination mechanically equivalent +to Ferguson's Paradox, the three last wheels rotating in vertical +planes about horizontal axes. The relative motions of those three +wheels will be the same, obviously, as in Fig. 18; and according to +the formula their absolute motions are the same, and we are invited to +perceive that the central one does not rotate at all about its axis. + +But it _does_ rotate, nevertheless; and this unquestioned fact is of +itself enough to show that there is something wrong with the formula +as applied to trains like those in question. What that something is, +we think, has been made clear by what precedes; since it is impossible +in any sense to add together motions which are unlike, it will be seen +that in order to obtain an intelligible result in cases like these, +the equation must be of the form _n'_/(_m'_ - _a_) = _n_/_m_. We shall +then have: + + n 20 n' 20 + For the wheel F, --- = ---- = ----, [therefore] n' = - ---- a; + m 19 -a 19 + + n n' + For the wheel H, --- = 1 = ----, [therefore] n' = -a; + m -a + + n 20 n' 20 + For the wheel K, --- = ---- = ----, [therefore] n' = - ---- a, + m 21 -a 21 + +which corresponds with the actual state of things; all three wheels +rotate in the same direction, the central one at the same rate as the +train arm, one a little more rapidly and the third a little more +slowly. + +It is, then, absolutely necessary to make this modification in the +general formula, in order to apply it in determining the rotations of +any wheel of an epicyclic train whose axis is not parallel to that of +the sun-wheels. And in this modified form it applies equally well to +the original arrangement of Ferguson's paradox, if we abandon the +artificial distinction between "absolute" and "relative" rotations of +the planet-wheels, and regard a spur-wheel, like any other, as +rotating on its axis when it turns in its bearings; the action of the +device shown in Fig. 18 being thus explained by saying that the wheel +H turns once backward during each forward revolution of the train-arm, +while F turns a little more and K a little less than once, in the same +direction. In this way the classification and analysis of these +combinations are made more simple and consistent, and the +incongruities above pointed out are avoided; since, without regard to +the kind of gearing employed or the relative positions of the axes, we +have the two equations: + + n' - a n + I. -------- = ---, for all complete trains; + m' - a m + + n' n + II. -------- = ---, for all incomplete trains. + m' - a m + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 19] + +As another example of the difference in the application of these +formulæ, let us take Watt's sun and planet wheels, Fig. 19. This +device, as is well known, was employed by the illustrious inventor as +a substitute for the crank, which some one had succeeded in patenting. +It consists merely of two wheels A and F connected by the link T; A +being keyed on the shaft of the engine and F being rigidly secured to +the connecting-rod. Suppose the rod to be of infinite length, so as to +remain always parallel to itself, and the two wheels to be of equal +size. + +Then, according to Prof. Willis' analysis, we shall have-- + + n' - a n -s + -------- = --- = -1, n' = 0, [therefore] -------- = -1, whence + m' - a m m' - a + + -a = a - m', or m = 2a. + +The other view of the question is, that F turns once backward in its +bearings during each forward revolution of T; whence in Eq. 2 we +have-- + + n' n + -------- = --- = -1, n' = -a, + m' - a m + + -a + [therefore] -------- -1, which gives -a = a - m', or m' = 2a, + m' - a + +as before. + +It is next to be remarked, that the errors which arise from applying +Eq. I. to incomplete trains may in some cases counterbalance and +neutralize each other, so that the final result is correct. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 20] + +For example, take the combination shown in Fig. 20. This consists of a +train-arm T revolving about the vertical axis OO of the fixed wheel A, +which is equal in diameter to F, which receives its motion by the +intervention of one idle wheel carried by a stud S fixed in the arm. +The second train-arm T' is fixed to the shaft of F and turns with it; +A' is secured to the arm T, and F' is actuated by A' also through a +single idler carried by T'. + +We have here a compound train, consisting of two simple planetary +trains, A--F and A'--F'; and its action is to be determined by +considering them separately. First suppose T' to be removed and find +the motion of F; next suppose F to be removed and T fixed, and find +the rotation of F'; and finally combine these results, noting that the +motion of T' is the same as that of F, and the motion of A' the same +as that of T. + +Then, according to the analysis of Prof. Willis, we shall have +(substituting the symbol _t_ for _a_ in the equation of the second +train, in order to avoid confusion): + + n n' - a + 1. Train A--F. --- = 1 = --------; m' = 0, + m m' - a + + n' - a + whence -------- = 1, n' = 0, = rot. of F. + a + + n n' - t + 2. Train A'--F'. --- = 1 = --------; m' = 0, + m m' - t + + n' - t + whence again -------- = 1, t = 0, = rot. of F'. + -t + +Of these results, the first is explicable as being the _absolute_ +rotation of F, but the second is not; and it will be readily seen that +the former would have been equally absurd, had the axis LL been +inclined instead of vertical. But in either case we should find the +errors neutralized upon combining the two, for according to the theory +now under consideration, the wheel A', being fixed to T, turns once +upon its axis each time that train arm revolves, and in the same +direction; and the revolutions of T' equal the rotations of F, whence +finally in train A'--F' we have: + + n n' - t + 3. --- = 1 = --------; in which t = 0, m' = a, + m m' - t + + n' - 0 +which gives --------- = 1, or n' = a. + a - 0 + +This is, unquestionably, correct; and indeed it is quite obvious that +the effect upon F' is the same, whether we say that during a +revolution of T the wheel A' turns once forward and T' not at all, or +adopt the other view and assert that T' turns once backward and A' not +at all. But the latter view has the advantage of giving concordant +results when the trains are considered separately, and that without +regard to the relative positions of the axes or the kind of gearing +employed. Analyzing the action upon this hypothesis, we have: + + In train A--F: + + n n' n' + --- = 1 = --------; m' = 0, [therefore] ---- = 1, or n' = -a; + m m' - a -a + + In train A'--F': + + n' n' n' + --- = 1 = --------; m' = 0, [therefore] ---- = 1, or n' = -t; + m m' - t -t + +In combining, we have in the latter train m' = 0, t = -a, whence + + n n' n' + --- = 1 = -------- gives ---- = 1, or n' = a, as before. + m m' - t +a + +Now it happens that the only examples given by Prof. Willis of +incomplete trains in which the axis of a planet-wheel whose motion is +to be determined is not parallel to the central axis of the system, +are similar to the one just discussed; the wheel in question being +carried by a secondary train-arm which derives its motion from a wheel +of the primary train. + +The application of his general equation in these cases gives results +which agree with observed facts; and it would seem that this +circumstance, in connection doubtless with the complexity of these +compound trains, led him to the too hasty conclusion that the formula +would hold true in all cases; although we are still left to wonder at +his overlooking the fact that in these very cases the "absolute" and +the "relative" rotations of the last wheel are identical. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 21] + +In Fig. 21 is shown a combination consisting also of two distinct +trains, in which, however, there is but one train-arm T turning freely +upon the horizontal shaft OO, to which shaft the wheels A', F, are +secured; the train-arm has two studs, upon which turn the idlers B B', +and also carries the bearings of the last wheel F'; the first wheel A +is annular, and fixed to the frame of the machine. Let it be required +to determine the results of one revolution of the crank H, the numbers +of teeth being assigned as follows: + + A = 60, F = 30, A' = 60, F' = 10. + +We shall then have, for the train ABF (Eq. I.), + + n 60 n' - a + --- = - ---- = -2 = --------, in which n' = 1, m' = 0, + m 30 m' - a' + + 1 - a 1 +whence -2 = -------, 2a = 1 - a, 3a = 1, a = ---. + -a 3 + +And for the train A'B'F' (Eq. II.), + + n 60 n' 1 + --- = ---- = 6 = --------, in which a = ---, m' = 1, + m 10 m' - a' 3 + + n' +whence 6 = -----------, or n' = 4. + 1 - (1/3) + +That is, the last wheel F' turns _four_ times about the axis LL during +one revolution of the crank H. But according to Profs. Willis and +Goodeve, we should have for the second train: + + n 60 n' - a 1 + --- = ---- = 6 = --------, in which a = ---, m' = 1, + m 10 m' - a' 3 + + n' - (1/3) +which gives 6 = -----------, n' - (1/3) = 4, n' = 4-1/3, + 1 - (1/3) + +or _four and one-third_ revolutions of F' for one of H. + +This result, no doubt, might be near enough to the truth to serve all +practical purposes in the application of this mechanism to its +original object, which was that of paring apples, impaled upon the +fork K; but it can hardly be regarded as entirely satisfactory in a +general way; nor can the analysis which renders such a result +possible. + + * * * * * + + + + +THE PANTANEMONE. + + +The need of irrigating prairies, inundating vines, drying marshes, and +accumulating electricity cheaply has, for some time past, led to a +search for some means of utilizing the forces of nature better than +has ever hitherto been done. Wind, which figures in the first rank as +a force, has thus far, with all the mills known to us, rendered +services that are much inferior to those that we have a right to +expect from it with improved apparatus; for the work produced, +whatever the velocity of the wind, has never been greater than that +that could be effected by wind of seven meters per second. But, thanks +to the experiments of recent years, we are now obtaining an effective +performance double that which we did with apparatus on the old system. + +Desirous of making known the efforts that have been made in this +direction, we lately described Mr. Dumont's atmospheric turbine. In +speaking of this apparatus we stated that aerial motors generally stop +or are destroyed in high winds. Recently, Mr. Sanderson has +communicated to us the result of some experiments that he has been +making for years back by means of an apparatus which he styles a +pantanemone. + +The engraving that we give of this machine shows merely a cabinet +model of it; and it goes without saying that it is simply designed to +exhibit the principle upon which its construction is based. + +[Illustration: THE PANTANEMONE.] + +Two plane surfaces in the form of semicircles are mounted at right +angles to each other upon a horizontal shaft, and at an angle of 45° +with respect to the latter. It results from this that the apparatus +will operate (even without being set) whatever be the direction of the +wind, except when it blows perpendicularly upon the axle, thus +permitting (owing to the impossibility of reducing the surfaces) of +three-score days more work per year being obtained than can be with +other mills. Three distinct apparatus have been successively +constructed. The first of these has been running for nine years in the +vicinity of Poissy, where it lifts about 40,000 liters of water to a +height of 20 meters every 24 hours, in a wind of a velocity of from 7 +to 8 meters per second. The second raises about 150,000 liters of +water to the Villejuif reservoir, at a height of 10 meters, every 24 +hours, in a wind of from 5 to 6 meters. The third supplies the +laboratory of the Montsouris observatory. + +The first is not directible, the second may be directed by hand, and +the third is directed automatically. These three machines defied the +hurricane of the 26th of last January.--_La Nature._ + + * * * * * + + + + +RELVAS'S NEW LIFE-BOAT. + + +The Spanish and Portuguese papers have recently made known some +interesting experiments that have been made by Mr. Carlos Relvas with +a new life-boat which parts the waves with great facility and exhibits +remarkable stability. This boat, which is shown in front view in one +of the corners of our engraving, is T-shaped, and consists of a very +thin keel connected with the side-timbers by iron rods. Cushions of +cork and canvas are adapted to the upper part, and, when the boat is +on the sea, it has the appearance of an ordinary canoe, although, as +may be seen, it differs essentially therefrom in the submerged part. +When the sea is heavy, says Mr. Relvas, and the high waves are +tumbling over each other, they pass over my boat, and are powerless to +capsize it. My boat clears waves that others are obliged to recoil +before. It has the advantage of being able to move forward, whatever +be the fury of the sea, and is capable, besides, of approaching rocks +without any danger of its being broken. + +[Illustration: RELVAS'S NEW LIFE BOAT.] +A committee was appointed by the Portuguese government to examine this +new life-boat, and comparative experiments were made with it and an +ordinary life-boat at Porto on a very rough sea. Mr. Relvas's boat was +manned by eight rowers all provided with cork girdles, while the +government life-boat was manned by twelve rowers and a pilot, all +likewise wearing cork girdles. The chief of the maritime department, +an engineer of the Portuguese navy and a Portuguese deputy were +present at the trial in a pilot boat. The three boats proceeded to the +entrance of the bar, where the sea was roughest, and numerous +spectators collected upon the shore and wharfs followed their +evolutions from afar. + +The experiments began at half past three o'clock in the afternoon. The +two life-boats shot forward to seek the most furious waves, and were +seen from afar to surmount the billows and then suddenly disappear. It +was a spectacle as moving as it was curious. It was observed that Mr. +Relvas's boat cleft the waves, while the other floated upon their +surface like a nut-shell. After an hour's navigation the two boats +returned to their starting point. + +The official committee that presided over these experiments has again +found in this new boat decided advantages, and has pointed out to its +inventor a few slight modifications that will render it still more +efficient.--_La Nature._ + + * * * * * + + + + +EXPERIMENTS WITH DOUBLE-BARRELED GUNS AND RIFLES. + + +The series of experiments we are about to describe has recently been +made by Mr. Horatio Phillips, a practical gun maker of London. The +results will no doubt prove of interest to those concerned in the use +or manufacture of firearms. + +The reason that the two barrels of a shot gun or rifle will, if put +together parallel, throw their charges in diverging lines has never +yet been satisfactorily accounted for, although many plausible and +ingenious theories have been advanced for the purpose. The natural +supposition would be that this divergence resulted from the axes of +the barrels not being in the same vertical plane as the center line of +the stock. That this is not the true explanation of the fact, the +following experiment would tend to prove. + +[Illustration: EXPERIMENTS WITH DOUBLE-BARRELLED GUNS.] + +Fig. 1 represents a single barrel fitted with sights and firmly +attached to a heavy block of beech. This was placed on an ordinary +rifle rest, being fastened thereto by a pin at the corner, A, the +block and barrel being free to revolve upon the pin as a center. +Several shots were fired both with the pin in position and with it +removed, the barrel being carefully pointed at the target each time. +No practical difference in the accuracy of fire was discernible under +either condition. When the pin was holding the corner of the block, +the recoil caused the barrel to move from right to left in a circular +path; but when the pin was removed, so that the block was not attached +to the rest in any way, the recoil took place in a line with the axis +of the bore. It will be observed that the conditions which are present +when a double barreled gun is fired in the ordinary way from the +shoulder were in some respects much exaggerated in the apparatus, for +the pin was a distance of 3 in. laterally from the axis of the barrel, +whereas the center of resistance of the stock of a gun against the +shoulder would ordinarily be about one-sixth of this distance from the +axis of the barrel. This experiment would apparently tend to prove +that the recoil does not appreciably affect the path of the +projectile, as it would seem that the latter must clear the muzzle +before any considerable movement of the barrel takes place. + +With a view to obtain a further confirmation of the result of this +experiment, it was repeated in a different form by a number of shots +being fired from a "cross-eyed" rifle,[1] in which the sights were +fixed in the center of the rib. Very accurate shooting was obtained +with this arm. + + [Footnote 1: A cross-eyed rifle is one made with a crooked stock + for the purpose of shooting from the right shoulder, aim being + taken with the left eye.] + +A second theory, often broached, in order to account for the +divergence of the charge, is that the barrel which is not being fired, +by its _vis inertia_ in some way causes the shot to diverge. In order +to test this, Mr. Phillips took a single rifle and secured it near the +muzzle to a heavy block of metal, when the accuracy of the shooting +was in no way impaired. + +So far the experiments were of a negative character, and the next step +was made with a view to discover the actual cause of the divergence +referred to. A single barrel was now taken, to which a template was +fitted, in order to record its exact length. The barrel was then +subjected to a heavy internal hydrostatic pressure. Under this +treatment it expanded circumferentially and at the same time was +reduced in length. This, it was considered, gave a clew to the +solution of the problem. A pair of barrels was now taken and a +template fitted accurately to the side of the right-hand one. As the +template fitted the barrel when the latter was not subject to internal +pressure, upon such pressure being applied any alterations that might +ensue in the length or contour of the barrel could be duly noted. The +right-hand barrel was then subjected to internal hydrostatic pressure. +The result is shown in an exaggerated form in Fig. 2. It will be seen +that both barrels are bent into an arched form. This would be caused +by the barrel under pressure becoming extended circumferentially, and +thereby reduced in length, because the metal that is required to +supply the increased circumference is taken to some extent from the +length, although the substance of metal in the walls of the barrel by +its expansion contributes also to the increased diameter. A simple +illustration of this effect is supplied by subjecting an India-rubber +tube to internal pressure. Supposing the material to be sufficiently +elastic and the pressure strong enough, the tube would ultimately +assume a spherical form. It is a well known fact that heavy barrels +with light charges give less divergence than light barrels with heavy +charges. + +After the above experiments it was hoped that, if a pair of barrels +were put together parallel and soldered only for a space of 3 in. at +the breech end, and were then coupled by two encircling rings joined +together as in Fig. 4, the left-hand ring only being soldered to the +barrel, very accurate shooting would be obtained. For, it was argued, +that by these means the barrel under fire would be able to contract +without affecting or being affected by the other barrel; that on the +right-hand, it will be seen by the illustration, was the one to slide +in its ring. + +A pair of able 0.500 bore express rifle barrels were accordingly +fitted in this way. Fig. 3 shows the arrangement with the rings in +position. Upon firing these barrels with ordinary express charges it +was found that the lines of fire from each barrel respectively crossed +each other, the bullet from the right-hand barrel striking the target +10 in. to the left of the bull's eye, while the left barrel placed its +projectile a similar distance in the opposite direction; or, as would +be technically said, the barrels crossed 20 in. at 100 yards, the +latter distance being the range at which the experiment was made. +These last results have been accounted for in the following manner: +The two barrels were rigidly joined for a space of 3 in., and for that +distance they would behave in a manner similar to that illustrated in +Fig. 2, and were they not coupled at the muzzles by the connecting +rings they would shoot very wide, the charges taking diverging +courses. When the connecting rings are fitted on, the barrel not being +fired will remain practically straight, and, as it is coupled to the +barrel being fired by the rings, the muzzle of the latter will be +restrained from pointing outward. + +The result will be as shown in an exaggerated manner by the dotted +lines on the right barrel in Fig. 3. + +It would appear from these experiments that when very accurate +shooting is required at long ranges with double-barreled rifles, they +should be mounted in a manner similar to that adopted in the +manufacture of the Nordenfelt machine gun, in which weapon the barrels +are fitted into a plate at the extreme breech end, the muzzles +projecting through holes bored to receive them in a metal plate. No +unequal expansion would then take place, and the barrels would be free +to become shorter independently of each other. We give the above +experiments on the authority of their author, who, we believe, has +taken great pains to render them as exhaustive as possible, so far as +they go.--_Engineering._ + + * * * * * + + + + +BALL TURNING MACHINE. + + +The distinguishing feature in the ball turning machine shown opposite +is that the tool is stationary, while the work revolves in two +directions simultaneously. In the case of an ordinary spherical +object, such as brass clack ball, the casting is made from a perfect +pattern having two small caps or shanks, in which the centers are also +marked to avoid centering by hand. It is fixed in the machine between +two centers carried on a face plate or chuck, with which they revolve. +One of these centers, when the machine is in motion, receives a +continuous rotary motion about its axis from a wormwheel, D. This is +driven by a worm, C, carried on a shaft at the back of the chuck, and +driven itself by a wormwheel, B, which gears with a screw which rides +loosely upon the mandrel, and is kept from rotating by a finger on the +headstock. This center, in its rotation, carries with it the ball, +which is thus slowly moved round an axis parallel to the face plate, +at the same time that it revolves about the axis of the mandrel, the +result being that the tool cuts upon the ball a scroll, of which each +convolution is approximately a circle, and lies in a plane parallel to +the line of centers. + +When the chuck is set for one size of ball, which may be done in a few +minutes, any quantity of that diameter may be turned without further +adjustment. A roughing cut for a 2 in. ball may be done in one minute, +and a finishing cut leaving the ball quite bright in the same time. +The two paps are cut off within one-sixteenth of an inch and then +broken off, and the ball finished in the usual way. On account of the +work being geometrically true, the finishing by the ferrule tool is +done in one quarter of the time usually required. + +[Illustration: IMPROVED BALL TURNING MACHINE.] + +The chuck may be applied to an ordinary lathe or may be combined with +a special machine tool, as show in our illustration. In the latter +case everything is arranged in the most handy way for rapid working, +and six brass balls of 2 in. in diameter can be turned and finished in +an hour. The machine is specially adapted for turning ball valves for +pumps, pulsometers, and the like, and in the larger sizes for turning +governor balls and spherical nuts for armor plates, and is +manufactured by Messrs. Wilkinson and Lister, of Bradford Road Iron +Works, Keighley.--_Engineering._ + + * * * * * + + + + +COOLING APPARATUS FOR INJECTION WATER. + + +It often happens in towns and where manufactories are crowded +together, that the supply of water for condensing purposes is very +small, and consequently that it attains an inconveniently high +temperature under unfavorable conditions of weather, resulting in the +deterioration of the vacuum and a consequent increase in the +consumption of fuel. To remedy or to diminish this difficulty, Messrs. +Boase and Miller, of London, have brought out the water cooler +illustrated above. This consists, says _Engineering_, of a revolving +basket of wire gauze surrounding an inner stationary vessel pierced +with numerous small holes, through which the heated water discharged +by the air pump finds its way into the basket, to be thrown out in the +form of fine spray to a distance of 20 ft. at each side. The drops are +received in the tank or pond, and in their rapid passage through the +air are sufficiently cooled to be again injected into the condenser. + +The illustration shows a cooler having a basket three feet in +diameter, revolving at 300 revolutions per minute, and discharging +into a tank 40 ft. square. It requires 3 to 4 indicated horse-power to +drive it, and will cool 300 gallons per minute. The following decrease +of temperature has been observed in actual practice: Water entering at +95 deg. fell 20 deg. in temperature; water entering at 100 deg. to 110 +deg. fell 25 deg.; and water entering at 110 deg. to 120 deg. fell 30 +deg. The machine with which these trials were made was so placed that +the top of the basket was four ft. from the surface of the water in +the pond. With a greater elevation, as shown in the engraving, better +results can be obtained. + +[Illustration: IMPROVED WATER COOLING APPARATUS.] + +The advantages claimed for the cooler are that by its means the +temperature of the injection water can be reduced, the cost and size +of cooling ponds can be diminished, and condensing engines can be +employed where hitherto they have not been possible. The apparatus has +been for two years in operation at several large factories, and there +is every reason to believe that its use will extend, as it supplies a +real want in a very simple and ingenious manner. Messrs. Duncan +Brothers, of Dundee and 32 Queen Victoria Street, E.C., are the +manufacturers. + + * * * * * + + + + +CORRUGATED DISK PULLEYS. + + +This is a pulley recently introduced by Messrs. J. and E. Hall, of +Dartford Eng. With the exception of the boss, which is cast, it is +composed entirely of steel or sheet iron. In place of the usual arms a +continuous web of corrugated sheet metal connects the boss to the rim; +this web is attached to the boss by means of Spence's metal. Inside +the rim, which is flanged inward, a double hoop iron ring is fixed for +strengthening purposes. The advantageous disposition of metal obtained +by means of the corrugated web enables the pulley to be made of a +given strength with less weight of material, and from this cause and +also on account of being accurately balanced these pulleys are well +adapted for high speeds. + +[Illustration] + + * * * * * + +[KANSAS CITY REVIEW.] + + + + +EARLY HISTORY OF THE TELEGRAPH. + + +Although the electric telegraph is, comparatively speaking, a recent +invention, yet methods of communication at a distance, by means of +signals, have probably existed in all ages and in all nations. There +is reason to believe that among the Greeks a system of telegraphy was +in use, as the burning of Troy was certainly known in Greece very soon +after it happened, and before any person had returned from Troy. +Polybius names the different instruments used by the ancients for +communicating information--"pyrsia," because the signals were always +made by means of fire lights. At first they communicated information +of events in an imperfect manner, but a new method was invented by +Cleoxenus, which was much improved by Polybius, as he himself informs +us, and which may be described as follows: + +Take the letters of the alphabet and arrange them on a board in five +columns, each column containing five letters; then the man who signals +would hold up with his left hand a number of torches which would +represent the number of the column from which the letter is to be +taken, and with his right hand a number of torches that will represent +the particular letter in that column that is to be taken. It is thus +easy to understand how the letters of a short sentence are +communicated from station to station as far as required. This is the +pyrsia or telegraph of Polybius. + +It seems that the Romans had a method of telegraphing in their walled +cities, either by a hollow formed in the masonry, or by a tube fixed +thereto so as to confine the sound, in order to convey information to +any part they liked. This method of communicating is in the present +age frequently employed in the well known speaking tubes. It does not +appear that the moderns had thought of such a thing as a telegraph +until 1661, when the Marquis of Worcester, in his "Century of +Inventions," affirmed that he had discovered a method by which a man +could hold discourse with his correspondent as far as they could +reach, by night as well as by day; he did not, however, describe this +invention. + +Dr. Hooke delivered a discourse before the Royal Society in 1684, +showing how to communicate at great distances. In this discourse he +asserts the possibility of conveying intelligence from one place to +another at a distance of 120 miles as rapidly as a man can write what +he would have sent. He takes to his aid the then recent invention of +the telescope, and explains how characters exposed at one station on +the top of one hill may be made visible to the next station on the top +of the next hill. He invented twenty-four simple characters, each +formed of a combination of three deal boards, each character +representing a letter by the use of cords; these characters were +pushed from behind a screen and exposed, and then withdrawn behind the +screen again. It was not, however, until the French revolution that +the telegraph was applied to practical purposes; but about the end of +1703 telegraphic communication was established between Paris and the +frontiers, and shortly afterward telegraphs were introduced into +England. + +The history of the invention and introduction of the electric +telegraph by Prof. Morse is one of inexhaustible interest, and every +incident relating to it is worthy of preservation. The incidents +described below will be found of special interest. The article is from +the pen of the late Judge Neilson Poe, and was the last paper written +by him. He prepared it during his recent illness, the letter embodied +in it from Mr. Latrobe being of course obtained at the time of its +date. It is as follows: + +On the 5th of April, 1843, when the monthly meeting of the directors +of the Baltimore & Ohio Railroad Company was about to adjourn, the +President, the Hon. Louis McLane, rose with a paper in his hand which +he said he had almost overlooked, and which the Secretary would read. +It proved to be an application from Prof. Morse for the privilege of +laying the wires of his electric telegraph along the line of the +railroad between Baltimore and Washington, and was accompanied by a +communication from B.H. Latrobe, Esq., Chief Engineer, recommending +the project as worthy of encouragement. + +On motion of John Spear Nicholas, seconded by the Hon. John P. +Kennedy, the following resolution was then considered: + +_Resolved_, "That the President be authorized to afford Mr. Morse such +facilities as may be requisite to give his invention a proper trial +upon the Washington road, provided in his opinion and in that of the +engineer it can be done without injury to the road and without +embarrassment to the operations of the company, and provided Mr. Morse +will concede to the company the use of the telegraph upon the road +without expense, and reserving to the company the right of +discontinuing the use if, _upon experiment_, it should prove _in any +manner injurious_." + +"Whatever," said Mr. McLane, "may be our individual opinions as to the +feasibility of Mr. Morse's invention, it seems to me that it is our +duty to concede to him the privilege he asks, and to lend him all the +aid in our power, especially as the resolution carefully protects the +company against all present or future injury to its works, and secures +us the right of requiring its removal at any time." + +[In view of the fact that no railroad can now be run safely without +the aid of the telegraph, the cautious care with which the right to +remove it if it should become a nuisance was reserved, strikes one at +this day as nearly ludicrous.] + +A short pause ensued, and the assent of the company was about to be +assumed, when one of the older directors, famed for the vigilance with +which he watched even the most trivial measure, begged to be heard. + +He admitted that the rights and interests of the work were all +carefully guarded by the terms of the resolution, and that the company +was not called upon to lay out any of its means for the promotion of +the scheme. But notwithstanding all this, he did not feel, as a +conscientious man, that he could, without further examination, give +his vote for the resolution. He knew that this idea of Mr. Morse, +however plausible it might appear to theorists and dreamers, and +so-called men of science, was regarded by all practical people as +destined, like many other similar projects, to certain failure, and +must consequently result in loss and possibly ruin to Mr. Morse. For +one, he felt conscientiously scrupulous in giving a vote which would +aid or tempt a visionary enthusiast to ruin himself. + +Fortunately, the views of this cautious, practical man did not +prevail. A few words from the mover of the resolution, Mr. Nicholas, +who still lives to behold the wonders he helped to create, and from +Mr. Kennedy, without whose aid the appropriation would not have passed +the House of Representatives, relieved the other directors from all +fear of contributing to Mr. Morse's ruin, and the resolution was +adopted. Of the President and thirty directors who took part in this +transaction, only three, Samuel W. Smith, John Spear Nicholas, and the +writer, survive. Under it Morse at once entered upon that test of his +invention whose fruits are now enjoyed by the people of all the +continents. + +It was not, however, until the spring of 1844 that he had his line and +its appointments in such a condition as to allow the transmission of +messages between the two cities, and it was in May of that year that +the incident occurred which has chiefly led to the writing of this +paper. + + +MR. LATROBE'S RECOLLECTIONS. + +MY DEAR MR. POE: Agreeably to my promise, this morning I put +on paper my recollection of the introduction of the magnetic telegraph +between Baltimore and Washington. I was counsel of the Baltimore & +Ohio Railroad Co. at the time, and calling on Mr. Louis McLane, the +President, on some professional matter, was asked in the course of +conversation whether I knew anything about an electric telegraph which +the inventor, who had obtained an appropriation from Congress, wanted +to lay down on the Washington branch of the road. He said he expected +Mr. Morse, the inventor, to call on him, when he would introduce me to +him, and would be glad if I took an opportunity to go over the subject +with him and afterward let him, Mr. McLane, know what I thought about +it. While we were yet speaking, Mr. Morse made his appearance, and +when Mr. McLane introduced me he referred to the fact that, as I had +been educated at West Point, I might the more readily understand the +scientific bearings of Mr. Morse's invention. The President's office +being no place for prolonged conversation, it was agreed that Mr. +Morse should take tea at my dwelling, when we would go over the whole +subject. We met accordingly, and it was late in the night before we +parted. Mr. Morse went over the history of his invention from the +beginning with an interest and enthusiasm that had survived the +wearying toil of an application to Congress, and with the aid of +diagrams drawn on the instant made me master of the matter, and wrote +for me the telegraphic alphabet which is still in use over the world. +Not a small part of what Mr. Morse said on this occasion had reference +to the future of his invention, its influence upon communities and +individuals, and I remember regarding as the wild speculations of an +active imagination what he prophesied in this connection, and which I +have lived to see even more than realized. Nor was his conversation +confined to his invention. A distinguished artist, an educated +gentleman, an observant traveler, it was delightful to hear him talk, +and at this late day I recall few more pleasant evenings than the only +one I passed in his company. + +Of course, my first visit the next morning was to Mr. McLane to make +my report. By this time I had become almost as enthusiastic as Mr. +Morse himself, and repeated what had passed between us. I soon saw +that Mr. McLane was becoming as eager for the construction of the line +to Washington as Mr. Morse could desire. He entered warmly into the +spirit of the thing, and laughed heartily, if not incredulously, when +I told him that although he had been Minister to England, Secretary of +State, and Secretary of the Treasury, his name would be forgotten, +while that of Morse would never cease to be remembered with gratitude +and praise. We then considered the question as to the right of the +company to permit the line to be laid in the bed of the road--the plan +of construction at that time being to bury in a trench some eight or +ten inches deep a half inch leaden tube containing the wrapped wire +that was to form the electric circuit. About this there was, in my +opinion, no doubt, and it was not long after that the work of +construction commenced. I met Mr. Morse from time to time while he +lived, and often recurred to the evening's discussion at my house in +Baltimore. + +The above is the substance of what I have more than once related to +other persons. I hope you will persist in your design of putting on +paper your own very interesting recollections in this connection, and +if what I have contributed of mine is of service to you, I shall be +much pleased. + + Most truly yours, + JOHN H.B. LATROBE. +March 3, 1881. + + * * * * * + + + + +THE KRAVOGL ELECTRIC MOTOR. + + +At the origin of every science, of whatever nature it may be, there is +always a fruitless period, of greater or less length, characterized by +the warfare of a few superior minds against general apathy. The finest +discoveries pass unperceived, so to speak, since they cannot cross the +limits of a narrow circle; and it often happens that they fall into +oblivion before they have been seriously judged. Meanwhile, a slow +progress is imperceptibly made, and, in measure as theoretical +principles more clearly disengage themselves, a few industrial +applications spring up and have the effect of awakening curiosity. An +impulse is thus given, and from this moment a movement in advance goes +on increasing at a headlong pace from day to day. + +With electricity this period has been of comparatively short duration, +since scarcely a century and a half separate us from the first +experiments made in this line of research. Now that it has truly taken +its place in a rank with the other sciences, we like to go back to the +hesitations of the first hour, and trace, step by step, the history of +the progress made, so as to assign to each one that portion of the +merit that belongs to him in the common work. When we thus cast a +retrospective glance we find ourselves in the presence of one strange +fact, and that is the simultaneousness of discoveries. That an +absolutely original idea, fertile in practical consequences, should +rise at a given moment in a fine brain is well; we admire the +discovery, and, in spite of us, a little surprise mingles with our +admiration. But is it not a truly curious thing that _several_ +individuals should have had at nearly the same time that idea that was +so astonishing in one? This, however, is a fact that the history of +electrical inventions offers more than one example of. No one ignores +the fact that the invention of the telephone gave rise to a notorious +lawsuit, two inventors having had this ingenious apparatus patented on +the same day and at nearly the same hour. This is one example among a +thousand. In the history of dynamo-electric machines it is an equally +delicate matter to fix upon the one to whom belongs the honor of +having first clearly conceived the possibility of engendering +continuous currents. + +We do not wish to take up this debate nor to go over the history of +the question again. Every one knows that the first continuous current +electric generator whose form was practical is due to Zenobius Gramme, +and dates back to July, 1871, an epoch at which appeared a memoir +(entitled "Note upon a magneto-electric machine that produces +continuous currents") that was read to the Academy of Sciences by Mr. +Jamin. Ten years previous, Pacinotti had had a glimpse of the +phenomenon, and of its practical realization, but was unfortunately +unable to appreciate the importance of his discovery and the benefit +that might be reaped from it. It is of slight consequence whether +Gramme knew of this experiment or not, for the glory that attaches to +his name could not be diminished for all that. But an interesting fact +that we propose to dwell upon now has recently been brought to light +in an electrical review published at Vienna.[1] It results from +documents whose authenticity cannot be doubted that, as far back as +1867, Mr. L. Pfaundler, a professor at Innsbruck, very clearly +announced the reversibility of a magneto-electric motor constructed by +Kravogl, a mechanician of the same place, and that he succeeded some +time before Gramme in obtaining continuous currents. + + [Footnote 1: _Zeitschrift des Electrotechnischen Vereines_ in + _Wien_, July, 1883.] + +The Kravogl motor that figured at the Universal Exhibition of 1867 is +but little known, and it is now very difficult to obtain drawings of +it. What is certain is that this motor is an application of the +properties of the solenoid, and, from this standpoint, resembles the +Bessolo motor that was patented in 1855. We may figure the apparatus +to our mind very well if we suppose that in the Gramme ring a half and +almost two-thirds of the core are removed, and the spirals are movable +around the said core. If a current be sent into a portion of the +spirals only, and in such a way that only half of the core be exposed, +the latter will move with respect to the bobbin or the bobbin with +respect to the core, according as we suppose the solenoid or the +bobbin fixed. In the first case we have a Bessolo motor, and in the +second a Kravogl one. + +In order to obtain a continuous motion it is only necessary to allow +the current to circulate successively in the different portions of the +solenoid. It is difficult to keep the core in place, since it is +unreachable, being placed in the interior of the bobbin. Kravogl +solved this difficulty by constructing a hollow core into which he +poured melted lead. This heavy piece, mounted upon rollers, assumed a +position of equilibrium that resulted from its weight, from friction, +and from magnetic attraction. But for a current of given intensity +this position, once reached, did not vary, and so necessitated a +simple adjustment of the rubbers. Under such circumstances, with a +somewhat large number of sections, the polarity of the core was nearly +constant. The spirals as a whole were attached to a soft iron armature +that had the effect of closing up the lines of forces and forming a +shell, so to speak. + +Like Bessolo, Kravogl never thought of making anything but a motor, +and did not perceive that his machine was reversible. It results from +some correspondence between Dr. A. Von Waltenhofen and Mr. L. +Pfaundler at this epoch that the latter clearly saw the possibility of +utilizing this motor as a current generator. Under date of November 9, +1867, he wrote, in speaking of the Kravogl motor, which had just been +taken to Innsbruck in order to send it to Paris. "I regret that I +shall not be able to see it any more, for I should have liked to try +to make it act in an opposite direction, that is to say, to produce a +current or an electric light by means of mechanical work." A little +more than two years later these experiments were carried out on a +larger motor constructed by Kravogl in 1869, and Mr. Pfaundler was +enabled to write as follows: "Upon running the machine by hand we +obtain a current whose energy is that of one Bunsen element." This +letter is dated February 11, 1870, that is to say, it is a year +anterior to the note of Gramme. + +[Illustration: FIG. 1.] + +In the presence of the historic interest that attaches to the +question, we do not think it will be out of place to reproduce here +the considerations that guided Prof. Pfaundler in the researches that +led him to convert the Kravogl motor into a dynamo-electric machine. +Let us consider two magnetized bars, _db_ and _bd'_, placed end to end +and surrounded by a cylindrical armature forming a shell, this +armature being likewise supposed to be a permanent magnet and to +present poles of contrary direction opposite the poles of the bars. +For the sake of greater simplicity this shell is represented by a part +only in the figure, _s n n s_. If, into a magnetic field thus +formed, we pass a spiral from left to right, the spiral will be +traversed by a current whose direction will change according to the +way in which the moving is done. It is only necessary to apply Lenz's +law to see that a reversal of the currents will occur at the points, +_a_ and _c_, the direction of the current being represented by arrows +in the figure. If we suppose a continual displacement of the spirals +from left to right, we shall collect a continuous current by placing +two rubbers at _a_ and _c_. Either the core or the shell may be +replaced by a piece of soft iron. In such a case this piece will move +with the spiral and keep its poles that are developed by induction +fixed in space. From this, in order to reach a dynamo-electric machine +it is necessary to try to develop the energy of the magnetic field by +the action of the current itself. If we suppose the core to be of soft +iron, and make a closer study of the action of the current as regards +the polarity that occurs under the influence of the poles, _s_, _n_, +_s_, we shall see that from _d_ to _a_ and from _b_ to _c_ the current +is contrary, while that from _a_ to _b_ and from _c_ to _d'_ it is +favorable to the development of such polarity. In short, with a spiral +moving from _d_ to _d'_ the resulting effect is _nil_, a fact, +moreover, that is self-evident. Under such circumstances, if we +suppose the shell, as well as the core, to be of soft iron, we shall +obtain a feeble current due to the presence of remanent magnetism; but +this magnetism will not be able to continue increasing under the +influence of the current. To solve this difficulty two means present +themselves: (1) to cause a, favorable magnetic current and act upon +the armature, and (2) to suppress such portions of the current in the +spirals as are injurious in effect. The first solution was thought of +by Gramme in 1871, and is represented diagramatically in Fig. 2. The +second is due to Prof. Pfaundler, and dates back to 1870. The core is +cut through the center (Fig. 3), and the portion to the right is +suppressed; the current is interrupted between _da_ and _cd'_, and is +closed only between _a_ and _c_ (_v_, Fig. 1). It results from this +arrangement that, under the action of the current, the polarity due to +remanent magnetism does nothing but increase. It suffices then for but +little remanent magnetism to prime the machine; the polarity of the +shell continues to increase, and the energy of the magnetic field, and +consequently of the current, has for a limit only the saturation of +the soft iron. If, now, we curve the core, the spirals, and the +armature into a circle, we have a Gramme or a Pfaundler machine, +according as we consider Fig. 2 or Fig. 3. + +[Illustration: FIG. 2.] + +[Illustration: FIG. 3.] + +This latter apparatus has in this case the form shown in Fig. 4. + +[Illustration: FIG. 4.] + +The spiral, _s m b_, is movable, and the core, N _o s_, is kept in a +position of equilibrium by virtue of its weight, and is provided with +rollers. For the sake of greater clearness, the front part of the +armature is supposed to be removed. The current does not circulate in +the spirals to the right of the diameter, W O, which latter is not +absolutely vertical. The position of the rubbers and armature is +regulated once for all. We do not know just what were the means +devised by Kravogl to suppress the current in the spheres to the +right. At all events, it is probable that the system has grown old +since Gramme invented his collector. In the application of the Kravogl +motor to the generation of continuous currents, Professor Pfaundler +now proposes to ingeniously utilize the Gramme collector. In such a +case the arrangement shown in Fig. 5 would be adopted. Let us suppose +an ordinary collector having as many plates as there are sections in +the ring, these plates being connected as usual with the entrance and +exit wires of the sections. The diametrically opposite touches that +are in the line, W O, are divided, and one of the halves is connected +at the entrance, _c a'_ (Fig. 4), with the corresponding section, +while the other communicates with the exit, _c' a_, of the neighboring +section. Each of these halves is prolonged by a piece of metal bent +into the form of an arc of a circle and embracing a little less than a +semi-circumference. Between these prolongations there is an insulating +part. In the rotary motion of the spiral, at least one of the touches +is always outside of the arc comprised between the brushes, R. In +order to secure a continuity of the circuit in the effective arc, W S_ o_, +it is only necessary to arrange a rubber, M, in such a way as to +establish a communication between the two parts of the divided touch +as soon as this latter enters the arc under consideration. + +In order to produce a current in the direction of the arrows shown in +Fig. 4, the spiral and axle must revolve from right to left. In this +case the rubber, M, occupies the position shown in the same figure, +the brushes embracing an arc of a little less than 180°. As soon as +the lower touch comes in contact with the brush, R, when the +revolution is being effected from left to right, the rubber, M, +establishes a communication between the two halves that have until now +been isolated, and the current is no longer interrupted. The second +touch during this time is at any point whatever of the arc, W N _o_, +and the spirals corresponding to the latter arc outside of the +circuit. In short, thanks to the rubber, M, we have an ordinary Gramme +collector in that portion of the circuit comprised between the +brushes, and a collector with a breakage of the circuit in the portion +to the right. + +[Illustration: FIG. 5.] + +This type of machine is entirely theoretical. In the apparatus used +for Prof. Pfaundler's experiments in 1870, the armature revolved with +the solenoid. The core and armature were of soft iron, and the core +was arranged in a manner analogous to the preceding, and remained in +place under the action of its weight, and the shell, forming a +complete circle, revolved with poles fixed in space. + +Practically, the machine that we have just described would prove +inconvenient to realize, and would present serious inconveniences. In +the first place, it seems to us quite difficult to transmit the motion +of the solenoid to the axle, supposing the former to revolve within +the armature. In the second place, considerable friction would surely +occur between the spirals and core, and the axle, being submitted to a +lateral stress, would be placed in a poor condition for work. It is +even allowable to doubt whether such a type could be practically got +up. At all events, no trial has as yet been made of it. + +Compared with the Gramme machine, from an absolutely theoretical point +of view, the Pfaundler apparatus presents undoubted advantages. A +theoretically perfect dynamo electric machine would be one in which +there was a complete reciprocity between the magnetizing action of the +current and the inductive action of the magnetic field. Now, such is +not the case in the Gramme machine. In this apparatus the soft iron +core is at the same time a magnet through favorable induction and a +disadvantageous electro-magnet. This double polarization is only +remedied to a certain extent by the adjustment of the brushes. In the +Pfaundler machine, on the contrary, the electro-magnetism and +magnetism through induction act in the same direction, and concur in +effecting a polarization that favors the production of the current. +Looked at it in this light, the latter machine more nearly approaches +the type of perfection than does that of Gramme. + +But we must not forget that such qualities are purely theoretical. In +practice the best machine is that in which the copper is best +utilized, that is to say, that which with a given weight of this metal +furnishes the most work. Now, this is certainly not the case in the +Pfaundler machine, for here half or more than half of the ring is +inert--a defect which is apparent at first sight. It results from this +that as soon as we propose to obtain an electromotive force, however +slight it be, we must get it with machines of large dimensions. Now, +it is permissible to believe that under such circumstances (taking +into consideration the complication of mechanical means that the +construction of such apparatus necessitates, and the great friction +that occurs) it would be impossible to obtain practical rotary +velocities. Comparing his machine with Gramme's, Prof. Pfaundler +expresses the idea that between them there is the same analogy as +there is between a constant pressure and an expansion engine. With +cylinders of equal diameters the work performed by the former of these +is greater than that done by the second, but in the latter the +expansive force of the steam is better utilized. This comparison seems +to us to be more ingenious than exact. Would it not be coming nearer +to the truth if we were to suppose a case of a hydraulic motor whose +performance continued diminishing with the height of the fall, and +would it not be advantageous under such circumstances to utilize only +a portion of the fall for the purpose of increasing the motor's +performance? + +This machine, however, as before stated, has never as yet been +constructed, so that experimental data relative to its mode of working +are wanting. It is especially interesting as regards its origin, which +dates back to an epoch at which researches on the dynamo electric +machine were at their heat. It is in its historical aspect that it is +proper to regard it, and it is from such a point of view that we have +deemed it well to say a few words about it in this place.--_La Lumiere +Electrique._ + + * * * * * + + + + +BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES. + + +We shall not attempt to pass in review the several apparatus that have +hitherto been devised for igniting blasts in mining operations, but +shall simply describe in this place a machine recently invented for +this purpose by Mr. Bornhardt, an engineer to the Grand Duke of +Brunswick. + +This apparatus (shown in the accompanying engravings) consists +essentially of two hard-rubber disks, A (Figs. 2 and 3), keyed to an +iron axle, and of two rubbers, B, that are formed of skin and are held +against the disks by small springs, R; motion is communicated to the +axle, _a_, by means of a pair of gearings, _a_ and _b_, and a crank, +_f_. + +[Illustration: BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES.] + +Each disk revolves between two metallic rings, _c_, provided with +points that attract and collect in Leyden jars, D, the electricity +produced by the friction. For discharging the condensers there is +employed a manipulator formed of a rod, mm, which can be acted upon, +from the exterior, by means of a button, _k_. Upon bringing the ball, +_m_, of the rod in contact with the ball, _p_, of the condenser, the +lever (which then takes the position shown by the dotted line) +continues to remain in connection with a small ring, _q_, through a +special spring. Another ring, _t_, is connected in the same way with +the external armature of the condenser. Upon connecting the rings, _p_ +and _t_, by a wire to which cartridges are attached, any number of the +latter may be ignited. + +The parts that we have just enumerated are inclosed in a tin box +covered with a wooden casing, P. Between the two there is inserted a +sheet of hard rubber in order to prevent a loss of electricity; the +whole is held in place by strong springs. + +In order to show the normal state of the condenser, a scale consisting +of 15 metallic buttons to give the dimensions of the sparks, is +arranged at X. This scale is capable of being connected with the +rings, _q_ and _t_, by means of chains; when the spark obtained after 15 +or 20 revolutions considerably exceeds the intervals of the scale, it +is a sure thing that the machine is in a proper state. + +In order to prepare the apparatus for carriage, the winch is taken off +and placed in the compartment, _m_, which is closed by means of a +door, Q. + +Figs. 5 and 6 show the arrangement of the dynamite cartridges and +wires in the blast hole. Figs. 7 to 10 show different arrangements of +the igniting wires. Figs. 11 and 12 give the general arrangement for +igniting a number of cartridges simultaneously by means of the +electric machine. Fig. 13 shows the arrangement where powder is +employed. Fig. 14 shows the arrangement of a horizontal +hole.--_Annales Industrielles._ + + * * * * * + + + + +IMPROVED ELECTRIC FIRE ALARM. + + +The object of this apparatus is to close an electric circuit when the +temperature of a room rises above a certain point. Many devices have +been invented for effecting this object, each of which have their own +advantages or disadvantages. The invention of Mr. Pritchett enables +the required result to be obtained in a very satisfactory manner. The +apparatus consists (as shown by the figure) of a long glass vessel +containing air; connected to this vessel there is a glass tube filled +with mercury. The whole is mounted on a metal cradle, which turns on +pivots. According to the position which the glass vessel and its +adjuncts occupy in the cradle (this position being adjustable by means +of a thumb-screw, seen at the upper part of the cradle), so will the +same have a tendency to rock longitudinally over to one side or the +other. Now, if we suppose the position to be such that the right hand +end of the glass vessel is depressed, and the left hand end raised, +then if the vessel becomes subjected to an elevation of temperature, +the air inside the same will become expanded, and the mercury column +in the tube will be driven over to the left, and will rise in the +turned up end of the tube. This will cause the left hand branch of the +glass vessel, and its attachments, to become increased in weight, +while the right hand branch will become proportionally lighter; the +consequence of this will be that the vessel and its cradle will cant +over, and by falling on an electrical contact will close a circuit and +sound an alarm. It is obvious that the apparatus is equally well +adapted for indicating a diminution as well as an increase of +temperature, for if the electrical contact be placed under the right +hand portion of the cradle, and the latter be adjusted so that in its +normal position its left hand portion is depressed, then when the +glass vessel becomes cooled, the air in it will contract, and the +mercury will fall in the turned-up portion of the tube before referred +to, and will rise in the limb connected to the vessel, consequently +the cradle and glass vessel will cant over in the reverse way to that +which it did in the first case. + +Owing to the surface which the glass vessel exposes, the air inside +quickly responds to any external change of temperature, consequently +the apparatus is very sensitive. Another important feature is the fact +that the cradle and vessel in canting over acquires a certain +momentum, and thus the contact made becomes very certain. + +[Illustration: PRITCHETT'S ELECTRIC FIRE ALARM.] + +Mr. Pritchett proposes that his apparatus shall give external evidence +outside the house by ringing a gong, and by dropping a semaphore arm +released by an electromagnet. He also proposes (as has often been +suggested) that a water supply shall be automatically turned +on.--_Electrical Review._ + + * * * * * + + + + +A STANDARD THERMOPILE. + + +Dr. G. Gore, F.R.S., has invented an improved thermopile for +measuring small electromotive forces. It consists of about 300 pairs +of horizontal, slender, parallel wires of iron and German silver, the +former being covered with cotton. They are mounted on a wooden frame. +About 1― in. of the opposite ends of the wires are bent downward to a +vertical position to enable them to dip into liquids at different +temperatures contained in long narrow troughs; the liquids being +non-conductors, such as melted paraffin for the hot junctions, and the +non-volatile petroleum, known as thin machinery oil. The electromotive +force obtained varies with the temperature; a pile of 295 pairs having +a resistance of 95.6 ohms at 16 deg. Cent. gave with a difference of +temperature of 100 deg. Cent. an electromotive force of 0.7729 volts, +or with 130 deg. Cent. an electromotive force of 1.005 volt. Each +element, therefore, equaled 0.0000262 volt for each degree Cent. +difference of temperature. On having been verified with a standard +voltaic cell the apparatus becomes itself a standard, especially for +small electromotive forces. It is capable of measuring the 1/34861 +part of a volt. For higher electromotive forces than a volt, several +of these piles would have to be connected in series. The fractional +electromotive force is obtained by means of a sliding contact which +cuts out so many pairs as is required. + + * * * * * + + + + +TELEPHONIC TRANSMISSION WITHOUT RECEIVERS. + + +The annual meeting of the French Society of Physics, the success of +which is continually increasing, took place this year in the salons of +the Observatory, which were kindly placed at the Society's disposal by +Admiral Mouchez. + +There were three consecutive sessions, the one of Tuesday, April 15, +being set apart for the members of the Association, the one of the +16th for the invited guests of Admiral Mouchez, and that of the 17th +for the invited guests of the Society. The salons were partially +lighted by the Siemens differential arc, continuous current lamps, and +partially by the Swan incandescent lamp supplied by a distributing +machine that permitted of the lamps being lighted and extinguished at +will without changing the normal operation of all the rest. Many +apparatus figured at this exhibition, but we shall on the present +occasion merely call attention to those that presented a certain +character of novelty or of originality. + +Among the apparatus that we shall reserve a description of for the +present was Messrs. Richard Bros.' registering thermometer designed +for the Concarneau laboratory, an instrument which, when sunk at one +mile from the coast, and to a depth of 40 meters, will give a diagram +of the temperature of the ocean at that depth; and Mr. Hospitalier's +continuous electrical indicators, designed for making known from a +distance such mechanical or physical phenomena as velocities, levels, +temperatures, pressures, etc. + +Among the most important of the apparatus exhibited we must reckon Mr. +Cailletet's devices for liquefying gases, and those of Mr. Mascart for +determining the ohm. The results obtained by Mr. Mascart (which have +been submitted to the Committee on Unities of the Congress of +Electricians now in session at Paris), are sensibly concordant with +those obtained independently in England by Lord Rayleigh. Everything +leads to the hope, then, that a rapid and definite solution will be +given of this important question of electric unities, and that nothing +further will prevent the international development of the C.G.S. +system. + +Mr. Jules Duboscq made a number of very successful projections, and we +particularly remarked the peculiar experiment made in conjunction with +Mr. Parinaud, that gave in projection two like spectra produced by the +same prism, and which, through superposition, were capable of +increasing the intensity of the colors, or, on the contrary, of +reconstituting white light. + +Among the optical applications we may cite Mr. Leon Laurent's +apparatus for controlling plane, parallel, perpendicular, and oblique +surfaces, and magic mirrors obtained with an ordinary light; Mr. S.P. +Thompson's apparatus for demonstrating the propagation of +electro-magnetic waves in ether (according to Maxwell's theory), as +well as some new polarizing prisms; and a mode of lighting the +microscope (presented by Mr. Yvon), that was quite analogous to the +one employed more than a year ago by Dr. Van Heurck, director of the +Botanical Garden of Anvers. + +Acoustics were represented by an electro-magnetic brake siren of Mr. +Bourbouze; Konig's apparatus for the synthesis of sounds; and Mr. S.P. +Thompson's cymatograph--a pendulum apparatus for demonstrating the +phenomena of beats. + +It was electricity again that occupied the largest space in the +programme of the session. + +Apparatus for teaching are assuming greater and greater importance +every day, and the exhibit of Mr. Ducretet included a large number of +the most interesting of these. The house of Breguet exhibited on a +reduced scale the magnificent experiments of Gaston Plante, wherein +320 leaden wire secondary elements charged for quantity with 3 Daniell +elements, and afterward coupled for tension, served to charge a +rheostatic machine formed of 50 condensers coupled for quantity. These +latter, coupled anew for tension, furnished upon being discharged a +spark due to a difference of potential of about 32,000 volts that +presented all the characters of the spark produced by induction coils +on the machines so improperly called "static." Finally, we may cite +the apparatus arranged by Mr. S.P. Thompson for studying the +development of currents in magneto-electric machines. The inventor +studies the influence of the forms of the inductors and armatures of +machines by means of an arrangement that allows him to change the +rings or armatures at will and to take out the induced bobbins in +order to sound every part of the magnetic field. Upon giving the +armature an angular motion limited by two stops, there develops a +certain quantity of electricity that may be measured by causing it to +traverse an appropriate ballistic galvanometer. Messrs. Deprez and +D'Arsonval's galvanometer answers very well for this purpose, and its +aperiodicity, which causes it quickly to return to zero as soon as the +induced current ceases, permits of a large number of readings being +taken within a very short space of time. + +Measuring apparatus were represented by a new and very elegant +arrangement of Sir William Thomson's reflecting galvanometers, due to +Mr. J. Carpentier. The mounting adopted by Mr. Carpentier permits of +an easy removal of the bobbins and of an instantaneous substitution +therefor. The galvanometric part, composed of the needles and mirror, +therefore remains entirely free, thus allowing of its being verified, +and making it convenient to attach the silken fiber. Mr. Carpentier +has, moreover, adopted for all the minor apparatus a transparent +celluloid scale which simplifies them, facilitates observations, and +renders the use of reflection almost industrial. + +We shall complete our enumeration of the measuring apparatus by citing +Ducretet's non-oscillating galvanometer, Sir William Thomson's +amperemeters, voltameters, ohmmeters, and mhosmeters, constructed and +exhibited by Breguet, and a new aperiodic galvanoscope of Mr. Maiche. +Mr. Baudot exhibited the recent improvements that he has made in his +multiplex printing telegraph, and M. Boudet of Paris showed a new +system of telephone transmission by submarine cables. + +[Illustration: FIG. 1.--DIAGRAM EXHIBITING THE ARRANGEMENT FOR +TELEPHONIC TRANSMISSIONS WITHOUT A RECEIVER.] + +Finally, we shall conclude our enumeration by referring to the +curiosities. The house of Siemens exhibited a miniature electric +railway actuated by a new model of Reynier accumulators; M. Maiche +operated a system of musical telephonic auditions that differed only +in detail from those instituted by Mr. Ader at the exhibition of 1881; +and Mr. Hospitalier presented a new form of an experiment devised by +Mr. Giltay, consisting of a telephonic transmission of sounds without +the use of receivers. Mr. Giltay's experiment is nothing but Mr. +Dunand's speaking condenser without the condenser. A glance at Fig. 1 +will show how things are arranged for the experiment. The transmitting +system comprises two distinct circuits, viz.: (1) one formed of a +pile, P, of 2 or 3 Leclanche elements, or of 1 or 2 small sized +accumulators, an Ader microphane transmitter, M, and the inducting +wire of a small induction coil, B; and (2) the other formed of the +induced wire of the coil, B, of a pile, P', of 10 or 12 Leclanche +elements, and of a line whose extremities terminate at R, in two +ordinary electro-medical handles. With this arrangement the experiment +performed is as follows: When any one speaks or sings in front of the +transmitter, T, while two persons, A and B, each having one hand +gloved, are holding the handles in the ungloved hand, it is only +necessary for A to place his gloved hand upon B's ear, or for the +latter to place his hand upon A's, or for each to place his hand on +the other's ear simultaneously, in order that A or B, or A and B +simultaneously, may hear a voice issuing from the glove. Under these +circumstances, Mr. Giltay's experiment is explained like Dunand's +speaking condenser--the hand of A and the ear of B here constituting +the armature of an elementary condenser in which the glove performs +the role of dielectric. + +Upon repeating this experiment at the laboratory of the School of +Physics and Industrial Chemistry of Paris, it has been found that the +glove maybe replaced by a sheet of plain or paraffined paper. In this +case, when two persons are holding the handles, and have their ears +applied, one against the other, if a sheet of paper be interposed, +airs or words will be heard to proceed therefrom. Finally, it has been +found possible to entirely suppress the paper, or dielectric, and to +hear directly, by simply interposing the auditor or auditors in the +circuit. One of the most curious forms of the experiment is the one +shown in Fig. 2. Here a third person, C, hears the hands of A and B +speak when a circuit is formed by means of three persons, A, B, and C, +the two former, A and B, each holding one of the wires of the circuit +and applying his free hand to the ear of C. Although the experiment is +one that requires entire silence, and could not on that account be +performed at the laboratory, a sort of telephonic chain can be formed +in which five or six persons may hear at the same time. A, putting his +hand on the ear of B, the latter putting his to that of C, and so on +up to the last person, who closes the circuit by grasping one of the +handles, the other one being held by A. + +[Illustration: EXPERIMENT ON TELEPHONIC TRANSMISSION WITHOUT +RECEIVING APPARATUS.] + +It is difficult in the present state of science to explain very +clearly how these telephonic transmissions are effected without a +receiver. All that we can conclude from it so far is that the ear is +an instrument of incomparable delicacy and of exquisite sensitiveness, +since it perceives vibrations in which the energy developer, +particularly in the telephonic chain, is exceedingly feeble. + +Without any desire to seek an application for an experiment that is +simply curious, we yet believe that there is here a phenomenon of a +nature to be studied by physicists. Discoveries in telephony and +microphony have certainly opened up to science, as regards both theory +and practice, new horizons that still promise other surprises for the +future. But to return to the observatory: The success obtained by the +exhibition of the French Society of Physics shows that these reunions +respond to a genuine need--that of instructing in and popularizing +science. While warmly congratulating the organizers of these meetings, +we may express a wish that the good example set by the Society of +Physics may be followed by other societies. We are convinced in +advance that an equal success awaits them.--_La Nature._ + + * * * * * + + + + +ON THE ARRANGEMENT OF GROUND CONDUCTORS. + + +In telegraphy, as well as in the question of lightning rods, attention +has been but incidentally paid to the improvement of ground +conductors, and this point has not been the object of that careful +study that has been bestowed upon the establishment of aerial lines. +It is only recently that the interest created by lightning rods has +given rise to new forms of conductors differing from those formerly +used. The publications of the Prussian Academy of Sciences of from +1876 to 1880 contain some information of special importance in regard +to this. It is stated therein that the effect of ground conductors may +be notably increased by the division of the earth plates and the use +of metallic rods, without necessitating a greater output of material. +These facts, however, have not as yet been put to profit in practice +for the reason, perhaps, that the considerations, which have remained +general, have not at once permitted of obtaining forms what could be +employed with perfect knowledge of the results. This is what led Mr. +Ulbricht, of Dresden, to make calculations for a few forms of +conductors, and to test their approximate values. The results of these +researches are printed in the _Elektrotechnischen Zeitschrift_ for +1883 (p. 18). + +[Illustration] + +The equations found show, in the first place, that there exist three +means of obtaining a considerable effect, as regards the ground +conductor, with a slight expenditure of material: The cylindrical +electrode may be drawn out into the form of a bar or wire; the plate +may be rendered narrow, and elongated in the form of a ribbon; and, +besides, the annular plate may be enlarged in lessening the metallic +surface. + +Finally, a short, open cylinder with a vertical axis may be formed by +curving a narrow plate or ribbon. It is not necessary to see the +formula to recognize the fact that this cylinder must behave like a +ribbon and a flat ring. The radius increasing, and the surface +remaining constant, the resistance of the earth here likewise +approaches zero. + +As the resistance of the earth is inversely proportional to the +diameter of the plates, the zero resistance can also be reached by +dividing a plate _ad infinitum_. As the parts of the plate may be +brought quite close to each other without perceptibly interfering with +the action, a _network_ has finally been reached by a division carried +very far, yet limited, and by connecting the parts with one another by +conducting cylinders. + +If we seek to determine what forms of ground conductors are efficient +and economical under given conditions, we shall have to begin by +informing ourselves as to the choice of material to be used for the +electrode, and shall then have to ascertain whether putting it in the +ground will or will not necessitate much outlay. The most suitable +material is copper, which may be used with advantage, in that it lasts +pretty well underground, and that the facility which it may be worked +permits of easily giving it more appropriate forms than those that can +be obtained with cast iron, which is of itself less costly. + +If the burying in the ground requires little or no labor, as when +there exist ponds, rivers, and wells, or subterranean strata of water +near the surface of the earth, elongated forms of conductors will be +employed, such as the solid or hollow cylinder, the wire, the ribbon, +the narrow ring, and the network. Plates approaching a square or +circular shape are not advantageous. But if the ground has to be dug +deeply in order to sink the conductor, the form of the electrode must +be more condensed, and selected in such a way that the necessary +action may be obtained with a minimum output of copper and labor. For +great depths, and when the ground will permit of boring, an elongated +and narrow cylinder will be used. Such a system, however, can only be +employed when the cylinder is surrounded by spring water, since, +without that, an intimate contact with earth that is only moist, +cannot be obtained with certainty. In earth that is only moist and for +moderate depths, preference may be given to an electrode laid down +flat. The digging necessary in this case is onerous, it is true, but +it permits of very accurately determining the state of the earth +beneath and of obtaining a very perfect adherence of the electrode +therewith. Two forms, the annular ribbon or the flat ring and the +network, present themselves, according to calculations, as a +substitute for copper plates, which are so expensive; and these forms +are satisfactory on condition that the labor of digging be not notably +increased. These forms should always have a diameter a little greater +than that of the plate. The flat ring and the network, however, offer +one weak point, which they possess in common with the plate, and that +is, their dimensions cannot be easily adapted to the nature of the +ground met with without a notable increase in the expense. Now, if the +ground should offer a conductivity less than what was anticipated, and +it were desired to increase the plate, say by one-third, it would be +impossible to do so as a consequence of the closed form. + +One important advantage is realized in this respect by combining the +ring and the network in the form of a reticulated ring having a +diameter of from 1 to 1― meters. On cutting this ring at a given place +and according to a certain radius we obtain the reticulated ribbon +shown in the accompanying figure. The thickness of the wires is 2.5 +mm., and their weight is 0.475 kilo. per meter. L, L, and L are the +points at which the conducting cable is soldered. A reticulated ribbon +of copper can be made in advance of any length whatever, and, +according to local exigencies, it may be easily curved and given the +form of a flat or cylindrical ring of varying width. Even though the +ribbon has already been cut for a ring of given diameter, it may be +still further enlarged by drawing it out and leaving a bit of the ring +open, so as to thus obtain a nearly corresponding diminution in the +resistance. Such a resistance may be still further diminished by +rendering the ring higher, that is to say, by employing an annular +cylindrical form. + +After assuring himself, by experiments on a small scale, that +calculation and observation gave concordant results for the flat ring, +the author made an experiment on a larger scale with the annular +network. For practical reasons he employed for this purpose a copper +wire 2.5 mm. in diameter, which may be expected to last as long as one +of iron plate 2 mm. in thickness. Calculation showed that in a ribbon +160 mm. wide, meshes 40 mm. in breadth were advantageous and favorable +as regards rigidity. A reticulated ribbon like this, 4 meters in +length, was made and formed into a flat ring having an external +diameter of 1.42 m. and an internal one of 1.10 m. The resistance of +this ring was found to be W = 0.3485 (1/_k_), and that of a plate one +meter square, W0 = 0.368 (1/_k_). + +As the conductivity of the earth is very variable, and as we cannot +have an absolute guarantee that the ramming will be uniform, it seemed +proper to make the measurements of the resistance by fixing the plate +and the ring in succession to the lower surface of a small raft, in +such a way that the contact with the water should correspond as well +as possible to the suppositions made for the calculation. As a second +ground conductor, a system of water pipes was used, and, after this, a +lightning rod conductor, etc. + +Repeated and varied experiments gave, for the calculation of the +values of the resistances, equations so concordant that the following +results may be considered very approximate. + +The square plate had a resistance of 35.5 Siemens units, and the +reticulated ring one of 32.5. From the first figure we deduce k = +1/91.12, that is to say, the specific conductivity of river-water is +1:91120000. Calculation, then, gives as the resistance of the earth in +Siemens units: + + Calculated. Observed. + Square plate. 33.5 33.5 + Annular ring. 31.76 32.5 + +These figures prove the accuracy of the calculations that had been +made in an approximate way. + +The experiments were performed upon the Elba, above Dresden. Other +experiments still had reference to the influence of immersion. In +order to diminish polarization, only instantaneous currents from the +measuring pile were employed. It was to be supposed that the current +of water through which the bubbles of gas were removed from the +electrodes would not have permitted of a notable resistance of +polarization. Later measurements, made upon a ribbon buried, like the +plates, in the earth, gave likewise most favorable results. + +As a result of these experiments, the State railways of Saxony have, +in such cases as were practicable, introduced the annular network of +copper. There are some manufacturers, too, who seem desirous of +adopting this system, although it has hardly emerged from the period +of experiment. The pecuniary advantages that will result from an +application of it ought, it would seem, to dispel a large proportion +of the criticisms directed against the erection of lightning rods, +from the standpoint of expense, and contribute to extend an +arrangement which may be considered as a very happy one. + +If we compare the square plate with the equivalent annular network, +constructed as above indicated, and which should possess, according to +the author an external diameter of 1.26 m. and of 3.45 m., we find +that: + + The square plate, 1 mm. thick weighs 8.9 kilos. + " 2 " " " 17.8 " + The annular network " 1.64 " + +The cost of reticulated ribbon per meter amounts to about 4.4 francs, +supposing it to be arranged as shown in the cut. + +As term of comparison, we may admit that the following forms are +nearly the equivalent of a horizontal, unburied plate one meter +square. + + Length. Diameter. + Vertical cylinder buried 1.40 m. 0.13 m. + " " " 1.80 m. 0.06 m. + Vertical bar " 2.60 m. 0.013 m. + Horizontal bar " 5.20 m. 0.013 m. + +Horizontal flat ring 1.32 m. in external diameter, and 1.08 m. +internal. + +Horizontal network 1.01 m. square, and having meshes of the same size +as those of the reticulated ribbon. + +Horizontal reticulated ribbon 3 m. in length and of the structure +described. + +Horizontal annular ring 1.26 m. in external diameter, 0.94 m. +internal. + +In conclusion, let us meet an objection that might be made to the +accuracy of the hypotheses that serve as a base to the preceding +calculations, in cases where ground plates for lightning rods and not +for telegraphs are concerned. Between the two ground plates of a +telegraph line there is generally a distance such that the curves of +the current undergo no deviation in the vicinity of one of the +electrodes (the only part important for integrations) through the +influence of the other. But it might be admitted that such would prove +the case with a lightning rod in a storm, at the time of the passage +of the fluid into the earth. The ground plate here is one of the +electrodes, and the other is replaced by the surface of the earth +strongly charged to a great distance under the storm clouds. If we +suppose (what may be admitted in a good lightning rod) that there no +longer occurs any spark from the point downward, the curves of the +current, in starting perpendicularly from the ground plate, would be +obliged to leave their rectilinear trajectory and strike the surface +of the earth at right angles. When the electricity flows through a +plane surface into an infinite body, it is only when such surface +presents a very great development that the respective potentials +decrease very slowly in the vicinity of the said surface. No notable +modification occurs, then, in the curves of equal potential, in the +vicinity of the ground plate through the action of this extended +charge, nor consequently any modification in the curves of the +current; but the electricity which spreads has but a short distance to +travel in order to overcome the most important resistances. + +The calculations of resistances given above have, then, the same value +for discharges of atmospheric electricity.--_Bull. du Musee de +l'Industrie._ + + * * * * * + + + + +ON ELECTROLYSIS. + +By H. SCHUCHT. + + +Concerning the separations which take place at the positive pole, the +composition of the peroxides, and the manner of their determination, +relatively little has been done. + +If solutions of the salts of lead, thallium, silver, bismuth, nickel, +and cobalt are decomposed by the current between platinum electrodes, +metal is deposited at the negative, and oxide at the positive +electrode. Manganese is precipitated only as peroxide. The formation +of peroxide is, of course, effected by the ozone found in the +electrolytic oxygen at the positive pole; the oxide existing in +solution is brought to a higher degree of oxidation, and is separated +out. Its formation may be decreased or entirely prevented by the +addition of readily oxidizible bodies, such as organic acids, lactose, +glycerine, and preferably by an excess of oxalic acid; but only until +the organic matter is transformed into carbonic acid. In this manner +Classen separates other metals from manganese in order to prevent the +saline solutions from being retained by the peroxide. + +With solutions of silver, bismuth, nickel, and cobalt, it is often +practicable to prevent the separation of oxide by giving the current a +greater resistance--increasing the distance between the electrodes. + +The proportion between the quantities of metal and of peroxide +deposited is not constant, and even if we disregard the concentration +of the solution, the strength of the current and secondary influences +(action of nascent hydrogen) is different in acid and in alkaline +solutions. In acid solutions much peroxide is formed; in alkaline +liquids, little or none. The reason of the difference is that ozone is +evolved principally in acid solutions, but appears in small quantities +only in alkaline liquids, or under certain circumstances not at all. +The quantity of peroxide deposited depends also on the temperature of +the saline solution; at ordinary temperatures the author obtained more +peroxide--the solution, the time, and the strength of current being +equal--than from a heated liquid. The cause is that ozone is destroyed +by heat and converted into ordinary oxygen. With the exception of lead +and thallium the quantity of metal deposited from an acid solution is +always greater than that of the peroxide. + +_Lead._--Luckow has shown that from acid solutions--no matter what may +be the acid--lead is deposited at the anode as a mixture of anhydrous +and hydrated peroxide of variable composition. Only very strongly acid +solutions let all their lead fall down as peroxide; the precipitation +is rapid immediately on closing the circuit, and complete separation +is effected only in presence of at least 10 per cent. of free nitric +acid. As the current becomes stronger with the increase of free acid, +there is deposited upon the first compact layer a new stratum of +loosely adhering peroxide. + +In presence of small quantities of other metals which are thrown down +by the current in the metallic state, such as copper, mercury, etc., +peroxide alone is deposited from a solution of lead containing small +quantities only of free nitric acid. + +The lead peroxide deposited is at first light brown or dark red, and +becomes constantly darker and finally taking a velvet-black. As its +stratification upon the platinum is unequal, it forms beautifully +colored rings. + +Experiments show that the quantity of peroxide deposited depends on +the nature of the solution and the strength of the current. In case of +very feeble currents and slight acidity, its quantity is so small that +it does not need to be taken into consideration. If the lead solution +is very dilute scarcely any current is observed, lead solutions _per +se_ being very bad conductors of electricity. + +Faintly acid concentrated lead solutions give loose peroxide along +with much spongy metallic lead. Free alkali decreases the separation +of peroxide; feebly alkaline solutions, concentrated and dilute, yield +relatively much peroxide along with metallic lead, while strongly +alkaline solutions deposit no peroxide. + +Dried lead peroxide is so sparingly hygroscopic that it may be weighed +as such; its weight remains constant upon the balance for a long time. +In order to apply the peroxide for quantitative determinations, a +large surface must be exposed to action. As positive electrode a +platinum capsule is convenient, and a platinum disk as negative pole. +The capsule shape is necessary because the peroxide when deposited in +large quantities adheres only partially, and falls in part in thin +loose scales. It is necessary to siphon off the nitric solution, +since, like all peroxides, that of lead is not absolutely insoluble in +nitric acid. The methods of Riche and May give results which are +always too high, since portions of saline solution are retained by the +spongy deposit and can be but very imperfectly removed by washing. +This is especially the case in presence of free alkali. + +The author has proceeded as follows: The lead peroxide is dried in the +capsule, and there is passed over it pure dry gaseous sulphurous acid +in a strong current from a rather narrow delivery tube. Lead sulphate +is formed with evolution of heat; it is let cool under the exsiccator, +and weighed as such. Or he ignites the peroxide along with finely +pulverized ammonium sulphite; the mass must have a pure white color. +After the conclusion of the reaction it is ignited for about 20 +minutes. The results are too high. The proportion of actual lead +peroxide in the deposit ranges from 94 to 94.76 per cent. The peroxide +precipitated from a nitric solution may, under certain circumstances, +be anhydrous. This result is due to the secondary influences at the +positive pole, where the free acid gradually withdraws water from the +peroxide. + +The peroxide thrown down from alkaline solutions retains alkali so +obstinately that it cannot be removed by washing; the peroxide plays +here the part of an acid. The lead nitrate mechanically inclosed in +the peroxide is resolved by ignition into oxide, hyponitric acid, and +oxygen; this small proportion of lead oxide does not exert an +important influence on the final result. The quantity of matter +mechanically inclosed is relatively high, as in the precipitation of +much lead peroxide there is relatively more saline matter occluded +than when a few centigrammes are deposited. The peroxide incloses also +more foreign matter if it is thrown down upon a small surface than if +it is deposited in a thin layer over a broad surface. From numerous +analyses the author concludes that in presence of much free nitric +acid the proportion of water is increased; with free alkali the +reverse holds good. + +_Thallium_ behaves similarly to lead. From a nitric acid solution it +is thrown down, according to the proportion of free acid, either as +sesquioxide only or in small quantities as silvery, metallic leaflets; +from alkaline solutions it is deposited as sesquioxide and metal, the +latter of a lead-gray color. Thallium solutions conduct the electric +current badly. Thallium oxide resembles lead peroxide in color; at a +strong heat it melts, becomes darker, and is converted into peroxide, +in which state it can be weighed. + +_Silver._--All solutions of silver salts, except the nitrate, and +those containing a very large quantity of free nitric acid or +nitrates, deposit electrolytically merely metallic silver. In the +above mentioned exceptional cases there is formed a small quantity of +peroxide which adheres to the anode as a blackish-gray deposit. The +greatest quantity of peroxide is obtained on employing a concentrated, +strongly acid solution of the nitrate, and a strong current. If the +solution is very dilute we obtain no peroxide, or mere traces which +disappear again toward the end of the process. The peroxide is +deposited at first in small, dark, shining octahedral crystals; +subsequently, in an amorphous state. At 110° it evolves oxygen +suddenly, and is converted into metallic silver. It dissolves in +ammonia with a violent escape of nitrogen. In nitric acid it dissolves +without decomposition and with a red color. + +The author uses a galvanic current for reducing silver residues, +consisting of sulphocyanide. The salt is mixed with sulphuric acid in +a roomy platinum capsule, and a fine platinum wire gauze is used as +positive electrode. + +_Bismuth._--The current resolves bismuth solutions into metal and +bismutic acid. The latter is deposited at the positive pole, and in +thin layers appears of a golden-yellow, but in thick strata is darker, +approaching to red. Its formation is very gradual, and in time it +disappears again, owing to secondary actions of the current. On +ignition it becomes lemon yellow, and transitorily darker, even brown, +and passes into the sexquioxide. + +_Nickel and Cobalt._--On the electrolysis of the ammonical solution +the sesquioxide appears at the positive pole. Its formation is +prevented by an excess of ammonia. The author never obtains more than +3― per cent. of the quantity of the metal. The sesquioxides dissolve +in ammonia without escape of nitrogen, and are usually anhydrous. + +_Manganese._--Manganese is the only metal which is precipitated only +as peroxide. It is deposited at once on closing the circuit, and is at +first brown, then black and shining. Organic acids, ferrous oxide, +chromic oxide, ammonium salts, etc., prevent the formation of peroxide +and the red color produced by permanganic acid. In very dilute +strongly acid nitric solutions there is formed only permanganic acid, +which according to Riche is plainly visible in solutions containing +1/1000000 grm. manganese. On electrolyzing a manganiferous solution of +copper nitrate, red permanganic acid appeared in a stratum floating +above the platinum disk coated with brown peroxide. No manganese +peroxide was deposited. The peroxide adheres firmly to the platinum +when the proportion of free acid is small, not exceeding 3 per cent., +and the current is not too strong. If the action of the current is +prolonged after the peroxide is thrown down, it falls off in laminæ. +According to Riche, in a nitric solution the manganese is deposited as +peroxide, also at the negative pole. This formation is not directly +due to the current, but is a precipitate occasioned by the production +of ammonia by the reduction of nitric acid. To determine the manganese +in peroxide electrolytically precipitated, it is heated to bright +redness in the platinum capsule until the weight becomes constant. The +results are too high. + +_Selenium and Tellurium._--Both these bodies are readily and +completely reduced by the current either in acid or alkaline +solutions. Selenium is thrown down at first of a fine brownish red, +which gradually becomes darker. The deposit of tellurium is of a +bluish black color. If the current is feeble, the deposit of selenium +is moderately compact; that of tellurium is always loose, and it often +floats on the liquid. A strong current precipitates both as powders. +The positive pole is coated during electrolysis with a film of a dark +color in case of selenium, but of a lemon yellow with tellurium. As in +case of arsenic and antimony, the hydrogen evolved at the negative +pole combines with the reduced substances, forming hydrogen, selenide, +or telluride, which remain in part in solution in the liquid. The +reduced metal separates out at the anode in a friable +condition.--_Zeitschrift fur Analytische Chemie, and Chemical News._ + + * * * * * + + + + +THE ELECTRO-CHEMICAL EQUIVALENT OF SILVER. + + + +A very careful and important determination of the electrochemical +equivalent of silver has been made at the observatory of the Physical +Institute of Würzbourg, and the results are that an ampere current +flowing for a second, or a coulomb of electricity deposits 1.1183 +milligrammes of silver or 0.3281 milligramme of copper, and decomposes +0.09328 milligramme of water, a result agreeing closely with that of +Lord Rayleigh recently communicated to the Physical Society. An ampere +therefore deposits 4.0259 grammes of silver per hour; Kohlrausch's +value is 4.0824, a value hitherto accepted universally. This value is +so useful in measuring electric currents with accuracy, and free from +the disturbances of magnetism, etc., that it is eminently satisfactory +to find the German value agree with that of Lord Rayleigh, which will +probably be adopted by English electricians. + + * * * * * + + + + +A NEW STANDARD LIGHT. + + +Herr Hefner-Alteneck has suggested a new standard light for +photometric purposes, which promises to be very simple and effective +in operation. The light is produced by an open flame of amyl-acetate +burning from a wick of cotton fiber which fills a tube of German +silver 1 in. long and 316 mils. internal diameter; the external +diameter being 324 mils. The flame is 1.58 in. high from top to +bottom; and it should be lighted at least ten minutes before using the +light for testing. A cylindrical glass chimney surrounds it to ward +off air currents. About 2 per cent. of the light is absorbed by the +glass. The power of the flame is that of a standard English candle; +and experiments have shown that amyl acetate, which besides is not +expensive, is the best fuel for steadiness and brilliance. Neither the +substitution of commercial amyl-acetate for pure nor the use of a wick +of cotton thread for loose cotton fiber alters the illuminating power; +but the wick should be trimmed square across the mouth of the tube, +for if it project and droop the illuminating power is increased. + + * * * * * + +[NATURE.] + + + + +DR. FEUSSNER'S NEW POLARIZING PRISM. + + +In a recent number of the _Zeitschrift fur Instrumentenkunde_ (iv., +42-50, February, 1884), Dr. K. Feussner of Karlsruhe has given a +detailed description of a polarizing prism lately devised by him, +which presents several points of novelty, and for which certain +advantages are claimed. The paper also contains an account, although +not an exhaustive one, of the various polarizing prisms which have +from time to time been constructed by means of different combinations +of Iceland spar. The literature of this subject is scattered and +somewhat difficult of access, and moreover only a small part of it has +hitherto been translated into English; and it would appear therefore +that a brief abstract of the paper may not be without service to those +among the readers of _Nature_ who may be unacquainted with the +original memoirs, or who may not have the necessary references at +hand. + +Following the order adopted by Dr. Feussner, the subject may be +divided into two parts: + + +I.--OLDER FORMS OF POLARIZING PRISMS. + +In comparing the various forms of polarizing prisms, the main points +which need attention are--the angular extent of the field of view, the +direction of the emergent polarized ray, whether it is shifted to one +side of, or remains symmetrical to the long axis of the prism; the +proportion which the length of the prism bears to its breadth; and +lastly, the position of the terminal faces, whether perpendicular or +inclined to the long axis. These requirements are fulfilled in +different degrees by the following methods of construction: + +[Illustration: Fig. 1., Fig. 2., and Fig. 3.] + +1. _The Nicol Prism_ (_Edin. New Phil. Journal_, 1828, vi., 83).--This +(Fig. 1), as is well known, is constructed from a rhombohedron of +Iceland spar, the length of which must be fully three times as great +as the width. The end faces are cut off in such a manner that the +angle of 72° which they originally form with the lateral edge of the +rhombohedron is reduced to 68°. The prism is then cut in two in a +plane perpendicular to the new end surfaces, the section being carried +obliquely from one obtuse corner of the prism to the other, in the +direction of its length. The surfaces of this section, after having +been carefully polished, are cemented together again by means of +Canada balsam. A ray of light, on entering the prism, is separated by +the double refraction of the calc-spar into an ordinary and an +extraordinary ray; the former undergoes total reflection at the layer +of balsam at an incidence which allows the extraordinary ray to be +transmitted; the latter, therefore, passes through unchanged. This +principle of obtaining a single polarized ray by means of total +reflection of the other is common to all the forms of prism now to be +described. + +Dr. Feussner gives a mathematical analysis of the paths taken by the +two polarized rays within the Nicol prism, and finds that the emergent +extraordinary ray can include an angular field of 29°, but that this +extreme value holds good only for rays incident upon that portion of +the end surface which is near to the obtuse corner, and that from +thence it gradually decreases until the field includes an angle of +only about half the previous amount. He finds, moreover, that, +although of course the ray emerges parallel to its direction of +incidence, yet that the zone of polarized light is shifted to one side +of the central line. Also that the great length of the Nicol--3.28 +times its breadth--is not only an inconvenience, but owing to the +large pieces of spar thus required for its construction, prisms of any +but small size become very expensive. To this it may be added that +there is a considerable loss of light by reflection from the first +surface, owing to its inclined position in regard to the long axis of +the prism. + +[Illustration: Fig. 4., Fig. 5., and Fig. 6.] + +It is with the view of obviating these defects that the modifications +represented in Figs. 2 to 6 have been devised. + +2. _The Shortened Nicol Prism_.--This arrangement of the Nicol prism +is constructed by Dr. Steeg and Reuter of Homburg v.d.H. For the sake +of facility of manufacture, the end surfaces are cleavage planes, and +the oblique cut, instead of being perpendicular, makes with these an +angle of about 84°. By this alteration the prism becomes shorter, and +is now only 2.83 times its breadth; but if Canada balsam is still used +as the cement, the field will occupy a very unsymmetrical position in +regard to the long axis. If balsam of copaiba is made use of, the +index of refraction of which is 1.50, a symmetrical field of about 24° +will be obtained. A prism of this kind has also been designed by Prof. +B. Hasert of Eisenach (_Pogg. Ann._, cxiii., 189), but its performance +appears to be inferior to the above. + +3. _The Nicol Prism with Perpendicular Ends._--The terminal surfaces +in this prism are perpendicular to the long axis, and the sectional +cut makes with them an angle of about 75°. The length of the prism is +3.75 times its breadth, and if the cement has an index of refraction +of 1.525, the field is symmetrically disposed, and includes an angle +of 27°. Prisms of this kind have been manufactured by Dr. Steeg, Mr. +C.D. Ahrens, and others. + +4. _The Foucault Prism_ (_Comptes Rendus_, 1857, xlv., 238).--This +construction differs from all those hitherto mentioned, in that a film +of air is employed between the two cut surfaces as the totally +reflecting medium instead of a layer of cement. The two halves of the +prism are kept in position, without touching each other, by means of +the mounting. The length of the prism is in this way much reduced, and +amounts to only 1.528 times its breadth. The end surfaces are cleavage +planes, and the sectional cut makes with them an angle of 59°. The +field, however, includes not more than about 8°, so that this prism +can be used only in the case of nearly parallel rays; and in addition +to this the pictures which may be seen through it are to some extent +veiled and indistinct, owing to repeated internal reflection. + +5. _The Hartnack Prism_ (_Ann. de Ch. et de Physique_, ser. iv., vii., +181).--This form of prism was devised in 1866 by MM. Hartnack and +Prazmowiski; the original memoir is a valuable one; a translation of +it, with some additions, has lately been published (_Journ. of the R. +Microscopical Soc._, June, 1883, 428). It is considered by Dr. +Feussner to be the most perfect prism capable of being prepared from +calc-spar. The ends of the prism are perpendicular to its length; the +section carried through it is in a plane perpendicular to the +principal axis of the crystal. The cementing medium is linseed oil, +the index of refraction of which is 1.485. This form of prism is +certainly not so well known in this country as it deserves to be; a +very excellent one, supplied to the present writer by Dr. Steeg is of +rectangular form throughout, the terminal surfaces are 19 Ũ 15 mm., +and the length 41 mm. The lateral shifting of the field is scarcely +perceptible, the prism is perfectly colorless and transparent, and its +performance is far superior to that of the ordinary Nicol. The field +of view afforded by this construction depends upon the cementing +substance used, and also upon the inclination of the sectional cut in +regard to the end of the prism; it may vary from 20° to 41°. If the +utmost extent of field is not required, the prism may be shortened by +lessening the angle of the section, at the expense, however, of +interfering with the symmetrical disposition of the field. + +6. _The Glan Prism_ (Carl's "Repertorium," xvi., 570, and xvii., +195).--This is a modification of the Foucault, and in a similar manner +includes a film of air between the sectional surfaces. The end +surfaces and also the cut carried through the prism are parallel to +the principal axis of the calc-spar. The ends are normal to the +length, and the field includes about 8°. This prism is very short, and +may indeed be even shorter than it is broad. It is subject to the same +defect as that mentioned in the case of the Foucault, although perhaps +not quite to the same extent. + + +II.--THE NEW POLARIZING PRISM. + +This prism differs very considerably from the preceding forms, and +consists of a thin plate of a doubly refracting crystal cemented +between two wedge-shaped pieces of glass, the terminal faces of which +are normal to the length. The external form of the prism may thus be +similar to the Hartnack, the calc-spar being replaced by glass. The +indices of refraction of the glass and of the cementing medium should +correspond with the greater index of refraction of the crystal, and +the directions of greatest and least elasticity in the latter must +stand in a plane perpendicular to the direction of the section. One of +the advantages claimed for the new prism is that, it dispenses with +the large and valuable pieces of spar hitherto found necessary; a +further advantage being that other crystalline substances may be used +in this prism instead of calc-spar. The latter advantage, however, +occurs only when the difference between the indices of refraction for +the ordinary and extraordinary rays in the particular crystal made use +of is greater than in calc-spar. When this is the case, the field +becomes enlarged, and the length of the prism is reduced. + +[Illustration: Fig. 7.] + +The substance which Dr. Feussner has employed as being most suitable +for the separating crystal plate is nitrate of soda (_natronsalpeter_), +in which the above-mentioned values are [omega] = 1.587 and [eta] = +1.336. It crystallizes in similar form to calcite, and in both cases +thin plates obtained by cleavage may be used. + +As the cementing substance for the nitrate of soda, a mixture of gum +dammar with monobromonaphthalene was used, which afforded an index of +refraction of 1.58. In the case of thin plates of calcite, a solid +cementing substance of sufficiently high refractive power was not +available, and a fluid medium was therefore employed. For this purpose +the whole prism was inclosed in a short glass tube with airtight ends, +which was filled with monobromonaphthalene. In an experimental prism a +mixture of balsam of tolu was made use of, giving a cement with an +index of refraction of 1.62, but the low refractive power resulted in +a very considerable reduction of the field. The extent and disposition +of the field may be varied by altering the inclination at which the +crystal lamina is inserted (Fig. 7), and thereby reducing the length +of the prism, as in the case of the Hartnack. + +In order to obviate the effects of reflection from the internal side +surfaces if the prism, the wedge-shaped blocks of glass of which it is +built up may be made much broader than would otherwise be necessary; +the edges of this extra width are cut obliquely and suitably +blackened. + +The accompanying diagram (Fig. 8) represents a prism of cylindrical +external form constructed in this manner, the lower surface being that +of the incident light. In this the field amounts to 30°, and the +breadth is about double the length. + +[Illustration: Fig. 8.] + +Dr. Feussner remarks that a prism similar in some respects to his new +arrangement was devised in 1869 by M. Jamin (_Comptes Rendus_, +lxviii., 221), who used a thin plate of calc-spar inclosed in a cell +filled with bisulphide of carbon; and also by Dr. Zenker, who replaced +the liquid in M. Jamin's construction by wedges of flint glass. + +Among others, the carefully considered modifications of the Nicol +prism which have recently been devised by Prof. S.P. Thompson (_Phil. +Mag._, November, 1881, 349, and _Jour. R. Micros. Soc._, August, 1883, +575), and by Mr. R.T. Glazebrook (_Phil. Mag._, May, 1883, 352), do +not appear to have been known to Dr. Feussner. + +The following tabular view of different forms of polarizing prisms is +taken from the conclusion of Dr. Feussner's paper: + + ---------------------------------------+------+---------+------+------ + | |Inclina- |Ratio | + | |tion of | of | + | |section |length| + | |in regard| to | + | |to long |clear | + |Field.|axis. |width.|Fig. + ---------------------------------------+------+---------+------+------ + I. THE OLD POLARISING PRISMS. | ° | ° | | + 1. Nicol's prism. | 29 | 22 | 3.28 | 1 + 2. Shortened Nicol prism-- | | | | + a. Cemented with Canada balsam.| 13 | 25 | 2.83 | 2 + b. Cemented with copaiba " | 24 | 25 | 2.83 | 2 + 3. Nicol with perpendicular ends-- | | | | + a. With Canada balsam. | 20 | 15 | 3.73 | 3 + b. With cement of index of | | | | + refraction of 1.525. | 27 | 15 | 3.73 | 3 + 4. Foucault's prism. | 8 | 40 | 1.528| 4 + 5. Hartnack's prism-- | | | | + a. Original form. | 35 | 15.9 | 3.51 |5 _a b_ + b. With largest field. | 41.9 | 13.9 | 4.04 |5 _a a_ + c. With field of 30°. | 30 | 17.4 | 3.19 |5 _a c_ + d. With field of 20°. | 20 | 20.3 | 2.70 |5 _a d_ + 6. Glan's prism. | 7.9 | 50.3 | 0.831| 6 + | | | | + II. THE NEW POLARISING PRISM. | | | | + 1. With calc-spar: largest field. | 44 | 13.2 | 4.26 |5 _a a_ + 2. " field of 30°. | 30 | 17.4 | 3.19 |5 _a c_ + 3. " field of 20°. | 20 | 20.3 | 2.70 |5 _a d_ + 4. With nitrate of soda: | | | | + " largest field. | 54 | 16.7 | 3.53 |7 _a a_ + 5. " field of 30°. | 30 | 24 | 2.25 |7 _a b_ + 6. " field of 20°. | 20 | 27 | 1.96 |7 _a c_ + ---------------------------------------+------+---------+------+------ + +As an analyzing prism of about 6 mm. clear width, and 13.5 mm. long, +the new prism is stated by its inventor to be of the most essential +service, and it would certainly appear that the arrangement is rather +better adapted for small prisms than for those of considerable size. +Any means by which a beam of polarized light of large diameter--say 3 +to 3― inches--could be obtained with all the convenience of a Nicol +would be a real advance, for spar of sufficient size and purity for +such a purpose has become so scarce and therefore so valuable that +large prisms are difficult to procure at all. So far as an analyzer is +concerned, the experience of the writer of this notice would lead to +the opinion that improvements are to be looked for rather in the way +of the discovery of an artificial crystal which absorbs one of the +polarized rays than by further modifications depending upon total +reflection. The researches of Dr. Herapath on iodosulphate of quinine +(_Phil. Mag._, March, 1852, 161, and November, 1853, 346) are in this +direction; but crystals of the so-called herapathite require great +manipulative skill for their production. If these could be readily +obtained of sufficient size, they would be invaluable as analyzers. + +This opinion is supported by the existence of an inconvenience which +attends every form of analyzing prism. It is frequently, and +especially in projecting apparatus, required to be placed at the focus +of a system of lenses, so that the rays may cross in the interior of +the prism. This is an unfavorable position for a prismatic analyzer, +and in the case of a powerful beam of light, such as that from the +electric arc, the crossing of the rays within the prism is not +unattended with danger to the cementing substance, and to the surfaces +in contact with it. + +PHILIP R. SLEEMAN. + + * * * * * + + + + +ZIRCON. + +By F. STOLBA. + + +Finely ground zircon is quickly rendered soluble if fused with a +mixture of potassium borofluoride and potassium carbonate. The author +takes two parts of the former to three of the latter, and prepares an +intimate, finely divided mixture, which is kept ready for use. + +Of this mixture four parts are taken to one of zircon, thoroughly +mixed, and melted in a platinum crucible at a red heat. The mass fuses +readily, froths at first and gives off bubbles of gas, and flows then +quietly, forming a very fluid melt. If the zircon is finely ground, 15 +minutes are sufficient for this operation. The loss of weight is 16 +per cent., and is not notably increased on prolonged fusion. It +corresponds approximately to the weight of the carbonic anhydride +present in the potassium carbonate. + +As pungent vapors are given off during fusion, the operation should be +conducted under a draught hood. The activity of the mixture in +attacking zircon appears from the following experiment: Two zircon +crystals, each weighing ― grm., were introduced into the melted +mixture and subjected to prolonged heat. In a short time they +decreased perceptibly in size; each of them broke up into two +fragments, and within an hour they were entirely dissolved. The melted +mass is poured upon a dry metal plate, and when congealed is thrown +into water. It is at once intersected with a number of fissures, which +facilitate pulverization. This process is the more necessary as the +unbroken mass is very slowly attacked by water even on prolonged +boiling. The powder is boiled in a large quantity of water so as to +remove everything soluble. There is obtained a faintly alkaline +solution and a sediment insoluble in water. From the filtrate alkalies +throw down zirconium hydroxide, free from iron. + +The portion insoluble in water is readily dissolved in hydrofluoric +acid, and is converted into zircon potassium fluoride. The chief bulk +of the zirconium is found in the aqueous solution in the state of +double fluorides. The platinum crucible is not in the least attacked +during melting. On the contrary, dirty platinum crucibles may be +advantageously cleaned by melting in them a little of the above +mentioned mixture. + +If finely divided zircon is boiled for a long time with caustic lye, +it is perceptibly attacked. It is very probable that in this manner +zircon might be entirely dissolved under a pressure of 10 atmospheres. + +Potassium borofluoride may be readily prepared from cryolite. +Crucibles of nickel seem especially well adapted for the fusion of +zircon in caustic alkalies.--_Ber. Boehm. Gesell. Wissenschaft; +Chem. News_. + + * * * * * + + + + +A PROCESS FOR MAKING WROUGHT IRON DIRECT FROM THE ORE.[1] + + [Footnote 1: A paper read at the Cincinnati Meeting of the + American Institute of Mining Engineers, by Willard P. Ward, A.M., + M.E., February, 1884.] + + +The numerous direct processes which have been patented and brought +before the iron masters of the world, differ materially from that now +introduced by Mr. Wilson. After a careful examination of his process, +I am convinced that Mr. Wilson has succeeded in producing good blooms +from iron ore, and I think that I am able to point out theoretically +the chief reasons of the success of his method. + +Without going deeply into the history of the metal, I may mention the +well known fact that wrought iron was extensively used in almost all +quarters of the globe, before pig or cast iron was ever produced. +Without entering into the details of the processes by which this +wrought iron was made, it suffices for my present purpose to say that +they were crude, wasteful, and expensive, so that they can be employed +to-day only in a very few localities favored with good and cheap ore, +fuel, and labor. + +The construction of larger furnaces and the employment of higher +temperatures led to the production of a highly carbonized, fusible +metal, without any special design on the part of the manufacturers in +producing it. This pig iron, however, could be used only for a few +purposes for which metallic iron was needed; but it was produced +cheaply and with little loss of metal, and the attempt to decarbonize +this product and bring it into a state in which it could be hammered +and welded was soon successfully made. This process of decarbonization, +or some modification of it, has successfully held the field against +all so-called, direct processes up to the present time. Why? Because +the old fashioned bloomeries and Catalan forges could produce blooms +only at a high cost, and because the new processes introduced failed +to turn out good blooms. Those produced were invariably "red short," +that is, they contained unreduced oxide of iron, which prevented the +contact of the metallic particles, and rendered the welding together +of these particles to form a solid bloom impossible. + +The process of puddling cast iron, and transforming it by +decarbonization into wrought iron, has, as everybody knows, been in +successful practical operation for many years, and the direct process +referred to so closely resembles this, that a short description of the +theory of puddling is not out of place here. + +The material operated on in puddling is iron containing from 2― to 4 +per cent. of carbon. During the first stage of the process this iron +is melted down to a fluid bath in the bottom of a reverberatory +furnace. Then the oxidation of the carbon contained in the iron +commences, and at the same time a fluid, basic cinder, or slag, is +produced, which covers a portion of the surface of the metal bath, and +prevents too hasty oxidation. This slag results from the union of +oxides of iron with the sand adhering to the pigs, and the silica +resulting from the oxidation of the silicon contained in the iron. + +This cinder now plays a very important part in the process. It takes +up the oxides of iron formed by the contact of the oxidizing flame +with the exposed portion of the metal bath, and at the same time the +carbon of the iron, coming in contact with the under surface of the +cinder covering, where it is protected from oxidizing influences, +reduces these oxides from the cinder and restores them to the bath in +metallic form. This alternate oxidation of exposed metal, and its +reduction by the carbon of the cast iron, continues till the carbon is +nearly exhausted, when the iron assumes a pasty condition, or "comes +to nature," as the puddlers call this change. The charge is then +worked up into balls, and removed for treatment in the squeezer, and +then hammered or rolled. In the Wilson process the conditions which we +have noted in the puddling operation are very closely approximated. +Iron ore reduced to a coarse sand is mixed with the proper proportion +of charcoal or coke dust, and the mixture fed into upright retorts +placed in the chimney of the puddling furnace. By exposure for 24 +hours to the heat of the waste gases from the furnace, in the presence +of solid carbon, a considerable portion of the oxygen of the ore is +removed, but little or no metallic iron is formed. The ore is then +drawn from the deoxidizer into the rear or second hearth of the +puddling furnace, situated below it, where it is exposed for 20 +minutes to a much higher temperature than that of the deoxidizer. Here +the presence of the solid carbon, mixed with the ore, prevents any +oxidizing action, and the temperature of the mass is raised to a point +at which the cinder begins to form. Then the charge is carried forward +by the workmen to the front hearth, in which the temperature of a +puddling furnace prevails. Here the cinder melts, and at the same +time the solid carbon reacts on the oxygen remaining combined with the +ore, and forms metallic iron; but by this time the molten cinder is +present to prevent undue oxidation of the metal formed, and solid +carbon is still present in the mixture to play the same role, of +reducing protoxide of iron from the cinder, as the carbon of the cast +iron does in the ordinary puddling process. I have said that the cast +iron used as the material for puddling contains about 3 per cent. of +carbon; but in this process sufficient carbon is added to effect the +reduction of the ore to a metallic state, and leave enough in the mass +to play the part of the carbon of the cast iron when the metallic +stage has been reached. + +It would be interesting to compare the Wilson with the numerous other +direct processes to which allusion has already been made, but there +have been so many of them, and the data concerning them are so +incomplete, that this is impossible. Two processes, however, the Blair +and the Siemens, have attracted sufficient attention, and are +sufficiently modern to deserve notice. In the Blair process a metallic +iron sponge was made from the ore in a closed retort, this sponge +cooled down in receptacles from which the air was excluded, to the +temperature of the atmosphere, then charged into a puddling furnace +and heated for working. In this way (and the same plan essentially has +been followed by other inventors), the metallic iron, in the finest +possible state of subdivision, is subjected to the more or less +oxidizing influences of the flame, without liquid slag to save it from +oxidation, and with no carbon present to again reduce the iron oxides +from the cinder after it is formed. The loss of metal is consequently +very large, but oxides of iron being left in the metal the blooms are +invariably "red short." + +In the Siemens process pieces of ore of the size of beans or peas, +mixed with lime or other fluxing material, form the charge, which is +introduced into a rotating furnace; and when this charge has become +heated to a bright-red heat, small coal of uniform size is added in +sufficient quantity to effect the reduction of the ore. + +The size of the pieces of the material employed prevents the intimate +mixture of the particles of iron with the particles of carbon, and +hence we would, on theoretical grounds, anticipate just what practice +has proved, viz., that the reduction is incomplete, and the resulting +metal being charged with oxides is red-short. In practice, blooms made +by this process have been so red-short that they could not be hammered +at all. + +It would be impracticable in this process to employ ore and carbon in +as fine particles as Wilson does, as a very large portion of the +charge would be carried off by the draught, and a sticking of the +material to the sides of the rotating furnace could scarcely be +avoided. I do not imagine that a division of the material into +anything like the supposed size of molecules is necessary; we know +that the graphitic carbon in the pig-iron employed in puddling is not +so finely divided, but it is much smaller particles than bean or pea +size, and by approximating the size of the graphite particles in pig +iron, Wilson has succeeded in obtaining good results. + +If we examine the utilization of the heat developed by the combustion +of a given quantity of coal in this process, and compare it with the +result of the combustion of an equivalent amount of fuel in a blast +furnace, we shall soon see the theoretical economy of the process. The +coal is burned on the grate of the puddling-furnace, to carbonic acid, +and the flame is more fully utilized than in an ordinary +puddling-furnace, for besides the ordinary hearth there is the second +or rear hearth, where additional heat is taken up, and then the +products of combustion are further utilized in heating the retorts in +which the ore is partly reduced. After this the heat is still further +utilized by passing it under the boilers for the generation of steam, +and the heat lost in the gases, when they finally escape, is very +small. In a blast furnace the carbon is at first burned only to +carbonic oxide, and the products of combustion issue mainly in this +form from the top of the furnace. Then a portion of the heat resulting +from the subsequent burning of these gases is pretty well utilized in +making steam to supply the power required about the works, but the +rest of the gas can only be utilized for heating the blast, and here +there is an enormous waste, the amount of heat returned to the furnace +by the heated blast being very small in proportion to the amount +generated by the burning of that portion of carbonic oxide expended in +heating it, and the gases escape from both the hot-blast and the +boilers at a high temperature. + +In the direct process under consideration the fuel burned is more +completely utilized than in the puddling process, to which the cast +iron from the blast furnace is subjected to convert it into wrought +iron. + +The economy claimed for this process, over the blast furnace and +puddling practice for the production of wrought iron, is that nearly +all the fuel used in the puddling operation is saved, and that with +about the same amount of fuel used in the blast furnace to produce a +ton of pig iron, a ton of wrought iron blooms can be made. I had no +opportunity of weighing the charges of ore and coal used, but I saw +the process in actual operation at Rockaway, N.J. The iron produced +was hammered up into good solid blooms, containing but little cinder. +The muck-bar made from the blooms was fibrous in fracture, and showed +every appearance of good iron. I am informed by the manager of the +Sanderson Brothers' steel works, at Syracuse, N.Y., that they +purchased blooms made by the Wilson process in 1881-1882, that _none_ +of them showed red-shortness, and that they discontinued their use +only on account of the injurious action of the titanium they contained +on the melting pots. These blooms were made from magnetic sands from +the Long Island and Connecticut coasts. + +[Illustration: NEW PROCESS FOR MAKING WROUGHT IRON FROM THE ORE.] + +The drawing given shows the construction of the furnace employed. I +quote from the published description: + + "The upper part, or deoxidizer, is supported on a strong + mantel plate resting on four cast iron columns. + + "The retorts and flues are made entirely of fire-brick, from + special patterns. The outside is protected by a wrought iron + jacket made of No. 14 iron. The puddling furnace is of the + ordinary construction, except in the working bottom, which is + made longer to accommodate two charges of ore, and thus + utilize more of the waste heat in reducing the ore to metallic + iron. + + "The operation of the furnace is as follows: The pulverized + ore is mixed with 20 per cent. of pulverized charcoal or coke, + and is fed into an elevator which discharges into the hopper + on the deoxidizer leading into the retorts marked C. These + retorts are proportioned so that they will hold ore enough to + run the puddling furnace 24 hours, the time required for + perfect deoxidation. After the retorts are filled, a fire is + started in the furnace, and the products of combustion pass up + through the main flue, or well, B, where they are deflected by + the arch, and pass out through suitable openings, as indicated + by arrows, into the down-takes marked E, and out through an + annular flue, where they are passed under a boiler. + + "It will be noticed that the ore is exposed to the waste heat + on three sides of the retorts, and owing to the great surface + so exposed, the ore is very thoroughly deoxidized, and reduced + in the retorts before it is introduced into the puddling + furnace for final reduction. The curved cast iron pipes marked + D are provided with slides, and are for the purpose of + introducing the deoxidized ore into the second bottom of the + furnace. As before stated, the furnace is intended to + accommodate two charges of ore, and as fast as it is balled up + and taken out of the working bottom, the charge remaining in + the second bottom is worked up in the place occupied by the + first charge, and a _new_ charge is introduced. As fast as the + ore is drawn out from the retorts the elevator supplies a new + lot, so that the retorts are always filled, thus making the + process continuous." + +The temperature of the charge in the deoxidizer is from 800° to 1,000° +F.--_Amer. Engineer._ + + * * * * * + + + + +SOME REMARKS ON THE DETERMINATION OF HARDNESS IN WATERS. + +By HERBERT JACKSON. + + +Having had occasion some short time ago to examine a hard water which +owed half its hardness to salts of magnesium, I noticed that the soap +test, applied in the usual way, gave a result which differed very much +from that obtained by the quantitative estimation of calcium and +magnesium. A perfectly normal lather was obtained when soap had been +added in quantities sufficient to neutralize 14° of hardness, whereas +the water contained salts of calcium and magnesium equivalent, on +Clark's scale, to a hardness of 27°. + +Although I was aware that similar observations had been made before, I +thought that it might be useful to determine the conditions under +which the soap test could not be depended upon for reliable results. + +I found with waters containing calcium or magnesium alone that, +whenever salts of either of these metals were in solution in +quantities sufficient to give 23° of hardness on Clark's scale, no +dependence could be placed upon the results given by the soap test. In +the case of waters containing salts of both calcium and magnesium, I +found that if the salts of the latter metal were in solution in +quantities sufficient to give more than 10° of hardness, no evidence +could be obtained of their presence so long as the salts of calcium in +the same water exceeded 6°; in such a case a perfect and permanent +lather was produced when soap had been added equivalent to 7° of +hardness. + +If any water be diluted so as to reduce the proportions of the salts +of calcium and magnesium below those stated above, perfectly reliable +results will of course be obtained. + +Instead of dilution I found that heating the water to about 70° C. was +sufficient to cause a complete reaction between the soap and the salts +of calcium and magnesium, even if these were present in far larger +quantities than any given here. + +The experiments so far had all been made with a solution of Castile +soap of the strength suggested by Mr. Wanklyn in his book on "Water +Analysis." My attention was next directed to the use of any one of the +compounds of which such a soap is composed. I commenced with sodium +oleate, and found that by employing this substance in a moderately +pure condition, perfectly reliable results could be obtained in very +hard waters without the trouble of either diluting or heating. I was +unable to try sodium stearate directly because of the slight +solubility of this substance in cold water or dilute alcohol; but I +found that a mixture of sodium oleate and stearate behaved in exactly +the same manner as the Castile soap. + +I am not prepared at present to state the exact reaction which takes +place between salts of calcium and magnesium and a compound soap +containing sodium oleate and stearate. I publish these results because +I have not noticed anywhere the fact that some waters show a greater +hardness with soap when their temperatures approach the boiling point +than they do at the average temperature of the air, it being, I +believe, the ordinary impression that cold water wastes more soap than +hot water before a good and useful lather can be obtained, whereas +with very many waters the case is quite the reverse. Neither am I +aware at present whether it is well known that the use of sodium +oleate unmixed with sodium stearate dispenses with the process of +dilution even in very hard waters.--_Chem. News._ + + * * * * * + + + + +THE DENSITY AND PRESSURE OF DETONATING GAS MIXTURES. + + +MM. Berthelot and Vielle have recently been studying the influence of +the density of detonating gaseous mixtures upon the pressure +developed. The measure of pressure developed by the same gaseous +system, taken under two initial states of different density to which +the same quantity of heat is communicated, is an important matter in +thermodynamics. If the pressures vary in the same ratio as the +densities, we may conclude, independently of all special hypotheses on +the laws of gases, first, that the specific heat of the system is +independent of its density (that is to say, of its initial pressure), +and depends only on the absolute temperature, whatever that may mean; +and secondly, that the relative variation of the pressure at constant +volume, produced by the introduction of a determinate quantity of +heat, is also independent of the pressure, and a function only of the +temperature. Lastly, the pressure itself will vary proportionally with +the absolute temperature, as defined by the theory of a perfect gas, +and will serve to determine it. MM. Berthelot and Vielle operated with +a bomb, at first kept at ordinary temperatures in the air, and +afterward heated in an oil bath to 153 deg. Cent. They also employed +isomeric mixtures of the gases; methylic ether, cyanogen, hydrogen, +acetylene, and other gases were experimented upon, and the general +conclusions are as follows: 1. The same quantity of heat being +furnished to a gaseous system, the pressure of the system varies +proportionally to the density of the system. 2. The specific heat of +the gas is sensibly independent of the density as well toward very +high temperatures as about deg. Cent. This is all true for densities +near to those that the gas possesses cold under normal pressure, and +which varied in the experiment to double the original value. 3. The +pressure increases with the quantity of heat furnished to the same +system. 4. The apparent specific heat increases parallel with this +quantity of heat. These conclusions are independent of all hypotheses +on the nature and laws of gases, and were simply drawn from the +experiments in question. + + * * * * * + + + + +TURKISH BATHS FOR HORSES. + + +The Turkish bath has become an established institution in this +country; men of all classes now use it for sanitary as well as +remedial purposes. Athletes of various descriptions find it invaluable +in "training," and all the distinguished jockeys and light weights +keep themselves in condition by its use. + +It was thought probable that what was good for man might also be good +for the horse, and the fact has been proved. Messrs. Pickford, the +eminent carriers, in their hospital for horses at Finchley, have had a +bath in operation over eleven years, and find the horses derive great +benefit from its use. The bath is put in operation three days a week, +and is administered to over twenty horses in this time. The value of +the bath having been thus proved, it is rather strange that it has not +been more generally adopted by the large carrying firms. However, the +Great Northern Railway Company at their new hospital for horses at +Totteridge, are erecting a very complete Turkish bath. It consists of +three rooms. First, a large wash room or grooming room, from which is +entered the first hot room, or tepidarium, from 140° to 150° Fahr.; +from this room, the horse, after being thoroughly acclimated, can, if +necessary, pass to the hottest room, or calidarium, from 160° to 170° +Fahr., and without any turning round can pass on into the grooming and +washing room again. This last room is slightly heated from the two +other rooms, and in each are stocks in which the animal can he +fastened if required. The heating is done most economically by +Constantine's convoluted stove, and thorough ventilation is secured +from the large volume of hot air constantly supplied, which passes +through the baths, and as it becomes vitiated is drawn off by +specially designed outlets. The wash room is supplied with hot and +cold water, which can, of course, be mixed to any required +temperature.--_Building News._ + +[Illustration] + + || + |+-------------------------------------------------------+ + |+-------------------++---__-------____------------__---+| + || ||FOUL AIR FOUL AIR FOUL AIR|| + || || || + || || || + || || ============== || + || / / || + || / / 1ST HOT ROOM || + || / / || + || / / ============== || + || || || + / =======+ || || + / || || CURTAIN|| + WASHING ROOM|| |+=========================== =|| + \ || || || + \ =======+ || || + || || || + || \ \ ============== || + || \ \ || + || \ \ 2ND HOT ROOM || FRESH + || \ \ || / AIR + || || ============== ||== + || || +======|| | + || || | WARM || | + || ||FOUL AIR FOUL AIR| AIR || | + |+-------------------++---__--+===+---------__----------+|== + |+----------------------------|_|_|---------------------+| + || | ||||| | || + || | ||||| | || + || |============ S T O K E R Y || + || || || + || || || + || |+-----------------------------------|| + +-------------------------------------+ + + + * * * * * + + + + +MIRYACHIT, A NEWLY DESCRIBED DISEASE OF THE NERVOUS SYSTEM, AND +ITS ANALOGUES.[1] + + [Footnote 1: Read before the New York Neurological Society, + February 5, 1884.] + +By WILLIAM A. HAMMOND, M.D., Surgeon-General, U.S. Army (Retired +List); Professor of Diseases of the Mind and Nervous System in the New +York Post-Graduate Medical School and Hospital. + + +In a very interesting account of a journey from the Pacific Ocean +through Asia to the United States, by Lieutenant B.H. Buckingham and +Ensigns George C. Foulk and Walter McLean,[2] United States navy, I +find an affection of the nervous system described which, on account of +its remarkable characteristics, as well as by reason of certain known +analogies, I think should be brought to the special notice of the +medical profession. I quote from the work referred to, the following +account of this disease. The party is on the Ussuri River not far from +its junction with the Amur in Eastern Siberia: "While we were walking +on the bank here we observed our messmate, the captain of the general +staff (of the Russian army), approach the steward of the boat +suddenly, and, without any apparent reason or remark, clap his hands +before his face; instantly the steward clapped _his_ hands in the same +manner, put on an angry look, and passed on. The incident was somewhat +curious, as it involved a degree of familiarity with the steward +hardly to have been expected. After this we observed a number of queer +performances of the steward, and finally comprehended the situation. +It seemed that he was afflicted with a peculiar mental or nervous +disease, which forced him to imitate everything suddenly presented to +his senses. Thus, when the captain slapped the paddle-box suddenly in +the presence of the steward, the latter instantly gave it a similar +thump; or, if any noise were made suddenly, he seemed compelled +against his will to imitate it instantly, and with remarkable +accuracy. To annoy him, some of the passengers imitated pigs grunting, +or called out absurd names; others clapped their hands and shouted, +jumped, or threw their hats on the deck suddenly, and the poor +steward, suddenly startled, would echo them all precisely, and +sometimes several consecutively. Frequently he would expostulate, +begging people not to startle him, and again would grow furiously +angry, but even in the midst of his passion he would helplessly +imitate some ridiculous shout or motion directed at him by his +pitiless tormenters. Frequently he shut himself up in his pantry, +which was without windows, and locked the door, but even there he +could be heard answering the grunts, shouts, or pounds on the bulkhead +outside. He was a man of middle age, fair physique, rather intelligent +in facial expression, and without the slightest indication in +appearance of his disability. As we descended the bank to go on board +the steamer, some one gave a loud shout and threw his cap on the +ground; looking about for the steward, for the shout was evidently +made for his benefit, we saw him violently throw his cap, with a +shout, into a chicken-coop, into which he was about to put the result +of his foraging expedition among the houses of the stanitza. + + [Footnote 2: "Observations upon the Korean Coast, Japanese-Korean + Ports, and Siberia, made during a journey from the Asiatic + Station to the United States, through Siberia to Europe, June 3 + to September 8, 1882." Published by the United States Navy + Department, Washington, 1883, pp. 51.] + +"We afterward witnessed an incident which illustrated the extent of +his disability. The captain of the steamer, running up to him, +suddenly clapping his hands at the same time, accidentally slipped and +fell hard on the deck; without having been touched by the captain, the +steward instantly clapped his bands and shouted, and then, in +powerless imitation, he too fell as hard and almost precisely in the +same manner and position as the captain. In speaking of the steward's +disorder, the captain of the general staff stated that it was not +uncommon in Siberia; that he had seen a number of cases of it, and +that it was commonest about Yakutsk, where the winter cold is extreme. +Both sexes were subject to it, but men much less than women. It was +known to Russians by the name of 'miryachit'". + +So far as I am aware--and I have looked carefully through several +books of travel in Siberia--no account of this curious disease has +been hitherto published. + +The description given by the naval officers at once, however, brings +to mind the remarks made by the late Dr. George M. Beard, before the +meeting of the American Neurological Association in 1880, relative to +the "Jumpers" or "Jumping Frenchmen" of Maine and northern New +Hampshire.[3] + + [Footnote 3: "Journal of Nervous and Mental Diseases," vol. vii., + 1880, p. 487.] + +In June, 1880, Dr. Beard visited Moosehead Lake, found the "Jumpers," +and experimented with them. He ascertained that whatever order was +given them was at once obeyed. Thus, one of the jumpers who was +sitting in a chair with a knife in his hand was told to throw it, and +he threw it quickly, so that it stuck in a beam opposite; at the same +time he repeated the order to throw it with a cry of alarm not unlike +that of hysteria or epilepsy. He also threw away his pipe, which he +was filling with tobacco, when he was slapped upon the shoulder. Two +jumpers standing near each other were told to strike, and they struck +each other very forcibly. One jumper, when standing by a window, was +suddenly commanded by a person on the other side of the window to +jump, and he jumped up half a foot from the floor, repeating the +order. When the commands are uttered in a quick, loud voice, the +jumper repeats the order. When told to strike he strikes, when told to +throw he throws whatever he may happen to have in his hand. Dr. Beard +tried this power of repetition with the first part of the first line +of Virgil's "Æneid" and the first part of the first line of Homer's +"Iliad," and out-of-the-way words of the English language with which +the jumper could not be familiar, and he repeated or echoed the sound +of the word as it came to him in a quick, sharp voice, at the same +time he jumped, or struck, or threw, or raised his shoulders, or made +some other violent muscular motion. They could not help repeating the +word or sound that came from the person that ordered them, any more +than they could help striking, dropping, throwing, jumping, or +starting; all of these phenomena were indeed but parts of the general +condition known as jumping. It was not necessary that the sound should +come from a human being; any sudden or unexpected noise, as the +explosion of a gun or pistol, the falling of a window, or the slamming +of a door--provided it was unexpected and loud enough--would cause +these jumpers to exhibit some one or all of these phenomena. One of +these jumpers came very near cutting his throat, while shaving, on +hearing a door slam. They had been known to strike their fists against a +red-hot stove, to jump into the fire and into water. They could not +help striking their best friend if near them when ordered. The noise +of a steam whistle was especially obnoxious to them. One of these +jumpers, when taking some bromide of sodium in a tumbler, was told to +throw it, and he dashed the tumbler upon the floor. It was dangerous +to startle them in any way when they had an ax or an knife in their +hands. All of the jumpers agreed that it tired them to be jumped, and +they dreaded it, but they were constantly annoyed by their companions. + +From this description it will at once, I think, be perceived that +there are striking analogies between "miryachit" and this disorder of +the "Jumping Frenchmen" of Maine. Indeed, it appears to me that, if +the two affections were carefully studied, it would be found that they +were identical, or that, at any rate, the phenomena of the one could +readily be developed into those of the others. It is not stated that +the subjects of miryachit do what they are told to do. They require an +example to reach their brains through the sense of sight or that of +hearing, whereas the "Jumpers" do not apparently perform an act which +is executed before them, but they require a command. It seems, +however, that a "Jumper" starts whenever any sudden noise reaches his +ears. + +In both classes of cases a suggestion of some kind is required, and +then the act takes place independently of the will. There is another +analogous condition known by the Germans as _Schlaftrunkenheit_, and +to English and American neurologists as somnolentia, or +sleep-drunkenness. In this state an individual, on being suddenly +awakened, commits some incongruous act of violence, ofttimes a murder. +Sometimes this appears to be excited by a dream, but in others no such +cause could be discovered. + +Thus, a sentry fell asleep during his watch, and, being suddenly +aroused by the officer in command, attacked the latter with his sword, +and would have killed him but for the interposition of the bystanders. +The result of the medical examination was that the act was +involuntary, being the result of a violent confusion of mind +consequent upon the sudden awaking from a profound sleep. Other cases +are cited by Wharton and Stille in their work on medical +jurisprudence, by Hoffbauer, and by myself in "Sleep and its +Derangements." + +The following cases among others have occurred in my own experience: + +A gentleman was roused one night by his wife, who heard the +street-door bell ring. He got up, and, without paying attention to +what she said, dragged the sheets off of the bed, tore them hurriedly +into strips, and proceeded to tie the pieces together. She finally +succeeded in bringing him to himself, when he said he had thought the +house was on fire, and he was providing means for their escape. He did +not recollect having had any dream of the kind, but was under the +impression that the idea had occurred to him at the instant of his +awaking. + +Another was suddenly aroused from a sound sleep by the slamming of a +window-shutter by the wind. He sprang instantly from his bed, and, +seizing a chair that was near, hurled it with all his strength against +the window. The noise of the breaking of glass fully awakened him. He +explained that he imagined some one was trying to get into the room +and had let his pistol fall on the floor, thereby producing the noise +which had startled him. + +In another case a man dreamed that he heard a voice telling him to +jump out of the window. He at once arose, threw open the sash, and +jumped to the ground below, fortunately only a distance of about ten +feet, so that he was not injured beyond receiving a violent shock. +Such a case as this appears to me to be very similar to those +described by Dr. Beard in all its essential aspects. + +A few years ago I had a gentleman under my charge who would attempt to +execute any order given him while he was asleep by a person +whispering into his ear. Thus, if told in this way to shout, he +shouted as loud as he could; if ordered to get up, he at once jumped +from the bed; if directed to repeat certain words, he said them, and +so on. + +I am not able to give any certain explanation of the phenomena of +miryachit or of the "Jumpers," or of certain of those cases of +sleep-drunkenness which seem to be of like character. But they all +appear to be due to the fact a motor impulse is excited by perceptions +without the necessary concurrence of the volition of the individual to +cause the discharge. They are, therefore, analogous to reflex actions, +and especially to certain epileptic paroxysms due to reflex +irritations. It would seem as though the nerve cells were very much in +the condition of a package of dynamite or nitro glycerin, in which a +very slight impression is sufficient to effect a discharge of nerve +force. They differ, however, from the epileptic paroxysm in the fact +that the discharge is consonant with the perception--which is in these +cases an irritation--and is hence an apparently logical act, whereas +in epilepsy the discharge is more violent, is illogical, and does not +cease with the cessation of the irritation. + +Certainly the whole subject is of sufficient importance to demand the +careful study of competent observers. + + * * * * * + + + + +THE GUM DISEASE IN TREES.[1] + + [Footnote 1: Communicated to the _Medical Times_ by Sir James Paget.] + + +An essay by Dr. Beijerinck, on the contagion of the gum disease in +plants, lately published by the Royal Academy of Sciences at +Amsterdam, contains some useful facts. The gum disease (_gummosis, +gum-flux)_ is only too well known to all who grow peaches, apricots, +plums, cherries, or other stone fruits. A similar disease produces gum +arabic, gum tragacanth, and probably many resins and gum resins. It +shows itself openly in the exudation of thick and sticky or hard and +dry lumps of gum, which cling on branches of any of these trees where +they have been cracked or wounded through the bark. Dr. Beijerinck was +induced to make experimental inoculations of the gum disease by +suspicions that, like some others observed in plants, it was due to +bacteria. He ascertained that it is in a high degree contagious, and +can easily be produced by inserting the gum under the edge of a wound +through the bark of any of the trees above named. The observation that +heated or long boiled pieces of gum lose their contagious property +made it most probable that a living organism was concerned in the +contagions; and he then found that only those pieces of the gum +conveyed contagion in which, whether with or without bacteria, there +were spores of a relatively highly organized fungus, belonging to the +class of Ascomycetes; and that these spores, inserted by themselves +under the bark, produced the same pathological changes as did the +pieces of gum. The fungus thus detected, was examined by Professor +Oudemans, who ascertained it to be a new species of Coryneum, and has +named it _Coryneum Beijerincki_. The inoculation experiments are best +made by means of incisions through the bark of young branches of +healthy peach trees or cherry trees, and by slightly raising the cut +edge of the bark and putting under it little bits of gum from a +diseased tree of the same kind. In nearly every instance these wounds +become the seats of acute gum disease, while similar wounds in the +same or other branches of the same tree, into which no gum is +inserted, remain healthy, unless, by chance, gum be washed into them +during rain. The inoculation fails only when the inserted pieces of +gum contain no Coryneum. By similar inoculations similar diseases can +be produced in plum, almond, and apricot trees, and with the gum of +any one of these trees any other can be infected; but of many other +substances which Beijerinck tried, not one produced any similar +disease. The inoculation with the gum is commonly followed by the +death of more or less of the adjacent structures; first of the bark, +then of the wood. Small branches or leaf stalks thus infected in +winter, or in many places at the same time, may be completely killed; +but, in the more instructive experiments the first symptom of the gum +disease is the appearance of a beautiful red color around the wound. +It comes out in spots like those which often appear spontaneously on +the green young branches of peach trees that have the gum disease; and +in these spots it is usual to find Coryneum stromata or mycelium +filaments. The color is due to the formation of a red pigment in one +or more of the layers of the cells of the bark. But in its further +progress the disease extends beyond the parts at which the Coryneum or +any structures derived from it can be found; and this extension, +Beijerinck believes, is due to the production of a fluid of the nature +of a ferment, produced by the Coryneum, and penetrating the adjacent +structures. This, acting on the cell walls, the starch granules, and +other constituents of the cells, transforms them into gum, and even +changes into gum the Coryneum itself, reminding the observer of the +self-digestion of a stomach. + +In the cells of the cambium, the same fluid penetrating unites with +the protoplasm, and so alters it that the cells produced from it form, +not good normal wood, but a morbid parenchymatous structure. The cells +of this parenchyma, well known among the features of gum disease, are +cubical or polyhedral, thin walled, and rich in protoplasm. This, in +its turn, is transformed into gum, such as fills the gum channels and +other cavities found in wood, and sometimes regarded as gum glands. +And from this also the new ferment fluid constantly produced, and +tracking along the tissues of the branches, conveys the Coryneum +infection beyond the places in which its mycelium can be found. + + * * * * * + + + + +DRINKSTONE PARK. + + +Drinkstone has long been distinguished on account of the successful +cultivation of remarkable plants. It lies some eight miles southeast +from Bury St. Edmund's, and is the seat of T.H. Powell, Esq. The +mansion or hall is a large old-fashioned edifice, a large portion of +its south front being covered by a magnificent specimen of the +Magnolia grandiflora, not less than 40 feet in height, while other +portions of its walls are covered with the finest varieties of +climbing roses and other suitable plants. The surrounding country, +although somewhat flat, is well wooded, and the soil is a rich loam +upon a substratum of gravel, and is consequently admirably suited to +the development of the finer kinds of coniferous and other ornamental +trees and shrubs, so that the park and grounds contain a fine and well +selected assortment of such plants. + +[Illustration: THE SNOWFLAKE, LEUCOJUM VERNUM, AT DRINKSTONE +PARK.] + +Coniferous trees are sometimes considered as out of place in park +scenery; this, however, does not hold good at Drinkstone, where Mr. +Powell has been displayed excellent taste in the way of improving the +landscape and creating a really charming effect by so skillfully +blending the dressed grounds with the rich greensward of the park +that it is not easy to tell where the one terminates or the other +commences. + +The park, which covers some 200 acres, including a fine lake over +eight acres in extent, contains also various large groups or clumps of +such species as the Sequoia gigantea, Taxodium sempervirens, Cedres +deodora, Picea douglasii, Pinsapo, etc., interspersed with groups of +ornamental deciduous trees, producing a warm and very pleasing effect +at all seasons of the year. Among species which are conspicuous in the +grounds are fine, well-grown examples of Araucaria imbricata, some 30 +feet high; Cedrus deodara, 60 feet in height; Abies pinsapo, 40 feet; +and fine specimens of Abies grandis, A. nobilis, and A. nordmanniana, +etc., together with Abies albertiana or mertensiana, a fine, +free-growing species; also Libocedrus gigantea, Thuiopsis borealis, +Thuia lobbii, Juniperus recurva, Taxas adpressa, fine plants; with +fine golden yews and equally fine examples of the various kinds of +variegated hollies, etc. + +[Illustration: ODONTOGLOSSUM ROSSI MAJOR VAR. RUBESCENS, AT DRINKSTONE +PARK.] + +Particular attention is here paid to early spring flowers. Drinkstone +is also celebrated as a fruit growing establishment, more particularly +as regards the grape vine; the weight and quality of the crops of +grapes which are annually produced here are very remarkable.--_The +Gardeners' Chronicle._ + + * * * * * + + + + +ON THE CHANGES WHICH TAKE PLACE IN THE CONVERSION OF HAY INTO +ENSILAGE. + +By FREDK. JAS. LLOYD, F.C.S., Lecturer on Agriculture, King's +College. + + +The recently published number of the _Royal Agricultural Society's +Journal_ contains some information upon the subject of silage which +appears to me of considerable interest to those chemists who are at +present investigating the changes which take place in the conversion +of grass into silage. The data[1] are, so far as I know, unique, and +though the analytical work is not my own, yet it is that of an +agricultural chemist, Mr. A. Smetham, of Liverpool, whose work I know +from personal experience to be thoroughly careful and reliable. I have +therefore no hesitation in basing my remarks upon it. + + [Footnote 1: _Royal Agricultural Society's Journal_, vol. xx., + part i., pp. 175 and 380.] + +We have here for the first time an accurate account of the quantity of +grass put into a silo, of the quantity of silage taken out, and of the +exact composition both of the grass and resulting silage. I desire +merely to place myself in the position of, so to speak, a "chemical +accountant." + +The ensilage has been analyzed at three depths, or rather in three +layers, the first being 1 foot, the second 1 ft. to 1 ft. 6 in., and +the third 1 ft. 6 in. to 2 ft. from the bottom of the silo. By +doubling the figures of the bottom layer analysis, adding these to the +second and third layer analysis, and dividing by 4, we obtain a fair +representation of the average composition of the silage taken +throughout the silo, for by so doing we obtain the average of the +analyses of each 6-inch layer of silage. The results of the analyses +are as follows, calculated on the dry matter. The moisture was +practically the same, being 70.48 per cent, in the grass and 72.97 in +the silage. + + + _Composition of Grass and Silage (dried at 100°C.)._ + + Grass. Ensilage. + Fat (ether extract) 2.80 5.38 + Soluble albuminous compounds 3.06 5.98 + Insoluble albuminous compounds 6.94 3.77 + Mucilage, sugar, and extractives, etc. 11.65 4.98 + Digestible fiber 36.24 33.37 + Indigestible woody fiber 32.33 31.79 + ------- ------- + 93.02 85.27 + Soluble mineral matters 5.24 12.62 + Insoluble mineral matters 1.74 2.11 + ------- ------- + 100.00 100.00 + +The striking difference in the mineral matter of the grass and silage +I will merely draw attention to; it is not due to the salt added to +the silage. I may say, however, that other analysts and I myself have +found similar striking differences. For instance, Prof. Kinch[2] +found in grass 8.50 per cent. mineral matter, in silage 10.10 per +cent., which, as be points out, is equivalent, to a "loss of about 18 +per cent. of combustible constituents"--a loss which we have no proof +of having taken place. In Mr. Smetham's sample the loss would have to +be 50 per cent., which did not occur, and in fact is not possible. +What is the explanation? + + [Footnote 2: _Journ. Chem. Society_, March, 1884, p. 124.] + +I am, however, considering now the organic constituents. Calculating +the percentages of these in the grass and silage, we obtain the +following figures: + + _Percentage Composition of Organic Compounds._ + + Grass. Ensilage. + Fat (ether extract) 3.01 6.31 + Soluble albuminous compounds 8.29} {7.01 + }10.75 11.43{ + Insoluble " " 7.46} {4.42 + + Mucilage, sugar, and extractives 12.52 5.84 + Digestible fiber 38.96 39.14 + Indigestible woody fiber 34.76 37.28 + ------- ------- + 100.00 100.00 + +The difference in the total nitrogen in the grass and silage is equal +to 0.68 per cent. of albuminoids. Practically it is a matter of +impossibility that the nitrogen could have increased in the silo, and +it will be a very safe premise upon which to base any further +calculations that the total amount of nitrogen in the silage was +identical with that in the grass. There may have been a loss, but +that is not yet proved. Arguing then upon the first hypothesis, it is +evident that 100 parts of the organic matters of silage represent more +than 100 parts of the organic matter of grass, and by the equation we +obtain 10.75:11.43 :: 100:106 approximately. If now we calculate the +composition of 106 parts organic matter of grass, it will represent +exactly the organic matter which has gone to form 100 parts of that +present in silage. + +The following table gives these results, and also the loss or gain in +the various constitutents arising from the conversion into silage: + + _Organic Matter_. + + In 106 pts. In 100 pts. Loss or + Grass. Silage. Gain. + +Fat (ether extract) 3.19 6.31 +3.12 +Soluble albuminous compounds 3.49 7.01 +3.52 +Insoluble " " 7.91 4.42 -3.49 +Mucilage 13.27 5.84 -7.43 +Digestible Fiber 41.30 39.14 -2.16 +Indigestible woody fiber 36.84 37.28 +0.44 + ------- ------- + 106.00 100.00 + +These calculations show, provided my reasoning be correct, that the +chief changes which take place are in the albuminous compounds, which +has already been pointed out by Professors Voelcker, Kinch, and +others; and in the starch, gum, mucilage, sugar, and those numerous +bodies termed extractives, which was to be expected. But they show +most conclusively that the "decrease in the amount of indigestible +fiber and increase in digestible" so much spoken of is, so far as our +present very imperfect methods of analyzing these compounds permit us +to judge, a myth; and I have not yet found any sufficient evidence to +support this statement. A loss, then, of 6 parts of organic matter out +of every 106 parts put into the silo has in this instance taken place, +due chiefly to the decomposition of starch, sugar, and mucilage, etc. +And as the grass contained 70 parts of water when put into the silo, +the total loss would only be 1.7 per cent. of the total weight. This +theoretical deduction was found by practical experience correct, for +Mr. Smith, agent to Lord Egerton, upon whose estate this silage was +made, in his report to Mr. Jenkins says the "actual weight out of the +silo corresponds exactly with the weight we put into the same." + +In my judgment these figures are of interest to the agricultural +chemist for many reasons. First, they will clear the ground for future +workers and eliminate from their researches what would have greatly +complicated them--changes in the cellulose bodies. + +Secondly, they are of interest because our present methods of +distinguishing between and estimating digestible and indigestible +fiber is most rough, and probably inaccurate, and may not in the least +represent the power of an animal--say a cow--to digest these various +substances; and most of us know that when a new method of analysis +becomes a necessity, a new method is generally discovered. Lastly, +they are of interest to the agriculturist, for they point out, I +believe for the first time, the exact amount of loss which grass--or +at least one sample--has undergone in conversion into silage, and also +that much of the nitrogenous matter is changed, and so far as we know +at present, lost its nutritive value. This, however, is only comparing +silage with grass. What is wanted is to compare silage with hay--both +made out of the same grass. Then, and then only, will it be possible +to sum up the relative advantages or disadvantages of the two methods +of preserving grass as food for cattle.--_Chem. News_. + + * * * * * + + + + +THE ILLUMINATING POWER OF ETHYLENE. + + +Dr. Percy Frankland has obtained results which may be thus briefly +summarized: (1.) That pure ethylene, when burnt at the rate of 5 cubic +feet per hour from a Referee's Argand burner, emits a light of 68.5 +standard candles. (2.) That the illuminating power of equal volumes of +mixtures of ethylene with either hydrogen carbonic oxide or +marsh-gas is less than that of pure ethylene. (3.) That when the +proportion of ethylene in such mixtures is above 63 per cent. the +illuminating power of the mixture is but slightly affected by the +nature of the diluent. When, on the other hand, the proportion of +ethylene in such mixtures is low, the illuminating power of the +mixture is considerably the highest when marsh-gas is the diluent, and +the lowest when the ethylene is mixed with carbonic oxide. (4.) That +if 5 cubic feet of ethylene be uniformly consumed irrespectively of +the composition of the mixture, the calculated illuminating power is +in every case equal to or actually greater than that of pure ethylene +until a certain degree of dilution is attained. This intrinsic +luminosity of ethylene remains almost constant when the latter is +diluted with carbonic oxide, until the ethylene forms only 40 per +cent. of the mixture, after which it rapidly diminishes to zero when +the ethylene forms only 20 per cent. of the mixture. When the ethylene +is diluted with hydrogen, its intrinsic luminosity rises to 81 candles +when the ethylene constitutes 30 per cent. of the mixture, after which +it rapidly falls to zero when the ethylene amounts to only 10 per +cent. In the case of mixtures of ethylene and marsh-gas, the intrinsic +luminosity of the former is augmented with increasing rapidity as the +proportion of marsh gas rises, the intrinsic luminosity of ethylene, +in a mixture containing 10 per cent. of the latter, being between 170 +and 180 candles. + + * * * * * + + + + +DIFFRACTION PHENOMENA DURING TOTAL SOLAR ECLIPSES.[1] + + [Footnote 1: A paper read before the American Astronomical + Society, May 5, 1884.] + +By G.D. Hiscox. + + +The reality of the sun's corona having been cast in doubt by a leading +observer of the last total eclipse, who, from the erratic display +observed in the spectroscope, has declared it a subjective phenomenon +of diffraction, has led me to an examination and inquiry as to the +bearing of an obscurely considered and heretofore only casually +observed phenomenon seen to take place during total solar eclipses. +This phenomenon, it seems to me, ought to account for, and will +possibly satisfy, the spectroscopic conditions observed just before, +during, and after totality; which has probably led to the epithet used +by some leading observers--"the fickle corona." The peculiar +phenomenon observed in the spectroscope, the flickering bands or lines +of the solar spectrum flashing upon and across the coronal spectrum, +has caused no little speculation among observers. + +The diffraction or interference bands projected by the passage of a +strong beam of light by a solid body, as discovered long since by +Grimaldi, and investigated later by Newton, Fresnel, and Fraunhofer, +are explained and illustrated in our text books; but the grand display +of this phenomenon in a total solar eclipse, where the sun is the +source of light and the moon the intercepting body, has as yet +received but little attention from observers, and is not mentioned to +my knowledge in our text books. + +In the instructions issued from the United States Naval Observatory +and the Signal Office at Washington for the observation of the eclipse +of July 29, 1878, attention was casually directed to this phenomenon, +and a few of the observers at Pike's Peak, Central City, Denver, and +other places have given lucid and interesting descriptions of the +flight of the diffraction bands as seen coursing over the face of the +earth at the speed of the moon's shadow, at the apparent enormous +velocity of thirty-three miles per minute, or fifty times the speed of +a fast railway train. + +From a known optical illusion derived from interference or fits of +perception, as illustrated in quick moving shadows, this great speed +was not realized to the eye, as the observed motion of these shadows +was apparently far less rapid than their reality. + +The ultra or diffraction bands outside of the shadow were distinctly +seen and described by Mr. J.E. Keeler at Central City, both before and +after totality. He estimates the shadow bands at 8 inches wide and 4 +feet apart. + +Professor E.S. Holden, also at Central City, estimated the dark bands +as about 3 feet apart, and variable. + +From estimates which he obtained from other observers of his party, +the distances between the bands varied from 6 to l― feet, but so +quickly did they pass that they baffled all attempts to count even the +number that passed in one second. + +He observed the time of continuance of their passage from west to east +as forty-eight seconds, which indicates a width of 33 miles of +diffraction bands stretching outward from the edge of the shadow to +the number of many thousands. + +Mr. G.W. Hill, at Denver, a little to the north of the central track +of the shadow, observed the infra or bands within the shadow, alluding +to the fact that they must be moving at the same rate as the shadow, +although their apparent motion was much slower, or like the shadows of +flying clouds. He attributes the discrepancy to optical illusion. + +At Virginia City the _colors_ of the _ultra_ bands were observed, and +estimated at five seconds' duration from the edge of the shadow, which +is equal to about 4 miles in width. These are known to be the +strongest color bands in the diffraction spectrum, which accounts for +their being generally observed. + +Mr. W.H. Bush, observing at Central City, in a communication to Prof. +Holden alludes to the brilliancy of the colors of these bands as seen +through small clouds floating near the sun's place during totality, +and of the rapid change of their rainbow colors as observed dashing +across the clouds with the rapidity of thought. + +All of these bands, both ultra and infra, as seen in optical +experiments, are colored in reverse order, being from violet to red +for each band outward and inward from the edge of the shadow. + +It is very probable that the velocity of the passage of all the bands +during a total eclipse very much modifies the distinctness of the +colors or possibly obliterates them by optically blending so as to +produce the dull white and black bands which occupied so large a +portion of this grand panorama. + +The phenomenon of these faint colored bands, with the observed light +and dark shadows, may be attributed to one or all of the following +causes: + +1. A change in the direction of a small portion of the sun's light +passing by the solid body of the moon, it being deflected outward by +repulsion or reflection from its surface, and other portions being +deflected inward after passing the body by mutual repulsion of its own +elements toward a _light vacuum_ or space devoid of the element of +vibration. + +2. The colored spectral bands being the direct result of the property +of interference, or the want of correspondence of the wave lengths due +to divergence; the same phenomenon being also observed in convergent +light. This is practically illustrated in the hazy definition of the +reduced aperture of telescopes, and its peculiarities shown in the +spectral rings within and beyond the focus. + +3. Chromatic dispersion by our atmosphere, together with selective +absorption, also by our atmosphere and its vapors, have been suggested +as causes in this curious and complicated phenomena. + +In none of the reports descriptive of the phenomena of polarization of +the corona is there the slightest allusion to the influence that the +diffraction bands may possibly have in modifying or producing the +various conditions of polarization observed; although these +observations have been made and commented upon during the past +twenty-five years. + +Investigations now in progress of the modifying relation of the +phenomenon of diffraction in its effect upon not only the physical +aspect of the corona, but also in some strange spectroscopic anomalies +that have been observed near the sun at other times than during a +total solar eclipse, will, it is hoped, result in a fuller +interpretation of the physical nature of one of the grandest elements +of creation--_light_; let there be more of it. + + * * * * * + + +A CATALOGUE containing brief notices of many important scientific +papers heretofore published in the SUPPLEMENT, may be had gratis at +this office. + + * * * * * + + +The Scientific American Supplement. + +PUBLISHED WEEKLY. + +Terms of Subscription, $5 a Year. + +Sent by mail, postage prepaid, to subscribers in any part of the +United States or Canada. 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You may copy it, give it away or +re-use it under the terms of the Project Gutenberg License included +with this eBook or online at www.gutenberg.org + + +Title: Scientific American Supplement, No. 441, June 14, 1884. + +Author: Various + +Release Date: May 16, 2005 [EBook #15833] + +Language: English + +Character set encoding: ISO-8859-1 + +*** START OF THIS PROJECT GUTENBERG EBOOK SCIENTIFIC AMERICAN *** + + + + +Produced by Juliet Sutherland and the Online Distributed +Proofreading Team at www.pgdp.net. + + + + + + +</pre> + +<p class="ctr" style="margin-left: -10%; margin-right: -10%;"><a href="./images/title.png"> +<img src="./images/title_th.png" alt="Issue Title" /></a></p> +<h1>SCIENTIFIC AMERICAN SUPPLEMENT NO. 441</h1> +<h2>NEW YORK, JUNE 14, 1884</h2> +<h4>Scientific American Supplement. Vol. XVII, No. 441.</h4> +<h4>Scientific American established 1845</h4> +<h4>Scientific American Supplement, $5 a year.</h4> +<h4>Scientific American and Supplement, $7 a year.</h4> +<hr /> +<table summary="Contents" border="0" cellspacing="5"> +<tr> +<th colspan="2">TABLE OF CONTENTS.</th> +</tr> +<tr> +<td valign="top">I.</td> +<td><a href="#art01"> +CHEMISTRY AND METALLURGY.—On Electrolysis.—Precipitation + of lead, thallium, silver, bismuth, manganese, etc.—By H. + SCHUCHT</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art02"> +The Electro-Chemical Equivalent of Silver +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art03"> + Zircon.—How it can be rendered soluble.—By F. STOLBA +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art04"> +A New Process for Making Wrought Iron Directly from the Ore. + —Comparison with other processes.—With descriptions and + engravings of the apparatus used</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art05"> +Some Remarks on the Determination of Hardness in Water</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art06"> +On the changes which Take Place in the Conversion of Hay + into Ensilage.—By F.J. Lloyd</a></td> +</tr> +<tr> +<td valign="top">II.</td> +<td><a href="#art07"> +ENGINEERING AND MECHANICS.—Faure's Machine for + Decorticating Sugar Cane.—With full description + and 13 figures +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art08"> +The Generation of Steam and the Thermodynamic Problems + Involved.—By WM. ANDERSON.—Apparatus used in the + experimental determination of the heat of combustion and + the laws which govern its development.—Ingredients of + fuel.—Potential energy of fuel.—With 7 figures and + several tables +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art09"> +Planetary Wheel Trains.—Rotations of the wheels relatively + to the train arm.—By Prof. C.W. MACCORD +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art10"> +The Pantanemone.—A New Windwheel.—1 engraving +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art11"> +Relvas's New Life Boat.—With engraving +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art12"> + Experiments with Double Barreled Guns and Rifles. + —Cause of the divergence of the charge.—4 figures +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art13"> +Improved Ball Turning Machine.—1 figure +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art14"> +Cooling Apparatus for Injection Water.—With engraving +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art15"> +Corrugated Disk Pulleys.—1 engraving +</a></td> +</tr> +<tr> +<td valign="top">III.</td> +<td><a href="#art16"> +TECHNOLOGY.—A New Standard Light +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art17"> +Dr. Feussner's New Polarizing Prism.—Points of difference + between the old and new prisms.—By P.R. SLEEMAN +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art18"> +Density and Pressure of Detonating Gas +</a></td> +</tr> +<tr> +<td valign="top">IV.</td> +<td><a href="#art19"> + ELECTRICITY, LIGHT, ETC.—Early History of the Telegraph. + —Pyrsia, or the system of telegraphy among the Greeks. + —Communication by means of characters and the telescope. + —Introduction of the magnetic telegraph between Baltimore + and Washington +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art20"> + The Kravogl Electro Motor and its Conversion Into a Dynamo + Electric Machine.—5 figures +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art21"> +Bornhardt's Electric Machine for Blasting in Mines. + —15 figures +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art22"> +Pritchett's Electric Fire Alarm.—1 figure +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art23"> +A Standard Thermopile +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art24"> +Telephonic Transmission without Receivers.—Some of the + apparatus exhibited at the annual meeting of the French + Society of Physics.—Telephonic transmission through a + chain of persons +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art25"> +Diffraction Phenomena during Total Solar Eclipses.—By G.D. + Hiscox +</a></td> +</tr> +<tr> +<td valign="top">V.</td> +<td><a href="#art26"> +BOTANY AND HORTICULTURE.—Gum Diseases in Trees.— + Cause and contagion of the same</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art27"> +Drinkstone Park.—Trees and plants cultivated therein.— + With 2 engravings +</a></td> +</tr> +<tr> +<td valign="top">VI.</td> +<td><a href="#art28"> +MEDICINE AND HYGIENE.—Miryachit.—A newly-discovered + disease of the nervous system, and its analogues.—By WM. A. + HAMMOND +</a></td> +</tr> + +<tr> +<td valign="top">VII.</td> +<td><a href="#art29"> +MISCELLANEOUS.—Turkish Baths for Horses.—With + diagram. +</a></td> +</tr> +<tr> +<td></td> +<td><a href="#art30"> +<ins title="Transcriber's Note: This article not in original Table of Contents."> +On The Arrangement Of Ground Conductors.</ins> +</a></td> +</tr> +</table> + + + +<hr /> + + +<h2><a name="Page_7031" id="Page_7031"></a><a name="art07" id="art07"></a>FAURE'S MACHINE FOR DECORTICATING SUGAR-CANE.</h2> + +<p>The object of the apparatus shown in the accompanying engraving is to +effect a separation of the tough epidermis of the sugar-cane from the +internal spongy pith which is to be pressed. Its function consists in +isolating and separating the cells from their cortex, and in putting +them in direct contact with the rollers or cylinders of the mill. +After their passage into the apparatus, which is naturally placed in a +line with the endless chain that carries them to the mill, the canes +arrive in less compact layers, pass through much narrower spaces, and +finally undergo a more efficient pressure, which is shown by an +abundant flow of juice. The first trials of the machine were made in +1879 at the Pointe Simon Works, at Martinique, with the small type +that was shown at the Paris Exhibition of 1878. These experiments, +which were applied to a work of 3,000 kilos of cane per hour, gave +entire satisfaction, and decided the owners of three of the colonial +works (Pointe Simon, Larcinty, and Marin) to adopt it for the season +of 1880.</p> + +<p>The apparatus is shown in longitudinal section in Fig. 1, and in plan +in Fig. 2.</p> + +<p>Fig. 3 gives a transverse section passing through the line 3-4, and +Fig. 4 an external view on the side whence the decorticated canes make +their exit from the apparatus.</p> + +<p class="ctr"><a href="./images/1a.png"><img src="./images/1a_th.png" alt="FAURE'S MACHINE FOR DECORTICATING SUGAR CANE." /></a><br /> FAURE'S MACHINE FOR DECORTICATING SUGAR CANE.</p> + +<p>The other figures relate to details that will be referred to further +along.</p> + +<p><i>The Decorticating Cylinder.</i>—The principal part of the apparatus is +a hollow drum, A, of cast iron, 430 mm. in internal diameter by 1.41 +m. in length, which is keyed at its two extremities to the shaft, a. +Externally, this drum (which is represented apart in transverse +section in Fig. 5) has the form of an octagonal prism with well +dressed projections between which are fixed the eight plates, C, that +constitute the decorticating cylinder. These plates, which are of +tempered cast iron, and one of which is shown in transverse section in +Fig. 7, when once in place form a cylindrical surface provided with 48 +helicoidal, dentate channels. The length of these plates is 470 mm. +There are three of them in the direction of the generatrices of the +cylinder, and this makes a total of 24. All are strengthened by ribs +(as shown in Fig. 8), and each is fixed by 4 bolts, <i>c</i>, 20mm. in +diameter. The pitch of the helices of each tooth is very elongated, +and reaches about 7.52 m. The depth of the toothing is 18 mm.</p> + +<p><i>Frame and Endless Chain.</i>—The cylinder thus constructed rotates with +a velocity of 50 revolutions per minute over a cylindrical vessel, B', +cast in a piece with the frame, B. This vessel is lined with two +series of tempered cast iron plates, D and D', called exit and +entrance plates, which rest thereon, through the intermedium of well +dressed pedicels, and which are held in place by six 20-millimeter +bolts. Their length is 708 mm. The entrance plates, D, are provided +with 6 spiral channels, whose pitch is equal to that of the channels +of the decorticating cylinder, C, and in the same direction. The depth +of the toothing is 10 mm.</p> + +<p>The exit plates, D', are provided with 7 spiral channels of the same +pitch and direction as those of the preceding, but the depth of which +increases from 2 to 10 mm. The axis of the decorticating cylinder does +not coincide with that of the vessel, B', so that the free interval +for the passage of the cane continues to diminish from the entrance to +the exit.</p> + +<p>The passage of the cane to the decorticator gives rise to a small +quantity of juice, which flows through two orifices, <i>b'</i>, into a sort +of cast iron trough, G, suspended beneath the vessel. The cane, which +is brought to the apparatus by an endless belt, empties in a conduit +formed of an inclined bottom, E, of plate iron, and two cast iron +sides provided with ribs. These sides rest upon the two ends of the +vessel, B', and are cross-braced by two flat bars, <i>e</i>, to which is +bolted the bottom, E. This conduit is prolonged beyond the +decorticating cylinder by an inclined chute, F, the bottom of which is +made of plate iron 7 mm. thick and the sides of the same material 9 +mm. thick. The hollow frame, B, whose general form is like that of a +saddle, carries the bearings, <i>b</i>, in which revolves the shaft, <i>a</i>. +One of these bearings is represented in detail in Figs. 9 and 10. It +will be seen that the cap is held by bolts with sunken heads, and that +the bearing on the bushes is through horizontal surfaces only. In a +piece with this frame are cast two similar brackets, Bē, which support +the axle, <i>h</i>, of the endless chain. To this axle, whose diameter is +100 mm., are keyed, toward the extremities, the pinions, H, to which +correspond the endless pitch chains, <i>i</i>. These latter are formed, as +may be seen in Figs. 11 and 12, of two series of links. The shorter of +these latter are only 100 mm. in length, while the longer are 210 mm., +and are hollowed out so as to receive the butts of the boards, I. The +chain thus formed passes over two pitch pinions, J, like the pinions, +H, that are mounted at the extremities of an axle, <i>j</i>, that revolves +in bearings, I', whose position with regard to the apparatus is +capable of being varied so as to slacken or tauten the chain, I. This +arrangement is shown in elevation in Fig. 13.</p> + +<p><i>Transmission.</i>—The driving shaft, <i>k</i>, revolves in a pillow block, +K, cast in a piece with the frame, B. It is usually actuated by a +special motor, and carries a fly-wheel (not shown in the figure for +want of space). It receives in addition a cog-wheel, L, which +transmits its motion to the decorticating cylinder through, the +intermedium of a large wooden-toothed gear wheel, L'. The shaft, <i>a</i>, +whose diameter is 228 mm., actuates in its turn, through the pinions, +M' and M, the pitch pinion, N, upon whose prolonged hub is keyed the +pinion, M. This latter is mounted loosely upon the intermediate axle, +<i>m</i>. Motion is transmitted to the driving shaft, <i>h</i>, of the endless +chain, I, by an ordinary pitch chain, through a gearing which is shown +in Fig. 12. The pitch pinion, N', is cast in a piece with a hollow +friction cone, Nē, which is mounted loosely upon the shaft, <i>h</i>, and +to which corresponds a second friction cone, O. This latter is +connected by a key to a socket, <i>o</i>, upon which it slides, and which +is itself keyed to the shaft, <i>h</i>. The hub of the cone, O, is +connected by a ring with a bronze nut, <i>p</i>, mounted at the threaded +end of the shaft, <i>h</i>, and carrying a hand-wheel, P. It is only +necessary to turn this latter in one direction or the other in order +to throw the two cones into or out of gear.</p> + +<p>If we allow that the motor has a velocity of 70 revolutions per +minute, the decorticating cylinder will run at the rate of 50, and the +sugar-cane will move forward at the rate of 12 meters per minute.</p> + +<p>This new machine is a very simple and powerful one. The decortication +is effected with wonderful rapidity, and the canes, opened throughout +their entire length and at all points of their circumference, leave +the apparatus in a state that allows of no doubt as to what the result +of the pressure will be that they have to undergo. There is no +tearing, no trituration, no loss of juice, but merely a simple +preparation for a rational pressure effected under most favorable +conditions.</p> + +<p>The apparatus, which is made in several sizes, has already received +numerous applications in Martinique, Trinidad, Cuba, Antigua, St. +Domingo, Peru, Australia, the Mauritius Islands, and +Brazil.—<i>Publication Industrielle.</i></p> + +<hr /> + +<h3>MOVING A BRIDGE.</h3> + + +<p>An interesting piece of engineering work has recently been +accomplished at Bristol, England, which consisted in the moving of a +foot-bridge 134 feet in length, bodily, down the river a considerable +distance. The pontoons by means of which the bridge was floated to its +new position consisted of four 80-ton barges, braced together so as to +form one solid structure 64 feet in width, and were placed in position +soon after the tide commenced to rise. At six o'clock A.M. the top of +the stages, which was 24 feet above the water, touched the under part +of the bridge, and in a quarter of an hour later both ends rose from +their foundations. When the tide had risen 4 ft. the stage and bridge +were floated to the new position, when at 8.30 the girders dropped on +to their beds.</p> + +<hr /> + + +<h2><a name="Page_7032" id="Page_7032"></a><a name="art08" id="art08"></a>THE GENERATION OF STEAM, AND THE THERMODYNAMIC PROBLEMS +INVOLVED.<a name="FNanchor_1" id="FNanchor_1"></a><a href="#Footnote_1"><sup>1</sup></a></h2> + + +<h3>By Mr. WILLIAM ANDERSON, M.I.C.E.</h3> + + +<p>It will not be necessary to commence this lecture by explaining the +origin of fuel; it will be sufficient if I remind you that it is to +the action of the complex rays of the sun upon the foliage of plants +that we mainly owe our supply of combustibles. The tree trunks and +branches of our forests, as well as the subterranean deposits of coal +and naphtha, at one time formed portions of the atmosphere in the form +of carbonic acid gas; that gas was decomposed by the energy of the +solar rays, the carbon and the oxygen were placed in positions of +advantage with respect to each other—endowed with potential energy; +and it is my duty this evening to show how we can best make use of +these relations, and by once more combining the constituents of fuel +with the oxygen of the air, reverse the action which caused the growth +of the plants, that is to say, by destroying the plant reproduce the +heat and light which fostered it. The energy which can be set free by +this process cannot be greater than that derived originally from the +sun, and which, acting through the frail mechanism of green leaves, +tore asunder the strong bonds of chemical affinity wherein the carbon +and oxygen were hound, converting the former into the ligneous +portions of the plants and setting the latter free for other uses. The +power thus silently exerted is enormous; for every ton of carbon +separated in twelve hours necessitates an expenditure of energy +represented by at least 1,058 horse power, but the action is spread +over an enormous area of leaf surface, rendered necessary by the small +proportion of carbonic acid contained in the air, by measure only +1/2000 part, and hence the action is silent and imperceptible. It is +now conceded on all hands that what is termed heat is the energy of +molecular motion, and that this motion is convertible into various +kinds and obeys the general laws relating to motion. Two substances +brought within the range of chemical affinity unite with more or less +violence; the motion of transition of the particles is transformed, +wholly or in part, into a vibratory or rotary motion, either of the +particles themselves or the interatomic ether; and according to the +quality of the motions we are as a rule, besides other effects, made +conscious of heat or light, or of both. When these emanations come to +be examined they are found to be complex in the extreme, intimately +bound up together, and yet capable of being separated and analyzed.</p> + +<p>As soon as the law of definite chemical combination was firmly +established, the circumstance that changes of temperature accompanied +most chemical combinations was noticed, and chemists were not long in +suspecting that the amount of heat developed or absorbed by chemical +reaction should be as much a property of the substances entering into +combination as their atomic weights. Solid ground for this expectation +lies in the dynamic theory of heat. A body of water at a given height +is competent by its fall to produce a definite and invariable quantity +of heat or work, and in the same way two substances falling together +in chemical union acquire a definite amount of kinetic energy, which, +if not expended in the work of molecular changes, may also by suitable +arrangements be made to manifest a definite and invariable quantity of +heat.</p> + +<p>At the end of last century Lavoisier and Laplace, and after them, down +to our own time, Dulong, Desprez, Favre and Silbermann, Andrews, +Berthelot, Thomson, and others, devoted much time and labor to the +experimental determination of the heat of combustion and the laws +which governed its development. Messrs. Favre and Silbermann, in +particular, between the years 1845 and 1852, carried out a splendid +series of experiments by means of the apparatus partly represented in +Fig. 1 (opposite), which is a drawing one-third the natural size of +the calorimeter employed. It consisted essentially of a combustion +chamber formed of thin copper, gilt internally. The upper part of the +chamber was fitted with a cover through which the combustible could be +introduced, with a pipe for a gas jet, with a peep hole closed by +adiathermanous but transparent substances, alum and glass, and with a +branch leading to a thin copper coil surrounding the lower part of the +chamber and descending below it. The whole of this portion of the +apparatus was plunged into a thin copper vessel, silvered internally +and filled with water, which was kept thoroughly mixed by means of +agitators. This second vessel stood inside a third one, the sides and +bottom of which were covered with the skins of swans with the down on, +and the whole was immersed in a fourth vessel tilled with water, kept +at the average temperature of the laboratory. Suitable thermometers of +great delicacy were provided, and all manner of precautions were taken +to prevent loss of heat.</p> + +<p class="ctr"><a href="./images/3a-1.png"><img src="./images/3a-1_th.png" alt="THE GENERATION OF STEAM. Fig 1." /></a><br /> THE GENERATION OF STEAM. Fig 1.</p> + +<p>It is impossible not to admire the ingenuity and skill exhibited in +the details of the apparatus, in the various accessories for +generating and storing the gases used, and for absorbing and weighing +the products of combustion; but it is a matter of regret that the +experiments should have been carried out on so small a scale. For +example, the little cage which held the solid fuel tested was only 5/8 +inch diameter by barely 2 inches high, and held only 38 grains of +charcoal, the combustion occupying about sixteen minutes. Favre and +Silbermann adopted the plan of ascertaining the weight of the +substances consumed by calculation from the weight of the products of +combustion. Carbonic acid was absorbed by caustic potash, as also was +carbonic oxide, after having been oxidized to carbonic acid by heated +oxide of copper, and the vapor of water was absorbed by concentrated +sulphuric acid. The adoption of this system showed that it was in any +case necessary to analyze the products of combustion in order to,m +detect imperfect action. Thus, in the case of substances containing +carbon, carbonic oxide was always present to a variable extent with +the carbonic acid, and corrections were necessary in order to +determine the total heat due to the complete combination of the +substance with oxygen. Another advantage gained was that the +absorption of the products of combustion prevents any sensible +alteration in the volumes during the process, so that corrections for +the heat absorbed in the work of displacing the atmosphere were not +required. The experiments on various substances were repeated many +times. The mean results for those in which we are immediately +interested are given in Table I., next column.</p> + +<p>Comparison with later determinations have established their +substantial accuracy. The general conclusion arrived at is thus +stated:</p> + +<p>"As a rule there is an equality between the heat disengaged or +absorbed in the acts, respectively, of chemical combination or +decomposition of the same elements, so that the heat evolved during +the combination of two simple or com-pound substances is equal to the +heat absorbed at the time of their chemical segregation."</p> + + +<p class="ctr">TABLE I.—SUBSTANCES ENTERING INTO THE COMPOSITION OF FUEL.</p> + +<div class="ctr"> +<table border="1" cellpadding="4" cellspacing="0" summary=""> +<colgroup span="7"><col align="left" span="2" /><col align="right" /><col align="left" /><col align="right" span="3" /></colgroup> +<tr><td rowspan="2"><br /></td><th colspan="4" align="center">Symbol and Atomic Weight.</th><th colspan="2" align="center">Heat evolved in<br /> the Combustion of<br />1 lb. of Fuel.</th></tr> +<tr><th colspan="2">Before Combustion</th><th colspan="2">After Combustion</th><th align="center">In British<br /> Thermal<br />Units.</th><th align="center">In Pounds<br />of Water<br />Evaporated<br />from and<br /> at 212°.</th></tr> +<tr><td>Hydrogen burned in oxygen.</td><td>H</td><td>1</td><td>H<sub>2</sub>O</td><td>18</td><td>62,032</td><td>64.21</td></tr> +<tr><td>Carbon burned to carbonic oxide.</td><td>C</td><td>12</td><td>CO</td><td>28</td><td>4,451</td><td>4.61</td></tr> +<tr><td>Carbon burned to carbonic acid.</td><td>C</td><td>12</td><td>CO<sub>2</sub></td><td>44</td><td>14,544</td><td>15.06</td></tr> +<tr><td>Carbonic oxide burned to carbonic acid.</td><td>CO</td><td>28</td><td>CO<sub>2</sub></td><td>44</td><td>4,326</td><td>4.48</td></tr> +<tr><td>Olefiant gas (ethylene) burnt in oxygen.</td><td>C<sub>2</sub>H<sub>4</sub><br />2H<sub>2</sub>O</td><td>28</td><td>2CO<sub>2</sub></td><td>124</td><td>21,343</td><td>22.09</td></tr> +<tr><td>Marsh gas (methane) burnt in oxygen.</td><td>CH<sub>4</sub></td><td>16</td><td>2CO<sub>2</sub><br />2H<sub>2</sub>O</td><td>80</td><td>23,513</td><td>24.34</td></tr> +</table></div> + +<p>Composition of air—</p> + +<div class="ctr"> +<table summary=""> +<tr><td rowspan="2"><span class="xxl">{</span></td><td>by volume 0.788 N + 0.197 O + 0.001 CO<sub>2</sub> + 0.014 H<sub>2</sub>O</td></tr> +<tr><td>by weight 0.771 N + 0.218 O + 0.009 CO<sub>2</sub> + 0.017 H<sub>2</sub>O</td></tr> +</table></div> + +<p>This law is, however, subject to some apparent exceptions. Carbon +burned in protoxide of nitrogen, or laughing gas, N<sub>2</sub>O, produces +about 38 per cent. more heat than the same substance burned in pure +oxygen, notwithstanding that the work of decomposing the protoxide of +nitrogen has to be performed. In marsh gas, or methane, CH<sub>4</sub>, again, +the energy of combustion is considerably less than that due to the +burning of its carbon and hydrogen separately. These exceptions +probably arise from the circumstance that the energy of chemical +action is absorbed to a greater or less degree in effecting molecular +changes, as, for example, the combustion of 1 pound of nitrogen to +form protoxide of nitrogen results in the absorption of 1,157 units of +heat. Berthelot states, as one of the fundamental principles of +thermochemistry, "that the quantity of heat evolved is the measure of +the sum of the chemical and physical work accomplished in the +reaction"; and such a law will no doubt account for the phenomena +above noted. The equivalent heat of combustion of the compounds we +have practically to deal with has been experimentally determined, and +therefore constitutes a secure basis on which to establish +calculations of the caloric value of fuel; and in doing so, with +respect to substances composed of carbon, hydrogen, and oxygen, it is +convenient to reduce the hydrogen to its heat-producing equivalent of +carbon. The heat of combustion of hydrogen being 62,032 units, that of +carbon 14,544 units, it follows that 4.265 times the weight of +hydrogen will represent an equivalent amount of carbon. With respect +to the oxygen, it is found that it exists in combination with the +hydrogen in the form of water, and, being combined already, abstracts +its combining equivalent of hydrogen from the efficient ingredients of +the fuel; and hence hydrogen, to the extent of 1/8 of the weight of +the oxygen, must be deducted. The general formula then becomes:</p> + +<p class="ctr">Heat of combustion = 14,544 {C + 4.265 (H-(O/8))},</p> + +<p>and water evaporated from and at 212°, taking 966 units as the heat +necessary to evaporate 1 pound of water,</p> + +<p class="ctr">lb. evaporated = 15.06 {C + 4.265 (H-(O/8))},</p> + +<p>carbon, hydrogen, and oxygen being taken at their weight per cent. in +the fuel. Strictly speaking, marsh gas should be separately +determined. It often happens that available energy is not in a form in +which it can be applied directly to our needs. The water flowing down +from the mountains in the neighborhood of the Alpine tunnels was +competent to provide the power necessary for boring through them, but +it was not in a form in which it could be directly applied. The +kinetic energy of the water had first to be changed into the potential +energy of air under pressure, then, in that form, by suitable +mechanism, it was used with signal success to disintegrate and +excavate the hard rock of the tunnels. The energy resulting from +combustion is also incapable of being directly transformed into useful +motive power; it must first be converted into potential force of steam +or air at high temperature and pressure, and then applied by means of +suitable heat engines to produce the motions we require. It is +probably to this circumstance that we must attribute the slowness of +the human race to take advantage of the energy of combustion. The +history of the steam engine hardly dates back 200 years, a very small +fraction of the centuries during which man has existed, even since +historic times.</p> + +<p>The apparatus by means of which the potential energy of fuel with +respect to oxygen is converted into the potential energy of steam, we +call a steam boiler; and although it has neither cylinder nor piston, +crank nor fly wheel, I claim for it that it is a veritable heat +engine, because it transmits the undulations and vibrations caused by +the energy of chemical combination in the fuel to the water in the +boiler; these motions expend themselves in overcoming the liquid +cohesion of the water and imparting to its molecules that vigor of +motion which converts them into the molecules of a gas which, +impinging on the surfaces which confine it and form the steam space, +declare their presence and energy in the shape of pressure and +temperature. A steam pumping engine, which furnishes water under high +pressure to raise loads by means of hydraulic cranes, is not more +truly a heat engine than a simple boiler, for the latter converts the +latent energy of fuel into the latent energy of steam, just as the +pumping engine converts the latent energy of steam into the latent +energy of the pumped-up accumulator or the hoisted weight.</p> + +<p>If I am justified in taking this view, then I am justified in applying +to my heat engine the general principles laid down in 1824 by Sadi +Carnot, namely, that the proportion of work which can be obtained out +of any substance working between two temperatures depends entirely and +solely upon the difference between the temperatures at the beginning +and end of the operation; that is to say, if T be the higher +temperature at the beginning, and <i>t</i> the lower temperature at the end +of the action, then the maximum possible work to be got out of the +substance will be a function of (T-<i>t</i>). The greatest range of +temperature possible or conceivable is from the absolute temperature +of the substance at the commencement of the operation down to absolute +zero of temperature, and the fraction of this which can be utilized is +the ratio which the range of temperature through which the substance +is working bears to the absolute temperature at the commencement of +the action. If W = the greatest amount of effect to be expected, T and +<i>t</i> the absolute temperatures, and H the total quantity of heat +(expressed in foot pounds or in water evaporated, as the case may be) +potential in the substance at the higher temperature, T, at the +beginning of the operation, then Carnot's law is expressed by the +equation:</p> + +<div class="ctr"> +<table summary="Equation"> +<colgroup span="3" align="center"></colgroup> +<tr><td rowspan="2">W = H <span class="xxl">(</span></td> +<td><span class="underline">T - <i>t</i></span></td> +<td rowspan="2"><span class="xxl">)</span></td></tr> +<tr><td>T</td></tr> +</table></div> + + +<p>I will illustrate this important doctrine in the manner which Carnot +himself suggested.</p> + +<p class="ctr"><a href="./images/3a-2.png"><img src="./images/3a-2_th.png" alt=" THE GENERATION OF STEAM. Fig 2." /></a><br /> THE GENERATION OF STEAM. Fig 2.</p> + +<p>Fig. 2 represents a hillside rising from the sea. Some distance up +there is a lake, L, fed by streams coming down from a still higher +level. Lower down on the slope is a millpond, P, the tail race from +which falls into the sea. At the millpond is established a factory, +the turbine driving which is supplied with water by a pipe descending +from the lake, L. Datum is the mean sea level; the level of the lake +is T, and of the millpond <i>t</i>. Q is the weight of water falling +through the turbine per minute. The mean sea level is the lowest level +to which the water can possibly fall; hence its greatest potential +energy, that of its position in the lake, = QT = H. The water is +working between the absolute levels, T and <i>t</i>; hence, according to +Carnot, the maximum effect, W, to be expected is—</p> + +<div class="ctr"> +<table summary="Equation"> +<colgroup span="4" align="left"></colgroup> +<tr><td></td><td>W = H <span class="xxl">(</span></td> +<td align="center"><span class="underline">T - <i>t</i></span><br />T</td> +<td><span class="xxl">)</span></td></tr> +<tr><td rowspan="2" valign="bottom">but H = QT ∴</td><td rowspan="2" valign="bottom">W = QT <span class="xxl">(</span></td> +<td><span class="underline">T - <i>t</i></span></td> +<td rowspan="2" valign="bottom"><span class="xxl">)</span></td></tr> +<tr><td align="center">T</td></tr> +<tr><td></td><td colspan="2" align="left">W = Q (T - <i>t</i>),</td></tr> +</table></div> + + +<p>that is to say, the greatest amount of work which can be expected is +found by multiplying the weight of water into the clear fall, which +is, of course, self-evident.</p> + +<p>Now, how can the quantity of work to be got out of a given weight of +water be increased without in any way improving the efficiency of the +turbine? In two ways:</p> + +<div class="indlist"><p>1. By collecting the water higher up the mountain, and by that means +increasing T.</p> + +<p>2. By placing the turbine lower down, nearer the sea, and by that +means reducing <i>t</i>.</p></div> + +<p>Now, the sea level corresponds to the absolute zero of temperature, +and the heights T and <i>t</i> to the maximum and minimum temperatures +between which the substance is working; therefore similarly, the way +to increase the efficiency of a heat engine, such as a boiler, is to +raise the temperature of the furnace to the utmost, and reduce the +heat of the smoke to the lowest possible point. It should be noted, in +addition, that it is immaterial what liquid there may be in the lake; +whether water, oil, mercury, or what not, the law will equally apply, +and so in a heat engine, the nature of the working substance, provided +that it does not change its physical state during a cycle, does not +affect the question of efficiency with which the heat being expended +is so utilized. To make this matter clearer, and give it a practical +bearing, I will give the symbols a numerical value, and for this +purpose I will, for the sake of simplicity, suppose that the fuel used +is pure carbon, such as coke or charcoal, the heat of combustion of +which is 14,544 units, that the specific heat of air, and of the +products of combustion at constant pressure, is 0.238, that only +sufficient air is passed through the fire to supply the quantity of +oxygen theoretically required for the combustion of the carbon, and +that the temperature of the air is at 60° Fahrenheit = 520° absolute. +The symbol T represents the absolute temperature of the furnace, a +value which is easily calculated in the following manner: 1 lb. of +carbon requires 2-2/3 lb. of oxygen to convert it into carbonic acid, +and this quantity is furnished by 12.2 lb. of air, the result being +13.2 lb. of gases, heated by 14,544 units of heat due to the energy of +combustion; therefore:</p> + +<div class="ctr"> +<table summary="Equation"> +<tr><td rowspan="2"> T = 520° + </td><td>14,544 units</td> +<td rowspan="2"> = 5,150° absolute.</td></tr> +<tr><td><span class="overline">13.2 lb. Ũ 0.238</span></td></tr> +</table></div> + +<p>The lower temperature, <i>t</i>, we may take as that of the feed water, say +at 100° or 560° absolute, for by means of artificial draught and +sufficiently extending the heating surface, the temperature of the +smoke may be reduced to very nearly that of the feed water. Under such +circumstances the proportion of heat which can be realized is</p> + +<div class="ctr"> +<table summary="Equation"> +<tr><td rowspan="2"> = </td><td><span class="underline">5,150° - 560°</span></td> +<td rowspan="2"> = 0.891;</td></tr> +<tr><td>5,150°</td></tr> +</table></div> + +<p>that is to say, under the extremely favorable if not impracticable +conditions assumed, there must be a loss of 11 per cent. Next, to give +a numerical value to the potential energy, H, to be derived from a +pound of carbon, calculating from absolute zero, the specific heat of +carbon being 0.25, and absolute temperature of air 520°:</p> + + +<div class="ctr"> +<table border="0" summary="" width="80%"> +<colgroup span="3"><col align="left"/><col align="right"/><col align="right"/></colgroup> +<tr><td colspan="2"></td><td>Units.</td></tr> +<tr><td>1 lb. of carbon Ũ 0.25 Ũ 520</td><td>=</td><td>130</td></tr> +<tr><td>12.2 of air Ũ 0.238 Ũ 520</td><td>=</td><td>1,485</td></tr> +<tr><td>Heat of combustion</td><td>=</td><td>14,544</td></tr> +<tr><td colspan="2"></td><td><span class="overline">16,159</span></td></tr> +<tr><td>Deduct heat equivalent to work of displacing atmosphere by products of combustion raised from 60° to 100°, or from 149.8 cubic feet to 161.3 cubic feet,</td><td></td><td>32</td></tr> +<tr><td>Total units of heat available</td><td></td><td><span class="overline">16,127</span></td></tr> +</table></div> + +<p>Equal to 16.69 lb. of water evaporated from and at 212°. Hence the +greatest possible evaporation from and at 212° from a lb. of carbon—</p> + +<div class="ctr"> +<table border="0" summary="Equation"> +<tr> +<td rowspan="2">W =</td><td> +<span class="underline"> 16,159 u. Ũ 0.891 - 32 u.</span></td> +<td rowspan="2">= 14.87 lb.</td></tr> +<tr><td>966 u.</td></tr> +</table></div> + +<p>I will now take a definite case, and compare the potential energy of a +certain kind of fuel with the results actually obtained. For this +purpose the boiler of the eight-horse portable engine, which gained +the first prize at the Cardiff show of the Royal Agricultural Society +in 1872, will serve very well, because the trials, all the details of +which are set forth very fully in vol. ix. of the <i>Journal</i> of the +Society, were carried out with great care and skill by Sir Frederick +Bramwell and the late Mr. Menelaus; <a name="Page_7033" id="Page_7033"></a>indeed, the only fact left +undetermined was the temperature of the furnace, an omission due to +the want of a trustworthy pyrometer, a want which has not been +satisfied to this day.<a name="FNanchor_2" id="FNanchor_2"></a><a href="#Footnote_2"><sup>2</sup></a> The data necessary for our purpose are:</p> + +<div class="ctr"> +<table border="0" summary=""> +<colgroup><col align="left" /><col align="right" /><col align="center" /></colgroup> +<tr><td>Steam pressure 80 lb. temperature</td><td>324° = 784°</td><td>absolute.</td></tr> +<tr><td>Mean temperature of smoke</td><td>389° = 849°</td><td>"</td></tr> +<tr><td>Water evaporated per 1 lb of coal, from and at 212°</td><td>11.83 lb.</td></tr> +<tr><td>Temperature of the air</td><td>60° = 520°</td><td>absolute.</td></tr> +<tr><td>Temperature of feed water</td><td>209° = 669°</td><td>"</td></tr> +<tr><td>Heating surface</td><td>220 square feet.</td></tr> +<tr><td>Grate surface</td><td>3.29 feet.</td></tr> +<tr><td>Coal burnt per hour</td><td>41 lb.</td></tr> +</table></div> + +<p>The fuel used was a smokeless Welsh coal, from the Llangennech +colleries. It was analyzed by Mr. Snelus, of the Dowlais Ironworks, +and in Table II. are exhibited the details of its composition, and the +weight and volume of air required for its combustion. The total heat +of combustion in 1 lb of water evaporated:</p> + +<div class="ind"> +<p> + = 15.06 Ũ (0.8497 + 4.265 Ũ (0.426 - 0.035/8)) <br /> + = 15.24 lb. of water from and at 212°<br /> + = 14,727 units of heat. +</p></div> + +<p class="ctr">TABLE II.—PROPERTIES OF LLANGENNECH COAL.</p> + +<div class="ctr"> +<table border="1" summary="" width="90%"> +<colgroup span="5"><col align="left" /><col span="4" align="right" /></colgroup> +<tr><th rowspan="2"> </th><th rowspan="2" align="center">Analyses of 1 lb. of Coal.</th><th rowspan="2">Oxygen required for Combustion.<br />Pounds.</th><th colspan="2">Products of Combustion at 32° F.</th></tr> +<tr><th>Cubic feet.</th><th>Volume per cent.</th></tr> +<tr><td>Carbon</td><td>0.8497</td><td>2.266</td><td>25.3</td><td>11.1</td></tr> +<tr><td>Hydrogen</td><td>0.0426</td><td>0.309</td><td>7.6</td><td>3.4</td></tr> +<tr><td>Oxygen</td><td>0.0350</td><td>—</td><td>—</td><td>—</td></tr> +<tr><td>Sulphur</td><td>0.0042</td><td>—</td><td>—</td><td>—</td></tr> +<tr><td>Nitrogen</td><td>0.1045</td><td>—</td><td>0.18</td><td rowspan="5" valign="middle"><span class="xxl">}</span>85.5</td></tr> +<tr><td>Ash</td><td>0.0540</td><td>—</td><td>—</td></tr> +<tr><td>Total</td><td>1.0000</td><td>2.572</td><td>—</td></tr> +<tr><td>9-1/3.lb nitrogen</td><td>—</td><td>—</td><td>118.9</td></tr> +<tr><td>6 lb. excess of air.</td><td>—</td><td>—</td><td>71.4</td></tr> +<tr><td>Total cubic feet of products per 1 lb. of coal</td><td>—</td><td>—</td><td>226.4</td><td>100.0</td></tr> +</table></div> + +<p>The temperature of the furnace not having been determined, we must +calculate it on the supposition, which will be justified later on, +that 50 per cent more air was admitted than was theoretically +necessary to supply the oxygen required for perfect combustion. This +would make 18 lb. of air per 1 lb. of coal; consequently 19 lb. of +gases would be heated by 14,727 units of heat. Hence:</p> + +<div class="ctr"> +<table border="0" summary="Equation"> +<tr> +<td rowspan="2">T =</td> +<td>14,727 u.</td> +<td rowspan="2">= 3,257°</td></tr> +<tr><td><span class="overline">19 lb. Ũ 0.238</span></td></tr> +</table></div> + +<p>above the temperatures of the air, or 3,777° absolute. The temperature +of the smoke, <i>t</i>, was 849° absolute; hence the maximum duty would be</p> + +<div class="ctr"> +<table border="0" summary="Equation"> +<tr> +<td> +<span class="underline">3,777° - 849°</span></td> +<td rowspan="2">= 0.7752.</td></tr> +<tr><td>3,777°</td></tr> +</table></div> + +<p>The specific heat of coal is very nearly that of gases at constant +pressure, and may, without sensible error, be taken as such. The +potential energy of 1 lb. of coal, therefore, with reference to the +oxygen with which it will combine, and calculated from absolute zero, +is:</p> + +<div class="ctr"> +<table border="0" summary=""> +<colgroup><col align="left" /><col align="right" /></colgroup> +<tr><td></td><td>Units.</td></tr> +<tr><td>19 lb. of coal and air at the temperature of the air contained 19 lb. Ũ 520° Ũ 0.238</td><td>2,350</td></tr> +<tr><td>Heat of combustion</td><td><span class="underline">14,727</span></td></tr> +<tr><td></td><td>17,078</td></tr> +<tr><td>Deduct heat expended in displacing atmosphere 151 cubic feet</td><td><span class="underline">- 422</span></td></tr> +<tr><td align="center">Total potential energy</td><td>16,656</td></tr> +</table></div> + +<p>Hence work to be expected from the boiler:</p> + +<div class="ctr"> +<table border="0" summary="Equation"> +<tr><td></td> +<td rowspan="2">17,078 units Ũ <span class="xxl">(</span></td> +<td> +<span class="underline">3,777° - 849°</span></td> +<td rowspan="2"><span class="xxl">)</span> - 422 units</td> +</tr> +<tr><td></td><td>3,777°</td></tr> +<tr><td>=</td><td colspan="3">—————————————————</td> +<td>= 13.27 lb.</td></tr> +<tr><td></td><td colspan="3">966 units</td></tr> +</table></div> + +<p>of water evaporated from and at 212°, corresponding to 12,819 units. +The actual result obtained was 11.83 lb.; hence the efficiency of this +boiler was</p> + +<div class="ctr"> +<table border="0" summary="equation"> +<tr><td><span class="underline">11.83</span></td><td rowspan="2">= 0.892.</td></tr> +<tr><td>13.27</td></tr> +</table></div> + +<p>I have already claimed for a boiler that it is a veritable heat +engine, and I have ventured to construct an indicator diagram to +illustrate its working. The rate of transfer of heat from the furnace +to the water in the boiler, at any given point, is some way +proportional to the difference of temperature, and the quantity of +heat in the gases is proportional to their temperatures. Draw a base +line representing -460° Fahr., the absolute zero of temperature. At +one end erect an ordinate, upon which set off T = 3,777°, the +temperature of the furnace. At 849° = <i>t</i>, on the scale of +temperature, draw a line parallel to the base, and mark on it a length +proportional to the heating surface of the boiler; join T by a +diagonal with the extremity of this line, and drop a perpendicular on +to the zero line. The temperature of the water in the boiler being +uniform, the ordinates bounded by the sloping line, and by the line, +<i>t</i>, will at any point be approximately proportional to the rate of +transmission of heat, and the shaded area above <i>t</i> will be +proportional to the quantity of heat imparted to the water. Join T by +another diagonal with extremity of the heating surface on the zero +line, then the larger triangle, standing on the zero line, will +represent the whole of the heat of combustion, and the ratio of the +two triangles will be as the lengths of their respective bases, that +is, as (T-<i>t</i>) / T, which is the expression we have already used. The +heating surface was 220 square feet, and it was competent to transmit +the energy developed by 41 lb. of coal consumed per hour = 12,819 u. Ũ +41 u. = 525,572 units, equal to an average of 2,389 units per square +foot per hour; this value will correspond to the mean pressure in an +ordinary diagram, for it is a measure of the energy with which +molecular motion is transferred from the heated gases to the +boiler-plate, and so to the water. The mean rate of transmission, +multiplied by the area of heating surface, gives the area of the +shaded portion of the figure, which is the total work which should +have been done, that is to say, the work of evaporating 544 lb. of +water per hour. The actual work done, however, was only 485 lb. To +give the speculations we have indulged in a practical turn, it will be +necessary to examine in detail the terms of Carnot's formula. Carnot +labored under great disadvantages. He adhered to the emission theory +of heat; he was unacquainted with its dynamic equivalent; he did not +know the reason of the difference between the specific heat of air at +constant pressure and at constant volume, the idea of an absolute zero +of temperature had not been broached; but the genius of the man, while +it made him lament the want of knowledge which he felt must be +attainable, also enabled him to penetrate the gloom by which he was +surrounded, and enunciate propositions respecting the theory of heat +engines, which the knowledge we now possess enables us to admit as +true. His propositions are:</p> + +<div class="indlist"><p>1. The motive power of heat is independent of the agents employed to +develop it, and its quantity is determined solely by the temperature +of the bodies between which the final transfer of caloric takes place.</p> + +<p><a name="Page_7034" id="Page_7034"></a>2. The temperature of the agent must in the first instance be raised +to the highest degree possible in order to obtain a great fall of +caloric, and as a consequence a large production of motive power.</p> + +<p>3. For the same reason the cooling of the agent must be carried to as +low a degree as possible.</p> + +<p>4. Matters must be so arranged that the passage of the elastic agent +from the higher to the lower temperature must be due to an increase of +volume, that is to say, the cooling of the agent must be caused by its +rarefaction.</p></div> + +<p>This last proposition indicates the defective information which Carnot +possessed. He knew that expansion of the elastic agent was accompanied +by a fall of temperature, but he did not know that that fall was due +to the conversion of heat into work. We should state this clause more +correctly by saying that "the cooling of the agent must be caused by +the external work it performs." In accordance with these propositions, +it is immaterial what the heated gases or vapors in the furnace of a +boiler may be, provided that they cool by doing external work and, in +passing over the boiler surfaces, impart their heat energy to the +water. The temperature of the furnace, it follows, must be kept as +high as possible. The process of combustion is usually complex. First, +in the case of coal, close to the fire-bars complete combustion of the +red hot carbon takes place, and the heat so developed distills the +volatile hydrocarbons and moisture in the upper layers of the fuel. +The inflammable gases ignite on or near the surface of the fuel, if +there be a sufficient supply of air, and burn with a bright flame for +a considerable distance around the boiler. If the layer of fuel be +thin, the carbonic acid formed in the first instance passes through +the fuel and mixes with the other gases. If, however, the layer of +fuel be thick, and the supply of air through the bars insufficient, +the carbonic acid is decomposed by the red hot coke, and twice the +volume of carbonic oxide is produced, and this, making its way through +the fuel, burns with a pale blue flame on the surface, the result, as +far as evolution of heat is concerned, being the same as if the +intermediate decomposition of carbonic acid had not taken place. This +property of coal has been taken advantage of by the late Sir W. +Siemens in his gas producer, where the supply of air is purposely +limited, in order that neither the hydrocarbons separated by +distillation, nor the carbonic oxide formed in the thick layer of +fuel, may be consumed in the producer, but remain in the form of crude +gas, to be utilized in his regenerative furnaces.</p> + +<p class="ctr"><a href="./images/3a-3.png"><img src="./images/3a-3_th.png" alt=" THE GENERATION OF STEAM. Fig 3." /></a><br /> THE GENERATION OF STEAM. Fig 3.</p> + +<p class="ctr"><a href="./images/3a-4.png"><img src="./images/3a-4_th.png" alt=" THE GENERATION OF STEAM. Fig 4." /></a><br /> THE GENERATION OF STEAM. Fig 4.</p> + +<p class="ctr"><a href="./images/3a-5.png"><img src="./images/3a-5_th.png" alt=" THE GENERATION OF STEAM. Fig 5." /></a><br /> THE GENERATION OF STEAM. Fig 5.</p> + +<p class="ctr"><img src="./images/3a-6.png" alt="THE GENERATION OF STEAM. Fig 6." /><br />THE GENERATION OF STEAM. Fig 6.</p> + +<p class="ctr"><a href="./images/3a-7.png"><img src="./images/3a-7_th.png" alt="THE GENERATION OF STEAM. Fig 7." /></a><br /> THE GENERATION OF STEAM. Fig 7.</p> + +<p class="ctr"><i>(To be continued.)</i></p> + + +<div class="note"><p><a name="Footnote_1" id="Footnote_1"></a><a href="#FNanchor_1">[1]</a></p> +<p>Lecture delivered at the Institution of Civil Engineers, +session 1883-84. For the illustrations we are indebted to the courtesy +of Mr. J. Forrest, the secretary.</p> + +<p><a name="Footnote_2" id="Footnote_2"></a><a href="#FNanchor_2">[2]</a></p> +<p>In the fifty-second volume of the <i>Proceedings</i> +(1887-78), page 154, will be found a remarkable experiment on the +evaporative power of a vertical boiler with internal circulating +pipes. The experiment was conducted by Sir Frederick Bramwell and Dr. +Russell, and is remarkable in this respect, that the quantity of air +admitted to the fuel, the loss by convection and radiation, and the +composition of the smoke were determined. The facts observed were as +follows:</p> + +<div class="ctr"> +<table border="0" summary="" width="90%"> +<colgroup span="2"><col align="left" /><col align="right" width="100px" /></colgroup> +<tr><td>Steam pressure 53 lb</td><td>= 300.6° F.</td></tr> +<tr><td></td><td>lb.</td></tr> +<tr><td>Fuel—Water in coke and wood</td><td>26.08</td></tr> +<tr><td><span class="indlist">Ash</span></td><td>10.53</td></tr> +<tr><td><span class="indlist">Hydrogen, oxygen, nitrogen, and sulphur</span></td><td>7.18</td></tr> +<tr><td></td><td>———</td></tr> +<tr><td><span class="indlist"><span class="indlist">Total non-combustible</span></span></td><td>43.79</td></tr> +<tr><td><span class="indlist">Carbon, being useful combustible</span></td><td>194.46</td></tr> +<tr><td></td><td>———</td></tr> +<tr><td><span class="indlist">Total fuel</span></td><td>238.25</td></tr> +<tr><td> </td></tr> +<tr><td>Air per pound of carbon</td><td>17-1/8 lb.</td></tr> +<tr><td>Time of experiment</td><td>4 h. 12 min.</td></tr> +<tr><td>Water evaporated from 60° into steam at 53 lb. pressure</td><td>1,620 lb.</td></tr> +<tr><td>Heat lost by radiation and convection</td><td>70,430 units.</td></tr> +<tr><td>Mean temperature of chimney</td><td>700° F.</td></tr> +<tr><td>Mean temperature of air</td><td>70° F.</td></tr> +</table></div> + +<p>No combustible gas was found in the chimney.</p> + +<p>I will apply Carnot's doctrine to this case.</p> + +<p>Potential energy of the fuel with respect to absolute zero:</p> + +<div class="ctr"> +<table border="0" summary="" width="90%"> +<colgroup span="2"><col align="left" /><col align="right" width="100px" /></colgroup> +<tr><td></td><td>Units.</td></tr> +<tr><td>239.25 lb. Ũ 530° abs. Ũ 0.238</td><td>= 30,053</td></tr> +<tr><td>194.46 lb. Ũ 17-1/8 Ũ 530° Ũ 0.238, the weight and heat of air </td><td>420,660</td></tr> +<tr><td>194.46 Ũ 14,544 units heat of combustion of carbon </td><td>2,828,200</td></tr> +<tr><td></td><td>————</td></tr> +<tr><td><span class="indlist">Total energy</span></td><td>3,278,813</td></tr> +<tr><td>Heat absorbed in evaporating 26.08 lb. of water in fuel </td><td>-29,888</td></tr> +<tr><td></td><td>————</td></tr> +<tr><td><span class="indlist">Available energy</span></td><td>3,248,425</td></tr> +</table></div> + +<p>Temperature of furnace—</p> + +<p>The whole of the fuel was heated up, but the heat absorbed in the +evaporation of the water lowered the temperature of the furnace, and +must be deducted from the heat of combustion.</p> + +<div class="ctr"> +<table border="0" summary="" width="90%"> +<colgroup span="2"><col align="left" /><col align="right" width="100px" /></colgroup> +<tr><td></td><td>Units.</td></tr> +<tr><td>Heat of combustion</td><td>2,828,200</td></tr> +<tr><td>Heat of evaporation of 26.08 lb. water</td><td>-29,888</td></tr> +<tr><td></td><td>———</td></tr> +<tr><td><span class="indlist">Available heat of combustion</span></td><td>2,798,312</td></tr> +<tr><td>Dividing by 238.25 lb. gives the heat per 1 lb. of fuel used</td><td>= 11,745 units.</td></tr> +</table></div> + +<p>And temperature of furnace:</p> + +<div class="ctr"> +<table border="0" summary="" width="90%"> +<colgroup span="3"><col align="left" span="2" /><col align="right" width="100px" /></colgroup> +<tr><td align="center">11,745 units<br /><span class="overline">(18.125 lb. Ũ 0.238)</span></td><td> + 530°</td><td>= 3,253°</td></tr> +<tr><td colspan="2" align="left">Temperature of chimney 700° + 460°</td><td>= 1,160°</td></tr> +<tr><td>Maximum duty</td><td align="center"><span class="underline">(3,253° - 1,160°)</span><br />3,253°</td><td>= 0.643°</td></tr> +</table></div> + +<p>Work of displacing atmosphere by smoke at 700°:</p> + +<div class="ctr"> +<table border="0" summary="" width="90%"> +<colgroup span="2"><col align="left" /><col align="right" width="100px" /></colgroup> +<tr><td></td><td>Cubic feet.</td></tr> +<tr><td>Volumes of gases at 70°</td><td>= 228.3</td></tr> +<tr><td>Volumes of gases at 700°</td><td>= 499.8</td></tr> +<tr><td></td><td>———</td></tr> +<tr><td><span class="indlist">Increase of volume</span></td><td>271.5</td></tr> +<tr><td> </td></tr> +<tr><td>Work done= </td><td>Units.</td></tr> +<tr><td align="center"><span class="underline">(194.46 lb. Ũ 271.5 cub. ft. Ũ 144 sq. in. Ũ 15 lb.)</span><br /> 722 units</td><td>= 147,720</td></tr> +<tr><td>Maximum amount of work to be expected = 3,248,425 Ũ 0.643</td><td>= 2,101,700</td></tr> +<tr><td>Deduct work of displacing atmosphere</td><td>= 147,720</td></tr> +<tr><td></td><td>————</td></tr> +<tr><td><span class="indlist">Available work</span></td><td>1,953,980</td></tr> +</table></div> + +<p>Actual work done:</p> + +<div class="ctr"> +<table border="0" summary="" width="90%"> +<colgroup span="2"><col align="left" /><col align="right" width="100px" /></colgroup> +<tr><td></td><td>Units.</td></tr> +<tr><td>1,620 lb. of water raised from 60° and turned into steam at 53 lb</td><td>= 1,855,900</td></tr> +<tr><td>Loss by radiation and convection</td><td>70,430</td></tr> +<tr><td>10― lb. ashes left, say at 500°</td><td>1,129</td></tr> +<tr><td></td><td>————</td></tr> +<tr><td><span class="indlist">Total work actually done</span></td><td>1,927,459</td></tr> +<tr><td>Unaccounted for</td><td>26,521</td></tr> +<tr><td></td><td>————</td></tr> +<tr><td><span class="indlist">Calculated available work</span></td><td>1,953,980</td></tr> +</table></div> + +<p>The unaccounted-for work, therefore, amounts to only 1― per cent. of +the calculated available work.</p> + +<p>Sir Frederick Bramwell ingeniously arranged his data in the form of a +balance sheet, and showed 253,979 units unaccounted for; but if from +this we deduct the work lost in displacing the air, the +unaccounted-for heat falls to less than 4 per cent. of the total heat +of combustion. These results show how extremely accurate the +observations must have been, and that the loss mainly arises from +convection and radiation from the boiler.</p></div> + +<hr /> + +<p class="ctr">[Continued from SUPPLEMENT No. 437, page 6970.]</p> + + +<h2><a name="art09" id="art09"></a>PLANETARY WHEEL-TRAINS.</h2> + +<h3>By Prof. C.W. MACCORD, Sc.D.</h3> + + +<h3>II.</h3> + +<p class="ctr"><img src="./images/4-14.png" alt="PLANETARY WHEEL TRAINS. Fig. 14" /><br />PLANETARY WHEEL TRAINS. Fig. 14</p> + +<p>It has already been shown that the rotations of all the wheels of a +planetary train, relatively to the train-arm, are the same when the +arm is in motion as they would be if it were fixed. Now, in Fig. 14, +let A be the first and F the last wheel of an <i>incomplete</i> train, that +is, one having but one sun-wheel. As before, let these be so connected +by intermediate gearing that, when T is stationary, a rotation of A +through <i>m</i> degrees shall drive F through <i>n</i> degrees: and also as +before, let T in the same time move through <i>a</i> degrees. Then, if <i>m'</i> +represent the total motion of A, we have again,</p> + +<p class="ctr"> <i>m'</i> = <i>m</i> + <i>a</i>, or <i>m</i> = <i>m'</i> - <i>a</i>.</p> + +<p>This is, clearly, the motion of A relatively to the fixed frame of the +machine; and is measured from a fixed vertical line through the +center of A. Now, if we wish to express the total motion of F +relatively to the same fixed frame, we must measure it from a vertical +line through the center of F, wherever that maybe; which gives in this +case:</p> + +<p class="ctr"><i>n'</i> = <i>n</i> + <i>a</i>, or <i>n</i> = <i>n'</i> - <i>a</i>.</p> + +<p>but with respect to the train-arm when at rest, we have:</p> + +<div class="ctr"> +<table summary="equation"> +<tr><td><span class="underline">ang. vel. A</span><br /> ang. vel. F</td> +<td> = </td><td><span class="underline"><i>n</i></span><br /><i>m</i></td><td>, whence again,</td></tr> +<tr><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>m'</i> - <i>a</i></td> +<td> = </td><td><span class="underline"><i>n</i></span><br /><i>m</i></td><td align="left">.</td></tr> +</table> +</div> + +<p>This is the manner in which the equation is deduced by Prof. Willis, +who expressly states that it applies whether the last wheel F is or is +not concentric with the first wheel A, and also that the train may be +composed of any combinations which transmit rotation with both a +constant velocity ratio and a constant directional relation. He +designates the quantities <i>m'</i>, <i>n'</i>, <i>absolute revolutions</i>, as +distinguished from the <i>relative revolutions</i> (that is, revolutions +relatively to the train-arm), indicated by the quantities <i>m</i>, n: +adding, "Hence it appears that the absolute revolutions of the wheels +of epicyclic trains are equal to the sum of their relative revolutions +to the arm, and of the arm itself, when they take place in the same +direction, and equal to the difference of these revolutions when in +the opposite direction."</p> + +<p>In this deduction of the formula, as in that of Prof. Rankine, all the +motions are supposed to have the same direction, corresponding to that +of the hands of the clock; and in its application to any given train, +the signs of the terms must be changed in case of any contrary motion, +as explained in the preceding article.</p> + +<p>And both the deduction and the application, in reference to these +incomplete trains in which the last wheel is carried <a name="Page_7035" id="Page_7035"></a>by the +train-arm, clearly involve and depend upon the resolving of a motion +of revolution into the components of a circular translation and a +rotation, in the manner previously discussed.</p> + +<p class="ctr"><img src="./images/4-15.png" alt="PLANETARY WHEEL TRAINS. Fig. 15" /><br />PLANETARY WHEEL TRAINS. Fig. 15</p> + +<p>To illustrate: Take the simple case of two equal wheels, Fig. 15, of +which the central one A is fixed. Supposing first A for the moment +released and the arm to be fixed, we see that the two wheels will turn +in opposite directions with equal velocities, which gives <i>n</i>/<i>m</i> = -1; +but when A is fixed and T revolves, we have <i>m'</i> = 0, whence in the +general formula</p> + +<div class="ctr"> +<table summary="equation"> +<tr><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>-a</i></td> +<td align="left"> = -1, or <i>n'</i> = 2 <i>a</i>; </td></tr> +</table></div> + + +<p>which means, being interpreted, that F makes two rotations about its +axis during one revolution of T, and in the same direction. Again, let +A and F be equal in the 3-wheel train, Fig. 16, the former being fixed +as before. In this case we have:</p> + +<div class="ctr"> +<table summary="equation"> +<colgroup span="2"><col align="center" /><col align="left" /></colgroup> +<tr><td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td> = 1, <i>m'</i> = 0, which gives</td></tr> +<tr><td> </td></tr> +<tr><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>-a</i></td> +<td> = 1, ∴ <i>n'</i> = 0;</td></tr> +</table></div> + +<p>that is to say, the wheel F, which now evidently has a motion of +circular translation, does not rotate at all about its axis during the +revolution of the train-arm.</p> + +<p class="ctr"><img src="./images/4-16.png" alt="PLANETARY WHEEL TRAINS. Fig. 16" /><br />PLANETARY WHEEL TRAINS. Fig. 16</p> + +<p>All this is perfectly consistent, clearly, with the hypothesis that +the motion of circular translation is a simple one, and the motion of +revolution about a fixed axis is a compound one.</p> + +<p>Whether the hypothesis was made to substantiate the formula, or the +formula constructed to suit the hypothesis, is not a matter of +consequence. In either case, no difficulty will arise so long as the +equation is applied only to cases in which, as in those here +mentioned, that motion of revolution <i>can</i> be resolved into those +components.</p> + +<p>When the definition of an epicyclic train is restricted as it is by +Prof. Rankine, the consideration of the hypothesis in question is +entirely eliminated, and whether it be accepted or rejected, the whole +matter is reduced to merely adding the motion of the train-arm to the +rotation of each sun-wheel.</p> + +<p>But in attempting to apply this formula in analyzing the action of an +incomplete train, we are required to add this motion of the train-arm, +not only to that of a sun-wheel, but to that of a planet-wheel. This +is evidently possible in the examples shown in Figs. 15 and 16, +because the motions to be added are in all respects similar: the +trains are composed of spur-wheels, and the motions, whether of +revolution, translation, or rotation, <i>take place in parallel planes +perpendicular to parallel axes</i>. This condition, which we have +emphasized, be it observed, must hold true with regard to the motions +of the first and last wheels and the train-arm, in order to make this +addition possible. It is not essential that spur-wheels should be used +exclusively or even at all; for instance, in Fig. 16, A and F may be +made bevel or screw-wheels, without affecting the action or the +analysis; but the train-arm in all cases revolves around the central +axis of the system, that is, about the axis of A, and to this the axis +of F <i>must</i> be parallel, in order to render the deduction of the +formula, as made by Prof. Willis, and also by Prof. Goodeve, correct, +or even possible.</p> + +<p class="ctr"><img src="./images/4-17.png" alt="PLANETARY WHEEL TRAINS. Fig. 17" /><br />PLANETARY WHEEL TRAINS. Fig. 17</p> + +<p>This will be seen by an examination of Fig. 17; in which A and B are +two equal spur-wheels, E and F two equal bevel wheels, B and E being +secured to the same shaft, and A being fixed to the frame H. As the +arm T goes round, B will also turn in its bearings in the same +direction: let this direction be that of the clock, when the apparatus +is viewed from above, then the motion of F will also have the same +direction, when viewed from the central vertical axis, as shown at F': +and let these directions be considered as positive. It is perfectly +clear that F will turn in its bearings, in the direction indicated, at +a rate precisely equal to that of the train-arm. Let P be a pointer +carried by F, and R a dial fixed to T; and let the pointer be vertical +when OO is the plane containing the axes of A, B, and E. Then, when F +has gone through any angle a measured from OO, the pointer will have +turned from its original vertical position through an equal angle, as +shown also at F'.</p> + +<p>Now, there is no conceivable sense in which the motion of T can be +said to be added to the rotation of F about its axis, and the +expression "absolute revolution," as applied to the motion of the last +wheel in this train, is absolutely meaningless.</p> + +<p>Nevertheless, Prof. Goodeve states (Elements of Mechanism, p. 165) +that "We may of course apply the general formula in the case of bevel +wheels just as in that of spur wheels." Let us try the experiment; +when the train-arm is stationary, and A released and turned to the +right, F turns to the left at the same rate, whence:</p> + +<div class="ctr"> +<table summary="equation"> +<tr><td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td> = -1; also <i>m'</i>= 0 when A is fixed,</td></tr> +</table></div> + +<p>and the equation becomes</p> + +<div class="ctr"> +<table summary="equation"> +<tr><td><span class="underline"><i>n'</i> - <i>a</i></span><br /> - <i>a</i></td> +<td> = -1, ∴ <i>n</i>' = 2 <i>a</i>:</td></tr> +</table></div> + +<p>or in other words F turns <i>twice</i> on its axis during one revolution of +T: a result too palpably absurd to require any comment. We have seen +that this identical result was obtained in the case of Fig. 15, and it +would, of course, be the same were the formula applied to Figs. 5 and +6; whereas it has never, so far as we are aware, been pretended that a +miter or a bevel wheel will make more than one rotation about its axis +in rolling once around an equal fixed one.</p> + +<p>Again, if the formula be general, it should apply equally well to a +train of screw wheels: let us take, for example, the single pair shown +in Fig. 8, of which, when T is fixed, the velocity ratio is unity. The +directional relation, however, depends upon the direction in which the +wheels are twisted: so that in applying the formula, we shall have +<i>n/m</i> = +1, if the helices of both wheels are right handed, and <i>n</i>/<i>m</i> += -1, if they are both left handed. Thus the formula leads to the +surprising conclusion, that when A is fixed and T revolves, the +planet-wheel B will revolve about its axis twice as fast as T moves, +in one case, while in the other it will not revolve at all.</p> + +<p class="ctr"><img src="./images/4-18.png" alt="PLANETARY WHEEL TRAINS. Fig. 18" /><br />PLANETARY WHEEL TRAINS. Fig. 18</p> + +<p>A favorite illustration of the peculiarities of epicyclic mechanism, +introduced both by Prof. Willis and Prof. Goodeve, is found in the +contrivance known as Ferguson's Mechanical Paradox, shown in Fig. 18. +This consists of a fixed sun-wheel A, engaging with a planet-wheel B +of the same diameter. Upon the shaft of B are secured the three thin +wheels E, G, I, each having 20 teeth, and in gear with the three +others F, H, K, which turn freely upon a stud fixed in the train-arm, +and have respectively 19, 20, and 21 teeth. In applying the general +formula, we have the following results:</p> + +<div class="ctr"><table summary="equation"> +<tr><td>For the wheel</td><td>F,</td><td></td><td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td> = </td><td><span class="underline">20</span><br />19</td> +<td> = </td><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>-a</i></td> +<td>∴ <i>n'</i> =</td><td>-</td><td>1<br /><span class="overline">19</span></td><td><i>a</i>.</td></tr> + +<tr><td> </td></tr> +<tr><td>"</td><td>H,</td><td></td><td><span class="underline"><i>n</i></span><br /><i>m</i></td><td> = </td><td>1</td> +<td> = </td><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>-a</i></td> +<td>∴ <i>n'</i> =</td><td>0.</td></tr> + +<tr><td>"</td><td>K,</td><td></td><td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td> = </td><td><span class="underline">21</span><br />20</td> +<td> = </td><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>-a</i></td> +<td>∴ <i>n'</i> =</td><td>+</td><td>1<br /><span class="overline">21</span></td><td><i>a</i>.</td></tr> +</table></div> + + +<p>The paradoxical appearance, then, consists in this, that although the +drivers of the three last wheels each have the same number of teeth, +yet the central one, H, having a motion of circular translation, +remains always parallel to itself, and relatively to it the upper one +seems to turn in the same direction as the train-arm, and the lower in +the contrary direction. And the appearance is accepted, too, as a +reality; being explained, agreeably to the analysis just given, by +saying that H has no absolute rotation about its axis, while the other +wheels have; that of F being positive and that of K negative.</p> + +<p>The Mechanical Paradox, it is clear, may be regarded as composed of +three separate trains, each of which is precisely like that of Fig. +16: and that, again, differs from the one of Fig. 15 only in the +addition of a third wheel. Now, we submit that the train shown in Fig. +17 is mechanically equivalent to that of Fig. 15; the velocity ratio +and the directional relation being the same in both. And if in Fig. 17 +we remove the index P, and fix upon its shaft three wheels like E, G, +and I of Fig. 18, we shall have a combination mechanically equivalent +to Ferguson's Paradox, the three last wheels rotating in vertical +planes about horizontal axes. The relative motions of those three +wheels will be the same, obviously, as in Fig. 18; and according to +the formula their absolute motions are the same, and we are invited to +perceive that the central one does not rotate at all about its axis.</p> + +<p>But it <i>does</i> rotate, nevertheless; and this unquestioned fact is of +itself enough to show that there is something wrong with the formula +as applied to trains like those in question. What that something is, +we think, has been made clear by what precedes; since it is impossible +in any sense to add together motions which are unlike, it will be seen +that in order to obtain an intelligible result in cases like these, +the equation must be of the form <i>n'</i>/(<i>m'</i>-<i>a</i>) = <i>n</i>/<i>m</i>. We shall then have:</p> + +<div class="ctr"> +<table border="0" summary="equation"> +<tr><td>For the wheel F,</td> +<td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td>=</td> +<td><span class="underline">20</span><br />19</td> +<td>=</td> +<td><span class="underline"><i>n'</i></span><br /><i>-a</i></td> +<td>, ∴ <i>n'</i> = - </td> +<td><span class="underline">20</span><br />19</td> +<td><i>a</i>.</td></tr> +<tr><td> </td></tr> +<tr><td>For the wheel H,</td> +<td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td>=</td> +<td>1</td> +<td>=</td> +<td><span class="underline"><i>n'</i></span><br /><i>-a</i></td> +<td>, ∴ <i>n'</i> = -</td><td><i>a</i>;</td></tr> +<tr><td> </td></tr> +<tr><td>For the wheel K,</td> +<td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td>=</td> +<td><span class="underline">21</span><br />20</td> +<td>=</td> +<td><span class="underline"><i>n'</i></span><br /><i>-a</i></td> +<td>, ∴ <i>n'</i> = -</td> +<td><span class="underline">21</span><br />20</td> +<td><i>a</i>,</td></tr> +</table></div> + + +<p>which corresponds with the actual state of things; all three wheels +rotate in the same direction, the central one at the same rate as the +train arm, one a little more rapidly and the third a little more +slowly.</p> + +<p>It is, then, absolutely necessary to make this modification in the +general formula, in order to apply it in determining the rotations of +any wheel of an epicyclic train whose axis is not parallel to that of +the sun-wheels. And in this modified form it applies equally well to +the original arrangement of Ferguson's paradox, if we abandon the +artificial distinction between "absolute" and "relative" rotations of +the planet-wheels, and regard a spur-wheel, like any other, as +rotating on its axis when it turns in its bearings; the action of the +device shown in Fig. 18 being thus explained by saying that the wheel +H turns once backward during each forward revolution of the train-arm, +while F turns a little more and K a little less than once, in the same +direction. In this way the classification and analysis of these +combinations are made more simple and consistent, and the +incongruities above pointed out are avoided; since, without regard to +the kind of gearing employed or the relative positions of the axes, we +have the two equations:</p> + +<div class="ctr"> +<table summary="equation"> +<tr><td>I.</td><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>m'</i> - <i>a</i></td> +<td>=</td><td><span class="underline"><i>n</i></span><br /><i>m</i></td><td>, for all complete trains;</td></tr> +<tr><td> </td></tr> +<tr><td>II.</td><td><span class="underline"><i>n'</i></span><br /><i>m'</i> - <i>a</i></td> +<td>=</td><td><span class="underline"><i>n</i></span><br /><i>m</i></td><td>, for all incomplete trains.</td></tr> +</table></div> + +<p class="ctr"><img src="./images/4-19.png" alt="PLANETARY WHEEL TRAINS. Fig. 19" /><br />PLANETARY WHEEL TRAINS. Fig. 19</p> + +<p>As another example of the difference in the application of these +formulæ, let us take Watt's sun and planet wheels, Fig. 19. This +device, as is well known, was employed by the illustrious inventor as +a substitute for the crank, which some one had succeeded in patenting. +It consists merely of two wheels A and F connected by the link T; A +being keyed on the shaft of the engine and F being rigidly secured to +the connecting-rod. Suppose the rod to be of infinite length, so as to +remain always parallel to itself, and the two wheels to be of equal +size.</p> + +<p>Then, according to Prof. Willis' analysis, we shall have—</p> + +<div class="ctr"> +<table summary="Equation"> +<tr><td><span class="underline"><i>n'</i> - <i>a</i></span><br /><i>m'</i> - <i>a</i></td> +<td>=</td> +<td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td>= -1, <i>n'</i> = 0, ∴ </td> +<td><i>-a</i><br /><span class="overline"><i>m'</i> - <i>a</i></span></td> +<td>= -1, whence</td></tr> +</table> +<p class="ctr"><i>-a</i> = <i>a</i> - <i>m'</i>, or <i>m</i> = 2<i>a</i>.</p></div> + + +<p>The other view of the question is, that F turns once backward in its +bearings during each forward revolution of T; whence in Eq. 2 we +have—</p> + +<div class="ctr"><table summary="Equation"> +<tr><td><i>n'</i><br /><span class="overline"><i>m'</i> - <i>a</i></span></td> +<td>=</td> +<td><span class="underline"><i>n</i></span><br /><i>m</i></td> +<td>= -1, <i>n'</i> = - <i>a</i>,</td></tr> +</table></div> + +<div class="ctr"> +<table summary=""> +<tr><td> ∴</td> +<td><i>-a</i><br /><span class="overline"><i>m'</i> - <i>a</i></span></td> +<td>= -1 which gives <i>-a</i> = <i>a</i> - <i>m'</i>, or <i>m'</i> = 2<i>a</i>,</td></tr> +</table> +</div> + +<p>as before.</p> + +<p>It is next to be remarked, that the errors which arise from applying +Eq. I. to incomplete trains may in some cases counterbalance and +neutralize each other, so that the final result is correct.</p> + +<p class="ctr"><img src="./images/4-20.png" alt="PLANETARY WHEEL TRAINS. Fig. 20" /><br />PLANETARY WHEEL TRAINS. Fig. 20</p> + +<p>For example, take the combination shown in Fig. 20. This consists of a +train-arm T revolving about the vertical axis OO of the fixed wheel A, +which is equal in diameter to F, which receives its motion by the +intervention of one idle wheel carried by a stud S fixed in the arm. +The second train-arm T' is fixed to the shaft of F and turns with it; +A' is secured to the arm T, and F' is actuated by A' also through a +single idler carried by T'.</p> + +<p>We have here a compound train, consisting of two simple planetary +trains, A—F and A'—F'; and its action is to be determined by +considering them separately. First suppose T' to be removed and find +the motion of F; next suppose F to be removed and T fixed, and find +the rotation of F'; and finally combine these results, noting that the +motion of T' is the same as that of F, and the motion of A' the same +as that of T.</p> + +<p>Then, according to the analysis of Prof. Willis, we shall have +(substituting the symbol <i>t</i> for <i>a</i> in the equation of the second +train, in order to avoid confusion):</p> + +<div class="ctr"> +<table summary=""> +<colgroup span="5"><col align="left" /><col align="center" /> +<col align="left" /><col align="center" /><col align="left" /></colgroup> +<tr><td rowspan="2" valign="middle"> 1. Train A—F.</td> +<td><span class="underline"><i>n</i></span></td><td rowspan="2" valign="middle"> = 1 = </td> +<td><span class="underline"><i>m'</i> - <i>a</i></span></td><td rowspan="2" valign="middle">; <i>m'</i> = 0,</td></tr> +<tr><td><i>m</i></td><td><i>m'</i> - <i>a</i></td></tr> +<tr><td rowspan="2" valign="middle">whence</td><td colspan="2"></td> +<td><span class="underline"><i>n'</i> - <i>a</i></span></td> +<td rowspan="2" valign="middle">= 1, <i>n'</i> = 0, = rot. of F.</td></tr> +<tr><td colspan="2"></td><td><i>- a</i></td></tr> +<tr><td rowspan="2" valign="middle"> 2. Train A'—F'.</td> +<td><span class="underline"><i>n</i></span></td><td rowspan="2" valign="middle"> = 1 = </td> +<td><span class="underline"><i>m'</i> - <i>t</i></span></td><td rowspan="2" valign="middle">; <i>m'</i> = 0,</td></tr> +<tr><td><i>m</i></td><td><i>m'</i> - <i>t</i></td></tr> +<tr><td rowspan="2" valign="middle">whence again</td><td colspan="2"></td> +<td><span class="underline"><i>n'</i> - <i>t</i></span></td> +<td rowspan="2" valign="middle">= 1, <i>t</i> = 0, = rot. of F'.</td></tr> +<tr><td colspan="2"></td><td><i>- t</i></td></tr> +</table></div> + +<p>Of these results, the first is explicable as being the <i>absolute</i> +rotation of F, but the second is not; and it will be readily seen that +the former would have been equally absurd, had the axis LL been +inclined instead of vertical. But in either case we should find the +errors neutralized upon combining the two, for according to the theory +now under consideration, the wheel A', being fixed to T, turns once +upon its axis each time that train arm revolves, and in the same +direction; and the revolutions of T' equal the rotations of F, whence +finally in train A'—F' we have:</p> + +<div class="ctr"><table summary=""> +<tr><td rowspan="2" valign="middle"> 3.</td> +<td><span class="underline"><i>n</i></span></td> +<td rowspan="2" valign="middle"> = 1 = </td> +<td><span class="underline"><i>n'</i> - <i>t</i></span></td> +<td rowspan="2" valign="middle">; in which <i>t</i> = 0, <i>m'</i> = <i>a</i>,</td></tr> +<tr><td><i>m</i></td><td><i>m'</i> - <i>t</i></td></tr> +<tr><td colspan="3" rowspan="2" valign="middle">which gives</td> +<td><span class="underline"><i>n'</i> - 0</span></td> +<td rowspan="2" valign="middle" align="left">= 1, or <i>n'</i> = <i>a</i>.</td></tr> +<tr><td><i>a</i> - 0</td></tr></table></div> + + +<p>This is, unquestionably, correct; and indeed it is quite obvious that +the effect upon F' is the same, whether we say that during a +revolution of T the wheel A' turns once forward and T' not at all, or +adopt the other view and assert that T' turns once backward and A' not +at all. But the latter view has the advantage of giving concordant +results when the trains are considered separately, and that without +regard to the relative positions of the axes or the kind of gearing +employed. Analyzing the action upon this hypothesis, we have:</p> + + +<div class="ctr"><table summary=""> +<colgroup span="5"><col align="left" /><col align="center" /> +<col align="left" /><col align="center" /><col align="left" /></colgroup> +<tr><td rowspan="2" valign="middle">In train A—F:</td> +<td><i>n</i></td><td rowspan="2" valign="middle"> = 1 = </td> +<td><i>n'</i></td> +<td rowspan="2" valign="middle">; <i>m'</i> = 0, ∴</td> +<td><i>n'</i></td> +<td rowspan="2" valign="middle"> = 1, or <i>n'</i> = <i>-a</i>;</td></tr> +<tr><td><span class="overline"><i>m</i></span></td> +<td><span class="overline"><i>m'</i> - <i>a</i></span></td> +<td><span class="overline"><i>-a</i></span></td></tr> +<tr><td rowspan="2" valign="middle">In train A'—F':</td> +<td><i>n'</i></td><td rowspan="2" valign="middle"> = 1 = </td> +<td><i>n'</i></td> +<td rowspan="2" valign="middle">; <i>m'</i> = 0, ∴</td> +<td><i>n'</i></td> +<td rowspan="2" valign="middle"> = 1, or <i>n'</i> = <i>-t</i>;</td></tr> +<tr><td><span class="overline"><i>m</i></span></td> +<td><span class="overline"><i>m'</i> - <i>t</i></span></td> +<td><span class="overline"><i>-t</i></span></td></tr> +</table></div> + +<p>In combining, we have in the latter train <i>m'</i> = 0, <i>t</i> = <i>-a</i>, whence</p> + +<div class="ctr"><table summary=""> +<colgroup span="6"><col align="center" /><col align="left" /> +<col align="center" /><col align="left" /><col align="center" /><col align="left" /> +</colgroup> +<tr><td><i>n</i><br /><span class="overline"><i>m</i></span></td><td>= 1 =</td> +<td><i>n'</i><br /><span class="overline"><i>m'</i> - <i>t</i></span></td> +<td>gives</td><td><i>n'</i><br /><span class="overline"><i>+a</i></span></td> +<td> = 1, or <i>n'</i> = <i>a</i>, as before.</td></tr> +</table></div> + +<p>Now it happens that the only examples given by Prof. Willis of +incomplete trains in which the axis of a planet-wheel whose motion is +to be determined is not parallel to the central axis of the system, +are similar to the one just discussed; the wheel in question being +carried by a secondary train-arm which derives its motion from a wheel +of the primary train.</p> + +<p>The application of his general equation in these cases gives results +which agree with observed facts; and it would seem that this +circumstance, in connection doubtless with the complexity of these +compound trains, led him to the too hasty conclusion that the formula +would hold true in all cases; although we are still left to wonder at +his overlooking the fact that in these very cases the "absolute" and +the "relative" rotations of the last wheel are identical.</p> + +<p class="ctr"><img src="./images/4-21.png" alt="PLANETARY WHEEL TRAINS. Fig. 21" /><br />PLANETARY WHEEL TRAINS. Fig. 21</p> + +<p>In Fig. 21 is shown a combination consisting also of two distinct +trains, in which, however, there is but one train-arm T turning freely +upon the horizontal shaft OO, to which shaft the wheels A', F, are +secured; the train-arm has two studs, upon which turn the idlers B B', +and also carries the bearings of the last wheel F'; the first wheel A +is annular, and fixed to the frame of the machine. Let it be required +to determine the results of one revolution of the crank H, the numbers +of teeth being assigned as follows:</p> + +<p class="center">A = 60, F = 30, A' = 60, F' = 10.</p> + +<p>We shall then have, for the train ABF (Eq. I.),</p> + +<div class="ctr"> +<table summary=""> +<colgroup span="6"><col align="center" /><col align="left" /> +<col align="center" /><col align="left" /><col align="center" /> +<col align="left" /></colgroup> +<tr><td><i>n</i></td><td rowspan="2" valign="middle"> = -</td><td>60</td> +<td rowspan="2" valign="middle"> = -2 = </td><td><i>n'</i> - <i>a</i></td> +<td rowspan="2" valign="middle">, in which <i>n'</i> = 1, <i>m'</i> = 0,</td></tr> +<tr><td><span class="overline"><i>m</i></span></td><td><span class="overline">30</span></td> +<td><span class="overline"><i>m'</i> - <i>a'</i></span></td></tr> +</table></div> + + +<div class="ctr"><table summary=""> +<colgroup span="4"><col align="left" /> +<col align="center" /><col span="2" align="left" /></colgroup> +<tr><td>whence -2 = </td> +<td><span class="underline">1 - <i>a</i></span><br />-<i>a</i></td> +<td>, 2<i>a</i> = 1 - <i>a</i>, 3<i>a</i> - 1, <i>a</i> =</td> +<td><span class="underline">1</span><br />3</td><td>.</td></tr> +</table></div> + + +<p>And for the train A'B'F' (Eq. II.),</p> + +<div class="ctr"><table summary=""> +<tr><td><i>n</i></td> +<td rowspan="2" valign="middle"> = </td> +<td>60</td> +<td rowspan="2" valign="middle"> = 6 = </td> +<td><i>n'</i></td> +<td rowspan="2" valign="middle">, in which <i>a</i> =</td> +<td>1</td> +<td rowspan="2" valign="middle">, <i>m'</i> = 1,</td></tr> +<tr><td><span class="overline"><i>m</i></span></td> +<td><span class="overline">10</span></td> +<td><span class="overline"><i>m'</i> - <i>a'</i></span></td> +<td><span class="overline">3</span></td></tr> +</table></div> + +<div class="ctr"><table summary=""> +<tr><td rowspan="2" valign="middle">whence 6 = </td> +<td><i>n'</i></td> +<td rowspan="2" valign="middle">, or <i>n'</i> = 4.</td></tr> +<tr><td><span class="overline">1 - (1/3)</span></td></tr> +</table></div> + +<p>That is, the last wheel F' turns <i>four</i> times about the axis LL during +one revolution of the crank H. But according to Profs. Willis and +Goodeve, we should have for the second train:</p> + +<div class="ctr"><table summary=""> +<tr><td><i>n</i></td> +<td rowspan="2" valign="middle"> = </td> +<td>60</td> +<td rowspan="2" valign="middle"> = 6 = </td> +<td><i>n'</i> - <i>a</i></td> +<td rowspan="2" valign="middle">, in which <i>a</i> =</td> +<td>1</td> +<td rowspan="2" valign="middle">, <i>m'</i> = 1,</td></tr> +<tr><td><span class="overline"><i>m</i></span></td> +<td><span class="overline">10</span></td> +<td><span class="overline"><i>m'</i> - <i>a'</i></span></td> +<td><span class="overline">3</span></td></tr> +</table> + +<table summary=""> +<colgroup span="7"><col align="left" /><col align="center" /> +<col align="left" /><col align="center" /><col align="left" /><col span="2" align="center" /> +</colgroup> +<tr><td rowspan="2" valign="middle">which gives 6 =</td> +<td><span class="underline"><i>n'</i> - (1/3)</span></td> +<td rowspan="2" valign="middle">, <i>n'</i> - </td> +<td><span class="underline">1</span></td> +<td rowspan="2" valign="middle"> = 4, <i>n'</i> = 4</td> +<td><span class="underline">1</span></td><td>,</td></tr> +<tr><td>1 - (1/3)</td><td>3</td><td>3</td></tr> +</table></div> + +<p>or <i>four and one-third</i> revolutions of F' for one of H.</p> + +<p>This result, no doubt, might be near enough to the truth to serve all +practical purposes in the application of this mechanism to its +original object, which was that of paring apples, impaled upon the +fork K; but it can hardly be regarded as entirely satisfactory in a +general way; nor can the analysis which renders such a result +possible.</p> + +<hr /> + + +<h2><a name="art10" id="art10"></a>THE PANTANEMONE.</h2> + + +<p>The need of irrigating prairies, inundating vines, drying marshes, and +accumulating electricity cheaply has, for some time past, led to a +search for some means of utilizing the forces of nature better than +has ever hitherto been done. Wind, which figures in the first rank as +a force, has thus far, with all the mills known to us, rendered +services that are much inferior to those that we have a right to +expect from it with improved apparatus; for the work produced, +whatever the velocity of the wind, has never been greater than that +that could be effected by wind of seven meters per second. But, thanks +to the experiments of recent years, we are now obtaining an effective +performance double that which we did with apparatus on the old system.</p> + +<p>Desirous of making known the efforts that have been made in this +direction, we lately described Mr. Dumont's atmospheric <a name="Page_7036" id="Page_7036"></a>turbine. In +speaking of this apparatus we stated that aerial motors generally stop +or are destroyed in high winds. Recently, Mr. Sanderson has +communicated to us the result of some experiments that he has been +making for years back by means of an apparatus which he styles a +pantanemone.</p> + +<p>The engraving that we give of this machine shows merely a cabinet +model of it; and it goes without saying that it is simply designed to +exhibit the principle upon which its construction is based.</p> + +<p class="ctr"><a href="./images/6a.png"><img src="./images/6a_th.png" alt=" THE PANTANEMONE." /></a><br /> THE PANTANEMONE.</p> + +<p>Two plane surfaces in the form of semicircles are mounted at right +angles to each other upon a horizontal shaft, and at an angle of 45° +with respect to the latter. It results from this that the apparatus +will operate (even without being set) whatever be the direction of the +wind, except when it blows perpendicularly upon the axle, thus +permitting (owing to the impossibility of reducing the surfaces) of +three-score days more work per year being obtained than can be with +other mills. Three distinct apparatus have been successively +constructed. The first of these has been running for nine years in the +vicinity of Poissy, where it lifts about 40,000 liters of water to a +height of 20 meters every 24 hours, in a wind of a velocity of from 7 +to 8 meters per second. The second raises about 150,000 liters of +water to the Villejuif reservoir, at a height of 10 meters, every 24 +hours, in a wind of from 5 to 6 meters. The third supplies the +laboratory of the Montsouris observatory.</p> + +<p>The first is not directible, the second may be directed by hand, and +the third is directed automatically. These three machines defied the +hurricane of the 26th of last January.—<i>La Nature.</i></p> + +<hr /> + +<h2><a name="art11" id="art11"></a>RELVAS'S NEW LIFE-BOAT.</h2> + + +<p>The Spanish and Portuguese papers have recently made known some +interesting experiments that have been made by Mr. Carlos Relvas with +a new life-boat which parts the waves with great facility and exhibits +remarkable stability. This boat, which is shown in front view in one +of the corners of our engraving, is T-shaped, and consists of a very +thin keel connected with the side-timbers by iron rods. Cushions of +cork and canvas are adapted to the upper part, and, when the boat is +on the sea, it has the appearance of an ordinary canoe, although, as +may be seen, it differs essentially therefrom in the submerged part. +When the sea is heavy, says Mr. Relvas, and the high waves are +tumbling over each other, they pass over my boat, and are powerless to +capsize it. My boat clears waves that others are obliged to recoil +before. It has the advantage of being able to move forward, whatever +be the fury of the sea, and is capable, besides, of approaching rocks +without any danger of its being broken.</p> + +<p class="ctr"><a href="./images/6b.png"><img src="./images/6b_th.png" alt=" RELVAS'S NEW LIFE BOAT." /></a><br /> RELVAS'S NEW LIFE BOAT.</p> +<p>A committee was appointed by the Portuguese government to examine this +new life-boat, and comparative experiments were made with it and an +ordinary life-boat at Porto on a very rough sea. Mr. Relvas's boat was +manned by eight rowers all provided with cork girdles, while the +government life-boat was manned by twelve rowers and a pilot, all +likewise wearing cork girdles. The chief of the maritime department, +an engineer of the Portuguese navy and a Portuguese deputy were +present at the trial in a pilot boat. The three boats proceeded to the +entrance of the bar, where the sea was roughest, and numerous +spectators collected upon the shore and wharfs followed their +evolutions from afar.</p> + +<p>The experiments began at half past three o'clock in the afternoon. The +two life-boats shot forward to seek the most furious waves, and were +seen from afar to surmount the billows and then suddenly disappear. It +was a spectacle as moving as it was curious. It was observed that Mr. +Relvas's boat cleft the waves, while the other floated upon their +surface like a nut-shell. After an hour's navigation the two boats +returned to their starting point.</p> + +<p>The official committee that presided over these experiments has again +found in this new boat decided advantages, and has pointed out to its +inventor a few slight modifications that will render it still more +efficient.—<i>La Nature.</i></p> + +<hr /> + + + + +<h2><a name="art12" id="art12"></a>EXPERIMENTS WITH DOUBLE-BARRELED GUNS AND RIFLES.</h2> + + +<p>The series of experiments we are about to describe has recently been +made by Mr. Horatio Phillips, a practical gun maker of London. The +results will no doubt prove of interest to those concerned in the use +or manufacture of firearms.</p> + +<p>The reason that the two barrels of a shot gun or rifle will, if put +together parallel, throw their charges in diverging lines has never +yet been satisfactorily accounted for, although many plausible and +ingenious theories have been advanced for the purpose. The natural +supposition would be that this divergence resulted from the axes of +the barrels not being in the same vertical plane as the center line of +the stock. That this is not the true explanation of the fact, the +following experiment would tend to prove.</p> + +<p class="ctr"><img src="./images/6c.png" alt="EXPERIMENTS WITH DOUBLE-BARRELLED GUNS." /><br />EXPERIMENTS WITH DOUBLE-BARRELLED GUNS.</p> + +<p>Fig. 1 represents a single barrel fitted with sights and firmly +attached to a heavy block of beech. This was placed on an ordinary +rifle rest, being fastened thereto by a pin at the corner, A, the +block and barrel being free to revolve upon the pin as a center. +Several shots were fired both with the pin in position and with it +removed, the barrel being carefully pointed at the target each time. +No practical difference in the accuracy of fire was discernible under +either condition. When the pin was holding the corner of the block, +the recoil caused the barrel to move from right to left in a circular +path; but when the pin was removed, so that the block was not attached +to the rest in any way, the recoil took place in a line with the axis +of the bore. It will be observed that the conditions which are present +when a double barreled gun is fired in the ordinary way from the +shoulder were in some respects much exaggerated in the apparatus, for +the pin was a distance of 3 in. laterally from the axis of the barrel, +whereas the center of resistance of the stock of a gun against the +shoulder would ordinarily be about one-sixth of this distance from the +axis of the barrel. This experiment would apparently tend to prove +that the recoil does not appreciably affect the path of the +projectile, as it would seem that the latter must clear the muzzle +before any considerable movement of the barrel takes place.</p> + +<p>With a view to obtain a further confirmation of the result of this +experiment, it was repeated in a different form by a number of shots +being fired from a "cross-eyed" rifle,<a name="FNanchor_3" id="FNanchor_3"></a><a href="#Footnote_3"><sup>1</sup></a> in which the sights were +fixed in the center of the rib. Very accurate shooting was obtained +with this arm.</p> + +<p>A second theory, often broached, in order to account for the +divergence of the charge, is that the barrel which is not being fired, +by its <i>vis inertia</i> in some way causes the shot to diverge. In order +to test this, Mr. Phillips took a single rifle and secured it near the +muzzle to a heavy block of metal, when the accuracy of the shooting +was in no way impaired.</p> + +<p>So far the experiments were of a negative character, and the next step +was made with a view to discover the actual cause of the divergence +referred to. A single barrel was now taken, to which a template was +fitted, in order to record its exact length. The barrel was then +subjected to a heavy internal hydrostatic pressure. Under this +treatment it expanded circumferentially and at the same time was +reduced in length. This, it was considered, gave a clew to the +solution of the problem. A pair of barrels was now taken and a +template fitted accurately to the side of the right-hand one. As the +template fitted the barrel when the latter was not subject to internal +pressure, upon such pressure being applied any alterations that might +ensue in the length or contour of the barrel could be duly noted. The +right-hand barrel was then subjected to internal hydrostatic pressure. +The result is shown in an exaggerated form in Fig. 2. It will be seen +that both barrels are bent into an arched form. This would be caused +by the barrel under pressure becoming extended circumferentially, and +thereby reduced in length, because the metal that is required to +supply the increased circumference is taken to some extent from the +length, although the substance of metal in the walls of the barrel by +its expansion contributes also to the increased diameter. A simple +illustration of this effect is supplied by subjecting an India-rubber +tube to internal pressure. Supposing the material to be sufficiently +elastic and the pressure strong enough, the tube would ultimately +assume a spherical form. It is a well known fact that heavy barrels +with light charges give less divergence than light barrels with heavy +charges.</p> + +<p>After the above experiments it was hoped that, if a pair of barrels +were put together parallel and soldered only for a space of 3 in. at +the breech end, and were then coupled by two encircling rings joined +together as in Fig. 4, the left-hand ring only being soldered to the +barrel, very accurate shooting would be obtained. For, it was argued, +that by these means the barrel under fire would be able to contract +without affecting or being affected by the other barrel; that on the +right-hand, it will be seen by the illustration, was the one to slide +in its ring.</p> + +<p>A pair of able 0.500 bore express rifle barrels were accordingly +fitted in this way. Fig. 3 shows the arrangement with the rings in +position. Upon firing these barrels with ordinary express charges it +was found that the lines of fire from each barrel respectively crossed +each other, the bullet from the right-hand barrel striking the target +10 in. to the left of the bull's eye, while the left barrel placed its +projectile a similar distance in the opposite direction; or, as would +be technically said, the barrels crossed 20 in. at 100 yards, the +latter distance being the range at which the experiment was made. +These last results have been accounted for in the following manner: +The two barrels were rigidly joined for a space of 3 in., and for that +distance they would behave in a manner similar to that illustrated in +Fig. 2, and were they not coupled at the muzzles by the connecting +rings they would shoot very wide, the charges taking diverging +courses. When the connecting rings are fitted on, the barrel not being +fired will remain practically straight, and, as it is coupled to the +barrel being fired by the rings, the muzzle of the latter will be +restrained from pointing outward.</p> + +<p>The result will be as shown in an exaggerated manner by the dotted +lines on the right barrel in Fig. 3.</p> + +<p>It would appear from these experiments that when very accurate +shooting is required at long ranges with double-barreled rifles, they +should be mounted in a manner similar to that adopted in the +manufacture of the Nordenfelt machine gun, in which weapon the barrels +are fitted into a plate at the extreme breech end, the muzzles +projecting through holes bored to receive them in a metal plate. No +unequal expansion would then take place, and the barrels would be free +to become shorter independently of each other. We give the above +experiments on the authority of their author, who, we believe, has +taken great pains to render them as exhaustive as possible, so far as +they go.—<i>Engineering.</i></p> + + +<div class="note"><p><a name="Footnote_3" id="Footnote_3"></a><a href="#FNanchor_3">[1]</a></p> +<p>A cross-eyed rifle is one made with a crooked stock for +the purpose of shooting from the right shoulder, aim being taken with +the left eye.</p></div> + +<hr /> + + +<h2><a name="art13" id="art13"></a>BALL TURNING MACHINE.</h2> + + +<p>The distinguishing feature in the ball turning machine shown opposite +is that the tool is stationary, while the work revolves in two +directions simultaneously. In the case of an ordinary spherical +object, such as brass clack ball, the casting is made from a perfect +pattern having two small caps or shanks, in which the centers are also +marked to avoid centering by hand. It is fixed in the machine between +two centers carried on a face plate or chuck, with which they revolve. +One of these centers, when the machine is in motion,<a name="Page_7037" id="Page_7037"></a> receives a +continuous rotary motion about its axis from a wormwheel, D. This is +driven by a worm, C, carried on a shaft at the back of the chuck, and +driven itself by a wormwheel, B, which gears with a screw which rides +loosely upon the mandrel, and is kept from rotating by a finger on the +headstock. This center, in its rotation, carries with it the ball, +which is thus slowly moved round an axis parallel to the face plate, +at the same time that it revolves about the axis of the mandrel, the +result being that the tool cuts upon the ball a scroll, of which each +convolution is approximately a circle, and lies in a plane parallel to +the line of centers.</p> + +<p>When the chuck is set for one size of ball, which may be done in a few +minutes, any quantity of that diameter may be turned without further +adjustment. A roughing cut for a 2 in. ball may be done in one minute, +and a finishing cut leaving the ball quite bright in the same time. +The two paps are cut off within one-sixteenth of an inch and then +broken off, and the ball finished in the usual way. On account of the +work being geometrically true, the finishing by the ferrule tool is +done in one quarter of the time usually required.</p> + +<p class="ctr"><a href="./images/7a.png"><img src="./images/7a_th.png" alt="IMPROVED BALL TURNING MACHINE." /></a><br /> IMPROVED BALL TURNING MACHINE.</p> + +<p>The chuck may be applied to an ordinary lathe or may be combined with +a special machine tool, as show in our illustration. In the latter +case everything is arranged in the most handy way for rapid working, +and six brass balls of 2 in. in diameter can be turned and finished in +an hour. The machine is specially adapted for turning ball valves for +pumps, pulsometers, and the like, and in the larger sizes for turning +governor balls and spherical nuts for armor plates, and is +manufactured by Messrs. Wilkinson and Lister, of Bradford Road Iron +Works, Keighley.—<i>Engineering.</i></p> + +<hr /> + + + + +<h2><a name="art14" id="art14"></a>COOLING APPARATUS FOR INJECTION WATER.</h2> + + +<p>It often happens in towns and where manufactories are crowded +together, that the supply of water for condensing purposes is very +small, and consequently that it attains an inconveniently high +temperature under unfavorable conditions of weather, resulting in the +deterioration of the vacuum and a consequent increase in the +consumption of fuel. To remedy or to diminish this difficulty, Messrs. +Boase and Miller, of London, have brought out the water cooler +illustrated above. This consists, says <i>Engineering</i>, of a revolving +basket of wire gauze surrounding an inner stationary vessel pierced +with numerous small holes, through which the heated water discharged +by the air pump finds its way into the basket, to be thrown out in the +form of fine spray to a distance of 20 ft. at each side. The drops are +received in the tank or pond, and in their rapid passage through the +air are sufficiently cooled to be again injected into the condenser.</p> + +<p>The illustration shows a cooler having a basket three feet in +diameter, revolving at 300 revolutions per minute, and discharging +into a tank 40 ft. square. It requires 3 to 4 indicated horse-power to +drive it, and will cool 300 gallons per minute. The following decrease +of temperature has been observed in actual practice: Water entering at +95 deg. fell 20 deg. in temperature; water entering at 100 deg. to 110 +deg. fell 25 deg.; and water entering at 110 deg. to 120 deg. fell 30 +deg. The machine with which these trials were made was so placed that +the top of the basket was four ft. from the surface of the water in +the pond. With a greater elevation, as shown in the engraving, better +results can be obtained.</p> + +<p class="ctr"><a href="./images/7b.png"><img src="./images/7b_th.png" alt="IMPROVED WATER COOLING APPARATUS." /></a><br />IMPROVED WATER COOLING APPARATUS.</p> + +<p>The advantages claimed for the cooler are that by its means the +temperature of the injection water can be reduced, the cost and size +of cooling ponds can be diminished, and condensing engines can be +employed where hitherto they have not been possible. The apparatus has +been for two years in operation at several large factories, and there +is every reason to believe that its use will extend, as it supplies a +real want in a very simple and ingenious manner. Messrs. Duncan +Brothers, of Dundee and 32 Queen Victoria Street, E.C., are the +manufacturers.</p> + +<hr /> + + + + +<h2><a name="art15" id="art15"></a>CORRUGATED DISK PULLEYS.</h2> + + +<p>This is a pulley recently introduced by Messrs. J. and E. Hall, of +Dartford Eng. With the exception of the boss, which is cast, it is +composed entirely of steel or sheet iron. In place of the usual arms a +continuous web of corrugated sheet metal connects the boss to the rim; +this web is attached to the boss by means of Spence's metal. Inside +the rim, which is flanged inward, a double hoop iron ring is fixed for +strengthening purposes. The advantageous disposition of metal obtained +by means of the corrugated web enables the pulley to be made of a +given strength with less weight of material, and from this cause and +also on account of being accurately balanced these pulleys are well +adapted for high speeds.</p> + +<p class="ctr"><img src="./images/7c.png" alt="DISK PULLEY" /></p> + +<hr /> + +<h3>[KANSAS CITY REVIEW.]</h3> + + + + +<h2><a name="art19" id="art19"></a>EARLY HISTORY OF THE TELEGRAPH.</h2> + + +<p>Although the electric telegraph is, comparatively speaking, a recent +invention, yet methods of communication at a distance, by means of +signals, have probably existed in all ages and in all nations. There +is reason to believe that among the Greeks a system of telegraphy was +in use, as the burning of Troy was certainly known in Greece very soon +after it happened, and before any person had returned from Troy. +Polybius names the different instruments used by the ancients for +communicating information—"pyrsia," because the signals were always +made by means of fire lights. At first they communicated information +of events in an imperfect manner, but a new method was invented by +Cleoxenus, which was much improved by Polybius, as he himself informs +us, and which may be described as follows:</p> + +<p>Take the letters of the alphabet and arrange them on a board in five +columns, each column containing five letters; then the man who signals +would hold up with his left hand a number of torches which would +represent the number of the column from which the letter is to be +taken, and with his right hand a number of torches that will represent +the particular letter in that column that is to be taken. It is thus +easy to understand how the letters of a short sentence are +communicated from station to station as far as required. This is the +pyrsia or telegraph of Polybius.</p> + +<p>It seems that the Romans had a method of telegraphing in their walled +cities, either by a hollow formed in the masonry, or by a tube fixed +thereto so as to confine the sound, in order to convey information to +any part they liked. This method of communicating is in the present +age frequently employed in the well known speaking tubes. It does not +appear that the moderns had thought of such a thing as a telegraph +until 1661, when the Marquis of Worcester, in his "Century of +Inventions," affirmed that he had discovered a method by which a man +could hold discourse with his correspondent as far as they could +reach, by night as well as by day; he did not, however, describe this +invention.</p> + +<p>Dr. Hooke delivered a discourse before the Royal Society in 1684, +showing how to communicate at great distances. In this discourse he +asserts the possibility of conveying intelligence from one place to +another at a distance of 120 miles as rapidly as a man can write what +he would have sent. He takes to his aid the then recent invention of +the telescope, and explains how characters exposed at one station on +the top of one hill may be made visible to the next station on the top +of the next hill. He invented twenty-four simple characters, each +formed of a combination of three deal boards, each character +representing a letter by the use of cords; these characters were +pushed from behind a screen and exposed, and then withdrawn behind the +screen again. It was not, however, until the French revolution that +the telegraph was applied to practical purposes; but about the end of +1703 telegraphic communication was established between Paris and the +frontiers, and shortly afterward telegraphs were introduced into +England.</p> + +<p>The history of the invention and introduction of the electric +telegraph by Prof. Morse is one of inexhaustible interest, and every +incident relating to it is worthy of preservation. The incidents +described below will be found of special interest. The article is from +the pen of the late Judge Neilson Poe, and was the last paper written +by him. He prepared it during his recent illness, the letter embodied +in it from Mr. Latrobe being of course obtained at the time of its +date. It is as follows:</p> + +<p>On the 5th of April, 1843, when the monthly meeting of the directors +of the Baltimore & Ohio Railroad Company was about to adjourn, the +President, the Hon. Louis McLane, rose with a paper in his hand which +he said he had almost overlooked, and which the Secretary would read. +It proved to be an application from Prof. Morse for the privilege of +laying the wires of his electric telegraph along the line of the +railroad between Baltimore and Washington, and was accompanied by a +communication from B.H. Latrobe, Esq., Chief Engineer, recommending +the project as worthy of encouragement.</p> + +<p>On motion of John Spear Nicholas, seconded by the Hon. John P. +Kennedy, the following resolution was then considered:</p> + +<p><i>Resolved</i>, "That the President be authorized to afford Mr. Morse such +facilities as may be requisite to give his invention a proper trial +upon the Washington road, provided in his opinion and in that of the +engineer it can be done without injury to the road and without +embarrassment to the operations of the company, and provided Mr. Morse +will concede to the company the use of the telegraph upon the road +without expense, and reserving to the company the right of +discontinuing the use if, <i>upon experiment</i>, it should prove <i>in any +manner injurious</i>."</p> + +<p>"Whatever," said Mr. McLane, "may be our individual opinions as to the +feasibility of Mr. Morse's invention, it seems to me that it is our +duty to concede to him the privilege he asks, and to lend him all the +aid in our power, especially as the resolution carefully protects the +company against all present or future injury to its works, and secures +us the right of requiring its removal at any time."</p> + +<p>[In view of the fact that no railroad can now be run safely without +the aid of the telegraph, the cautious care with which the right to +remove it if it should become a nuisance was reserved, strikes one at +this day as nearly ludicrous.]</p> + +<p>A short pause ensued, and the assent of the company was about to be +assumed, when one of the older directors, famed for the vigilance with +which he watched even the most trivial measure, begged to be heard.</p> + +<p>He admitted that the rights and interests of the work were all +carefully guarded by the terms of the resolution, and that the company +was not called upon to lay out any of its means for the promotion of +the scheme. But notwithstanding all this, he did not feel, as a +conscientious man, that he could, without further examination, give +his vote for the resolution. He knew that this idea of Mr. Morse, +however plausible it might appear to theorists and dreamers, and +so-called men of science, was regarded by all practical people as +destined, like many other similar projects, to certain failure, and +must consequently result in loss and possibly ruin to Mr. Morse. For +one, he felt conscientiously scrupulous in giving a vote which would +aid or tempt a visionary enthusiast to ruin himself.</p> + +<p>Fortunately, the views of this cautious, practical man did not +prevail. A few words from the mover of the resolution, Mr. Nicholas, +who still lives to behold the wonders he helped to create, and from +Mr. Kennedy, without whose aid the appropriation would not have passed +the House of Representatives, relieved the other directors from all +fear of contributing to Mr. Morse's ruin, and the resolution was +adopted. Of the President and thirty directors who took part in this +transaction, only three, Samuel W. Smith, John Spear Nicholas, and the +writer, survive. Under it Morse at once entered upon that test of his +invention whose fruits are now enjoyed by the people of all the +continents.</p> + +<p>It was not, however, until the spring of 1844 that he had his line and +its appointments in such a condition as to allow the transmission of +messages between the two cities, and it was in May of that year that +the incident occurred which has chiefly led to the writing of this +paper.</p> + + +<h3>MR. LATROBE'S RECOLLECTIONS.</h3> + +<p>MY DEAR MR. POE: Agreeably to my promise, this morning I put +on paper my recollection of the introduction of the magnetic telegraph +between Baltimore and Washington. I was counsel of the Baltimore & +Ohio Railroad Co. at the time, and calling on Mr. Louis McLane, the +President, on some professional matter, was asked in the course of +conversation whether I knew anything about an electric telegraph which +the inventor, who had obtained an appropriation from Congress, wanted +to lay down on the Washington branch of the road. He said he expected +Mr. Morse, the inventor, to call on him, when he would introduce me to +him, and would be glad if I took an opportunity to go over the subject +with him and afterward let him, Mr. McLane, know what I thought about +it. While we were yet speaking, Mr. Morse made his appearance, and +when Mr. McLane introduced me he referred to the fact that, as I had +been educated at West Point, I might the more readily understand the +scientific bearings of Mr. Morse's invention. The President's office +being no place for prolonged conversation, it was agreed that Mr. +Morse should take tea at my dwelling, when we would go over the whole +subject. We met accordingly, and it was late in the night before we +parted. Mr. Morse went over the history of his invention from the +beginning with an interest and enthusiasm that had survived the +wearying toil of an application to Congress, and with the aid of +diagrams drawn on the instant made me master of the matter, and wrote +for me the telegraphic alphabet which is still in use over the world. +Not a small part of what Mr. Morse said on this occasion had reference +to the future of his invention, its influence upon communities and +individuals, and I remember regarding as the wild speculations of an +active imagination what he prophesied in this connection, and which I +have lived to see even more than realized. Nor was his conversation +confined to his invention. A distinguished artist, an educated +gentleman, an observant traveler, it was delightful <a name="Page_7038" id="Page_7038"></a>to hear him talk, +and at this late day I recall few more pleasant evenings than the only +one I passed in his company.</p> + +<p>Of course, my first visit the next morning was to Mr. McLane to make +my report. By this time I had become almost as enthusiastic as Mr. +Morse himself, and repeated what had passed between us. I soon saw +that Mr. McLane was becoming as eager for the construction of the line +to Washington as Mr. Morse could desire. He entered warmly into the +spirit of the thing, and laughed heartily, if not incredulously, when +I told him that although he had been Minister to England, Secretary of +State, and Secretary of the Treasury, his name would be forgotten, +while that of Morse would never cease to be remembered with gratitude +and praise. We then considered the question as to the right of the +company to permit the line to be laid in the bed of the road—the plan +of construction at that time being to bury in a trench some eight or +ten inches deep a half inch leaden tube containing the wrapped wire +that was to form the electric circuit. About this there was, in my +opinion, no doubt, and it was not long after that the work of +construction commenced. I met Mr. Morse from time to time while he +lived, and often recurred to the evening's discussion at my house in +Baltimore.</p> + +<p>The above is the substance of what I have more than once related to +other persons. I hope you will persist in your design of putting on +paper your own very interesting recollections in this connection, and +if what I have contributed of mine is of service to you, I shall be +much pleased.</p> + + +<p class="signature"> Most truly yours,<br /><br /> + JOHN H.B. LATROBE.</p> +<p>March 3, 1881.</p> + + +<hr /> + + +<h2><a name="art20" id="art20"></a>THE KRAVOGL ELECTRIC MOTOR.</h2> + +<p>At the origin of every science, of whatever nature it may be, there is +always a fruitless period, of greater or less length, characterized by +the warfare of a few superior minds against general apathy. The finest +discoveries pass unperceived, so to speak, since they cannot cross the +limits of a narrow circle; and it often happens that they fall into +oblivion before they have been seriously judged. Meanwhile, a slow +progress is imperceptibly made, and, in measure as theoretical +principles more clearly disengage themselves, a few industrial +applications spring up and have the effect of awakening curiosity. An +impulse is thus given, and from this moment a movement in advance goes +on increasing at a headlong pace from day to day.</p> + +<p>With electricity this period has been of comparatively short duration, +since scarcely a century and a half separate us from the first +experiments made in this line of research. Now that it has truly taken +its place in a rank with the other sciences, we like to go back to the +hesitations of the first hour, and trace, step by step, the history of +the progress made, so as to assign to each one that portion of the +merit that belongs to him in the common work. When we thus cast a +retrospective glance we find ourselves in the presence of one strange +fact, and that is the simultaneousness of discoveries. That an +absolutely original idea, fertile in practical consequences, should +rise at a given moment in a fine brain is well; we admire the +discovery, and, in spite of us, a little surprise mingles with our +admiration. But is it not a truly curious thing that <i>several</i> +individuals should have had at nearly the same time that idea that was +so astonishing in one? This, however, is a fact that the history of +electrical inventions offers more than one example of. No one ignores +the fact that the invention of the telephone gave rise to a notorious +lawsuit, two inventors having had this ingenious apparatus patented on +the same day and at nearly the same hour. This is one example among a +thousand. In the history of dynamo-electric machines it is an equally +delicate matter to fix upon the one to whom belongs the honor of +having first clearly conceived the possibility of engendering +continuous currents.</p> + +<p>We do not wish to take up this debate nor to go over the history of +the question again. Every one knows that the first continuous current +electric generator whose form was practical is due to Zenobius Gramme, +and dates back to July, 1871, an epoch at which appeared a memoir +(entitled "Note upon a magneto-electric machine that produces +continuous currents") that was read to the Academy of Sciences by Mr. +Jamin. Ten years previous, Pacinotti had had a glimpse of the +phenomenon, and of its practical realization, but was unfortunately +unable to appreciate the importance of his discovery and the benefit +that might be reaped from it. It is of slight consequence whether +Gramme knew of this experiment or not, for the glory that attaches to +his name could not be diminished for all that. But an interesting fact +that we propose to dwell upon now has recently been brought to light +in an electrical review published at Vienna.<a name="FNanchor_4" id="FNanchor_4"></a><a href="#Footnote_4"><sup>1</sup></a> It results from +documents whose authenticity cannot be doubted that, as far back as +1867, Mr. L. Pfaundler, a professor at Innsbruck, very clearly +announced the reversibility of a magneto-electric motor constructed by +Kravogl, a mechanician of the same place, and that he succeeded some +time before Gramme in obtaining continuous currents.</p> + +<p>The Kravogl motor that figured at the Universal Exhibition of 1867 is +but little known, and it is now very difficult to obtain drawings of +it. What is certain is that this motor is an application of the +properties of the solenoid, and, from this standpoint, resembles the +Bessolo motor that was patented in 1855. We may figure the apparatus +to our mind very well if we suppose that in the Gramme ring a half and +almost two-thirds of the core are removed, and the spirals are movable +around the said core. If a current be sent into a portion of the +spirals only, and in such a way that only half of the core be exposed, +the latter will move with respect to the bobbin or the bobbin with +respect to the core, according as we suppose the solenoid or the +bobbin fixed. In the first case we have a Bessolo motor, and in the +second a Kravogl one.</p> + +<p>In order to obtain a continuous motion it is only necessary to allow +the current to circulate successively in the different portions of the +solenoid. It is difficult to keep the core in place, since it is +unreachable, being placed in the interior of the bobbin. Kravogl +solved this difficulty by constructing a hollow core into which he +poured melted lead. This heavy piece, mounted upon rollers, assumed a +position of equilibrium that resulted from its weight, from friction, +and from magnetic attraction. But for a current of given intensity +this position, once reached, did not vary, and so necessitated a +simple adjustment of the rubbers. Under such circumstances, with a +somewhat large number of sections, the polarity of the core was nearly +constant. The spirals as a whole were attached to a soft iron armature +that had the effect of closing up the lines of forces and forming a +shell, so to speak.</p> + +<p>Like Bessolo, Kravogl never thought of making anything but a motor, +and did not perceive that his machine was reversible. It results from +some correspondence between Dr. A. Von Waltenhofen and Mr. L. +Pfaundler at this epoch that the latter clearly saw the possibility of +utilizing this motor as a current generator. Under date of November 9, +1867, he wrote, in speaking of the Kravogl motor, which had just been +taken to Innsbruck in order to send it to Paris. "I regret that I +shall not be able to see it any more, for I should have liked to try +to make it act in an opposite direction, that is to say, to produce a +current or an electric light by means of mechanical work." A little +more than two years later these experiments were carried out on a +larger motor constructed by Kravogl in 1869, and Mr. Pfaundler was +enabled to write as follows: "Upon running the machine by hand we +obtain a current whose energy is that of one Bunsen element." This +letter is dated February 11, 1870, that is to say, it is a year +anterior to the note of Gramme.</p> + +<p class="ctr"><img src="./images/8a.png" alt="FIG. 1." /><br />FIG. 1.</p> + +<p>In the presence of the historic interest that attaches to the +question, we do not think it will be out of place to reproduce here +the considerations that guided Prof. Pfaundler in the researches that +led him to convert the Kravogl motor into a dynamo-electric machine. +Let us consider two magnetized bars, <i>db</i> and <i>bd'</i>, placed end to end +and surrounded by a cylindrical armature forming a shell, this +armature being likewise supposed to be a permanent magnet and to +present poles of contrary direction opposite the poles of the bars. +For the sake of greater simplicity this shell is represented by a part +only in the figure, <i>s n n s</i>. If, into a magnetic field thus +formed, we pass a spiral from left to right, the spiral will be +traversed by a current whose direction will change according to the +way in which the moving is done. It is only necessary to apply Lenz's +law to see that a reversal of the currents will occur at the points, +<i>a</i> and <i>c</i>, the direction of the current being represented by arrows +in the figure. If we suppose a continual displacement of the spirals +from left to right, we shall collect a continuous current by placing +two rubbers at <i>a</i> and <i>c</i>. Either the core or the shell may be +replaced by a piece of soft iron. In such a case this piece will move +with the spiral and keep its poles that are developed by induction +fixed in space. From this, in order to reach a dynamo-electric machine +it is necessary to try to develop the energy of the magnetic field by +the action of the current itself. If we suppose the core to be of soft +iron, and make a closer study of the action of the current as regards +the polarity that occurs under the influence of the poles, <i>s</i>, <i>n</i>, +<i>s</i>, we shall see that from <i>d</i> to <i>a</i> and from <i>b</i> to <i>c</i> the current +is contrary, while that from <i>a</i> to <i>b</i> and from <i>c</i> to <i>d'</i> it is +favorable to the development of such polarity. In short, with a spiral +moving from <i>d</i> to <i>d'</i> the resulting effect is <i>nil</i>, a fact, +moreover, that is self-evident. Under such circumstances, if we +suppose the shell, as well as the core, to be of soft iron, we shall +obtain a feeble current due to the presence of remanent magnetism; but +this magnetism will not be able to continue increasing under the +influence of the current. To solve this difficulty two means present +themselves: (1) to cause a, favorable magnetic current and act upon +the armature, and (2) to suppress such portions of the current in the +spirals as are injurious in effect. The first solution was thought of +by Gramme in 1871, and is represented diagramatically in Fig. 2. The +second is due to Prof. Pfaundler, and dates back to 1870. The core is +cut through the center (Fig. 3), and the portion to the right is +suppressed; the current is interrupted between <i>da</i> and <i>cd'</i>, and is +closed only between <i>a</i> and <i>c</i> (<i>v</i>, Fig. 1). It results from this +arrangement that, under the action of the current, the polarity due to +remanent magnetism does nothing but increase. It suffices then for but +little remanent magnetism to prime the machine; the polarity of the +shell continues to increase, and the energy of the magnetic field, and +consequently of the current, has for a limit only the saturation of +the soft iron. If, now, we curve the core, the spirals, and the +armature into a circle, we have a Gramme or a Pfaundler machine, +according as we consider Fig. 2 or Fig. 3.</p> + +<p class="ctr"><img src="./images/8b.png" alt="FIG. 2." /><br />FIG. 2.</p> + +<p class="ctr"><img src="./images/8c.png" alt="FIG. 3." /><br />FIG. 3.</p> + +<p>This latter apparatus has in this case the form shown in Fig. 4.</p> + +<p class="ctr"><img src="./images/8d.png" alt="FIG. 4." /><br />FIG. 4.</p> + +<p>The spiral, <i>s m b</i>, is movable, and the core, N <i>o s</i>, is kept in a +position of equilibrium by virtue of its weight, and is provided with +rollers. For the sake of greater clearness, the front part of the +armature is supposed to be removed. The current does not circulate in +the spirals to the right of the diameter, W O, which latter is not +absolutely vertical. The position of the rubbers and armature is +regulated once for all. We do not know just what were the means +devised by Kravogl to suppress the current in the spheres to the +right. At all events, it is probable that the system has grown old +since Gramme invented his collector. In the application of the Kravogl +motor to the generation of continuous currents, Professor Pfaundler +now proposes to ingeniously utilize the Gramme collector. In such a +case the arrangement shown in Fig. 5 would be adopted. Let us suppose +an ordinary collector having as many plates as there are sections in +the ring, these plates being connected as usual with the entrance and +exit wires of the sections. The diametrically opposite touches that +are in the line, W O, are divided, and one of the halves is connected +at the entrance, <i>c a'</i> (Fig. 4), with the corresponding section, +while the other communicates with the exit, <i>c' a</i>, of the neighboring +section. Each of these halves is prolonged by a piece of metal bent +into the form of an arc of a circle and embracing a little less than a +semi-circumference. Between these prolongations there is an insulating +part. In the rotary motion of the spiral, at least one of the touches +is always outside of the arc comprised between the brushes, R. In +order to secure a continuity of the circuit in the effective arc, W S<i> o</i>, +it is only necessary to arrange a rubber, M, in such a way as to +establish a communication between the two parts of the divided touch +as soon as this latter enters the arc under consideration.</p> + +<p>In order to produce a current in the direction of the arrows shown in +Fig. 4, the spiral and axle must revolve from right to left. In this +case the rubber, M, occupies the position shown in the same figure, +the brushes embracing an arc of a little less than 180°. As soon as +the lower touch comes in contact with the brush, R, when the +revolution is being effected from left to right, the rubber, M, +establishes a communication between the two halves that have until now +been isolated, and the current is no longer interrupted. The second +touch during this time is at any point whatever of the arc, W N <i>o</i>, +and the spirals corresponding to the latter arc outside of the +circuit. In short, thanks to the rubber, M, we have an ordinary Gramme +collector in that portion of the circuit comprised between the +brushes, and a collector with a breakage of the circuit in the portion +to the right.</p> + +<p class="ctr"><img src="./images/8e.png" alt="FIG. 5." /><br />FIG. 5.</p> + +<p>This type of machine is entirely theoretical. In the apparatus used +for Prof. Pfaundler's experiments in 1870, the armature revolved with +the solenoid. The core and armature were of soft iron, and the core +was arranged in a manner analogous to the preceding, and remained in +place under the action of its weight, and the shell, forming a +complete circle, revolved with poles fixed in space.</p> + +<p>Practically, the machine that we have just described would prove +inconvenient to realize, and would present serious inconveniences. In +the first place, it seems to us quite difficult to transmit the motion +of the solenoid to the axle, supposing the former to revolve within +the armature. In the second place, considerable friction would surely +occur between the spirals and core, and the axle, being submitted to a +lateral stress, would be placed in a poor condition for work. It is +even allowable to doubt whether such a type <a name="Page_7039" id="Page_7039"></a>could be practically got +up. At all events, no trial has as yet been made of it.</p> + +<p>Compared with the Gramme machine, from an absolutely theoretical point +of view, the Pfaundler apparatus presents undoubted advantages. A +theoretically perfect dynamo electric machine would be one in which +there was a complete reciprocity between the magnetizing action of the +current and the inductive action of the magnetic field. Now, such is +not the case in the Gramme machine. In this apparatus the soft iron +core is at the same time a magnet through favorable induction and a +disadvantageous electro-magnet. This double polarization is only +remedied to a certain extent by the adjustment of the brushes. In the +Pfaundler machine, on the contrary, the electro-magnetism and +magnetism through induction act in the same direction, and concur in +effecting a polarization that favors the production of the current. +Looked at it in this light, the latter machine more nearly approaches +the type of perfection than does that of Gramme.</p> + +<p>But we must not forget that such qualities are purely theoretical. In +practice the best machine is that in which the copper is best +utilized, that is to say, that which with a given weight of this metal +furnishes the most work. Now, this is certainly not the case in the +Pfaundler machine, for here half or more than half of the ring is +inert—a defect which is apparent at first sight. It results from this +that as soon as we propose to obtain an electromotive force, however +slight it be, we must get it with machines of large dimensions. Now, +it is permissible to believe that under such circumstances (taking +into consideration the complication of mechanical means that the +construction of such apparatus necessitates, and the great friction +that occurs) it would be impossible to obtain practical rotary +velocities. Comparing his machine with Gramme's, Prof. Pfaundler +expresses the idea that between them there is the same analogy as +there is between a constant pressure and an expansion engine. With +cylinders of equal diameters the work performed by the former of these +is greater than that done by the second, but in the latter the +expansive force of the steam is better utilized. This comparison seems +to us to be more ingenious than exact. Would it not be coming nearer +to the truth if we were to suppose a case of a hydraulic motor whose +performance continued diminishing with the height of the fall, and +would it not be advantageous under such circumstances to utilize only +a portion of the fall for the purpose of increasing the motor's +performance?</p> + +<p>This machine, however, as before stated, has never as yet been +constructed, so that experimental data relative to its mode of working +are wanting. It is especially interesting as regards its origin, which +dates back to an epoch at which researches on the dynamo electric +machine were at their heat. It is in its historical aspect that it is +proper to regard it, and it is from such a point of view that we have +deemed it well to say a few words about it in this place.—<i>La Lumiere +Electrique.</i></p> + +<div class="note"><p><a name="Footnote_4" id="Footnote_4"></a><a href="#FNanchor_4">[1]</a></p> +<p><i>Zeitschrift des Electrotechnischen Vereines</i> in <i>Wien</i>, +July, 1883.</p></div> + +<hr /> + + +<h2><a name="art21" id="art21"></a>BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES.</h2> + + +<p>We shall not attempt to pass in review the several apparatus that have +hitherto been devised for igniting blasts in mining operations, but +shall simply describe in this place a machine recently invented for +this purpose by Mr. Bornhardt, an engineer to the Grand Duke of +Brunswick.</p> + +<p>This apparatus (shown in the accompanying engravings) consists +essentially of two hard-rubber disks, A (Figs. 2 and 3), keyed to an +iron axle, and of two rubbers, B, that are formed of skin and are held +against the disks by small springs, R; motion is communicated to the +axle, <i>a</i>, by means of a pair of gearings, <i>a</i> and <i>b</i>, and a crank, +<i>f</i>.</p> + +<p class="ctr"><a href="./images/9a.png"><img src="./images/9a_th.png" alt=" BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES." /></a><br /> BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES.</p> + +<p>Each disk revolves between two metallic rings, <i>c</i>, provided with +points that attract and collect in Leyden jars, D, the electricity +produced by the friction. For discharging the condensers there is +employed a manipulator formed of a rod, mm, which can be acted upon, +from the exterior, by means of a button, <i>k</i>. Upon bringing the ball, +<i>m</i>, of the rod in contact with the ball, <i>p</i>, of the condenser, the +lever (which then takes the position shown by the dotted line) +continues to remain in connection with a small ring, <i>q</i>, through a +special spring. Another ring, <i>t</i>, is connected in the same way with +the external armature of the condenser. Upon connecting the rings, <i>p</i> +and <i>t</i>, by a wire to which cartridges are attached, any number of the +latter may be ignited.</p> + +<p>The parts that we have just enumerated are inclosed in a tin box +covered with a wooden casing, P. Between the two there is inserted a +sheet of hard rubber in order to prevent a loss of electricity; the +whole is held in place by strong springs.</p> + +<p>In order to show the normal state of the condenser, a scale consisting +of 15 metallic buttons to give the dimensions of the sparks, is +arranged at X. This scale is capable of being connected with the +rings, <i>q</i> and <i>t</i>, by means of chains; when the spark obtained after 15 +or 20 revolutions considerably exceeds the intervals of the scale, it +is a sure thing that the machine is in a proper state.</p> + +<p>In order to prepare the apparatus for carriage, the winch is taken off +and placed in the compartment, <i>m</i>, which is closed by means of a +door, Q.</p> + +<p>Figs. 5 and 6 show the arrangement of the dynamite cartridges and +wires in the blast hole. Figs. 7 to 10 show different arrangements of +the igniting wires. Figs. 11 and 12 give the general arrangement for +igniting a number of cartridges simultaneously by means of the +electric machine. Fig. 13 shows the arrangement where powder is +employed. Fig. 14 shows the arrangement of a horizontal +hole.—<i>Annales Industrielles.</i></p> + +<hr /> + + + + +<h2><a name="art22" id="art22"></a>IMPROVED ELECTRIC FIRE ALARM.</h2> + + +<p>The object of this apparatus is to close an electric circuit when the +temperature of a room rises above a certain point. Many devices have +been invented for effecting this object, each of which have their own +advantages or disadvantages. The invention of Mr. Pritchett enables +the required result to be obtained in a very satisfactory manner. The +apparatus consists (as shown by the figure) of a long glass vessel +containing air; connected to this vessel there is a glass tube filled +with mercury. The whole is mounted on a metal cradle, which turns on +pivots. According to the position which the glass vessel and its +adjuncts occupy in the cradle (this position being adjustable by means +of a thumb-screw, seen at the upper part of the cradle), so will the +same have a tendency to rock longitudinally over to one side or the +other. Now, if we suppose the position to be such that the right hand +end of the glass vessel is depressed, and the left hand end raised, +then if the vessel becomes subjected to an elevation of temperature, +the air inside the same will become expanded, and the mercury column +in the tube will be driven over to the left, and will rise in the +turned up end of the tube. This will cause the left hand branch of the +glass vessel, and its attachments, to become increased in weight, +while the right hand branch will become proportionally lighter; the +consequence of this will be that the vessel and its cradle will cant +over, and by falling on an electrical contact will close a circuit and +sound an alarm. It is obvious that the apparatus is equally well +adapted for indicating a diminution as well as an increase of +temperature, for if the electrical contact be placed under the right +hand portion of the cradle, and the latter be adjusted so that in its +normal position its left hand portion is depressed, then when the +glass vessel becomes cooled, the air in it will contract, and the +mercury will fall in the turned-up portion of the tube before referred +to, and will rise in the limb connected to the vessel, consequently +the cradle and glass vessel will cant over in the reverse way to that +which it did in the first case.</p> + +<p>Owing to the surface which the glass vessel exposes, the air inside +quickly responds to any external change of temperature, consequently +the apparatus is very sensitive. Another important feature is the fact +that the cradle and vessel in canting over acquires a certain +momentum, and thus the contact made becomes very certain.</p> + +<p class="ctr"><img src="./images/9b.png" alt="PRITCHETT'S ELECTRIC FIRE ALARM." /><br />PRITCHETT'S ELECTRIC FIRE ALARM.</p> + +<p>Mr. Pritchett proposes that his apparatus shall give external evidence +outside the house by ringing a gong, and by dropping a semaphore arm +released by an electromagnet. He also proposes (as has often been +suggested) that a water supply shall be automatically turned +on.—<i>Electrical Review.</i></p> + +<hr /> + + + + +<h2><a name="art23" id="art23"></a>A STANDARD THERMOPILE.</h2> + + +<p>Dr. G. Gore, F.R.S., has invented an improved thermopile for +measuring small electromotive forces. It consists of about 300 pairs +of horizontal, slender, parallel wires of iron and German silver, the +former being covered with cotton. They are mounted on a wooden frame. +About 1― in. of the opposite ends of the wires are bent downward to a +vertical position to enable them to dip into liquids at different +temperatures contained in long narrow troughs; the liquids being +non-conductors, such as melted paraffin for the hot junctions, and the +non-volatile petroleum, known as thin machinery oil. The electromotive +force obtained varies with the temperature; a pile of 295 pairs having +a resistance of 95.6 ohms at 16 deg. Cent. gave with a difference of +temperature of 100 deg. Cent. an electromotive force of 0.7729 volts, +or with 130 deg. Cent. an electromotive force of 1.005 volt. Each +element, therefore, equaled 0.0000262 volt for each degree Cent. +difference of temperature. On having been verified with a standard +voltaic cell the apparatus becomes itself a standard, especially for +small electromotive forces. It is capable of measuring the 1/34861 +part of a volt. For higher electromotive forces than a volt, several +of these piles would have to be connected in series. The fractional +electromotive force is obtained by means of a sliding contact which +cuts out so many pairs as is required.</p> + +<hr /> + + + + +<h2><a name="Page_7040" id="Page_7040"></a><a name="art24" id="art24"></a>TELEPHONIC TRANSMISSION WITHOUT RECEIVERS.</h2> + + +<p>The annual meeting of the French Society of Physics, the success of +which is continually increasing, took place this year in the salons of +the Observatory, which were kindly placed at the Society's disposal by +Admiral Mouchez.</p> + +<p>There were three consecutive sessions, the one of Tuesday, April 15, +being set apart for the members of the Association, the one of the +16th for the invited guests of Admiral Mouchez, and that of the 17th +for the invited guests of the Society. The salons were partially +lighted by the Siemens differential arc, continuous current lamps, and +partially by the Swan incandescent lamp supplied by a distributing +machine that permitted of the lamps being lighted and extinguished at +will without changing the normal operation of all the rest. Many +apparatus figured at this exhibition, but we shall on the present +occasion merely call attention to those that presented a certain +character of novelty or of originality.</p> + +<p>Among the apparatus that we shall reserve a description of for the +present was Messrs. Richard Bros.' registering thermometer designed +for the Concarneau laboratory, an instrument which, when sunk at one +mile from the coast, and to a depth of 40 meters, will give a diagram +of the temperature of the ocean at that depth; and Mr. Hospitalier's +continuous electrical indicators, designed for making known from a +distance such mechanical or physical phenomena as velocities, levels, +temperatures, pressures, etc.</p> + +<p>Among the most important of the apparatus exhibited we must reckon Mr. +Cailletet's devices for liquefying gases, and those of Mr. Mascart for +determining the ohm. The results obtained by Mr. Mascart (which have +been submitted to the Committee on Unities of the Congress of +Electricians now in session at Paris), are sensibly concordant with +those obtained independently in England by Lord Rayleigh. Everything +leads to the hope, then, that a rapid and definite solution will be +given of this important question of electric unities, and that nothing +further will prevent the international development of the C.G.S. +system.</p> + +<p>Mr. Jules Duboscq** made a number of very successful projections, and we +particularly remarked the peculiar experiment made in conjunction with +Mr. Parinaud, that gave in projection two like spectra produced by the +same prism, and which, through superposition, were capable of +increasing the intensity of the colors, or, on the contrary, of +reconstituting white light.</p> + +<p>Among the optical applications we may cite Mr. Leon Laurent's +apparatus for controlling plane, parallel, perpendicular, and oblique +surfaces, and magic mirrors obtained with an ordinary light; Mr. S.P. +Thompson's apparatus for demonstrating the propagation of +electro-magnetic waves in ether (according to Maxwell's theory), as +well as some new polarizing prisms; and a mode of lighting the +microscope (presented by Mr. Yvon), that was quite analogous to the +one employed more than a year ago by Dr. Van Heurck, director of the +Botanical Garden of Anvers.</p> + +<p>Acoustics were represented by an electro-magnetic brake siren of Mr. +Bourbouze; Konig's apparatus for the synthesis of sounds; and Mr. S.P. +Thompson's cymatograph—a pendulum apparatus for demonstrating the +phenomena of beats.</p> + +<p>It was electricity again that occupied the largest space in the +programme of the session.</p> + +<p>Apparatus for teaching are assuming greater and greater importance +every day, and the exhibit of Mr. Ducretet included a large number of +the most interesting of these. The house of Breguet exhibited on a +reduced scale the magnificent experiments of Gaston Plante, wherein +320 leaden wire secondary elements charged for quantity with 3 Daniell +elements, and afterward coupled for tension, served to charge a +rheostatic machine formed of 50 condensers coupled for quantity. These +latter, coupled anew for tension, furnished upon being discharged a +spark due to a difference of potential of about 32,000 volts that +presented all the characters of the spark produced by induction coils +on the machines so improperly called "static." Finally, we may cite +the apparatus arranged by Mr. S.P. Thompson for studying the +development of currents in magneto-electric machines. The inventor +studies the influence of the forms of the inductors and armatures of +machines by means of an arrangement that allows him to change the +rings or armatures at will and to take out the induced bobbins in +order to sound every part of the magnetic field. Upon giving the +armature an angular motion limited by two stops, there develops a +certain quantity of electricity that may be measured by causing it to +traverse an appropriate ballistic galvanometer. Messrs. Deprez and +D'Arsonval's galvanometer answers very well for this purpose, and its +aperiodicity, which causes it quickly to return to zero as soon as the +induced current ceases, permits of a large number of readings being +taken within a very short space of time.</p> + +<p>Measuring apparatus were represented by a new and very elegant +arrangement of Sir William Thomson's reflecting galvanometers, due to +Mr. J. Carpentier. The mounting adopted by Mr. Carpentier permits of +an easy removal of the bobbins and of an instantaneous substitution +therefor. The galvanometric part, composed of the needles and mirror, +therefore remains entirely free, thus allowing of its being verified, +and making it convenient to attach the silken fiber. Mr. Carpentier +has, moreover, adopted for all the minor apparatus a transparent +celluloid scale which simplifies them, facilitates observations, and +renders the use of reflection almost industrial.</p> + +<p>We shall complete our enumeration of the measuring apparatus by citing +Ducretet's non-oscillating galvanometer, Sir William Thomson's +amperemeters, voltameters, ohmmeters, and mhosmeters, constructed and +exhibited by Breguet, and a new aperiodic galvanoscope of Mr. Maiche. +Mr. Baudot exhibited the recent improvements that he has made in his +multiplex printing telegraph, and M. Boudet of Paris showed a new +system of telephone transmission by submarine cables.</p> + +<p class="ctr"><img src="./images/10b.png" alt="FIG. 1.—DIAGRAM EXHIBITING THE ARRANGEMENT" /><br /> +FIG. 1.—DIAGRAM EXHIBITING THE ARRANGEMENT FOR TELEPHONIC TRANSMISSIONS WITHOUT A RECEIVER.</p> + +<p>Finally, we shall conclude our enumeration by referring to the +curiosities. The house of Siemens exhibited a miniature electric +railway actuated by a new model of Reynier accumulators; M. Maiche +operated a system of musical telephonic auditions that differed only +in detail from those instituted by Mr. Ader at the exhibition of 1881; +and Mr. Hospitalier presented a new form of an experiment devised by +Mr. Giltay, consisting of a telephonic transmission of sounds without +the use of receivers. Mr. Giltay's experiment is nothing but Mr. +Dunand's speaking condenser without the condenser. A glance at Fig. 1 +will show how things are arranged for the experiment. The transmitting +system comprises two distinct circuits, viz.: (1) one formed of a +pile, P, of 2 or 3 Leclanche elements, or of 1 or 2 small sized +accumulators, an Ader microphane transmitter, M, and the inducting +wire of a small induction coil, B; and (2) the other formed of the +induced wire of the coil, B, of a pile, P', of 10 or 12 Leclanche +elements, and of a line whose extremities terminate at R, in two +ordinary electro-medical handles. With this arrangement the experiment +performed is as follows: When any one speaks or sings in front of the +transmitter, T, while two persons, A and B, each having one hand +gloved, are holding the handles in the ungloved hand, it is only +necessary for A to place his gloved hand upon B's ear, or for the +latter to place his hand upon A's, or for each to place his hand on +the other's ear simultaneously, in order that A or B, or A and B +simultaneously, may hear a voice issuing from the glove. Under these +circumstances, Mr. Giltay's experiment is explained like Dunand's +speaking condenser—the hand of A and the ear of B here constituting +the armature of an elementary condenser in which the glove performs +the role of dielectric.</p> + +<p>Upon repeating this experiment at the laboratory of the School of +Physics and Industrial Chemistry of Paris, it has been found that the +glove maybe replaced by a sheet of plain or paraffined paper. In this +case, when two persons are holding the handles, and have their ears +applied, one against the other, if a sheet of paper be interposed, +airs or words will be heard to proceed therefrom. Finally, it has been +found possible to entirely suppress the paper, or dielectric, and to +hear directly, by simply interposing the auditor or auditors in the +circuit. One of the most curious forms of the experiment is the one +shown in Fig. 2. Here a third person, C, hears the hands of A and B +speak when a circuit is formed by means of three persons, A, B, and C, +the two former, A and B, each holding one of the wires of the circuit +and applying his free hand to the ear of C. Although the experiment is +one that requires entire silence, and could not on that account be +performed at the laboratory, a sort of telephonic chain can be formed +in which five or six persons may hear at the same time. A, putting his +hand on the ear of B, the latter putting his to that of C, and so on +up to the last person, who closes the circuit by grasping one of the +handles, the other one being held by A.</p> + +<p class="ctr"><a href="./images/10a.png"><img src="./images/10a_th.png" alt=" EXPERIMENT ON TELEPHONIC TRANSMISSION WITHOUT" /></a> +<br />EXPERIMENT ON TELEPHONIC TRANSMISSION WITHOUT RECEIVING APPARATUS.</p> + +<p>It is difficult in the present state of science to explain very +clearly how these telephonic transmissions are effected without a +receiver. All that we can conclude from it so far is that the ear is +an instrument of incomparable delicacy and of exquisite sensitiveness, +since it perceives vibrations in which the energy developer, +particularly in the telephonic chain, is exceedingly feeble.</p> + +<p>Without any desire to seek an application for an experiment that is +simply curious, we yet believe that there is here a phenomenon of a +nature to be studied by physicists. Discoveries in telephony and +microphony have certainly opened up to science, as regards both theory +and practice, new horizons that still promise other surprises for the +future. But to return to the observatory: The success obtained by the +exhibition of the French Society of Physics shows that these reunions +respond to a genuine need—that of instructing in and popularizing +science. While warmly congratulating the organizers of these meetings, +we may express a wish that the good example set by the Society of +Physics may be followed by other societies. We are convinced in +advance that an equal success awaits them.—<i>La Nature.</i></p> + +<hr /> + + +<h2><a name="art30" id="art30"></a>ON THE ARRANGEMENT OF GROUND CONDUCTORS.</h2> + + +<p>In telegraphy, as well as in the question of lightning rods, attention +has been but incidentally paid to the improvement of ground +conductors, and this point has not been the object of that careful +study that has been bestowed upon the establishment of aerial lines. +It is only recently that the interest created by lightning rods has +given rise to new forms of conductors differing from those formerly +used. The publications of the Prussian Academy of Sciences of from +1876 to 1880 contain some information of special importance in regard +to this. It is stated therein that the effect of ground conductors may +be notably increased by the division of the earth plates and the use +of metallic rods, without necessitating a greater output of material. +These facts, however, have not as yet been put to profit in practice +for the reason, perhaps, that the considerations, which have remained +general, have not at once permitted of obtaining forms what could be +employed with perfect knowledge of the results. This is what led Mr. +Ulbricht, of Dresden, to make calculations for a few forms of +conductors, and to test their approximate values. The results of these +researches are printed in the <i>Elektrotechnischen Zeitschrift</i> for +1883 (p. 18).</p> + +<p class="ctr"><img src="./images/10c.png" alt="" /></p> + +<p>The equations found show, in the first place, that there exist three +means of obtaining a considerable effect, as regards the ground +conductor, with a slight expenditure of material: The cylindrical +electrode may be drawn out into the form of a bar or wire; the plate +may be rendered narrow, and elongated in the form of a ribbon; and, +besides, the annular plate may be enlarged in lessening the metallic +surface.</p> + +<p>Finally, a short, open cylinder with a vertical axis may be formed by +curving a narrow plate or ribbon. It is not necessary to see the +formula to recognize the fact that this cylinder must behave like a +ribbon and a flat ring. The radius increasing, and the surface +remaining constant, the resistance of the earth here likewise +approaches zero.</p> + +<p>As the resistance of the earth is inversely proportional to the +diameter of the plates, the zero resistance can also be reached by +dividing a plate <i>ad infinitum</i>. As the parts of the plate may be +brought quite close to each other without perceptibly interfering with +the action, a <i>network</i> has finally been reached by a division carried +very far, yet limited, and by connecting the parts with one another by +conducting cylinders.</p> + +<p>If we seek to determine what forms of ground conductors are efficient +and economical under given conditions, we shall have to begin by +informing ourselves as to the choice of material to be used for the +electrode, and shall then have to ascertain whether putting it in the +ground will or will not necessitate much outlay. The most suitable +material is copper, which may be used with advantage, in that it lasts +pretty well underground, and that the facility which it may be worked +permits of easily giving it more appropriate forms than those that can +be obtained with cast iron, which is of itself less costly.</p> + +<p>If the burying in the ground requires little or no labor, as when +there exist ponds, rivers, and wells, or subterranean strata of water +near the surface of the earth, elongated forms of conductors will be +employed, such as the solid or hollow cylinder, the wire, the ribbon, +the narrow ring, and the network. Plates approaching a square or +circular shape are not advantageous. But if the ground has to be dug +deeply in order to sink the conductor, the form of the electrode must +be more condensed, and selected in such a way that the necessary +action may be obtained with a minimum output of copper and labor. For +great depths, and when the ground will permit of boring, an elongated +and narrow cylinder will be used. Such a system, however, can only be +employed when the cylinder is surrounded by spring water, since, +without that, an intimate contact with earth that is only moist, +cannot be obtained with certainty. In earth that is only moist and for +moderate depths, preference may be given to an electrode laid down +flat. The digging necessary in this case is onerous, it is true, but +it permits of very accurately determining the state of the earth +beneath and of obtaining a very perfect adherence of the electrode +therewith. Two forms, the annular ribbon or the flat ring and the +network, present themselves, according to calculations, as a +substitute for copper plates, which are so expensive; and these forms +are satisfactory on condition that the labor of digging be not notably +increased. These forms should always have a diameter a little greater +than that of the plate. The flat ring and the network, however, offer +one weak point, which they possess in common with the plate, and that +is, their dimensions cannot be easily adapted <a name="Page_7041" id="Page_7041"></a>to the nature of the +ground met with without a notable increase in the expense. Now, if the +ground should offer a conductivity less than what was anticipated, and +it were desired to increase the plate, say by one-third, it would be +impossible to do so as a consequence of the closed form.</p> + +<p>One important advantage is realized in this respect by combining the +ring and the network in the form of a reticulated ring having a +diameter of from 1 to 1― meters. On cutting this ring at a given place +and according to a certain radius we obtain the reticulated ribbon +shown in the accompanying figure. The thickness of the wires is 2.5 +mm., and their weight is 0.475 kilo. per meter. L, L, and L are the +points at which the conducting cable is soldered. A reticulated ribbon +of copper can be made in advance of any length whatever, and, +according to local exigencies, it may be easily curved and given the +form of a flat or cylindrical ring of varying width. Even though the +ribbon has already been cut for a ring of given diameter, it may be +still further enlarged by drawing it out and leaving a bit of the ring +open, so as to thus obtain a nearly corresponding diminution in the +resistance. Such a resistance may be still further diminished by +rendering the ring higher, that is to say, by employing an annular +cylindrical form.</p> + +<p>After assuring himself, by experiments on a small scale, that +calculation and observation gave concordant results for the flat ring, +the author made an experiment on a larger scale with the annular +network. For practical reasons he employed for this purpose a copper +wire 2.5 mm. in diameter, which may be expected to last as long as one +of iron plate 2 mm. in thickness. Calculation showed that in a ribbon +160 mm. wide, meshes 40 mm. in breadth were advantageous and favorable +as regards rigidity. A reticulated ribbon like this, 4 meters in +length, was made and formed into a flat ring having an external +diameter of 1.42 m. and an internal one of 1.10 m. The resistance of +this ring was found to be W = 0.3485 1/<i>k</i>, and that of a plate one +meter square, W<sub>0</sub> = 0.368 1/<i>k</i>.</p> + +<p>As the conductivity of the earth is very variable, and as we cannot +have an absolute guarantee that the ramming will be uniform, it seemed +proper to make the measurements of the resistance by fixing the plate +and the ring in succession to the lower surface of a small raft, in +such a way that the contact with the water should correspond as well +as possible to the suppositions made for the calculation. As a second +ground conductor, a system of water pipes was used, and, after this, a +lightning rod conductor, etc.</p> + +<p>Repeated and varied experiments gave, for the calculation of the +values of the resistances, equations so concordant that the following +results may be considered very approximate.</p> + +<p>The square plate had a resistance of 35.5 Siemens units, and the +reticulated ring one of 32.5. From the first figure we deduce k = +1/91.12, that is to say, the specific conductivity of river-water is +1:91120000. Calculation, then, gives as the resistance of the earth in +Siemens units:</p> + +<div class="ctr"> +<table border="0" cellpadding="4" cellspacing="0" summary=""> +<colgroup span="3" align="left"></colgroup> +<tr><td></td><th>Calculated</th><th>Observed.</th></tr> +<tr><td>Square plate.</td><td> 33.5</td><td> 33.5</td></tr> +<tr><td>Annular ring.</td><td> 31.76</td><td> 32.5</td></tr> +</table></div> + +<p>These figures prove the accuracy of the calculations that had been +made in an approximate way.</p> + +<p>The experiments were performed upon the Elba, above Dresden. Other +experiments still had reference to the influence of immersion. In +order to diminish polarization, only instantaneous currents from the +measuring pile were employed. It was to be supposed that the current +of water through which the bubbles of gas were removed from the +electrodes would not have permitted of a notable resistance of +polarization. Later measurements, made upon a ribbon buried, like the +plates, in the earth, gave likewise most favorable results.</p> + +<p>As a result of these experiments, the State railways of Saxony have, +in such cases as were practicable, introduced the annular network of +copper. There are some manufacturers, too, who seem desirous of +adopting this system, although it has hardly emerged from the period +of experiment. The pecuniary advantages that will result from an +application of it ought, it would seem, to dispel a large proportion +of the criticisms directed against the erection of lightning rods, +from the standpoint of expense, and contribute to extend an +arrangement which may be considered as a very happy one.</p> + +<p>If we compare the square plate with the equivalent annular network, +constructed as above indicated, and which should possess, according to +the author an external diameter of 1.26 m. and of 3.45 m., we find +that:</p> + +<div class="ctr"><table summary=""> +<colgroup span="3" align="left"></colgroup> +<tr><td>The square plate,</td><td>1 mm. thick</td><td>weighs 8.9 kilos.</td></tr> +<tr><td align="center">"</td><td>2 mm. thick</td><td>weighs 17.8 kilos.</td></tr> +<tr><td colspan="2">The annular network</td><td>weighs 1.64 kilos.</td></tr> +</table></div> + +<p>The cost of reticulated ribbon per meter amounts to about 4.4 francs, +supposing it to be arranged as shown in the cut.</p> + +<p>As term of comparison, we may admit that the following forms are +nearly the equivalent of a horizontal, unburied plate one meter +square.</p> + +<div class="ctr"> +<table border="0" cellpadding="4" cellspacing="0" summary=""> +<colgroup span="4"><col align="left" /><col align="center" /><col align="right" span="2" /></colgroup> +<tr><td></td><td></td><th>Length.</th><th>Diameter.</th></tr> +<tr><td>Vertical cylinder</td><td>buried</td><td>1.40 m.</td><td>0.13 m.</td></tr> +<tr><td align="center">"</td><td>"</td><td>1.80 m.</td><td>0.06 m.</td></tr> +<tr><td>Vertical bar</td><td>"</td><td>2.60 m.</td><td>0.013 m.</td></tr> +<tr><td>Horizontal bar</td><td>"</td><td>5.20 m.</td><td>0.013 m.</td></tr> +</table></div> + + +<p>Horizontal flat ring 1.32 m. in external diameter, and 1.08 m. +internal.</p> + +<p>Horizontal network 1.01 m. square, and having meshes of the same size +as those of the reticulated ribbon.</p> + +<p>Horizontal reticulated ribbon 3 m. in length and of the structure +described.</p> + +<p>Horizontal annular ring 1.26 m. in external diameter, 0.94 m. +internal.</p> + +<p>In conclusion, let us meet an objection that might be made to the +accuracy of the hypotheses that serve as a base to the preceding +calculations, in cases where ground plates for lightning rods and not +for telegraphs are concerned. Between the two ground plates of a +telegraph line there is generally a distance such that the curves of +the current undergo no deviation in the vicinity of one of the +electrodes (the only part important for integrations) through the +influence of the other. But it might be admitted that such would prove +the case with a lightning rod in a storm, at the time of the passage +of the fluid into the earth. The ground plate here is one of the +electrodes, and the other is replaced by the surface of the earth +strongly charged to a great distance under the storm clouds. If we +suppose (what may be admitted in a good lightning rod) that there no +longer occurs any spark from the point downward, the curves of the +current, in starting perpendicularly from the ground plate, would be +obliged to leave their rectilinear trajectory and strike the surface +of the earth at right angles. When the electricity flows through a +plane surface into an infinite body, it is only when such surface +presents a very great development that the respective potentials +decrease very slowly in the vicinity of the said surface. No notable +modification occurs, then, in the curves of equal potential, in the +vicinity of the ground plate through the action of this extended +charge, nor consequently any modification in the curves of the +current; but the electricity which spreads has but a short distance to +travel in order to overcome the most important resistances.</p> + +<p>The calculations of resistances given above have, then, the same value +for discharges of atmospheric electricity.—<i>Bull. du Musee de +l'Industrie.</i></p> + +<hr /> + + + + +<h2><a name="art01" id="art01"></a>ON ELECTROLYSIS.</h2> + +<h3>By H. SCHUCHT.</h3> + + +<p>Concerning the separations which take place at the positive pole, the +composition of the peroxides, and the manner of their determination, +relatively little has been done.</p> + +<p>If solutions of the salts of lead, thallium, silver, bismuth, nickel, +and cobalt are decomposed by the current between platinum electrodes, +metal is deposited at the negative, and oxide at the positive +electrode. Manganese is precipitated only as peroxide. The formation +of peroxide is, of course, effected by the ozone found in the +electrolytic oxygen at the positive pole; the oxide existing in +solution is brought to a higher degree of oxidation, and is separated +out. Its formation may be decreased or entirely prevented by the +addition of readily oxidizible bodies, such as organic acids, lactose, +glycerine, and preferably by an excess of oxalic acid; but only until +the organic matter is transformed into carbonic acid. In this manner +Classen separates other metals from manganese in order to prevent the +saline solutions from being retained by the peroxide.</p> + +<p>With solutions of silver, bismuth, nickel, and cobalt, it is often +practicable to prevent the separation of oxide by giving the current a +greater resistance—increasing the distance between the electrodes.</p> + +<p>The proportion between the quantities of metal and of peroxide +deposited is not constant, and even if we disregard the concentration +of the solution, the strength of the current and secondary influences +(action of nascent hydrogen) is different in acid and in alkaline +solutions. In acid solutions much peroxide is formed; in alkaline +liquids, little or none. The reason of the difference is that ozone is +evolved principally in acid solutions, but appears in small quantities +only in alkaline liquids, or under certain circumstances not at all. +The quantity of peroxide deposited depends also on the temperature of +the saline solution; at ordinary temperatures the author obtained more +peroxide—the solution, the time, and the strength of current being +equal—than from a heated liquid. The cause is that ozone is destroyed +by heat and converted into ordinary oxygen. With the exception of lead +and thallium the quantity of metal deposited from an acid solution is +always greater than that of the peroxide.</p> + +<p><i>Lead.</i>—Luckow has shown that from acid solutions—no matter what may +be the acid—lead is deposited at the anode as a mixture of anhydrous +and hydrated peroxide of variable composition. Only very strongly acid +solutions let all their lead fall down as peroxide; the precipitation +is rapid immediately on closing the circuit, and complete separation +is effected only in presence of at least 10 per cent. of free nitric +acid. As the current becomes stronger with the increase of free acid, +there is deposited upon the first compact layer a new stratum of +loosely adhering peroxide.</p> + +<p>In presence of small quantities of other metals which are thrown down +by the current in the metallic state, such as copper, mercury, etc., +peroxide alone is deposited from a solution of lead containing small +quantities only of free nitric acid.</p> + +<p>The lead peroxide deposited is at first light brown or dark red, and +becomes constantly darker and finally taking a velvet-black. As its +stratification upon the platinum is unequal, it forms beautifully +colored rings.</p> + +<p>Experiments show that the quantity of peroxide deposited depends on +the nature of the solution and the strength of the current. In case of +very feeble currents and slight acidity, its quantity is so small that +it does not need to be taken into consideration. If the lead solution +is very dilute scarcely any current is observed, lead solutions <i>per +se</i> being very bad conductors of electricity.</p> + +<p>Faintly acid concentrated lead solutions give loose peroxide along +with much spongy metallic lead. Free alkali decreases the separation +of peroxide; feebly alkaline solutions, concentrated and dilute, yield +relatively much peroxide along with metallic lead, while strongly +alkaline solutions deposit no peroxide.</p> + +<p>Dried lead peroxide is so sparingly hygroscopic that it may be weighed +as such; its weight remains constant upon the balance for a long time. +In order to apply the peroxide for quantitative determinations, a +large surface must be exposed to action. As positive electrode a +platinum capsule is convenient, and a platinum disk as negative pole. +The capsule shape is necessary because the peroxide when deposited in +large quantities adheres only partially, and falls in part in thin +loose scales. It is necessary to siphon off the nitric solution, +since, like all peroxides, that of lead is not absolutely insoluble in +nitric acid. The methods of Riche and May give results which are +always too high, since portions of saline solution are retained by the +spongy deposit and can be but very imperfectly removed by washing. +This is especially the case in presence of free alkali.</p> + +<p>The author has proceeded as follows: The lead peroxide is dried in the +capsule, and there is passed over it pure dry gaseous sulphurous acid +in a strong current from a rather narrow delivery tube. Lead sulphate +is formed with evolution of heat; it is let cool under the exsiccator, +and weighed as such. Or he ignites the peroxide along with finely +pulverized ammonium sulphite; the mass must have a pure white color. +After the conclusion of the reaction it is ignited for about 20 +minutes. The results are too high. The proportion of actual lead +peroxide in the deposit ranges from 94 to 94.76 per cent. The peroxide +precipitated from a nitric solution may, under certain circumstances, +be anhydrous. This result is due to the secondary influences at the +positive pole, where the free acid gradually withdraws water from the +peroxide.</p> + +<p>The peroxide thrown down from alkaline solutions retains alkali so +obstinately that it cannot be removed by washing; the peroxide plays +here the part of an acid. The lead nitrate mechanically inclosed in +the peroxide is resolved by ignition into oxide, hyponitric acid, and +oxygen; this small proportion of lead oxide does not exert an +important influence on the final result. The quantity of matter +mechanically inclosed is relatively high, as in the precipitation of +much lead peroxide there is relatively more saline matter occluded +than when a few centigrammes are deposited. The peroxide incloses also +more foreign matter if it is thrown down upon a small surface than if +it is deposited in a thin layer over a broad surface. From numerous +analyses the author concludes that in presence of much free nitric +acid the proportion of water is increased; with free alkali the +reverse holds good.</p> + +<p><i>Thallium</i> behaves similarly to lead. From a nitric acid solution it +is thrown down, according to the proportion of free acid, either as +sesquioxide only or in small quantities as silvery, metallic leaflets; +from alkaline solutions it is deposited as sesquioxide and metal, the +latter of a lead-gray color. Thallium solutions conduct the electric +current badly. Thallium oxide resembles lead peroxide in color; at a +strong heat it melts, becomes darker, and is converted into peroxide, +in which state it can be weighed.</p> + +<p><i>Silver.</i>—All solutions of silver salts, except the nitrate, and +those containing a very large quantity of free nitric acid or +nitrates, deposit electrolytically merely metallic silver. In the +above mentioned exceptional cases there is formed a small quantity of +peroxide which adheres to the anode as a blackish-gray deposit. The +greatest quantity of peroxide is obtained on employing a concentrated, +strongly acid solution of the nitrate, and a strong current. If the +solution is very dilute we obtain no peroxide, or mere traces which +disappear again toward the end of the process. The peroxide is +deposited at first in small, dark, shining octahedral crystals; +subsequently, in an amorphous state. At 110° it evolves oxygen +suddenly, and is converted into metallic silver. It dissolves in +ammonia with a violent escape of nitrogen. In nitric acid it dissolves +without decomposition and with a red color.</p> + +<p>The author uses a galvanic current for reducing silver residues, +consisting of sulphocyanide. The salt is mixed with sulphuric acid in +a roomy platinum capsule, and a fine platinum wire gauze is used as +positive electrode.</p> + +<p><i>Bismuth.</i>—The current resolves bismuth solutions into metal and +bismutic acid. The latter is deposited at the positive pole, and in +thin layers appears of a golden-yellow, but in thick strata is darker, +approaching to red. Its formation is very gradual, and in time it +disappears again, owing to secondary actions of the current. On +ignition it becomes lemon yellow, and transitorily darker, even brown, +and passes into the sexquioxide.</p> + +<p><i>Nickel and Cobalt.</i>—On the electrolysis of the ammonical solution +the sesquioxide appears at the positive pole. Its formation is +prevented by an excess of ammonia. The author never obtains more than +3― per cent. of the quantity of the metal. The sesquioxides dissolve +in ammonia without escape of nitrogen, and are usually anhydrous.</p> + +<p><i>Manganese.</i>—Manganese is the only metal which is precipitated only +as peroxide. It is deposited at once on closing the circuit, and is at +first brown, then black and shining. Organic acids, ferrous oxide, +chromic oxide, ammonium salts, etc., prevent the formation of peroxide +and the red color produced by permanganic acid. In very dilute +strongly acid nitric solutions there is formed only permanganic acid, +which according to Riche is plainly visible in solutions containing +1/1000000 grm. manganese. On electrolyzing a manganiferous solution of +copper nitrate, red permanganic acid appeared in a stratum floating +above the platinum disk coated with brown peroxide. No manganese +peroxide was deposited. The peroxide adheres firmly to the platinum +when the proportion of free acid is small, not exceeding 3 per cent., +and the current is not too strong. If the action of the current is +prolonged after the peroxide is thrown down, it falls off in laminæ. +According to Riche, in a nitric solution the manganese is deposited as +peroxide, also at the negative pole. This formation is not directly +due to the current, but is a precipitate occasioned by the production +of ammonia by the reduction of nitric acid. To determine the manganese +in peroxide electrolytically precipitated, it is heated to bright +redness in the platinum capsule until the weight becomes constant. The +results are too high.</p> + +<p><i>Selenium and Tellurium.</i>—Both these bodies are readily and +completely reduced by the current either in acid or alkaline +solutions. Selenium is thrown down at first of a fine brownish red, +which gradually becomes darker. The deposit of tellurium is of a +bluish black color. If the current is feeble, the deposit of selenium +is moderately compact; that of tellurium is always loose, and it often +floats on the liquid. A strong current precipitates both as powders. +The positive pole is coated during electrolysis with a film of a dark +color in case of selenium, but of a lemon yellow with tellurium. As in +case of arsenic and antimony, the hydrogen evolved at the negative +pole combines with the reduced substances, forming hydrogen, selenide, +or telluride, which remain in part in solution in the liquid. The +reduced metal separates out at the anode in a friable +condition.—<i>Zeitschrift fur Analytische Chemie, and Chemical News.</i></p> + +<hr /> + + +<h2><a name="art02" id="art02"></a>THE ELECTRO-CHEMICAL EQUIVALENT OF SILVER.</h2> + + +<p>A very careful and important determination of the electrochemical +equivalent of silver has been made at the observatory of the Physical +Institute of Würzbourg, and the results are that an ampere current +flowing for a second, or a coulomb of electricity deposits 1.1183 +milligrammes of silver or 0.3281 milligramme of copper, and decomposes +0.09328 milligramme of water, a result agreeing closely with that of +Lord Rayleigh recently communicated to the Physical Society. An ampere +therefore deposits 4.0259 grammes of silver per hour; Kohlrausch's +value is 4.0824, a value hitherto accepted universally. This value is +so useful in measuring electric currents with accuracy, and free from +the disturbances of magnetism, etc., that it is eminently satisfactory +to find the German value agree with that of Lord Rayleigh, which will +probably be adopted by English electricians.</p> + +<hr /> + + +<h2><a name="art16" id="art16"></a>A NEW STANDARD LIGHT.</h2> + + +<p>Herr Hefner-Alteneck has suggested a new standard light for +photometric purposes, which promises to be very simple and effective +in operation. The light is produced by an open flame of amyl-acetate +burning from a wick of cotton fiber which fills a tube of German +silver 1 in. long and 316 mils. internal diameter; the external +diameter being 324 mils. The flame is 1.58 in. high from top to +bottom; and it should be lighted at least ten minutes before using the +light for testing. A cylindrical glass chimney surrounds it to ward +off air currents. About 2 per cent. of the light is absorbed by the +glass. The power of the flame is that of a standard English candle; +and experiments have shown that amyl acetate, which besides is not +expensive, is the best fuel for steadiness and brilliance. Neither the +substitution of commercial amyl-acetate for pure nor the use of a wick +of cotton thread for loose cotton fiber alters the illuminating power; +but the wick should be trimmed square across the mouth of the tube, +for if it project and droop the illuminating power is increased.</p> + +<hr /> + +<p class="ctr">[NATURE.]</p> + + + + +<h2><a name="Page_7042" id="Page_7042"></a><a name="art17" id="art17"></a>DR. FEUSSNER'S NEW POLARIZING PRISM.</h2> + + +<p>In a recent number of the <i>Zeitschrift fur Instrumentenkunde</i> (iv., +42-50, February, 1884), Dr. K. Feussner of Karlsruhe has given a +detailed description of a polarizing prism lately devised by him, +which presents several points of novelty, and for which certain +advantages are claimed. The paper also contains an account, although +not an exhaustive one, of the various polarizing prisms which have +from time to time been constructed by means of different combinations +of Iceland spar. The literature of this subject is scattered and +somewhat difficult of access, and moreover only a small part of it has +hitherto been translated into English; and it would appear therefore +that a brief abstract of the paper may not be without service to those +among the readers of <i>Nature</i> who may be unacquainted with the +original memoirs, or who may not have the necessary references at +hand.</p> + +<p>Following the order adopted by Dr. Feussner, the subject may be +divided into two parts:</p> + + +<h3>I.—OLDER FORMS OF POLARIZING PRISMS.</h3> + +<p>In comparing the various forms of polarizing prisms, the main points +which need attention are—the angular extent of the field of view, the +direction of the emergent polarized ray, whether it is shifted to one +side of, or remains symmetrical to the long axis of the prism; the +proportion which the length of the prism bears to its breadth; and +lastly, the position of the terminal faces, whether perpendicular or +inclined to the long axis. These requirements are fulfilled in +different degrees by the following methods of construction:</p> + +<p class="ctr"><img src="./images/12a.png" alt="Fig. 1., Fig. 2., and Fig. 3." /><br />Figs. 1., 2., and 3.</p> + +<p>1. <i>The Nicol Prism</i> (<i>Edin. New Phil. Journal</i>, 1828, vi., 83).—This +(Fig. 1), as is well known, is constructed from a rhombohedron of +Iceland spar, the length of which must be fully three times as great +as the width. The end faces are cut off in such a manner that the +angle of 72° which they originally form with the lateral edge of the +rhombohedron is reduced to 68°. The prism is then cut in two in a +plane perpendicular to the new end surfaces, the section being carried +obliquely from one obtuse corner of the prism to the other, in the +direction of its length. The surfaces of this section, after having +been carefully polished, are cemented together again by means of +Canada balsam. A ray of light, on entering the prism, is separated by +the double refraction of the calc-spar into an ordinary and an +extraordinary ray; the former undergoes total reflection at the layer +of balsam at an incidence which allows the extraordinary ray to be +transmitted; the latter, therefore, passes through unchanged. This +principle of obtaining a single polarized ray by means of total +reflection of the other is common to all the forms of prism now to be +described.</p> + +<p>Dr. Feussner gives a mathematical analysis of the paths taken by the +two polarized rays within the Nicol prism, and finds that the emergent +extraordinary ray can include an angular field of 29°, but that this +extreme value holds good only for rays incident upon that portion of +the end surface which is near to the obtuse corner, and that from +thence it gradually decreases until the field includes an angle of +only about half the previous amount. He finds, moreover, that, +although of course the ray emerges parallel to its direction of +incidence, yet that the zone of polarized light is shifted to one side +of the central line. Also that the great length of the Nicol—3.28 +times its breadth—is not only an inconvenience, but owing to the +large pieces of spar thus required for its construction, prisms of any +but small size become very expensive. To this it may be added that +there is a considerable loss of light by reflection from the first +surface, owing to its inclined position in regard to the long axis of +the prism.</p> + +<p class="ctr"><img src="./images/12b.png" alt="Fig. 4., Fig. 5., and Fig. 6." /><br />Figs. 4., 5., and 6.</p> + +<p>It is with the view of obviating these defects that the modifications +represented in Figs. 2 to 6 have been devised.</p> + +<p>2. <i>The Shortened Nicol Prism</i>.—This arrangement of the Nicol prism +is constructed by Dr. Steeg and Reuter of Homburg v.d.H. For the sake +of facility of manufacture, the end surfaces are cleavage planes, and +the oblique cut, instead of being perpendicular, makes with these an +angle of about 84°. By this alteration the prism becomes shorter, and +is now only 2.83 times its breadth; but if Canada balsam is still used +as the cement, the field will occupy a very unsymmetrical position in +regard to the long axis. If balsam of copaiba is made use of, the +index of refraction of which is 1.50, a symmetrical field of about 24° +will be obtained. A prism of this kind has also been designed by Prof. +B. Hasert of Eisenach (<i>Pogg. Ann.</i>, cxiii., 189), but its performance +appears to be inferior to the above.</p> + +<p>3. <i>The Nicol Prism with Perpendicular Ends.</i>—The terminal surfaces +in this prism are perpendicular to the long axis, and the sectional +cut makes with them an angle of about 75°. The length of the prism is +3.75 times its breadth, and if the cement has an index of refraction +of 1.525, the field is symmetrically disposed, and includes an angle +of 27°. Prisms of this kind have been manufactured by Dr. Steeg, Mr. +C.D. Ahrens, and others.</p> + +<p>4. <i>The Foucault Prism</i> (<i>Comptes Rendus</i>, 1857, xlv., 238).—This +construction differs from all those hitherto mentioned, in that a film +of air is employed between the two cut surfaces as the totally +reflecting medium instead of a layer of cement. The two halves of the +prism are kept in position, without touching each other, by means of +the mounting. The length of the prism is in this way much reduced, and +amounts to only 1.528 times its breadth. The end surfaces are cleavage +planes, and the sectional cut makes with them an angle of 59°. The +field, however, includes not more than about 8°, so that this prism +can be used only in the case of nearly parallel rays; and in addition +to this the pictures which may be seen through it are to some extent +veiled and indistinct, owing to repeated internal reflection.</p> + +<p>5. <i>The Hartnack Prism</i> (<i>Ann. de Ch. et de Physique</i>, ser. iv., vii., +181).—This form of prism was devised in 1866 by MM. Hartnack and +Prazmowiski; the original memoir is a valuable one; a translation of +it, with some additions, has lately been published (<i>Journ. of the R. +Microscopical Soc.</i>, June, 1883, 428). It is considered by Dr. +Feussner to be the most perfect prism capable of being prepared from +calc-spar. The ends of the prism are perpendicular to its length; the +section carried through it is in a plane perpendicular to the +principal axis of the crystal. The cementing medium is linseed oil, +the index of refraction of which is 1.485. This form of prism is +certainly not so well known in this country as it deserves to be; a +very excellent one, supplied to the present writer by Dr. Steeg is of +rectangular form throughout, the terminal surfaces are 19 Ũ 15 mm., +and the length 41 mm. The lateral shifting of the field is scarcely +perceptible, the prism is perfectly colorless and transparent, and its +performance is far superior to that of the ordinary Nicol. The field +of view afforded by this construction depends upon the cementing +substance used, and also upon the inclination of the sectional cut in +regard to the end of the prism; it may vary from 20° to 41°. If the +utmost extent of field is not required, the prism may be shortened by +lessening the angle of the section, at the expense, however, of +interfering with the symmetrical disposition of the field.</p> + +<p>6. <i>The Glan Prism</i> (Carl's "Repertorium," xvi., 570, and xvii., +195).—This is a modification of the Foucault, and in a similar manner +includes a film of air between the sectional surfaces. The end +surfaces and also the cut carried through the prism are parallel to +the principal axis of the calc-spar. The ends are normal to the +length, and the field includes about 8°. This prism is very short, and +may indeed be even shorter than it is broad. It is subject to the same +defect as that mentioned in the case of the Foucault, although perhaps +not quite to the same extent.</p> + + +<h3>II.—THE NEW POLARIZING PRISM.</h3> + +<p>This prism differs very considerably from the preceding forms, and +consists of a thin plate of a doubly refracting crystal cemented +between two wedge-shaped pieces of glass, the terminal faces of which +are normal to the length. The external form of the prism may thus be +similar to the Hartnack, the calc-spar being replaced by glass. The +indices of refraction of the glass and of the cementing medium should +correspond with the greater index of refraction of the crystal, and +the directions of greatest and least elasticity in the latter must +stand in a plane perpendicular to the direction of the section. One of +the advantages claimed for the new prism is that, it dispenses with +the large and valuable pieces of spar hitherto found necessary; a +further advantage being that other crystalline substances may be used +in this prism instead of calc-spar. The latter advantage, however, +occurs only when the difference between the indices of refraction for +the ordinary and extraordinary rays in the particular crystal made use +of is greater than in calc-spar. When this is the case, the field +becomes enlarged, and the length of the prism is reduced.</p> + +<p class="ctr"><img src="./images/12c-7.png" alt="Fig. 7." /><br />Fig. 7.</p> + +<p>The substance which Dr. Feussner has employed as being most suitable +for the separating crystal plate is nitrate of soda +(<i>natronsalpeter</i>), in which the above-mentioned values are ω = +1.587 and η = 1.336. It crystallizes in similar form to calcite, +and in both cases thin plates obtained by cleavage may be used.</p> + +<p>As the cementing substance for the nitrate of soda, a mixture of gum +dammar with monobromonaphthalene was used, which afforded an index of +refraction of 1.58. In the case of thin plates of calcite, a solid +cementing substance of sufficiently high refractive power was not +available, and a fluid medium was therefore employed. For this purpose +the whole prism was inclosed in a short glass tube with airtight ends, +which was filled with monobromonaphthalene. In an experimental prism a +mixture of balsam of tolu was made use of, giving a cement with an +index of refraction of 1.62, but the low refractive power resulted in +a very considerable reduction of the field. The extent and disposition +of the field may be varied by altering the inclination at which the +crystal lamina is inserted (Fig. 7), and thereby reducing the length +of the prism, as in the case of the Hartnack.</p> + +<p>In order to obviate the effects of reflection from the internal side +surfaces if the prism, the wedge-shaped blocks of glass of which it is +built up may be made much broader than would otherwise be necessary; +the edges of this extra width are cut obliquely and suitably +blackened.</p> + +<p>The accompanying diagram (Fig. 8) represents a prism of cylindrical +external form constructed in this manner, the lower surface being that +of the incident light. In this the field amounts to 30°, and the +breadth is about double the length.</p> + +<p class="ctr"><img src="./images/12c-8.png" alt="Fig. 8." /><br />Fig. 8.</p> + +<p>Dr. Feussner remarks that a prism similar in some respects to his new +arrangement was devised in 1869 by M. Jamin (<i>Comptes Rendus</i>, +lxviii., 221), who used a thin plate of calc-spar inclosed in a cell +filled with bisulphide of carbon; and also by Dr. Zenker, who replaced +the liquid in M. Jamin's construction by wedges of flint glass.</p> + +<p>Among others, the carefully considered modifications of the Nicol +prism which have recently been devised by Prof. S.P. Thompson (<i>Phil. +Mag.</i>, November, 1881, 349, and <i>Jour. R. Micros. Soc.</i>, August, 1883, +575), and by Mr. R.T. Glazebrook (<i>Phil. Mag.</i>, May, 1883, 352), do +not appear to have been known to Dr. Feussner.</p> + +<p>The following tabular view of different forms of polarizing prisms is +taken from the conclusion of Dr. Feussner's paper:</p> + +<div class="ctr"> +<table border="1" cellpadding="4" cellspacing="0" summary=""> +<colgroup span="6"><col span="2" align="left" /><col span="3" align="right" /><col align="left" /></colgroup> +<tr><td colspan="2"> </td><th>Field.</th><th>Inclination of <br />section in <br /> regard to <br />long axis.</th><th>Ratio of<br /> length to <br />clear width.</th><th>Fig.</th></tr> +<tr><td colspan="2" align="left">I. THE OLD POLARISING PRISMS.</td><td>°</td><td>°</td><td colspan="2"> </td></tr> +<tr><td colspan="2"><span class="indlist">1. Nicol's prism.</span></td><td>29</td><td>22</td><td>3.28</td><td>1</td></tr> +<tr><td colspan="6"><span class="indlist">2. Shortened Nicol prism—</span></td></tr> +<tr><td rowspan="2"> </td><td><i>a.</i> Cemented with Canada balsam.</td><td>13</td><td>25</td><td>2.83</td><td>2</td></tr> +<tr><td><i>b.</i> Cemented with copaiba balsam.</td><td>24</td><td>25</td><td>2.83</td><td>2</td></tr> +<tr><td colspan="6"><span class="indlist">3. Nicol with perpendicular ends—</span></td></tr> +<tr><td rowspan="2"> </td><td><i>a.</i> With Canada balsam.</td><td>20</td><td>15</td><td>3.73</td><td>3</td></tr> +<tr><td><i>b.</i> With cement of index <br />of refraction of 1.525.</td><td>27</td><td>15</td><td>3.73</td><td>3</td></tr> +<tr><td colspan="2"><span class="indlist">4. Foucault's prism.</span></td><td>8</td><td>40</td><td>1.528</td><td>4</td></tr> +<tr><td colspan="6"><span class="indlist">5. Hartnack's prism—</span></td></tr> +<tr><td rowspan="4"> </td><td><i>a.</i> Original form.</td><td>35</td><td>15.9</td><td>3.51</td><td>5<i>a</i><i>b</i></td></tr> +<tr><td><i>b.</i> With largest field.</td><td>41.9</td><td>13.9</td><td>4.04</td><td>5<i>a</i><i>a</i></td></tr> +<tr><td><i>c.</i> With field of 30°.</td><td>30</td><td>17.4</td><td>3.19</td><td>5<i>a</i><i>c</i></td></tr> +<tr><td><i>d.</i> With field of 20°.</td><td>20</td><td>20.3</td><td>2.70</td><td>5<i>a</i><i>d</i></td></tr> +<tr><td colspan="2"><span class="indlist">6. Glan's prism.</span></td><td>7.9</td><td>50.3</td><td>0.831</td><td>6</td></tr> +<tr><td colspan="6" align="left">II. THE NEW POLARISING PRISM.</td></tr> +<tr><td><span class="indlist">1. With calc-spar:</span></td><td>largest field.</td><td>44</td><td>13.2</td><td>4.26</td><td>5<i>a</i><i>a</i></td></tr> +<tr><td><span class="indlist">2. "</span></td><td>field of 30°.</td><td>30</td><td>17.4</td><td>3.19</td><td>5<i>a</i><i>c</i></td></tr> +<tr><td><span class="indlist">3. "</span></td><td>field of 20°.</td><td>20</td><td>20.3</td><td>2.70</td><td>5<i>a</i><i>d</i></td></tr> +<tr><td><span class="indlist">4. With nitrate of soda:</span></td><td>largest field.</td><td>54</td><td>16.7</td><td>3.53</td><td>7<i>a</i><i>a</i></td></tr> +<tr><td><span class="indlist">5. "</span></td><td>field of 30°.</td><td>30</td><td>24</td><td>2.25</td><td>7<i>a</i><i>b</i></td></tr> +<tr><td><span class="indlist">6. "</span></td><td>field of 20°.</td><td>20</td><td>27</td><td>1.96</td><td>7<i>a</i><i>c</i></td></tr> +</table></div> + + +<p>As an analyzing prism of about 6 mm. clear width, and 13.5 mm. long, +the new prism is stated by its inventor to be of the most essential +service, and it would certainly appear that the arrangement is rather +better adapted for small prisms than for those of considerable size. +Any means by which a beam of polarized light of large diameter—say 3 +to 3― inches—could be obtained with all the convenience of a Nicol +would be a real advance, for spar of sufficient size and purity for +such a purpose has become so scarce and therefore so valuable that +large prisms are difficult to procure at all. So far as an analyzer is +concerned, the experience of the writer of this notice would lead to +the opinion that improvements are to be looked for rather in the way +of the discovery of an artificial crystal which absorbs one of the +polarized rays than by further modifications depending upon total +reflection. The researches of Dr. Herapath on iodosulphate of quinine +(<i>Phil. Mag.</i>, March, 1852, 161, and November, 1853, 346) are in this +direction; but crystals of the so-called herapathite require great +manipulative skill for their production. If these could be readily +obtained of sufficient size, they would be invaluable as analyzers.</p> + +<p>This opinion is supported by the existence of an inconvenience which +attends every form of analyzing prism. It is frequently, and +especially in projecting apparatus, required to be placed at the focus +of a system of lenses, so that the rays may cross in the interior of +the prism. This is an unfavorable position for a prismatic analyzer, +and in the case of a powerful beam of light, such as that from the +electric arc, the crossing of the rays within the prism is not +unattended with danger to the cementing substance, and to the surfaces +in contact with it.</p> + +<p class="signature">PHILIP R. SLEEMAN.</p> + +<hr /> + + + + +<h2><a name="art03" id="art03"></a>ZIRCON.</h2> + +<h3>By F. STOLBA.</h3> + + +<p>Finely ground zircon is quickly rendered soluble if fused with a +mixture of potassium borofluoride and potassium carbonate. The author +takes two parts of the former to three of the latter, and prepares an +intimate, finely divided mixture, which is kept ready for use.</p> + +<p>Of this mixture four parts are taken to one of zircon, thoroughly +mixed, and melted in a platinum crucible at a red heat. The mass fuses +readily, froths at first and gives off bubbles of gas, and flows then +quietly, forming a very fluid melt. If the zircon is finely ground, 15 +minutes are sufficient for this operation. The loss of weight is 16 +per cent., and is not notably increased on prolonged fusion. It +corresponds approximately to the weight of the carbonic anhydride +present in the potassium carbonate.</p> + +<p>As pungent vapors are given off during fusion, the operation should be +conducted under a draught hood. The activity of the mixture in +attacking zircon appears from the following experiment: Two zircon +crystals, each weighing ― grm., were introduced into the melted +mixture and subjected to prolonged heat. In a short time they +decreased perceptibly in size; each of them broke up into two +fragments, and within an hour they were entirely dissolved. The melted +mass is poured upon a dry metal plate, and when congealed is thrown +into water. It is at once intersected with a number of fissures, which +facilitate pulverization. This process is the more necessary as the +unbroken mass is very slowly attacked by water even on prolonged +boiling. The powder <a name="Page_7043" id="Page_7043"></a>is boiled in a large quantity of water so as to +remove everything soluble. There is obtained a faintly alkaline +solution and a sediment insoluble in water. From the filtrate alkalies +throw down zirconium hydroxide, free from iron.</p> + +<p>The portion insoluble in water is readily dissolved in hydrofluoric +acid, and is converted into zircon potassium fluoride. The chief bulk +of the zirconium is found in the aqueous solution in the state of +double fluorides. The platinum crucible is not in the least attacked +during melting. On the contrary, dirty platinum crucibles may be +advantageously cleaned by melting in them a little of the above +mentioned mixture.</p> + +<p>If finely divided zircon is boiled for a long time with caustic lye, +it is perceptibly attacked. It is very probable that in this manner +zircon might be entirely dissolved under a pressure of 10 atmospheres.</p> + +<p>Potassium borofluoride may be readily prepared from cryolite. +Crucibles of nickel seem especially well adapted for the fusion of +zircon in caustic alkalies.—<i>Ber. Bœhm. Gesell. Wissenschaft; +Chem. News</i>.</p> + +<hr /> + + + + +<h2><a name="art04" id="art04"></a>A PROCESS FOR MAKING WROUGHT IRON DIRECT FROM THE ORE.<a name="FNanchor_5" id="FNanchor_5"></a><a href="#Footnote_5"><sup>1</sup></a></h2> + +<p>The numerous direct processes which have been patented and brought +before the iron masters of the world, differ materially from that now +introduced by Mr. Wilson. After a careful examination of his process, +I am convinced that Mr. Wilson has succeeded in producing good blooms +from iron ore, and I think that I am able to point out theoretically +the chief reasons of the success of his method.</p> + +<p>Without going deeply into the history of the metal, I may mention the +well known fact that wrought iron was extensively used in almost all +quarters of the globe, before pig or cast iron was ever produced. +Without entering into the details of the processes by which this +wrought iron was made, it suffices for my present purpose to say that +they were crude, wasteful, and expensive, so that they can be employed +to-day only in a very few localities favored with good and cheap ore, +fuel, and labor.</p> + +<p>The construction of larger furnaces and the employment of higher +temperatures led to the production of a highly carbonized, fusible +metal, without any special design on the part of the manufacturers in +producing it. This pig iron, however, could be used only for a few +purposes for which metallic iron was needed; but it was produced +cheaply and with little loss of metal, and the attempt to decarbonize +this product and bring it into a state in which it could be hammered +and welded was soon successfully made. This process of decarbonization, +or some modification of it, has successfully held the field against +all so-called, direct processes up to the present time. Why? Because +the old fashioned bloomeries and Catalan forges could produce blooms +only at a high cost, and because the new processes introduced failed +to turn out good blooms. Those produced were invariably "red short," +that is, they contained unreduced oxide of iron, which prevented the +contact of the metallic particles, and rendered the welding together +of these particles to form a solid bloom impossible.</p> + +<p>The process of puddling cast iron, and transforming it by +decarbonization into wrought iron, has, as everybody knows, been in +successful practical operation for many years, and the direct process +referred to so closely resembles this, that a short description of the +theory of puddling is not out of place here.</p> + +<p>The material operated on in puddling is iron containing from 2― to 4 +per cent. of carbon. During the first stage of the process this iron +is melted down to a fluid bath in the bottom of a reverberatory +furnace. Then the oxidation of the carbon contained in the iron +commences, and at the same time a fluid, basic cinder, or slag, is +produced, which covers a portion of the surface of the metal bath, and +prevents too hasty oxidation. This slag results from the union of +oxides of iron with the sand adhering to the pigs, and the silica +resulting from the oxidation of the silicon contained in the iron.</p> + +<p>This cinder now plays a very important part in the process. It takes +up the oxides of iron formed by the contact of the oxidizing flame +with the exposed portion of the metal bath, and at the same time the +carbon of the iron, coming in contact with the under surface of the +cinder covering, where it is protected from oxidizing influences, +reduces these oxides from the cinder and restores them to the bath in +metallic form. This alternate oxidation of exposed metal, and its +reduction by the carbon of the cast iron, continues till the carbon is +nearly exhausted, when the iron assumes a pasty condition, or "comes +to nature," as the puddlers call this change. The charge is then +worked up into balls, and removed for treatment in the squeezer, and +then hammered or rolled. In the Wilson process the conditions which we +have noted in the puddling operation are very closely approximated. +Iron ore reduced to a coarse sand is mixed with the proper proportion +of charcoal or coke dust, and the mixture fed into upright retorts +placed in the chimney of the puddling furnace. By exposure for 24 +hours to the heat of the waste gases from the furnace, in the presence +of solid carbon, a considerable portion of the oxygen of the ore is +removed, but little or no metallic iron is formed. The ore is then +drawn from the deoxidizer into the rear or second hearth of the +puddling furnace, situated below it, where it is exposed for 20 +minutes to a much higher temperature than that of the deoxidizer. Here +the presence of the solid carbon, mixed with the ore, prevents any +oxidizing action, and the temperature of the mass is raised to a point +at which the cinder begins to form. Then the charge is carried forward +by the workmen to the front hearth, in which the temperature of a +puddling furnace prevails. Here the cinder melts, and at the same +time the solid carbon reacts on the oxygen remaining combined with the +ore, and forms metallic iron; but by this time the molten cinder is +present to prevent undue oxidation of the metal formed, and solid +carbon is still present in the mixture to play the same role, of +reducing protoxide of iron from the cinder, as the carbon of the cast +iron does in the ordinary puddling process. I have said that the cast +iron used as the material for puddling contains about 3 per cent. of +carbon; but in this process sufficient carbon is added to effect the +reduction of the ore to a metallic state, and leave enough in the mass +to play the part of the carbon of the cast iron when the metallic +stage has been reached.</p> + +<p>It would be interesting to compare the Wilson with the numerous other +direct processes to which allusion has already been made, but there +have been so many of them, and the data concerning them are so +incomplete, that this is impossible. Two processes, however, the Blair +and the Siemens, have attracted sufficient attention, and are +sufficiently modern to deserve notice. In the Blair process a metallic +iron sponge was made from the ore in a closed retort, this sponge +cooled down in receptacles from which the air was excluded, to the +temperature of the atmosphere, then charged into a puddling furnace +and heated for working. In this way (and the same plan essentially has +been followed by other inventors), the metallic iron, in the finest +possible state of subdivision, is subjected to the more or less +oxidizing influences of the flame, without liquid slag to save it from +oxidation, and with no carbon present to again reduce the iron oxides +from the cinder after it is formed. The loss of metal is consequently +very large, but oxides of iron being left in the metal the blooms are +invariably "red short."</p> + +<p>In the Siemens process pieces of ore of the size of beans or peas, +mixed with lime or other fluxing material, form the charge, which is +introduced into a rotating furnace; and when this charge has become +heated to a bright-red heat, small coal of uniform size is added in +sufficient quantity to effect the reduction of the ore.</p> + +<p>The size of the pieces of the material employed prevents the intimate +mixture of the particles of iron with the particles of carbon, and +hence we would, on theoretical grounds, anticipate just what practice +has proved, viz., that the reduction is incomplete, and the resulting +metal being charged with oxides is red-short. In practice, blooms made +by this process have been so red-short that they could not be hammered +at all.</p> + +<p>It would be impracticable in this process to employ ore and carbon in +as fine particles as Wilson does, as a very large portion of the +charge would be carried off by the draught, and a sticking of the +material to the sides of the rotating furnace could scarcely be +avoided. I do not imagine that a division of the material into +anything like the supposed size of molecules is necessary; we know +that the graphitic carbon in the pig-iron employed in puddling is not +so finely divided, but it is much smaller particles than bean or pea +size, and by approximating the size of the graphite particles in pig +iron, Wilson has succeeded in obtaining good results.</p> + +<p>If we examine the utilization of the heat developed by the combustion +of a given quantity of coal in this process, and compare it with the +result of the combustion of an equivalent amount of fuel in a blast +furnace, we shall soon see the theoretical economy of the process. The +coal is burned on the grate of the puddling-furnace, to carbonic acid, +and the flame is more fully utilized than in an ordinary +puddling-furnace, for besides the ordinary hearth there is the second +or rear hearth, where additional heat is taken up, and then the +products of combustion are further utilized in heating the retorts in +which the ore is partly reduced. After this the heat is still further +utilized by passing it under the boilers for the generation of steam, +and the heat lost in the gases, when they finally escape, is very +small. In a blast furnace the carbon is at first burned only to +carbonic oxide, and the products of combustion issue mainly in this +form from the top of the furnace. Then a portion of the heat resulting +from the subsequent burning of these gases is pretty well utilized in +making steam to supply the power required about the works, but the +rest of the gas can only be utilized for heating the blast, and here +there is an enormous waste, the amount of heat returned to the furnace +by the heated blast being very small in proportion to the amount +generated by the burning of that portion of carbonic oxide expended in +heating it, and the gases escape from both the hot-blast and the +boilers at a high temperature.</p> + +<p>In the direct process under consideration the fuel burned is more +completely utilized than in the puddling process, to which the cast +iron from the blast furnace is subjected to convert it into wrought +iron.</p> + +<p>The economy claimed for this process, over the blast furnace and +puddling practice for the production of wrought iron, is that nearly +all the fuel used in the puddling operation is saved, and that with +about the same amount of fuel used in the blast furnace to produce a +ton of pig iron, a ton of wrought iron blooms can be made. I had no +opportunity of weighing the charges of ore and coal used, but I saw +the process in actual operation at Rockaway, N.J. The iron produced +was hammered up into good solid blooms, containing but little cinder. +The muck-bar made from the blooms was fibrous in fracture, and showed +every appearance of good iron. I am informed by the manager of the +Sanderson Brothers' steel works, at Syracuse, N.Y., that they +purchased blooms made by the Wilson process in 1881-1882, that <i>none</i> +of them showed red-shortness, and that they discontinued their use +only on account of the injurious action of the titanium they contained +on the melting pots. These blooms were made from magnetic sands from +the Long Island and Connecticut coasts.</p> + +<p class="ctr"><a href="./images/13a.png"><img src="./images/13a_th.png" alt=" NEW PROCESS FOR MAKING WROUGHT IRON FROM THE ORE." /></a><br /> NEW PROCESS FOR MAKING WROUGHT IRON FROM THE ORE.</p> + +<p>The drawing given shows the construction of the furnace employed. I +quote from the published description:</p> + +<div class="indlist"> +<p> "The upper part, or deoxidizer, is supported on a strong + mantel plate resting on four cast iron columns.</p> + +<p> "The retorts and flues are made entirely of fire-brick, from + special patterns. The outside is protected by a wrought iron + jacket made of No. 14 iron. The puddling furnace is of the + ordinary construction, except in the working bottom, which is + made longer to accommodate two charges of ore, and thus + utilize more of the waste heat in reducing the ore to metallic + iron.</p> + +<p> "The operation of the furnace is as follows: The pulverized + ore is mixed with 20 per cent. of pulverized charcoal or coke, + and is fed into an elevator which discharges into the hopper + on the deoxidizer leading into the retorts marked C. These + retorts are proportioned so that they will hold ore enough to + run the puddling furnace 24 hours, the time required for + perfect deoxidation. After the retorts are filled, a fire is + started in the furnace, and the products of combustion pass up + through the main flue, or well, B, where they are deflected by + the arch, and pass out through suitable openings, as indicated + by arrows, into the down-takes marked<a name="Page_7044" id="Page_7044"></a> E, and out through an + annular flue, where they are passed under a boiler.</p> + +<p> "It will be noticed that the ore is exposed to the waste heat + on three sides of the retorts, and owing to the great surface + so exposed, the ore is very thoroughly deoxidized, and reduced + in the retorts before it is introduced into the puddling + furnace for final reduction. The curved cast iron pipes marked + D are provided with slides, and are for the purpose of + introducing the deoxidized ore into the second bottom of the + furnace. As before stated, the furnace is intended to + accommodate two charges of ore, and as fast as it is balled up + and taken out of the working bottom, the charge remaining in + the second bottom is worked up in the place occupied by the + first charge, and a <i>new</i> charge is introduced. As fast as the + ore is drawn out from the retorts the elevator supplies a new + lot, so that the retorts are always filled, thus making the + process continuous."</p> +</div> + +<p>The temperature of the charge in the deoxidizer is from 800° to 1,000° +F.—<i>Amer. Engineer.</i></p> + + +<div class="note"><p><a name="Footnote_5" id="Footnote_5"></a><a href="#FNanchor_5">[1]</a></p> +<p>A paper read at the Cincinnati Meeting of the American +Institute of Mining Engineers, by Willard P. Ward, A.M., M.E., +February, 1884.</p></div> + +<hr /> + + +<h2><a name="art05" id="art05"></a>SOME REMARKS ON THE DETERMINATION OF HARDNESS IN WATERS.</h2> + +<h3>By HERBERT JACKSON.</h3> + + +<p>Having had occasion some short time ago to examine a hard water which +owed half its hardness to salts of magnesium, I noticed that the soap +test, applied in the usual way, gave a result which differed very much +from that obtained by the quantitative estimation of calcium and +magnesium. A perfectly normal lather was obtained when soap had been +added in quantities sufficient to neutralize 14° of hardness, whereas +the water contained salts of calcium and magnesium equivalent, on +Clark's scale, to a hardness of 27°.</p> + +<p>Although I was aware that similar observations had been made before, I +thought that it might be useful to determine the conditions under +which the soap test could not be depended upon for reliable results.</p> + +<p>I found with waters containing calcium or magnesium alone that, +whenever salts of either of these metals were in solution in +quantities sufficient to give 23° of hardness on Clark's scale, no +dependence could be placed upon the results given by the soap test. In +the case of waters containing salts of both calcium and magnesium, I +found that if the salts of the latter metal were in solution in +quantities sufficient to give more than 10° of hardness, no evidence +could be obtained of their presence so long as the salts of calcium in +the same water exceeded 6°; in such a case a perfect and permanent +lather was produced when soap had been added equivalent to 7° of +hardness.</p> + +<p>If any water be diluted so as to reduce the proportions of the salts +of calcium and magnesium below those stated above, perfectly reliable +results will of course be obtained.</p> + +<p>Instead of dilution I found that heating the water to about 70° C. was +sufficient to cause a complete reaction between the soap and the salts +of calcium and magnesium, even if these were present in far larger +quantities than any given here.</p> + +<p>The experiments so far had all been made with a solution of Castile +soap of the strength suggested by Mr. Wanklyn in his book on "Water +Analysis." My attention was next directed to the use of any one of the +compounds of which such a soap is composed. I commenced with sodium +oleate, and found that by employing this substance in a moderately +pure condition, perfectly reliable results could be obtained in very +hard waters without the trouble of either diluting or heating. I was +unable to try sodium stearate directly because of the slight +solubility of this substance in cold water or dilute alcohol; but I +found that a mixture of sodium oleate and stearate behaved in exactly +the same manner as the Castile soap.</p> + +<p>I am not prepared at present to state the exact reaction which takes +place between salts of calcium and magnesium and a compound soap +containing sodium oleate and stearate. I publish these results because +I have not noticed anywhere the fact that some waters show a greater +hardness with soap when their temperatures approach the boiling point +than they do at the average temperature of the air, it being, I +believe, the ordinary impression that cold water wastes more soap than +hot water before a good and useful lather can be obtained, whereas +with very many waters the case is quite the reverse. Neither am I +aware at present whether it is well known that the use of sodium +oleate unmixed with sodium stearate dispenses with the process of +dilution even in very hard waters.—<i>Chem. News.</i></p> + +<hr /> + + +<h2><a name="art18" id="art18"></a>THE DENSITY AND PRESSURE OF DETONATING GAS MIXTURES.</h2> + + +<p>MM. Berthelot and Vielle have recently been studying the influence of +the density of detonating gaseous mixtures upon the pressure +developed. The measure of pressure developed by the same gaseous +system, taken under two initial states of different density to which +the same quantity of heat is communicated, is an important matter in +thermodynamics. If the pressures vary in the same ratio as the +densities, we may conclude, independently of all special hypotheses on +the laws of gases, first, that the specific heat of the system is +independent of its density (that is to say, of its initial pressure), +and depends only on the absolute temperature, whatever that may mean; +and secondly, that the relative variation of the pressure at constant +volume, produced by the introduction of a determinate quantity of +heat, is also independent of the pressure, and a function only of the +temperature. Lastly, the pressure itself will vary proportionally with +the absolute temperature, as defined by the theory of a perfect gas, +and will serve to determine it. MM. Berthelot and Vielle operated with +a bomb, at first kept at ordinary temperatures in the air, and +afterward heated in an oil bath to 153 deg. Cent. They also employed +isomeric mixtures of the gases; methylic ether, cyanogen, hydrogen, +acetylene, and other gases were experimented upon, and the general +conclusions are as follows: 1. The same quantity of heat being +furnished to a gaseous system, the pressure of the system varies +proportionally to the density of the system. 2. The specific heat of +the gas is sensibly independent of the density as well toward very +high temperatures as about deg. Cent. This is all true for densities +near to those that the gas possesses cold under normal pressure, and +which varied in the experiment to double the original value. 3. The +pressure increases with the quantity of heat furnished to the same +system. 4. The apparent specific heat increases parallel with this +quantity of heat. These conclusions are independent of all hypotheses +on the nature and laws of gases, and were simply drawn from the +experiments in question.</p> + +<hr /> + + +<h2><a name="art29" id="art29"></a>TURKISH BATHS FOR HORSES.</h2> + +<p>The Turkish bath has become an established institution in this +country; men of all classes now use it for sanitary as well as +remedial purposes. Athletes of various descriptions find it invaluable +in "training," and all the distinguished jockeys and light weights +keep themselves in condition by its use.</p> + +<p>It was thought probable that what was good for man might also be good +for the horse, and the fact has been proved. Messrs. Pickford, the +eminent carriers, in their hospital for horses at Finchley, have had a +bath in operation over eleven years, and find the horses derive great +benefit from its use. The bath is put in operation three days a week, +and is administered to over twenty horses in this time. The value of +the bath having been thus proved, it is rather strange that it has not +been more generally adopted by the large carrying firms. However, the +Great Northern Railway Company at their new hospital for horses at +Totteridge, are erecting a very complete Turkish bath. It consists of +three rooms. First, a large wash room or grooming room, from which is +entered the first hot room, or tepidarium, from 140° to 150° Fahr.; +from this room, the horse, after being thoroughly acclimated, can, if +necessary, pass to the hottest room, or calidarium, from 160° to 170° +Fahr., and without any turning round can pass on into the grooming and +washing room again. This last room is slightly heated from the two +other rooms, and in each are stocks in which the animal can he +fastened if required. The heating is done most economically by +Constantine's convoluted stove, and thorough ventilation is secured +from the large volume of hot air constantly supplied, which passes +through the baths, and as it becomes vitiated is drawn off by +specially designed outlets. The wash room is supplied with hot and +cold water, which can, of course, be mixed to any required +temperature.—<i>Building News.</i></p> + +<p class="ctr"><img src="./images/14a.png" alt="Diagram of Horse Bath" /></p> + + +<hr /> + + +<h2><a name="art28" id="art28"></a>MIRYACHIT, A NEWLY DESCRIBED DISEASE OF THE NERVOUS SYSTEM, AND +ITS ANALOGUES.<a name="FNanchor_6" id="FNanchor_6"></a><a href="#Footnote_6"><sup>1</sup></a></h2> + +<h3>By WILLIAM A. HAMMOND, M.D., Surgeon-General, U.S. Army (Retired +List); Professor of Diseases of the Mind and Nervous System in the New +York Post-Graduate Medical School and Hospital.</h3> + + +<p>In a very interesting account of a journey from the Pacific Ocean +through Asia to the United States, by Lieutenant B.H. Buckingham and +Ensigns George C. Foulk and Walter McLean,<a name="FNanchor_7" id="FNanchor_7"></a><a href="#Footnote_7"><sup>2</sup></a> United States navy, I +find an affection of the nervous system described which, on account of +its remarkable characteristics, as well as by reason of certain known +analogies, I think should be brought to the special notice of the +medical profession. I quote from the work referred to, the following +account of this disease. The party is on the Ussuri River not far from +its junction with the Amur in Eastern Siberia: "While we were walking +on the bank here we observed our messmate, the captain of the general +staff (of the Russian army), approach the steward of the boat +suddenly, and, without any apparent reason or remark, clap his hands +before his face; instantly the steward clapped <i>his</i> hands in the same +manner, put on an angry look, and passed on. The incident was somewhat +curious, as it involved a degree of familiarity with the steward +hardly to have been expected. After this we observed a number of queer +performances of the steward, and finally comprehended the situation. +It seemed that he was afflicted with a peculiar mental or nervous +disease, which forced him to imitate everything suddenly presented to +his senses. Thus, when the captain slapped the paddle-box suddenly in +the presence of the steward, the latter instantly gave it a similar +thump; or, if any noise were made suddenly, he seemed compelled +against his will to imitate it instantly, and with remarkable +accuracy. To annoy him, some of the passengers imitated pigs grunting, +or called out absurd names; others clapped their hands and shouted, +jumped, or threw their hats on the deck suddenly, and the poor +steward, suddenly startled, would echo them all precisely, and +sometimes several consecutively. Frequently he would expostulate, +begging people not to startle him, and again would grow furiously +angry, but even in the midst of his passion he would helplessly +imitate some ridiculous shout or motion directed at him by his +pitiless tormenters. Frequently he shut himself up in his pantry, +which was without windows, and locked the door, but even there he +could be heard answering the grunts, shouts, or pounds on the bulkhead +outside. He was a man of middle age, fair physique, rather intelligent +in facial expression, and without the slightest indication in +appearance of his disability. As we descended the bank to go on board +the steamer, some one gave a loud shout and threw his cap on the +ground; looking about for the steward, for the shout was evidently +made for his benefit, we saw him violently throw his cap, with a +shout, into a chicken-coop, into which he was about to put the result +of his foraging expedition among the houses of the stanitza.</p> + +<p>"We afterward witnessed an incident which illustrated the extent of +his disability. The captain of the steamer, running up to him, +suddenly clapping his hands at the same time, accidentally slipped and +fell hard on the deck; without having been touched by the captain, the +steward instantly clapped his bands and shouted, and then, in +powerless imitation, he too fell as hard and almost precisely in the +same manner and position as the captain. In speaking of the steward's +disorder, the captain of the general staff stated that it was not +uncommon in Siberia; that he had seen a number of cases of it, and +that it was commonest about Yakutsk, where the winter cold is extreme. +Both sexes were subject to it, but men much less than women. It was +known to Russians by the name of 'miryachit'".</p> + +<p>So far as I am aware—and I have looked carefully through several +books of travel in Siberia—no account of this curious disease has +been hitherto published.</p> + +<p>The description given by the naval officers at once, however, brings +to mind the remarks made by the late Dr. George M. Beard, before the +meeting of the American Neurological Association in 1880, relative to +the "Jumpers" or "Jumping Frenchmen" of Maine and northern New +Hampshire.<a name="FNanchor_8" id="FNanchor_8"></a><a href="#Footnote_8"><sup>3</sup></a></p> + +<p>In June, 1880, Dr. Beard visited Moosehead Lake, found the "Jumpers," +and experimented with them. He ascertained that whatever order was +given them was at once obeyed. Thus, one of the jumpers who was +sitting in a chair with a knife in his hand was told to throw it, and +he threw it quickly, so that it stuck in a beam opposite; at the same +time he repeated the order to throw it with a cry of alarm not unlike +that of hysteria or epilepsy. He also threw away his pipe, which he +was filling with tobacco, when he was slapped upon the shoulder. Two +jumpers standing near each other were told to strike, and they struck +each other very forcibly. One jumper, when standing by a window, was +suddenly commanded by a person on the other side of the window to +jump, and he jumped up half a foot from the floor, repeating the +order. When the commands are uttered in a quick, loud voice, the +jumper repeats the order. When told to strike he strikes, when told to +throw he throws whatever he may happen to have in his hand. Dr. Beard +tried this power of repetition with the first part of the first line +of Virgil's "Æneid" and the first part of the first line of Homer's +"Iliad," and out-of-the-way words of the English language with which +the jumper could not be familiar, and he repeated or echoed the sound +of the word as it came to him in a quick, sharp voice, at the same +time he jumped, or struck, or threw, or raised his shoulders, or made +some other violent muscular motion. They could not help repeating the +word or sound that came from the person that ordered them, any more +than they could help striking, dropping, throwing, jumping, or +starting; all of these phenomena were indeed but parts of the general +condition known as jumping. It was not necessary that the sound should +come from a human being; any sudden or unexpected noise, as the +explosion of a gun or pistol, the falling of a window, or the slamming +of a door—provided it was unexpected and loud enough—would cause +these jumpers to exhibit some one or all of these phenomena. One of +these jumpers came very near cutting his throat, while shaving, on +hearing a door slam. They had been known to strike their fists against a +red-hot stove, to jump into the fire and into water. They could not +help striking their best friend if near them when ordered. The noise +of a steam whistle was especially obnoxious to them. One of these +jumpers, when taking some bromide of sodium in a tumbler, was told to +throw it, and he dashed the tumbler upon the floor. It was dangerous +to startle them in any way when they had an ax or an knife in their +hands. All of the jumpers agreed that it tired them to be jumped, and +they dreaded it, but they were constantly annoyed by their companions.</p> + +<p>From this description it will at once, I think, be perceived that +there are striking analogies between "miryachit" and this disorder of +the "Jumping Frenchmen" of Maine. Indeed, it appears to me that, if +the two affections were carefully studied, it would be found that they +were identical, or that, at any rate, the phenomena of the one could +readily be developed into those of the others. It is not stated that +the subjects of miryachit do what they are told to do. They require an +example to reach their brains through the sense of sight or that of +hearing, whereas the "Jumpers" do not apparently perform an act which +is executed before them, but they require a command. It seems, +however, that a "Jumper" starts whenever any sudden noise reaches his +ears.</p> + +<p>In both classes of cases a suggestion of some kind is required, and +then the act takes place independently of the will. There is another +analogous condition known by the Germans as <i>Schlaftrunkenheit</i>, and +to English and American neurologists as somnolentia, or +sleep-drunkenness. In this state an individual, on being suddenly +awakened, commits some incongruous act of violence, ofttimes a murder. +Sometimes this appears to be excited by a dream, but in others no such +cause could be discovered.</p> + +<p>Thus, a sentry fell asleep during his watch, and, being suddenly +aroused by the officer in command, attacked the latter with his sword, +and would have killed him but for the interposition of the bystanders. +The result of the medical examination was that the act was +involuntary, being the result of a violent confusion of mind +consequent upon the sudden awaking from a profound sleep. Other cases +are cited by Wharton and Stille in their work on medical +jurisprudence, by Hoffbauer, and by myself in "Sleep and its +Derangements."</p> + +<p>The following cases among others have occurred in my own experience:</p> + +<p>A gentleman was roused one night by his wife, who heard the +street-door bell ring. He got up, and, without paying attention to +what she said, dragged the sheets off of the bed, tore them hurriedly +into strips, and proceeded to tie the pieces together. She finally +succeeded in bringing him to himself, when he said he had thought the +house was on fire, and he was providing means for their escape. He did +not recollect having had any dream of the kind, but was under the +impression that the idea had occurred to him at the instant of his +awaking.</p> + +<p>Another was suddenly aroused from a sound sleep by the slamming of a +window-shutter by the wind. He sprang instantly from his bed, and, +seizing a chair that was near, hurled it with all his strength against +the window. The noise of the breaking of glass fully awakened him. He +explained that he imagined some one was trying to get into the room +and had let his pistol fall on the floor, thereby producing the noise +which had startled him.</p> + +<p>In another case a man dreamed that he heard a voice telling him to +jump out of the window. He at once arose, threw open the sash, and +jumped to the ground below, fortunately only a distance of about ten +feet, so that he was not injured beyond receiving a violent shock. +Such a case as this appears to me to be very similar to those +described by Dr. Beard in all its essential aspects.</p> + +<p>A few years ago I had a gentleman under my charge who would attempt to +execute any order given him while he was <a name="Page_7045" id="Page_7045"></a>asleep by a person +whispering into his ear. Thus, if told in this way to shout, he +shouted as loud as he could; if ordered to get up, he at once jumped +from the bed; if directed to repeat certain words, he said them, and +so on.</p> + +<p>I am not able to give any certain explanation of the phenomena of +miryachit or of the "Jumpers," or of certain of those cases of +sleep-drunkenness which seem to be of like character. But they all +appear to be due to the fact a motor impulse is excited by perceptions +without the necessary concurrence of the volition of the individual to +cause the discharge. They are, therefore, analogous to reflex actions, +and especially to certain epileptic paroxysms due to reflex +irritations. It would seem as though the nerve cells were very much in +the condition of a package of dynamite or nitro glycerin, in which a +very slight impression is sufficient to effect a discharge of nerve +force. They differ, however, from the epileptic paroxysm in the fact +that the discharge is consonant with the perception—which is in these +cases an irritation—and is hence an apparently logical act, whereas +in epilepsy the discharge is more violent, is illogical, and does not +cease with the cessation of the irritation.</p> + +<p>Certainly the whole subject is of sufficient importance to demand the +careful study of competent observers.</p> + +<div class="note"> +<p><a name="Footnote_6" id="Footnote_6"></a><a href="#FNanchor_6">[1]</a></p> +<p>Read before the New York Neurological Society, February +5, 1884.</p> + +<p><a name="Footnote_7" id="Footnote_7"></a><a href="#FNanchor_7">[2]</a></p> +<p>"Observations upon the Korean Coast, Japanese-Korean +Ports, and Siberia, made during a journey from the Asiatic Station to +the United States, through Siberia to Europe, June 3 to September 8, +1882." Published by the United States Navy Department, Washington, +1883, pp. 51.</p> + +<p><a name="Footnote_8" id="Footnote_8"></a><a href="#FNanchor_8">[3]</a></p> +<p>"Journal of Nervous and Mental Diseases," vol. vii., +1880, p. 487.</p></div> + +<hr /> + +<h2><a name="art26" id="art26"></a>THE GUM DISEASE IN TREES.<a name="FNanchor_9" id="FNanchor_9"></a><a href="#Footnote_9"><sup>1</sup></a></h2> + +<p>An essay by Dr. Beijerinck, on the contagion of the gum disease in +plants, lately published by the Royal Academy of Sciences at +Amsterdam, contains some useful facts. The gum disease (<i>gummosis, +gum-flux)</i> is only too well known to all who grow peaches, apricots, +plums, cherries, or other stone fruits. A similar disease produces gum +arabic, gum tragacanth, and probably many resins and gum resins. It +shows itself openly in the exudation of thick and sticky or hard and +dry lumps of gum, which cling on branches of any of these trees where +they have been cracked or wounded through the bark. Dr. Beijerinck was +induced to make experimental inoculations of the gum disease by +suspicions that, like some others observed in plants, it was due to +bacteria. He ascertained that it is in a high degree contagious, and +can easily be produced by inserting the gum under the edge of a wound +through the bark of any of the trees above named. The observation that +heated or long boiled pieces of gum lose their contagious property +made it most probable that a living organism was concerned in the +contagions; and he then found that only those pieces of the gum +conveyed contagion in which, whether with or without bacteria, there +were spores of a relatively highly organized fungus, belonging to the +class of Ascomycetes; and that these spores, inserted by themselves +under the bark, produced the same pathological changes as did the +pieces of gum. The fungus thus detected, was examined by Professor +Oudemans, who ascertained it to be a new species of Coryneum, and has +named it <i>Coryneum Beijerincki</i>. The inoculation experiments are best +made by means of incisions through the bark of young branches of +healthy peach trees or cherry trees, and by slightly raising the cut +edge of the bark and putting under it little bits of gum from a +diseased tree of the same kind. In nearly every instance these wounds +become the seats of acute gum disease, while similar wounds in the +same or other branches of the same tree, into which no gum is +inserted, remain healthy, unless, by chance, gum be washed into them +during rain. The inoculation fails only when the inserted pieces of +gum contain no Coryneum. By similar inoculations similar diseases can +be produced in plum, almond, and apricot trees, and with the gum of +any one of these trees any other can be infected; but of many other +substances which Beijerinck tried, not one produced any similar +disease. The inoculation with the gum is commonly followed by the +death of more or less of the adjacent structures; first of the bark, +then of the wood. Small branches or leaf stalks thus infected in +winter, or in many places at the same time, may be completely killed; +but, in the more instructive experiments the first symptom of the gum +disease is the appearance of a beautiful red color around the wound. +It comes out in spots like those which often appear spontaneously on +the green young branches of peach trees that have the gum disease; and +in these spots it is usual to find Coryneum stromata or mycelium +filaments. The color is due to the formation of a red pigment in one +or more of the layers of the cells of the bark. But in its further +progress the disease extends beyond the parts at which the Coryneum or +any structures derived from it can be found; and this extension, +Beijerinck believes, is due to the production of a fluid of the nature +of a ferment, produced by the Coryneum, and penetrating the adjacent +structures. This, acting on the cell walls, the starch granules, and +other constituents of the cells, transforms them into gum, and even +changes into gum the Coryneum itself, reminding the observer of the +self-digestion of a stomach.</p> + +<p>In the cells of the cambium, the same fluid penetrating unites with +the protoplasm, and so alters it that the cells produced from it form, +not good normal wood, but a morbid parenchymatous structure. The cells +of this parenchyma, well known among the features of gum disease, are +cubical or polyhedral, thin walled, and rich in protoplasm. This, in +its turn, is transformed into gum, such as fills the gum channels and +other cavities found in wood, and sometimes regarded as gum glands. +And from this also the new ferment fluid constantly produced, and +tracking along the tissues of the branches, conveys the Coryneum +infection beyond the places in which its mycelium can be found.</p> + +<div class="note"> +<p><a name="Footnote_9" id="Footnote_9"></a><a href="#FNanchor_9">[1]</a></p> +<p>Communicated to the <i>Medical Times</i> by Sir James Paget.</p></div> + +<hr /> + +<h2><a name="art27" id="art27"></a>DRINKSTONE PARK.</h2> + +<p>Drinkstone has long been distinguished on account of the successful +cultivation of remarkable plants. It lies some eight miles southeast +from Bury St. Edmund's, and is the seat of T.H. Powell, Esq. The +mansion or hall is a large old-fashioned edifice, a large portion of +its south front being covered by a magnificent specimen of the +Magnolia grandiflora, not less than 40 feet in height, while other +portions of its walls are covered with the finest varieties of +climbing roses and other suitable plants. The surrounding country, +although somewhat flat, is well wooded, and the soil is a rich loam +upon a substratum of gravel, and is consequently admirably suited to +the development of the finer kinds of coniferous and other ornamental +trees and shrubs, so that the park and grounds contain a fine and well +selected assortment of such plants.</p> + +<p class="ctr"><a href="./images/15a.png"><img src="./images/15a_th.png" alt=" THE SNOWFLAKE, LEUCOJUM VERNUM, AT DRINKSTONE" /></a><br /> +THE SNOWFLAKE, LEUCOJUM VERNUM, AT DRINKSTONE PARK.</p> + +<p>Coniferous trees are sometimes considered as out of place in park +scenery; this, however, does not hold good at Drinkstone, where Mr. +Powell has been displayed excellent taste in the way of improving the +landscape and creating a really charming effect by so skillfully +blending the dressed grounds with the rich greensward of the park +that it is not easy to tell where the one terminates or the other +commences.</p> + +<p>The park, which covers some 200 acres, including a fine lake over +eight acres in extent, contains also various large groups or clumps of +such species as the Sequoia gigantea, Taxodium sempervirens, Cedres +deodora, Picea douglasii, Pinsapo, etc., interspersed with groups of +ornamental deciduous trees, producing a warm and very pleasing effect +at all seasons of the year. Among species which are conspicuous in the +grounds are fine, well-grown examples of Araucaria imbricata, some 30 +feet high; Cedrus deodara, 60 feet in height; Abies pinsapo, 40 feet; +and fine specimens of Abies grandis, A. nobilis, and A. nordmanniana, +etc., together with Abies albertiana or mertensiana, a fine, +free-growing species; also Libocedrus gigantea, Thuiopsis borealis, +Thuia lobbii, Juniperus recurva, Taxas adpressa, fine plants; with +fine golden yews and equally fine examples of the various kinds of +variegated hollies, etc.</p> + +<p class="ctr"> +<a href="./images/15b.png"><img src="images/15b_th.png" width="474" height="400" alt="ODONTOGLOSSUM ROSSI MAJOR VAR. RUBESCENS, AT DRINKSTONE +PARK." title="" /></a><br />ODONTOGLOSSUM ROSSI MAJOR VAR. RUBESCENS, AT DRINKSTONE +PARK.</p> + + +<p>Particular attention is here paid to early spring flowers. Drinkstone +is also celebrated as a fruit growing establishment, more particularly +as regards the grape vine; the weight and quality of the crops of +grapes which are annually produced here are very remarkable.—<i>The +Gardeners' Chronicle.</i></p> + +<hr /> + + + + +<h2><a name="art06" id="art06"></a>ON THE CHANGES WHICH TAKE PLACE IN THE CONVERSION OF HAY INTO +ENSILAGE.</h2> + +<h3>By FREDK. JAS. LLOYD, F.C.S., Lecturer on Agriculture, King's +College.</h3> + + +<p>The recently published number of the <i>Royal Agricultural Society's +Journal</i> contains some information upon the subject of silage which +appears to me of considerable interest to those chemists who are at +present investigating the changes which take place in the conversion +of grass into silage. The data<a name="FNanchor_10" id="FNanchor_10"></a><a href="#Footnote_10"><sup>1</sup></a> are, so far as I know, unique, and +though the analytical work is not my own, yet it is that of an +agricultural chemist, Mr. A. Smetham, of Liverpool, whose work I know +from personal experience to be thoroughly careful and reliable. I have +therefore no hesitation in basing my remarks upon it.</p> + +<p>We have here for the first time an accurate account of the quantity of +grass put into a silo, of the quantity of silage taken out, and of the +exact composition both of the grass and resulting silage. I desire +merely to place myself in the position of, so to speak, a "chemical +accountant."</p> + +<p>The ensilage has been analyzed at three depths, or rather <a name="Page_7046" id="Page_7046"></a>in three +layers, the first being 1 foot, the second 1 ft. to 1 ft. 6 in., and +the third 1 ft. 6 in. to 2 ft. from the bottom of the silo. By +doubling the figures of the bottom layer analysis, adding these to the +second and third layer analysis, and dividing by 4, we obtain a fair +representation of the average composition of the silage taken +throughout the silo, for by so doing we obtain the average of the +analyses of each 6-inch layer of silage. The results of the analyses +are as follows, calculated on the dry matter. The moisture was +practically the same, being 70.48 per cent, in the grass and 72.97 in +the silage.</p> + + +<p class="ctr"><i>Composition of Grass and Silage (dried at 100°C.).</i></p> + +<div class="ctr"> +<table border="0" width="75%" summary=""> +<colgroup span="3"><col align="left" /><col align="right" span="2" /></colgroup> +<tr><td></td><th>Grass.</th><th>Ensilage.</th></tr> +<tr><td>Fat (ether extract)</td><td>2.80</td><td>5.38</td></tr> +<tr><td>Soluble albuminous compounds</td><td>3.06</td><td>5.98</td></tr> +<tr><td>Insoluble albuminous compounds</td><td>6.94</td><td>3.77</td></tr> +<tr><td>Mucilage, sugar, and extractives, etc.</td><td>11.65</td><td>4.98</td></tr> +<tr><td>Digestible fiber</td><td>36.24</td><td>33.37</td></tr> +<tr><td>Indigestible woody fiber</td><td>32.33</td><td>31.79</td></tr> +<tr><td></td><td>——</td><td>——</td></tr> +<tr><td></td><td>93.02</td><td>85.27</td></tr> +<tr><td>Soluble mineral matters</td><td>5.24</td><td>12.62</td></tr> +<tr><td>Insoluble mineral matters</td><td>1.74</td><td>2.11</td></tr> +<tr><td></td><td>——</td><td>——</td></tr> +<tr><td></td><td>100.00</td><td>100.00</td></tr> +</table></div> + +<p>The striking difference in the mineral matter of the grass and silage +I will merely draw attention to; it is not due to the salt added to +the silage. I may say, however, that other analysts and I myself have +found similar striking differences. For instance, Prof. Kinch <a name="FNanchor_11" id="FNanchor_11"></a><a href="#Footnote_11"><sup>2</sup></a> +found in grass 8.50 per cent. mineral matter, in silage 10.10 per +cent., which, as be points out, is equivalent, to a "loss of about 18 +per cent. of combustible constituents"—a loss which we have no proof +of having taken place. In Mr. Smetham's sample the loss would have to +be 50 per cent., which did not occur, and in fact is not possible. +What is the explanation?</p> + +<p>I am, however, considering now the organic constituents. Calculating +the percentages of these in the grass and silage, we obtain the +following figures:</p> + +<p class="ctr"><i>Percentage Composition of Organic Compounds.</i></p> + +<div class="ctr"> +<table border="0" summary="" width="75%"> +<colgroup span="4"><col align="left" /><col align="right" /><col align="center" /><col align="right" /> +</colgroup> +<tr><td></td><th>Grass.</th><td></td><th>Ensilage.</th></tr> +<tr><td>Fat (ether extract)</td><td>3.01</td><td></td><td>6.31</td></tr> +<tr><td>Soluble albuminous compounds</td><td>8.29</td> +<td rowspan="2" valign="middle"><span class="large">} 10.75 11.43 {</span></td> +<td>7.01</td></tr> +<tr><td>Insoluble albuminous compounds</td><td>7.46</td><td>4.42</td></tr> +<tr><td>Mucilage, sugar, and extractives</td><td>12.52</td><td></td><td>5.84</td></tr> +<tr><td>Digestible fiber</td><td>38.96</td><td></td><td>39.14</td></tr> +<tr><td>Indigestible woody fiber</td><td>34.76</td><td></td><td>37.28</td></tr> +<tr><td></td><td>———</td><td></td><td>———</td></tr> +<tr><td></td><td>100.00</td><td></td><td>100.00</td></tr> +</table></div> + +<p>The difference in the total nitrogen in the grass and silage is equal +to 0.68 per cent. of albuminoids. Practically it is a matter of +impossibility that the nitrogen could have increased in the silo, and +it will be a very safe premise upon which to base any further +calculations that the total amount of nitrogen in the silage was +identical with that in the grass. There may have been a loss, but +that is not yet proved. Arguing then upon the first hypothesis, it is +evident that 100 parts of the organic matters of silage represent more +than 100 parts of the organic matter of grass, and by the equation we +obtain 10.75:11.43 :: 100:106 approximately. If now we calculate the +composition of 106 parts organic matter of grass, it will represent +exactly the organic matter which has gone to form 100 parts of that +present in silage.</p> + +<p>The following table gives these results, and also the loss or gain in +the various constitutents arising from the conversion into silage:</p> + +<p class="ctr"><i>Organic Matter.</i></p> + + +<div class="ctr"> +<table border="0" width="75%" summary=""> +<colgroup span="4"><col align="left" /><col span="3" align="right" /></colgroup> +<tr><td></td><th>In 106 pts.<br />Grass.</th><th>In 100 pts.<br />Silage.</th><th>Loss or<br /> Gain.</th></tr> +<tr><td>Fat (ether extract)</td><td>3.19</td><td>6.31</td><td>+3.12</td></tr> +<tr><td>Soluble albuminous compounds</td><td>3.49</td><td>7.01</td><td>+3.52</td></tr> +<tr><td>Insoluble albuminous compounds</td><td>7.91</td><td>4.42</td><td>-3.49</td></tr> +<tr><td>Mucilage</td><td>13.27</td><td>5.84</td><td>-7.43</td></tr> +<tr><td>Digestible Fiber</td><td>41.30</td><td>39.14</td><td>-2.16</td></tr> +<tr><td>Indigestible woody fiber</td><td>36.84</td><td>37.28</td><td>+0.44</td></tr> +<tr><td></td><td>———</td><td>———</td></tr> +<tr><td></td><td>106.00</td><td>100.00</td></tr> +</table></div> + +<p>These calculations show, provided my reasoning be correct, that the +chief changes which take place are in the albuminous compounds, which +has already been pointed out by Professors Voelcker, Kinch, and +others; and in the starch, gum, mucilage, sugar, and those numerous +bodies termed extractives, which was to be expected. But they show +most conclusively that the "decrease in the amount of indigestible +fiber and increase in digestible" so much spoken of is, so far as our +present very imperfect methods of analyzing these compounds permit us +to judge, a myth; and I have not yet found any sufficient evidence to +support this statement. A loss, then, of 6 parts of organic matter out +of every 106 parts put into the silo has in this instance taken place, +due chiefly to the decomposition of starch, sugar, and mucilage, etc. +And as the grass contained 70 parts of water when put into the silo, +the total loss would only be 1.7 per cent. of the total weight. This +theoretical deduction was found by practical experience correct, for +Mr. Smith, agent to Lord Egerton, upon whose estate this silage was +made, in his report to Mr. Jenkins says the "actual weight out of the +silo corresponds exactly with the weight we put into the same."</p> + +<p>In my judgment these figures are of interest to the agricultural +chemist for many reasons. First, they will clear the ground for future +workers and eliminate from their researches what would have greatly +complicated them—changes in the cellulose bodies.</p> + +<p>Secondly, they are of interest because our present methods of +distinguishing between and estimating digestible and indigestible +fiber is most rough, and probably inaccurate, and may not in the least +represent the power of an animal—say a cow—to digest these various +substances; and most of us know that when a new method of analysis +becomes a necessity, a new method is generally discovered. Lastly, +they are of interest to the agriculturist, for they point out, I +believe for the first time, the exact amount of loss which grass—or +at least one sample—has undergone in conversion into silage, and also +that much of the nitrogenous matter is changed, and so far as we know +at present, lost its nutritive value. This, however, is only comparing +silage with grass. What is wanted is to compare silage with hay—both +made out of the same grass. Then, and then only, will it be possible +to sum up the relative advantages or disadvantages of the two methods +of preserving grass as food for cattle.—<i>Chem. News</i>.</p> + +<div class="note"><p><a name="Footnote_10" id="Footnote_10"></a><a href="#FNanchor_10">[1]</a></p> +<p><i>Royal Agricultural Society's Journal</i>, vol. xx., part +i., pp. 175 and 380.</p> + +<p><a name="Footnote_11" id="Footnote_11"></a><a href="#FNanchor_11">[2]</a></p> +<p><i>Journ. Chem. Society</i>, March, 1884, p. 124.</p></div> + +<hr /> + + +<h3>THE ILLUMINATING POWER OF ETHYLENE.</h3> + +<p>Dr. Percy Frankland has obtained results which may be thus briefly +summarized: (1.) That pure ethylene, when burnt at the rate of 5 cubic +feet per hour from a Referee's Argand burner, emits a light of 68.5 +standard candles. (2.) That the illuminating power of equal volumes of +mixtures of ethylene with either hydrogen carbonic oxide or +marsh-gas is less than that of pure ethylene. (3.) That when the +proportion of ethylene in such mixtures is above 63 per cent. the +illuminating power of the mixture is but slightly affected by the +nature of the diluent. When, on the other hand, the proportion of +ethylene in such mixtures is low, the illuminating power of the +mixture is considerably the highest when marsh-gas is the diluent, and +the lowest when the ethylene is mixed with carbonic oxide. (4.) That +if 5 cubic feet of ethylene be uniformly consumed irrespectively of +the composition of the mixture, the calculated illuminating power is +in every case equal to or actually greater than that of pure ethylene +until a certain degree of dilution is attained. This intrinsic +luminosity of ethylene remains almost constant when the latter is +diluted with carbonic oxide, until the ethylene forms only 40 per +cent. of the mixture, after which it rapidly diminishes to zero when +the ethylene forms only 20 per cent. of the mixture. When the ethylene +is diluted with hydrogen, its intrinsic luminosity rises to 81 candles +when the ethylene constitutes 30 per cent. of the mixture, after which +it rapidly falls to zero when the ethylene amounts to only 10 per +cent. In the case of mixtures of ethylene and marsh-gas, the intrinsic +luminosity of the former is augmented with increasing rapidity as the +proportion of marsh gas rises, the intrinsic luminosity of ethylene, +in a mixture containing 10 per cent. of the latter, being between 170 +and 180 candles.</p> + +<hr /> + + + + +<h2><a name="art25" id="art25"></a>DIFFRACTION PHENOMENA DURING TOTAL SOLAR ECLIPSES.<a name="FNanchor_12" id="FNanchor_12"></a><a href="#Footnote_12"><sup>1</sup></a></h2> + +<h3>By G.D. Hiscox.</h3> + + +<p>The reality of the sun's corona having been cast in doubt by a leading +observer of the last total eclipse, who, from the erratic display +observed in the spectroscope, has declared it a subjective phenomenon +of diffraction, has led me to an examination and inquiry as to the +bearing of an obscurely considered and heretofore only casually +observed phenomenon seen to take place during total solar eclipses. +This phenomenon, it seems to me, ought to account for, and will +possibly satisfy, the spectroscopic conditions observed just before, +during, and after totality; which has probably led to the epithet used +by some leading observers—"the fickle corona." The peculiar +phenomenon observed in the spectroscope, the flickering bands or lines +of the solar spectrum flashing upon and across the coronal spectrum, +has caused no little speculation among observers.</p> + +<p>The diffraction or interference bands projected by the passage of a +strong beam of light by a solid body, as discovered long since by +Grimaldi, and investigated later by Newton, Fresnel, and Fraunhofer, +are explained and illustrated in our text books; but the grand display +of this phenomenon in a total solar eclipse, where the sun is the +source of light and the moon the intercepting body, has as yet +received but little attention from observers, and is not mentioned to +my knowledge in our text books.</p> + +<p>In the instructions issued from the United States Naval Observatory +and the Signal Office at Washington for the observation of the eclipse +of July 29, 1878, attention was casually directed to this phenomenon, +and a few of the observers at Pike's Peak, Central City, Denver, and +other places have given lucid and interesting descriptions of the +flight of the diffraction bands as seen coursing over the face of the +earth at the speed of the moon's shadow, at the apparent enormous +velocity of thirty-three miles per minute, or fifty times the speed of +a fast railway train.</p> + +<p>From a known optical illusion derived from interference or fits of +perception, as illustrated in quick moving shadows, this great speed +was not realized to the eye, as the observed motion of these shadows +was apparently far less rapid than their reality.</p> + +<p>The ultra or diffraction bands outside of the shadow were distinctly +seen and described by Mr. J.E. Keeler at Central City, both before and +after totality. He estimates the shadow bands at 8 inches wide and 4 +feet apart.</p> + +<p>Professor E.S. Holden, also at Central City, estimated the dark bands +as about 3 feet apart, and variable.</p> + +<p>From estimates which he obtained from other observers of his party, +the distances between the bands varied from 6 to l― feet, but so +quickly did they pass that they baffled all attempts to count even the +number that passed in one second.</p> + +<p>He observed the time of continuance of their passage from west to east +as forty-eight seconds, which indicates a width of 33 miles of +diffraction bands stretching outward from the edge of the shadow to +the number of many thousands.</p> + +<p>Mr. G.W. Hill, at Denver, a little to the north of the central track +of the shadow, observed the infra or bands within the shadow, alluding +to the fact that they must be moving at the same rate as the shadow, +although their apparent motion was much slower, or like the shadows of +flying clouds. He attributes the discrepancy to optical illusion.</p> + +<p>At Virginia City the <i>colors</i> of the <i>ultra</i> bands were observed, and +estimated at five seconds' duration from the edge of the shadow, which +is equal to about 4 miles in width. These are known to be the +strongest color bands in the diffraction spectrum, which accounts for +their being generally observed.</p> + +<p>Mr. W.H. Bush, observing at Central City, in a communication to Prof. +Holden alludes to the brilliancy of the colors of these bands as seen +through small clouds floating near the sun's place during totality, +and of the rapid change of their rainbow colors as observed dashing +across the clouds with the rapidity of thought.</p> + +<p>All of these bands, both ultra and infra, as seen in optical +experiments, are colored in reverse order, being from violet to red +for each band outward and inward from the edge of the shadow.</p> + +<p>It is very probable that the velocity of the passage of all the bands +during a total eclipse very much modifies the distinctness of the +colors or possibly obliterates them by optically blending so as to +produce the dull white and black bands which occupied so large a +portion of this grand panorama.</p> + +<p>The phenomenon of these faint colored bands, with the observed light +and dark shadows, may be attributed to one or all of the following +causes:</p> + +<p>1. A change in the direction of a small portion of the sun's light +passing by the solid body of the moon, it being deflected outward by +repulsion or reflection from its surface, and other portions being +deflected inward after passing the body by mutual repulsion of its own +elements toward a <i>light vacuum</i> or space devoid of the element of +vibration.</p> + +<p>2. The colored spectral bands being the direct result of the property +of interference, or the want of correspondence of the wave lengths due +to divergence; the same phenomenon being also observed in convergent +light. This is practically illustrated in the hazy definition of the +reduced aperture of telescopes, and its peculiarities shown in the +spectral rings within and beyond the focus.</p> + +<p>3. Chromatic dispersion by our atmosphere, together with selective +absorption, also by our atmosphere and its vapors, have been suggested +as causes in this curious and complicated phenomena.</p> + +<p>In none of the reports descriptive of the phenomena of polarization of +the corona is there the slightest allusion to the influence that the +diffraction bands may possibly have in modifying or producing the +various conditions of polarization observed; although these +observations have been made and commented upon during the past +twenty-five years.</p> + +<p>Investigations now in progress of the modifying relation of the +phenomenon of diffraction in its effect upon not only the physical +aspect of the corona, but also in some strange spectroscopic anomalies +that have been observed near the sun at other times than during a +total solar eclipse, will, it is hoped, result in a fuller +interpretation of the physical nature of one of the grandest elements +of creation—<i>light</i>; let there be more of it.</p> + +<div class="note"><p><a name="Footnote_12" id="Footnote_12"></a><a href="#FNanchor_12">[1]</a></p> +<p>A paper read before the American Astronomical Society, +May 5, 1884.</p></div> + +<hr /> + + +<p>A CATALOGUE containing brief notices of many important scientific +papers heretofore published in the SUPPLEMENT, may be had gratis at +this office.</p> + +<hr /> + + +<h3>The</h3> +<h2>Scientific American Supplement.</h2> + +<h3>PUBLISHED WEEKLY.</h3> + +<p class="ctr">Terms of Subscription, $5 a Year.</p> + +<p>Sent by mail, postage prepaid, to subscribers in any part of the +United States or Canada. 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files differnew file mode 100644 index 0000000..e254365 --- /dev/null +++ b/15833-h/images/9b.png diff --git a/15833-h/images/title.png b/15833-h/images/title.png Binary files differnew file mode 100644 index 0000000..89d808f --- /dev/null +++ b/15833-h/images/title.png diff --git a/15833-h/images/title_th.png b/15833-h/images/title_th.png Binary files differnew file mode 100644 index 0000000..5080de4 --- /dev/null +++ b/15833-h/images/title_th.png diff --git a/15833.txt b/15833.txt new file mode 100644 index 0000000..6c3cfb3 --- /dev/null +++ b/15833.txt @@ -0,0 +1,5041 @@ +The Project Gutenberg EBook of Scientific American Supplement, No. 441, +June 14, 1884., by Various + +This eBook is for the use of anyone anywhere at no cost and with +almost no restrictions whatsoever. You may copy it, give it away or +re-use it under the terms of the Project Gutenberg License included +with this eBook or online at www.gutenberg.org + + +Title: Scientific American Supplement, No. 441, June 14, 1884. + +Author: Various + +Release Date: May 16, 2005 [EBook #15833] + +Language: English + +Character set encoding: ASCII + +*** START OF THIS PROJECT GUTENBERG EBOOK SCIENTIFIC AMERICAN *** + + + + +Produced by Juliet Sutherland and the Online Distributed +Proofreading Team at www.pgdp.net. + + + + + +[Illustration] + + + + +SCIENTIFIC AMERICAN SUPPLEMENT NO. 441 + + + + +NEW YORK, JUNE 14, 1884 + +Scientific American Supplement. Vol. XVII., No. 441. + +Scientific American established 1845 + +Scientific American Supplement, $5 a year. + +Scientific American and Supplement, $7 a year. + + * * * * * + + + + +TABLE OF CONTENTS. + + +I. CHEMISTRY AND METALLURGY.--On Electrolysis.--Precipitation + of lead, thallium, silver, bismuth, manganese, etc.--By H. + SCHUCHT + + The Electro-Chemical Equivalent of Silver + + Zircon.--How it can be rendered soluble.--By F. STOLBA + + A New Process for Making Wrought Iron Directly from the Ore. + --Comparison with other processes.--With descriptions and + engravings of the apparatus used + + Some Remarks on the Determination of Hardness in Water + + On the changes which Take Place in the Conversion of Hay + into Ensilage.--By F.J. Lloyd + +II. ENGINEERING AND MECHANICS.--Faure's Machine for + Decorticating Sugar Cane.--With full description + and 13 figures + + The Generation of Steam and the Thermodynamic Problems + Involved.--By WM. ANDERSON.--Apparatus used in the + experimental determination of the heat of combustion and + the laws which govern its development.--Ingredients of + fuel.--Potential energy of fuel.--With 7 figures and + several tables + + Planetary Wheel Trains.--Rotations of the wheels relatively + to the train arm.--By Prof. C.W. MACCORD + + The Pantanemone.--A New Windwheel.--1 engraving + + Relvas's New Life Boat.--With engraving + + Experiments with Double Barreled Guns and Rifles. + --Cause of the divergence of the charge.--4 figures + + Improved Ball Turning Machine.--1 figure + + Cooling Apparatus for Injection Water.--With engraving + + Corrugated Disk Pulleys.--1 engraving + +III. TECHNOLOGY.--A New Standard Light + + Dr. Feussner's New Polarizing Prism.--Points of difference + between the old and new prisms.--By P.R. SLEEMAN + + Density and Pressure of Detonating Gas + +IV. ELECTRICITY, LIGHT, ETC.--Early History of the Telegraph. + --Pyrsia, or the system of telegraphy among the Greeks. + --Communication by means of characters and the telescope. + --Introduction of the magnetic telegraph between Baltimore + and Washington + + The Kravogl Electro Motor and its Conversion Into a Dynamo + Electric Machine.--5 figures + + Bornhardt's Electric Machine for Blasting in Mines. + --15 figures + + Pritchett's Electric Fire Alarm.--1 figure + + A Standard Thermopile + + Telephonic Transmission without Receivers.--Some of the + apparatus exhibited at the annual meeting of the French + Society of Physics.--Telephonic transmission through a + chain of persons + + Diffraction Phenomena during Total Solar Eclipses.--By G.D. + Hiscox + +V. BOTANY AND HORTICULTURE.--Gum Diseases in Trees.-- + Cause and contagion of the same + + Drinkstone Park.--Trees and plants cultivated therein.-- + With 2 engravings + +VI. MEDICINE AND HYGIENE.--Miryachit.--A newly-discovered + disease of the nervous system, and its analogues.--By WM. A. + HAMMOND + +VII. MISCELLANEOUS.--Turkish Baths for Horses.--With + diagram. + + * * * * * + + + + +FAURE'S MACHINE FOR DECORTICATING SUGAR-CANE. + + +The object of the apparatus shown in the accompanying engraving is to +effect a separation of the tough epidermis of the sugar-cane from the +internal spongy pith which is to be pressed. Its function consists in +isolating and separating the cells from their cortex, and in putting +them in direct contact with the rollers or cylinders of the mill. +After their passage into the apparatus, which is naturally placed in a +line with the endless chain that carries them to the mill, the canes +arrive in less compact layers, pass through much narrower spaces, and +finally undergo a more efficient pressure, which is shown by an +abundant flow of juice. The first trials of the machine were made in +1879 at the Pointe Simon Works, at Martinique, with the small type +that was shown at the Paris Exhibition of 1878. These experiments, +which were applied to a work of 3,000 kilos of cane per hour, gave +entire satisfaction, and decided the owners of three of the colonial +works (Pointe Simon, Larcinty, and Marin) to adopt it for the season +of 1880. + +The apparatus is shown in longitudinal section in Fig. 1, and in plan +in Fig. 2. + +Fig. 3 gives a transverse section passing through the line 3-4, and +Fig. 4 an external view on the side whence the decorticated canes make +their exit from the apparatus. + +[Illustration: FAURE'S MACHINE FOR DECORTICATING SUGAR CANE.] + +The other figures relate to details that will be referred to further +along. + +_The Decorticating Cylinder._--The principal part of the apparatus is +a hollow drum, A, of cast iron, 430 mm. in internal diameter by 1.41 +m. in length, which is keyed at its two extremities to the shaft, a. +Externally, this drum (which is represented apart in transverse +section in Fig. 5) has the form of an octagonal prism with well +dressed projections between which are fixed the eight plates, C, that +constitute the decorticating cylinder. These plates, which are of +tempered cast iron, and one of which is shown in transverse section in +Fig. 7, when once in place form a cylindrical surface provided with 48 +helicoidal, dentate channels. The length of these plates is 470 mm. +There are three of them in the direction of the generatrices of the +cylinder, and this makes a total of 24. All are strengthened by ribs +(as shown in Fig. 8), and each is fixed by 4 bolts, _c_, 20mm. in +diameter. The pitch of the helices of each tooth is very elongated, +and reaches about 7.52 m. The depth of the toothing is 18 mm. + +_Frame and Endless Chain._--The cylinder thus constructed rotates with +a velocity of 50 revolutions per minute over a cylindrical vessel, B', +cast in a piece with the frame, B. This vessel is lined with two +series of tempered cast iron plates, D and D', called exit and +entrance plates, which rest thereon, through the intermedium of well +dressed pedicels, and which are held in place by six 20-millimeter +bolts. Their length is 708 mm. The entrance plates, D, are provided +with 6 spiral channels, whose pitch is equal to that of the channels +of the decorticating cylinder, C, and in the same direction. The depth +of the toothing is 10 mm. + +The exit plates, D', are provided with 7 spiral channels of the same +pitch and direction as those of the preceding, but the depth of which +increases from 2 to 10 mm. The axis of the decorticating cylinder does +not coincide with that of the vessel, B', so that the free interval +for the passage of the cane continues to diminish from the entrance to +the exit. + +The passage of the cane to the decorticator gives rise to a small +quantity of juice, which flows through two orifices, _b'_, into a sort +of cast iron trough, G, suspended beneath the vessel. The cane, which +is brought to the apparatus by an endless belt, empties in a conduit +formed of an inclined bottom, E, of plate iron, and two cast iron +sides provided with ribs. These sides rest upon the two ends of the +vessel, B', and are cross-braced by two flat bars, _e_, to which is +bolted the bottom, E. This conduit is prolonged beyond the +decorticating cylinder by an inclined chute, F, the bottom of which is +made of plate iron 7 mm. thick and the sides of the same material 9 +mm. thick. The hollow frame, B, whose general form is like that of a +saddle, carries the bearings, _b_, in which revolves the shaft, _a_. +One of these bearings is represented in detail in Figs. 9 and 10. It +will be seen that the cap is held by bolts with sunken heads, and that +the bearing on the bushes is through horizontal surfaces only. In a +piece with this frame are cast two similar brackets, B squared, which support +the axle, _h_, of the endless chain. To this axle, whose diameter is +100 mm., are keyed, toward the extremities, the pinions, H, to which +correspond the endless pitch chains, _i_. These latter are formed, as +may be seen in Figs. 11 and 12, of two series of links. The shorter of +these latter are only 100 mm. in length, while the longer are 210 mm., +and are hollowed out so as to receive the butts of the boards, I. The +chain thus formed passes over two pitch pinions, J, like the pinions, +H, that are mounted at the extremities of an axle, _j_, that revolves +in bearings, I', whose position with regard to the apparatus is +capable of being varied so as to slacken or tauten the chain, I. This +arrangement is shown in elevation in Fig. 13. + +_Transmission._--The driving shaft, _k_, revolves in a pillow block, +K, cast in a piece with the frame, B. It is usually actuated by a +special motor, and carries a fly-wheel (not shown in the figure for +want of space). It receives in addition a cog-wheel, L, which +transmits its motion to the decorticating cylinder through, the +intermedium of a large wooden-toothed gear wheel, L'. The shaft, _a_, +whose diameter is 228 mm., actuates in its turn, through the pinions, +M' and M, the pitch pinion, N, upon whose prolonged hub is keyed the +pinion, M. This latter is mounted loosely upon the intermediate axle, +_m_. Motion is transmitted to the driving shaft, _h_, of the endless +chain, I, by an ordinary pitch chain, through a gearing which is shown +in Fig. 12. The pitch pinion, N', is cast in a piece with a hollow +friction cone, N squared, which is mounted loosely upon the shaft, _h_, and +to which corresponds a second friction cone, O. This latter is +connected by a key to a socket, _o_, upon which it slides, and which +is itself keyed to the shaft, _h_. The hub of the cone, O, is +connected by a ring with a bronze nut, _p_, mounted at the threaded +end of the shaft, _h_, and carrying a hand-wheel, P. It is only +necessary to turn this latter in one direction or the other in order +to throw the two cones into or out of gear. + +If we allow that the motor has a velocity of 70 revolutions per +minute, the decorticating cylinder will run at the rate of 50, and the +sugar-cane will move forward at the rate of 12 meters per minute. + +This new machine is a very simple and powerful one. The decortication +is effected with wonderful rapidity, and the canes, opened throughout +their entire length and at all points of their circumference, leave +the apparatus in a state that allows of no doubt as to what the result +of the pressure will be that they have to undergo. There is no +tearing, no trituration, no loss of juice, but merely a simple +preparation for a rational pressure effected under most favorable +conditions. + +The apparatus, which is made in several sizes, has already received +numerous applications in Martinique, Trinidad, Cuba, Antigua, St. +Domingo, Peru, Australia, the Mauritius Islands, and +Brazil.--_Publication Industrielle._ + + * * * * * + + + + +MOVING A BRIDGE. + + +An interesting piece of engineering work has recently been +accomplished at Bristol, England, which consisted in the moving of a +foot-bridge 134 feet in length, bodily, down the river a considerable +distance. The pontoons by means of which the bridge was floated to its +new position consisted of four 80-ton barges, braced together so as to +form one solid structure 64 feet in width, and were placed in position +soon after the tide commenced to rise. At six o'clock A.M. the top of +the stages, which was 24 feet above the water, touched the under part +of the bridge, and in a quarter of an hour later both ends rose from +their foundations. When the tide had risen 4 ft. the stage and bridge +were floated to the new position, when at 8.30 the girders dropped on +to their beds. + + * * * * * + + + + +THE GENERATION OF STEAM, AND THE THERMODYNAMIC PROBLEMS +INVOLVED.[1] + + [Footnote 1: Lecture delivered at the Institution of Civil + Engineers, session 1883-84. For the illustrations we are indebted + to the courtesy of Mr. J. Forrest, the secretary.] + +By Mr. WILLIAM ANDERSON, M.I.C.E. + + +It will not be necessary to commence this lecture by explaining the +origin of fuel; it will be sufficient if I remind you that it is to +the action of the complex rays of the sun upon the foliage of plants +that we mainly owe our supply of combustibles. The tree trunks and +branches of our forests, as well as the subterranean deposits of coal +and naphtha, at one time formed portions of the atmosphere in the form +of carbonic acid gas; that gas was decomposed by the energy of the +solar rays, the carbon and the oxygen were placed in positions of +advantage with respect to each other--endowed with potential energy; +and it is my duty this evening to show how we can best make use of +these relations, and by once more combining the constituents of fuel +with the oxygen of the air, reverse the action which caused the growth +of the plants, that is to say, by destroying the plant reproduce the +heat and light which fostered it. The energy which can be set free by +this process cannot be greater than that derived originally from the +sun, and which, acting through the frail mechanism of green leaves, +tore asunder the strong bonds of chemical affinity wherein the carbon +and oxygen were hound, converting the former into the ligneous +portions of the plants and setting the latter free for other uses. The +power thus silently exerted is enormous; for every ton of carbon +separated in twelve hours necessitates an expenditure of energy +represented by at least 1,058 horse power, but the action is spread +over an enormous area of leaf surface, rendered necessary by the small +proportion of carbonic acid contained in the air, by measure only +1/2000 part, and hence the action is silent and imperceptible. It is +now conceded on all hands that what is termed heat is the energy of +molecular motion, and that this motion is convertible into various +kinds and obeys the general laws relating to motion. Two substances +brought within the range of chemical affinity unite with more or less +violence; the motion of transition of the particles is transformed, +wholly or in part, into a vibratory or rotary motion, either of the +particles themselves or the interatomic ether; and according to the +quality of the motions we are as a rule, besides other effects, made +conscious of heat or light, or of both. When these emanations come to +be examined they are found to be complex in the extreme, intimately +bound up together, and yet capable of being separated and analyzed. + +As soon as the law of definite chemical combination was firmly +established, the circumstance that changes of temperature accompanied +most chemical combinations was noticed, and chemists were not long in +suspecting that the amount of heat developed or absorbed by chemical +reaction should be as much a property of the substances entering into +combination as their atomic weights. Solid ground for this expectation +lies in the dynamic theory of heat. A body of water at a given height +is competent by its fall to produce a definite and invariable quantity +of heat or work, and in the same way two substances falling together +in chemical union acquire a definite amount of kinetic energy, which, +if not expended in the work of molecular changes, may also by suitable +arrangements be made to manifest a definite and invariable quantity of +heat. + +At the end of last century Lavoisier and Laplace, and after them, down +to our own time, Dulong, Desprez, Favre and Silbermann, Andrews, +Berthelot, Thomson, and others, devoted much time and labor to the +experimental determination of the heat of combustion and the laws +which governed its development. Messrs. Favre and Silbermann, in +particular, between the years 1845 and 1852, carried out a splendid +series of experiments by means of the apparatus partly represented in +Fig. 1 (opposite), which is a drawing one-third the natural size of +the calorimeter employed. It consisted essentially of a combustion +chamber formed of thin copper, gilt internally. The upper part of the +chamber was fitted with a cover through which the combustible could be +introduced, with a pipe for a gas jet, with a peep hole closed by +adiathermanous but transparent substances, alum and glass, and with a +branch leading to a thin copper coil surrounding the lower part of the +chamber and descending below it. The whole of this portion of the +apparatus was plunged into a thin copper vessel, silvered internally +and filled with water, which was kept thoroughly mixed by means of +agitators. This second vessel stood inside a third one, the sides and +bottom of which were covered with the skins of swans with the down on, +and the whole was immersed in a fourth vessel tilled with water, kept +at the average temperature of the laboratory. Suitable thermometers of +great delicacy were provided, and all manner of precautions were taken +to prevent loss of heat. + +[Illustration: THE GENERATION OF STEAM. Fig 1.] + +It is impossible not to admire the ingenuity and skill exhibited in +the details of the apparatus, in the various accessories for +generating and storing the gases used, and for absorbing and weighing +the products of combustion; but it is a matter of regret that the +experiments should have been carried out on so small a scale. For +example, the little cage which held the solid fuel tested was only 5/8 +inch diameter by barely 2 inches high, and held only 38 grains of +charcoal, the combustion occupying about sixteen minutes. Favre and +Silbermann adopted the plan of ascertaining the weight of the +substances consumed by calculation from the weight of the products of +combustion. Carbonic acid was absorbed by caustic potash, as also was +carbonic oxide, after having been oxidized to carbonic acid by heated +oxide of copper, and the vapor of water was absorbed by concentrated +sulphuric acid. The adoption of this system showed that it was in any +case necessary to analyze the products of combustion in order to +detect imperfect action. Thus, in the case of substances containing +carbon, carbonic oxide was always present to a variable extent with +the carbonic acid, and corrections were necessary in order to +determine the total heat due to the complete combination of the +substance with oxygen. Another advantage gained was that the +absorption of the products of combustion prevents any sensible +alteration in the volumes during the process, so that corrections for +the heat absorbed in the work of displacing the atmosphere were not +required. The experiments on various substances were repeated many +times. The mean results for those in which we are immediately +interested are given in Table I., next column. + +Comparison with later determinations have established their +substantial accuracy. The general conclusion arrived at is thus +stated: + +"As a rule there is an equality between the heat disengaged or +absorbed in the acts, respectively, of chemical combination or +decomposition of the same elements, so that the heat evolved during +the combination of two simple or com-pound substances is equal to the +heat absorbed at the time of their chemical segregation." + + TABLE I.--SUBSTANCES ENTERING INTO THE COMPOSITION OF FUEL. + + -----------------------+-------------+-----------+-------------------+ + | | Heat evolved in | + | Symbol and Atomic |the Combustion of | + | Weight. | 1 lb. of Fuel. | + +------------+------------+--------+----------+ + | | | |In Pounds | + | | | In | of Water | + | | |British |Evaporated| + | Before | After |Thermal | from and | + | Combustion | Combustion | Units. | at 212 deg.. | + +------------+------------+--------+----------+ + Hydrogen burned | H 1 | H2O 18 | 62,032 | 64.21 | + in oxygen. | | | | | + -----------------------+------------+------------+--------+----------+ + Carbon burned to | C 12 | CO 28 | 4,451 | 4.61 | + carbonic oxide. | | | | | + -----------------------+------------+------------+--------+----------+ + Carbon burned to | C 12 | CO2 44 | 14,544 | 15.06 | + carbonic acid. | | | | | + -----------------------+------------+------------+--------+----------+ + Carbonic oxide burned | CO 28 | CO2 44 | 4,326 | 4.48 | + to carbonic acid. | | | | | + -----------------------+------------+------------+--------+----------+ + Olefiant gas (ethylene)| C2H4 28 | 2CO2 124 | 21,343 | 22.09 | + burnt in oxygen. | | 2H2O | | | + -----------------------+------------+------------+--------+----------+ + Marsh gas (methane) | CH4 16 | 2CO2 80 | 23,513 | 24.34 | + burnt in oxygen. | | 2H2O | | | + -----------------------+------------+------------+--------+----------+ + +Composition of air-- + + by volume 0.788 N + 0.197 O + 0.001 CO2 + 0.014 H2O + ---------------------------------------------------- + by weight 0.771 N + 0.218 O + 0.009 CO2 + 0.017 H2O + +This law is, however, subject to some apparent exceptions. Carbon +burned in protoxide of nitrogen, or laughing gas, N_{2}O, produces +about 38 per cent. more heat than the same substance burned in pure +oxygen, notwithstanding that the work of decomposing the protoxide of +nitrogen has to be performed. In marsh gas, or methane, CH_{4}, again, +the energy of combustion is considerably less than that due to the +burning of its carbon and hydrogen separately. These exceptions +probably arise from the circumstance that the energy of chemical +action is absorbed to a greater or less degree in effecting molecular +changes, as, for example, the combustion of 1 pound of nitrogen to +form protoxide of nitrogen results in the absorption of 1,157 units of +heat. Berthelot states, as one of the fundamental principles of +thermochemistry, "that the quantity of heat evolved is the measure of +the sum of the chemical and physical work accomplished in the +reaction"; and such a law will no doubt account for the phenomena +above noted. The equivalent heat of combustion of the compounds we +have practically to deal with has been experimentally determined, and +therefore constitutes a secure basis on which to establish +calculations of the caloric value of fuel; and in doing so, with +respect to substances composed of carbon, hydrogen, and oxygen, it is +convenient to reduce the hydrogen to its heat-producing equivalent of +carbon. The heat of combustion of hydrogen being 62,032 units, that of +carbon 14,544 units, it follows that 4.265 times the weight of +hydrogen will represent an equivalent amount of carbon. With respect +to the oxygen, it is found that it exists in combination with the +hydrogen in the form of water, and, being combined already, abstracts +its combining equivalent of hydrogen from the efficient ingredients of +the fuel; and hence hydrogen, to the extent of 1/8 of the weight of +the oxygen, must be deducted. The general formula then becomes: + + Heat of combustion = 14,544 {C + 4.265 (H-(O/8))}, + +and water evaporated from and at 212 deg., taking 966 units as the heat +necessary to evaporate 1 pound of water, + + lb. evaporated = 15.06 {C + 4.265 (H-(O/8))}, + +carbon, hydrogen, and oxygen being taken at their weight per cent. in +the fuel. Strictly speaking, marsh gas should be separately +determined. It often happens that available energy is not in a form in +which it can be applied directly to our needs. The water flowing down +from the mountains in the neighborhood of the Alpine tunnels was +competent to provide the power necessary for boring through them, but +it was not in a form in which it could be directly applied. The +kinetic energy of the water had first to be changed into the potential +energy of air under pressure, then, in that form, by suitable +mechanism, it was used with signal success to disintegrate and +excavate the hard rock of the tunnels. The energy resulting from +combustion is also incapable of being directly transformed into useful +motive power; it must first be converted into potential force of steam +or air at high temperature and pressure, and then applied by means of +suitable heat engines to produce the motions we require. It is +probably to this circumstance that we must attribute the slowness of +the human race to take advantage of the energy of combustion. The +history of the steam engine hardly dates back 200 years, a very small +fraction of the centuries during which man has existed, even since +historic times. + +The apparatus by means of which the potential energy of fuel with +respect to oxygen is converted into the potential energy of steam, we +call a steam boiler; and although it has neither cylinder nor piston, +crank nor fly wheel, I claim for it that it is a veritable heat +engine, because it transmits the undulations and vibrations caused by +the energy of chemical combination in the fuel to the water in the +boiler; these motions expend themselves in overcoming the liquid +cohesion of the water and imparting to its molecules that vigor of +motion which converts them into the molecules of a gas which, +impinging on the surfaces which confine it and form the steam space, +declare their presence and energy in the shape of pressure and +temperature. A steam pumping engine, which furnishes water under high +pressure to raise loads by means of hydraulic cranes, is not more +truly a heat engine than a simple boiler, for the latter converts the +latent energy of fuel into the latent energy of steam, just as the +pumping engine converts the latent energy of steam into the latent +energy of the pumped-up accumulator or the hoisted weight. + +If I am justified in taking this view, then I am justified in applying +to my heat engine the general principles laid down in 1824 by Sadi +Carnot, namely, that the proportion of work which can be obtained out +of any substance working between two temperatures depends entirely and +solely upon the difference between the temperatures at the beginning +and end of the operation; that is to say, if T be the higher +temperature at the beginning, and _t_ the lower temperature at the end +of the action, then the maximum possible work to be got out of the +substance will be a function of (T-_t_). The greatest range of +temperature possible or conceivable is from the absolute temperature +of the substance at the commencement of the operation down to absolute +zero of temperature, and the fraction of this which can be utilized is +the ratio which the range of temperature through which the substance +is working bears to the absolute temperature at the commencement of +the action. If W = the greatest amount of effect to be expected, T and +_t_ the absolute temperatures, and H the total quantity of heat +(expressed in foot pounds or in water evaporated, as the case may be) +potential in the substance at the higher temperature, T, at the +beginning of the operation, then Carnot's law is expressed by the +equation: + + / T - t \ + W = H( ------- ) + \ T / + +I will illustrate this important doctrine in the manner which Carnot +himself suggested. + +[Illustration: THE GENERATION OF STEAM. Fig 2.] + +Fig. 2 represents a hillside rising from the sea. Some distance up +there is a lake, L, fed by streams coming down from a still higher +level. Lower down on the slope is a millpond, P, the tail race from +which falls into the sea. At the millpond is established a factory, +the turbine driving which is supplied with water by a pipe descending +from the lake, L. Datum is the mean sea level; the level of the lake +is T, and of the millpond _t_. Q is the weight of water falling +through the turbine per minute. The mean sea level is the lowest level +to which the water can possibly fall; hence its greatest potential +energy, that of its position in the lake, = QT = H. The water is +working between the absolute levels, T and _t_; hence, according to +Carnot, the maximum effect, W, to be expected is-- + + / T - t \ + W = H( ------- ) + \ T / + / T - t \ +but H = QT [therefore] W = Q T( ------- ) + \ T / + + W = Q (T - t), + +that is to say, the greatest amount of work which can be expected is +found by multiplying the weight of water into the clear fall, which +is, of course, self-evident. + +Now, how can the quantity of work to be got out of a given weight of +water be increased without in any way improving the efficiency of the +turbine? In two ways: + +1. By collecting the water higher up the mountain, and by that means +increasing T. + +2. By placing the turbine lower down, nearer the sea, and by that +means reducing _t_. + +Now, the sea level corresponds to the absolute zero of temperature, +and the heights T and _t_ to the maximum and minimum temperatures +between which the substance is working; therefore similarly, the way +to increase the efficiency of a heat engine, such as a boiler, is to +raise the temperature of the furnace to the utmost, and reduce the +heat of the smoke to the lowest possible point. It should be noted, in +addition, that it is immaterial what liquid there may be in the lake; +whether water, oil, mercury, or what not, the law will equally apply, +and so in a heat engine, the nature of the working substance, provided +that it does not change its physical state during a cycle, does not +affect the question of efficiency with which the heat being expended +is so utilized. To make this matter clearer, and give it a practical +bearing, I will give the symbols a numerical value, and for this +purpose I will, for the sake of simplicity, suppose that the fuel used +is pure carbon, such as coke or charcoal, the heat of combustion of +which is 14,544 units, that the specific heat of air, and of the +products of combustion at constant pressure, is 0.238, that only +sufficient air is passed through the fire to supply the quantity of +oxygen theoretically required for the combustion of the carbon, and +that the temperature of the air is at 60 deg. Fahrenheit = 520 deg. absolute. +The symbol T represents the absolute temperature of the furnace, a +value which is easily calculated in the following manner: 1 lb. of +carbon requires 2-2/3 lb. of oxygen to convert it into carbonic acid, +and this quantity is furnished by 12.2 lb. of air, the result being +13.2 lb. of gases, heated by 14,544 units of heat due to the energy of +combustion; therefore: + + 14,544 units + T = 520 deg. + ------------------ = 5,150 deg. absolute. + 13.2 lb. X 0.238 + +The lower temperature, _t_, we may take as that of the feed water, say +at 100 deg. or 560 deg. absolute, for by means of artificial draught and +sufficiently extending the heating surface, the temperature of the +smoke may be reduced to very nearly that of the feed water. Under such +circumstances the proportion of heat which can be realized is + + 5,150 deg. - 560 deg. + = --------------- = 0.891; + 5,150 deg. + +that is to say, under the extremely favorable if not impracticable +conditions assumed, there must be a loss of 11 per cent. Next, to give +a numerical value to the potential energy, H, to be derived from a +pound of carbon, calculating from absolute zero, the specific heat of +carbon being 0.25, and absolute temperature of air 520 deg.: + + Units. + 1 lb. of carbon X 0.25 X 520 = 130 + 12.2 of air X 0.238 X 520 = 1,485 + Heat of combustion = 14,544 + ------ + 16,159 + Deduct heat equivalent to work of \ + displacing atmosphere by products of } + combustion raised from 60 deg. to 100 deg., } 32 + or from 149.8 cubic feet to 161.3 } + cubic feet, / + ------ + Total units of heat available 16,127 + +Equal to 16.69 lb. of water evaporated from and at 212 deg.. Hence the +greatest possible evaporation from and at 212 deg. from a lb. of carbon-- + + 16,159 u. X 0.891 - 32 u. + W = --------------------------- = 14.87 lb. + 966 u. + +I will now take a definite case, and compare the potential energy of a +certain kind of fuel with the results actually obtained. For this +purpose the boiler of the eight-horse portable engine, which gained +the first prize at the Cardiff show of the Royal Agricultural Society +in 1872, will serve very well, because the trials, all the details of +which are set forth very fully in vol. ix. of the _Journal_ of the +Society, were carried out with great care and skill by Sir Frederick +Bramwell and the late Mr. Menelaus; indeed, the only fact left +undetermined was the temperature of the furnace, an omission due to +the want of a trustworthy pyrometer, a want which has not been +satisfied to this day.[2] + + [Footnote 2: In the fifty-second volume of the _Proceedings_ + (1887-78), page 154, will be found a remarkable experiment on the + evaporative power of a vertical boiler with internal circulating + pipes. The experiment was conducted by Sir Frederick Bramwell and + Dr. Russell, and is remarkable in this respect, that the quantity + of air admitted to the fuel, the loss by convection and + radiation, and the composition of the smoke were determined. The + facts observed were as follows: + + Steam pressure 53 lb................................... = 300.6 deg. F. + lb. + Fuel--Water in coke and wood........................... 26.08 + Ash.............................................. 10.53 + Hydrogen, oxygen, nitrogen, and sulphur.......... 7.18 + ------ + Total non-combustible..................... 43.79 + Carbon, being useful combustible................. 194.46 + ------ + Total fuel................................ 238.25 + + Air per pound of carbon................................ 17-1/8 lb. + Time of experiment..................................... 4 h. 12 min. + Water evaporated from 60 deg. into steam at 53 lb. pressure 1,620 lb. + Heat lost by radiation and convection.................. 70,430 units. + Mean temperature of chimney............................ 700 deg. F. + " " " air................................ 70 deg. F. + + No combustible gas was found in the chimney. + + I will apply Carnot's doctrine to this case. + + Potential energy of the fuel with respect to absolute zero: + Units. + 239.25 lb. x 530 deg. abs. x 0.238 ...................... = 30,053 + 194.46 lb. x 17-1/8 x 530 deg. x 0.238, + the weight and heat of air....................... 420,660 + 194.46 x 14,544 units heat of combustion of carbon... 2,828,200 + --------- + Total energy 3,278,813 + Heat absorbed in evaporating 26.08 lb. of water + in fuel............................................ -29,888 + --------- + Available energy.......................... 3,248,425 + + Temperature of furnace-- + + The whole of the fuel was heated up, but the heat absorbed in the + evaporation of the water lowered the temperature of the furnace, + and must be deducted from the heat of combustion. + + Units. + Heat of combustion................................... 2,828,200 + " " evaporation of 26.08 lb. water............... -29,888 + --------- + Available heat of combustion.............. 2,798,312 + + Dividing by 238.25 lb. gives the heat per 1 lb. + of fuel used................................... = 11,745 units. + And temperature of furnace: + 11,745 units/(18.125 lb. x 0.238) + 530 deg.......... = 3,253 deg. + Temperature of chimney 700 deg. + 460 deg................ = 1,160 deg. + Maximum duty (3,253 deg. - 1,160 deg.)/3,253 deg............. = 0.643 deg. + + Work of displacing atmosphere by smoke at 700 deg.: + Cubic feet. + Volumes of gases at 70 deg......................... = 228.3 + " " " " 700 deg......................... = 499.8 + ----- + Increase of volume.................... 271.5 + + Units. + Work done= + (194.46 lb. x 271.5 cub. ft. x 144 sq. in. x 15 lb.) + /722 units ..................................... = 147,720 + Maximum amount of work to be expected = + 3,248,425 x 0.643.............................. = 2,101,700 + Deduct work of displacing atmosphere............. = 147,720 + --------- + Available work........................ 1,953,980 + + Actual work done: + Units. + 1,620 lb. of water raised from 60 deg. and turned + into steam at 53 lb..... ...................... = 1,855,900 + Loss by radiation and convection................. 70,430 + 10-1/2 lb. ashes left, say at 500 deg................ 1,129 + --------- + Total work actually done.............. 1,927,459 + Unaccounted for.................................. 26,521 + --------- + Calculated available work........................ 1,953,980 + + The unaccounted-for work, therefore, amounts to only 11/2 per cent. + of the calculated available work. + + Sir Frederick Bramwell ingeniously arranged his data in the form + of a balance sheet, and showed 253,979 units unaccounted for; but + if from this we deduct the work lost in displacing the air, the + unaccounted-for heat falls to less than 4 per cent. of the total + heat of combustion. These results show how extremely accurate the + observations must have been, and that the loss mainly arises from + convection and radiation from the boiler.] + +The data necessary for our purpose are: + +Steam pressure 80 lb. temperature 324 deg. = 784 deg. absolute. +Mean temperature of smoke 389 deg. = 849 deg. " +Water evaporated per 1 lb of coal, from and at 212 deg. 11.83 lb. +Temperature of the air 60 deg. = 520 deg. absolute. + " of feed water 209 deg. = 669 deg. " +Heating surface 220 square feet. +Grate surface 3.29 feet. +Coal burnt per hour 41 lb. + +The fuel used was a smokeless Welsh coal, from the Llangennech +colleries. It was analyzed by Mr. Snelus, of the Dowlais Ironworks, +and in Table II. are exhibited the details of its composition, and the +weight and volume of air required for its combustion. The total heat +of combustion in 1 lb of water evaporated: + + = 15.06 x (0.8497 + 4.265 x (0.426 - 0.035/8)) + = 15.24 lb. of water from and at 212 deg. + = 14,727 units of heat. + + TABLE II.--PROPERTIES OF LLANGENNECH COAL. + + ---------------------+----------+------------+---------------------+ + | | | | + | | | Products of | + | | Oxygen | Combustion at 32 deg. F.| + | Analyses | required +--------+------------+ + | of 1 lb. | for | | | + | of Coal. | Combustion.| Cubic | Volume | + | | Pounds. | feet. | per cent. | + ---------------------+----------+------------+--------+------------+ + Carbon........... | 0.8497 | 2.266 | 25.3 | 11.1 | + Hydrogen......... | 0.0426 | 0.309 | 7.6 | 3.4 | + Oxygen........... | 0.0350 | --- | --- | --- | + Sulphur.......... | 0.0042 | --- | --- | _ --- | + Nitrogen......... | 0.1045 | --- | 0.18 | | | + Ash.............. | 0.0540 | --- | --- | | | + +----------+------------+ | | 85.5 | + | | | | | | + Total........... | 1.0000 | 2.572 | --- | | | + 9-1/3.lb nitrogen | --- | --- | 118.9 | | | + 6 lb. excess of air. | --- | --- | 71.4 | _| | + +----------+------------+--------+------------+ + Total cubic feet of | | | | | + products per 1 lb. | | | | | + of coal........... | -- | -- | 226.4 | 100.0 | + ---------------------+----------+------------+--------+------------+ + +The temperature of the furnace not having been determined, we must +calculate it on the supposition, which will be justified later on, +that 50 per cent more air was admitted than was theoretically +necessary to supply the oxygen required for perfect combustion. This +would make 18 lb. of air per 1 lb. of coal; consequently 19 lb. of +gases would be heated by 14,727 units of heat. Hence: + + 14,727 u. + T = ---------------- = 3,257 deg. + 19 lb. x 0.238 + +above the temperatures of the air, or 3,777 deg. absolute. The temperature +of the smoke, _t_, was 849 deg. absolute; hence the maximum duty would be + + 3,777 deg. - 849 deg. + --------------- = 0.7752. + 3,777 deg. + +The specific heat of coal is very nearly that of gases at constant +pressure, and may, without sensible error, be taken as such. The +potential energy of 1 lb. of coal, therefore, with reference to the +oxygen with which it will combine, and calculated from absolute zero, +is: + + Units. +19 lb. of coal and air at the temperature + of the air contained 19 lb. x 520 deg. x 0.238 2,350 +Heat of combustion 14,727 + ------- + 17,078 +Deduct heat expended in displacing atmosphere 151 cubic feet - 422 + ------ + Total potential energy 16,656 + +Hence work to be expected from the boiler: + + / 3,777 deg. - 849 deg. \ + = 17,078 units X ( --------------- ) - 422 units + \ 3,777 deg. / + ---------------------------------------------- = 13.27 lb. + 966 units + +of water evaporated from and at 212 deg., corresponding to 12,819 units. +The actual result obtained was 11.83 lb.; hence the efficiency of this +boiler was + + 11.83 + ------- = 0.892. + 13.27 + +I have already claimed for a boiler that it is a veritable heat +engine, and I have ventured to construct an indicator diagram to +illustrate its working. The rate of transfer of heat from the furnace +to the water in the boiler, at any given point, is some way +proportional to the difference of temperature, and the quantity of +heat in the gases is proportional to their temperatures. Draw a base +line representing -460 deg. Fahr., the absolute zero of temperature. At +one end erect an ordinate, upon which set off T = 3,777 deg., the +temperature of the furnace. At 849 deg. = _t_, on the scale of +temperature, draw a line parallel to the base, and mark on it a length +proportional to the heating surface of the boiler; join T by a +diagonal with the extremity of this line, and drop a perpendicular on +to the zero line. The temperature of the water in the boiler being +uniform, the ordinates bounded by the sloping line, and by the line, +_t_, will at any point be approximately proportional to the rate of +transmission of heat, and the shaded area above _t_ will be +proportional to the quantity of heat imparted to the water. Join T by +another diagonal with extremity of the heating surface on the zero +line, then the larger triangle, standing on the zero line, will +represent the whole of the heat of combustion, and the ratio of the +two triangles will be as the lengths of their respective bases, that +is, as (T - _t_) / T, which is the expression we have already used. The +heating surface was 220 square feet, and it was competent to transmit +the energy developed by 41 lb. of coal consumed per hour = 12,819 u. x +41 u. = 525,572 units, equal to an average of 2,389 units per square +foot per hour; this value will correspond to the mean pressure in an +ordinary diagram, for it is a measure of the energy with which +molecular motion is transferred from the heated gases to the +boiler-plate, and so to the water. The mean rate of transmission, +multiplied by the area of heating surface, gives the area of the +shaded portion of the figure, which is the total work which should +have been done, that is to say, the work of evaporating 544 lb. of +water per hour. The actual work done, however, was only 485 lb. To +give the speculations we have indulged in a practical turn, it will be +necessary to examine in detail the terms of Carnot's formula. Carnot +labored under great disadvantages. He adhered to the emission theory +of heat; he was unacquainted with its dynamic equivalent; he did not +know the reason of the difference between the specific heat of air at +constant pressure and at constant volume, the idea of an absolute zero +of temperature had not been broached; but the genius of the man, while +it made him lament the want of knowledge which he felt must be +attainable, also enabled him to penetrate the gloom by which he was +surrounded, and enunciate propositions respecting the theory of heat +engines, which the knowledge we now possess enables us to admit as +true. His propositions are: + +1. The motive power of heat is independent of the agents employed to +develop it, and its quantity is determined solely by the temperature +of the bodies between which the final transfer of caloric takes place. + +2. The temperature of the agent must in the first instance be raised +to the highest degree possible in order to obtain a great fall of +caloric, and as a consequence a large production of motive power. + +3. For the same reason the cooling of the agent must be carried to as +low a degree as possible. + +4. Matters must be so arranged that the passage of the elastic agent +from the higher to the lower temperature must be due to an increase of +volume, that is to say, the cooling of the agent must be caused by its +rarefaction. + +This last proposition indicates the defective information which Carnot +possessed. He knew that expansion of the elastic agent was accompanied +by a fall of temperature, but he did not know that that fall was due +to the conversion of heat into work. We should state this clause more +correctly by saying that "the cooling of the agent must be caused by +the external work it performs." In accordance with these propositions, +it is immaterial what the heated gases or vapors in the furnace of a +boiler may be, provided that they cool by doing external work and, in +passing over the boiler surfaces, impart their heat energy to the +water. The temperature of the furnace, it follows, must be kept as +high as possible. The process of combustion is usually complex. First, +in the case of coal, close to the fire-bars complete combustion of the +red hot carbon takes place, and the heat so developed distills the +volatile hydrocarbons and moisture in the upper layers of the fuel. +The inflammable gases ignite on or near the surface of the fuel, if +there be a sufficient supply of air, and burn with a bright flame for +a considerable distance around the boiler. If the layer of fuel be +thin, the carbonic acid formed in the first instance passes through +the fuel and mixes with the other gases. If, however, the layer of +fuel be thick, and the supply of air through the bars insufficient, +the carbonic acid is decomposed by the red hot coke, and twice the +volume of carbonic oxide is produced, and this, making its way through +the fuel, burns with a pale blue flame on the surface, the result, as +far as evolution of heat is concerned, being the same as if the +intermediate decomposition of carbonic acid had not taken place. This +property of coal has been taken advantage of by the late Sir W. +Siemens in his gas producer, where the supply of air is purposely +limited, in order that neither the hydrocarbons separated by +distillation, nor the carbonic oxide formed in the thick layer of +fuel, may be consumed in the producer, but remain in the form of crude +gas, to be utilized in his regenerative furnaces. + +[Illustration: THE GENERATION OF STEAM. Fig 3.] + +[Illustration: THE GENERATION OF STEAM. Fig 4.] + +[Illustration: THE GENERATION OF STEAM. Fig 5.] + +[Illustration: THE GENERATION OF STEAM. Fig 6.] + +[Illustration: THE GENERATION OF STEAM. Fig 7.] + +_(To be continued.)_ + + * * * * * + +[Continued from SUPPLEMENT No. 437, page 6970.] + + + + +PLANETARY WHEEL-TRAINS. + +By Prof. C.W. MACCORD, Sc.D. + + +II. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 14] + +It has already been shown that the rotations of all the wheels of a +planetary train, relatively to the train-arm, are the same when the +arm is in motion as they would be if it were fixed. Now, in Fig. 14, +let A be the first and F the last wheel of an _incomplete_ train, that +is, one having but one sun-wheel. As before, let these be so connected +by intermediate gearing that, when T is stationary, a rotation of A +through _m_ degrees shall drive F through _n_ degrees: and also as +before, let T in the same time move through _a_ degrees. Then, if _m'_ +represent the total motion of A, we have again, + + m' = m + a, or m = m' - a. + +This is, clearly, the motion of A relatively to the fixed frame of the +machine; and is measured from a fixed vertical line through the +center of A. Now, if we wish to express the total motion of F +relatively to the same fixed frame, we must measure it from a vertical +line through the center of F, wherever that maybe; which gives in this +case: + + n' = n + a, or n = n' - a. + +but with respect to the train-arm when at rest, we have: + + ang. vel. A n + ------------ = ---, whence again + ang. vel. F m + + n' - a n + ------ = --- . + m' - a m + +This is the manner in which the equation is deduced by Prof. Willis, +who expressly states that it applies whether the last wheel F is or is +not concentric with the first wheel A, and also that the train may be +composed of any combinations which transmit rotation with both a +constant velocity ratio and a constant directional relation. He +designates the quantities _m'_, _n'_, _absolute revolutions_, as +distinguished from the _relative revolutions_ (that is, revolutions +relatively to the train-arm), indicated by the quantities _m_, _n_: +adding, "Hence it appears that the absolute revolutions of the wheels +of epicyclic trains are equal to the sum of their relative revolutions +to the arm, and of the arm itself, when they take place in the same +direction, and equal to the difference of these revolutions when in +the opposite direction." + +In this deduction of the formula, as in that of Prof. Rankine, all the +motions are supposed to have the same direction, corresponding to that +of the hands of the clock; and in its application to any given train, +the signs of the terms must be changed in case of any contrary motion, +as explained in the preceding article. + +And both the deduction and the application, in reference to these +incomplete trains in which the last wheel is carried by the +train-arm, clearly involve and depend upon the resolving of a motion +of revolution into the components of a circular translation and a +rotation, in the manner previously discussed. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 15] + +To illustrate: Take the simple case of two equal wheels, Fig. 15, of +which the central one A is fixed. Supposing first A for the moment +released and the arm to be fixed, we see that the two wheels will turn +in opposite directions with equal velocities, which gives _n_/_m_ = -1; +but when A is fixed and T revolves, we have _m'_ = 0, whence in the +general formula + + n' - a + ------ = -1, or n' = 2 a; + -a + +which means, being interpreted, that F makes two rotations about its +axis during one revolution of T, and in the same direction. Again, let +A and F be equal in the 3-wheel train, Fig. 16, the former being fixed +as before. In this case we have: + + n + --- = 1, m' = 0, which gives + m + + n' - a + ------- = 1, [therefore] n' = 0; + -a + +that is to say, the wheel F, which now evidently has a motion of +circular translation, does not rotate at all about its axis during the +revolution of the train-arm. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 16] + +All this is perfectly consistent, clearly, with the hypothesis that +the motion of circular translation is a simple one, and the motion of +revolution about a fixed axis is a compound one. + +Whether the hypothesis was made to substantiate the formula, or the +formula constructed to suit the hypothesis, is not a matter of +consequence. In either case, no difficulty will arise so long as the +equation is applied only to cases in which, as in those here +mentioned, that motion of revolution _can_ be resolved into those +components. + +When the definition of an epicyclic train is restricted as it is by +Prof. Rankine, the consideration of the hypothesis in question is +entirely eliminated, and whether it be accepted or rejected, the whole +matter is reduced to merely adding the motion of the train-arm to the +rotation of each sun-wheel. + +But in attempting to apply this formula in analyzing the action of an +incomplete train, we are required to add this motion of the train-arm, +not only to that of a sun-wheel, but to that of a planet-wheel. This +is evidently possible in the examples shown in Figs. 15 and 16, +because the motions to be added are in all respects similar: the +trains are composed of spur-wheels, and the motions, whether of +revolution, translation, or rotation, _take place in parallel planes +perpendicular to parallel axes_. This condition, which we have +emphasized, be it observed, must hold true with regard to the motions +of the first and last wheels and the train-arm, in order to make this +addition possible. It is not essential that spur-wheels should be used +exclusively or even at all; for instance, in Fig. 16, A and F may be +made bevel or screw-wheels, without affecting the action or the +analysis; but the train-arm in all cases revolves around the central +axis of the system, that is, about the axis of A, and to this the axis +of F _must_ be parallel, in order to render the deduction of the +formula, as made by Prof. Willis, and also by Prof. Goodeve, correct, +or even possible. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 17] + +This will be seen by an examination of Fig. 17; in which A and B are +two equal spur-wheels, E and F two equal bevel wheels, B and E being +secured to the same shaft, and A being fixed to the frame H. As the +arm T goes round, B will also turn in its bearings in the same +direction: let this direction be that of the clock, when the apparatus +is viewed from above, then the motion of F will also have the same +direction, when viewed from the central vertical axis, as shown at F': +and let these directions be considered as positive. It is perfectly +clear that F will turn in its bearings, in the direction indicated, at +a rate precisely equal to that of the train-arm. Let P be a pointer +carried by F, and R a dial fixed to T; and let the pointer be vertical +when OO is the plane containing the axes of A, B, and E. Then, when F +has gone through any angle a measured from OO, the pointer will have +turned from its original vertical position through an equal angle, as +shown also at F'. + +Now, there is no conceivable sense in which the motion of T can be +said to be added to the rotation of F about its axis, and the +expression "absolute revolution," as applied to the motion of the last +wheel in this train, is absolutely meaningless. + +Nevertheless, Prof. Goodeve states (Elements of Mechanism, p. 165) +that "We may of course apply the general formula in the case of bevel +wheels just as in that of spur wheels." Let us try the experiment; +when the train-arm is stationary, and A released and turned to the +right, F turns to the left at the same rate, whence: + + n + --- = -1; also m' = 0 when A is fixed, + m + +and the equation becomes + + n' - a + ------ = -1, [therefore] n' = 2a: + - a + +or in other words F turns _twice_ on its axis during one revolution of +T: a result too palpably absurd to require any comment. We have seen +that this identical result was obtained in the case of Fig. 15, and it +would, of course, be the same were the formula applied to Figs. 5 and +6; whereas it has never, so far as we are aware, been pretended that a +miter or a bevel wheel will make more than one rotation about its axis +in rolling once around an equal fixed one. + +Again, if the formula be general, it should apply equally well to a +train of screw wheels: let us take, for example, the single pair shown +in Fig. 8, of which, when T is fixed, the velocity ratio is unity. The +directional relation, however, depends upon the direction in which the +wheels are twisted: so that in applying the formula, we shall have +_n/m_ = +1, if the helices of both wheels are right handed, and +_n_/_m_ = -1, if they are both left handed. Thus the formula leads to +the surprising conclusion, that when A is fixed and T revolves, the +planet-wheel B will revolve about its axis twice as fast as T moves, +in one case, while in the other it will not revolve at all. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 18] + +A favorite illustration of the peculiarities of epicyclic mechanism, +introduced both by Prof. Willis and Prof. Goodeve, is found in the +contrivance known as Ferguson's Mechanical Paradox, shown in Fig. 18. +This consists of a fixed sun-wheel A, engaging with a planet-wheel B +of the same diameter. Upon the shaft of B are secured the three thin +wheels E, G, I, each having 20 teeth, and in gear with the three +others F, H, K, which turn freely upon a stud fixed in the train-arm, +and have respectively 19, 20, and 21 teeth. In applying the general +formula, we have the following results: + + n 20 n' - a 1 + For the wheel F, --- = ---- = ---------, [therefore] n' = - ---- a. + m 19 -a 19 + + n n' - a + " " " H, --- = 1 = --------, [therefore] n' = 0. + m -a + + n 20 n' - a 1 + " " " K, --- = ---- = ---------, [therefore] n' = + ---- a. + m 21 -a 21 + +The paradoxical appearance, then, consists in this, that although the +drivers of the three last wheels each have the same number of teeth, +yet the central one, H, having a motion of circular translation, +remains always parallel to itself, and relatively to it the upper one +seems to turn in the same direction as the train-arm, and the lower in +the contrary direction. And the appearance is accepted, too, as a +reality; being explained, agreeably to the analysis just given, by +saying that H has no absolute rotation about its axis, while the other +wheels have; that of F being positive and that of K negative. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 18] + +The Mechanical Paradox, it is clear, may be regarded as composed of +three separate trains, each of which is precisely like that of Fig. +16: and that, again, differs from the one of Fig. 15 only in the +addition of a third wheel. Now, we submit that the train shown in Fig. +17 is mechanically equivalent to that of Fig. 15; the velocity ratio +and the directional relation being the same in both. And if in Fig. 17 +we remove the index P, and fix upon its shaft three wheels like E, G, +and I of Fig. 18, we shall have a combination mechanically equivalent +to Ferguson's Paradox, the three last wheels rotating in vertical +planes about horizontal axes. The relative motions of those three +wheels will be the same, obviously, as in Fig. 18; and according to +the formula their absolute motions are the same, and we are invited to +perceive that the central one does not rotate at all about its axis. + +But it _does_ rotate, nevertheless; and this unquestioned fact is of +itself enough to show that there is something wrong with the formula +as applied to trains like those in question. What that something is, +we think, has been made clear by what precedes; since it is impossible +in any sense to add together motions which are unlike, it will be seen +that in order to obtain an intelligible result in cases like these, +the equation must be of the form _n'_/(_m'_ - _a_) = _n_/_m_. We shall +then have: + + n 20 n' 20 + For the wheel F, --- = ---- = ----, [therefore] n' = - ---- a; + m 19 -a 19 + + n n' + For the wheel H, --- = 1 = ----, [therefore] n' = -a; + m -a + + n 20 n' 20 + For the wheel K, --- = ---- = ----, [therefore] n' = - ---- a, + m 21 -a 21 + +which corresponds with the actual state of things; all three wheels +rotate in the same direction, the central one at the same rate as the +train arm, one a little more rapidly and the third a little more +slowly. + +It is, then, absolutely necessary to make this modification in the +general formula, in order to apply it in determining the rotations of +any wheel of an epicyclic train whose axis is not parallel to that of +the sun-wheels. And in this modified form it applies equally well to +the original arrangement of Ferguson's paradox, if we abandon the +artificial distinction between "absolute" and "relative" rotations of +the planet-wheels, and regard a spur-wheel, like any other, as +rotating on its axis when it turns in its bearings; the action of the +device shown in Fig. 18 being thus explained by saying that the wheel +H turns once backward during each forward revolution of the train-arm, +while F turns a little more and K a little less than once, in the same +direction. In this way the classification and analysis of these +combinations are made more simple and consistent, and the +incongruities above pointed out are avoided; since, without regard to +the kind of gearing employed or the relative positions of the axes, we +have the two equations: + + n' - a n + I. -------- = ---, for all complete trains; + m' - a m + + n' n + II. -------- = ---, for all incomplete trains. + m' - a m + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 19] + +As another example of the difference in the application of these +formulae, let us take Watt's sun and planet wheels, Fig. 19. This +device, as is well known, was employed by the illustrious inventor as +a substitute for the crank, which some one had succeeded in patenting. +It consists merely of two wheels A and F connected by the link T; A +being keyed on the shaft of the engine and F being rigidly secured to +the connecting-rod. Suppose the rod to be of infinite length, so as to +remain always parallel to itself, and the two wheels to be of equal +size. + +Then, according to Prof. Willis' analysis, we shall have-- + + n' - a n -s + -------- = --- = -1, n' = 0, [therefore] -------- = -1, whence + m' - a m m' - a + + -a = a - m', or m = 2a. + +The other view of the question is, that F turns once backward in its +bearings during each forward revolution of T; whence in Eq. 2 we +have-- + + n' n + -------- = --- = -1, n' = -a, + m' - a m + + -a + [therefore] -------- -1, which gives -a = a - m', or m' = 2a, + m' - a + +as before. + +It is next to be remarked, that the errors which arise from applying +Eq. I. to incomplete trains may in some cases counterbalance and +neutralize each other, so that the final result is correct. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 20] + +For example, take the combination shown in Fig. 20. This consists of a +train-arm T revolving about the vertical axis OO of the fixed wheel A, +which is equal in diameter to F, which receives its motion by the +intervention of one idle wheel carried by a stud S fixed in the arm. +The second train-arm T' is fixed to the shaft of F and turns with it; +A' is secured to the arm T, and F' is actuated by A' also through a +single idler carried by T'. + +We have here a compound train, consisting of two simple planetary +trains, A--F and A'--F'; and its action is to be determined by +considering them separately. First suppose T' to be removed and find +the motion of F; next suppose F to be removed and T fixed, and find +the rotation of F'; and finally combine these results, noting that the +motion of T' is the same as that of F, and the motion of A' the same +as that of T. + +Then, according to the analysis of Prof. Willis, we shall have +(substituting the symbol _t_ for _a_ in the equation of the second +train, in order to avoid confusion): + + n n' - a + 1. Train A--F. --- = 1 = --------; m' = 0, + m m' - a + + n' - a + whence -------- = 1, n' = 0, = rot. of F. + a + + n n' - t + 2. Train A'--F'. --- = 1 = --------; m' = 0, + m m' - t + + n' - t + whence again -------- = 1, t = 0, = rot. of F'. + -t + +Of these results, the first is explicable as being the _absolute_ +rotation of F, but the second is not; and it will be readily seen that +the former would have been equally absurd, had the axis LL been +inclined instead of vertical. But in either case we should find the +errors neutralized upon combining the two, for according to the theory +now under consideration, the wheel A', being fixed to T, turns once +upon its axis each time that train arm revolves, and in the same +direction; and the revolutions of T' equal the rotations of F, whence +finally in train A'--F' we have: + + n n' - t + 3. --- = 1 = --------; in which t = 0, m' = a, + m m' - t + + n' - 0 +which gives --------- = 1, or n' = a. + a - 0 + +This is, unquestionably, correct; and indeed it is quite obvious that +the effect upon F' is the same, whether we say that during a +revolution of T the wheel A' turns once forward and T' not at all, or +adopt the other view and assert that T' turns once backward and A' not +at all. But the latter view has the advantage of giving concordant +results when the trains are considered separately, and that without +regard to the relative positions of the axes or the kind of gearing +employed. Analyzing the action upon this hypothesis, we have: + + In train A--F: + + n n' n' + --- = 1 = --------; m' = 0, [therefore] ---- = 1, or n' = -a; + m m' - a -a + + In train A'--F': + + n' n' n' + --- = 1 = --------; m' = 0, [therefore] ---- = 1, or n' = -t; + m m' - t -t + +In combining, we have in the latter train m' = 0, t = -a, whence + + n n' n' + --- = 1 = -------- gives ---- = 1, or n' = a, as before. + m m' - t +a + +Now it happens that the only examples given by Prof. Willis of +incomplete trains in which the axis of a planet-wheel whose motion is +to be determined is not parallel to the central axis of the system, +are similar to the one just discussed; the wheel in question being +carried by a secondary train-arm which derives its motion from a wheel +of the primary train. + +The application of his general equation in these cases gives results +which agree with observed facts; and it would seem that this +circumstance, in connection doubtless with the complexity of these +compound trains, led him to the too hasty conclusion that the formula +would hold true in all cases; although we are still left to wonder at +his overlooking the fact that in these very cases the "absolute" and +the "relative" rotations of the last wheel are identical. + +[Illustration: PLANETARY WHEEL TRAINS. Fig. 21] + +In Fig. 21 is shown a combination consisting also of two distinct +trains, in which, however, there is but one train-arm T turning freely +upon the horizontal shaft OO, to which shaft the wheels A', F, are +secured; the train-arm has two studs, upon which turn the idlers B B', +and also carries the bearings of the last wheel F'; the first wheel A +is annular, and fixed to the frame of the machine. Let it be required +to determine the results of one revolution of the crank H, the numbers +of teeth being assigned as follows: + + A = 60, F = 30, A' = 60, F' = 10. + +We shall then have, for the train ABF (Eq. I.), + + n 60 n' - a + --- = - ---- = -2 = --------, in which n' = 1, m' = 0, + m 30 m' - a' + + 1 - a 1 +whence -2 = -------, 2a = 1 - a, 3a = 1, a = ---. + -a 3 + +And for the train A'B'F' (Eq. II.), + + n 60 n' 1 + --- = ---- = 6 = --------, in which a = ---, m' = 1, + m 10 m' - a' 3 + + n' +whence 6 = -----------, or n' = 4. + 1 - (1/3) + +That is, the last wheel F' turns _four_ times about the axis LL during +one revolution of the crank H. But according to Profs. Willis and +Goodeve, we should have for the second train: + + n 60 n' - a 1 + --- = ---- = 6 = --------, in which a = ---, m' = 1, + m 10 m' - a' 3 + + n' - (1/3) +which gives 6 = -----------, n' - (1/3) = 4, n' = 4-1/3, + 1 - (1/3) + +or _four and one-third_ revolutions of F' for one of H. + +This result, no doubt, might be near enough to the truth to serve all +practical purposes in the application of this mechanism to its +original object, which was that of paring apples, impaled upon the +fork K; but it can hardly be regarded as entirely satisfactory in a +general way; nor can the analysis which renders such a result +possible. + + * * * * * + + + + +THE PANTANEMONE. + + +The need of irrigating prairies, inundating vines, drying marshes, and +accumulating electricity cheaply has, for some time past, led to a +search for some means of utilizing the forces of nature better than +has ever hitherto been done. Wind, which figures in the first rank as +a force, has thus far, with all the mills known to us, rendered +services that are much inferior to those that we have a right to +expect from it with improved apparatus; for the work produced, +whatever the velocity of the wind, has never been greater than that +that could be effected by wind of seven meters per second. But, thanks +to the experiments of recent years, we are now obtaining an effective +performance double that which we did with apparatus on the old system. + +Desirous of making known the efforts that have been made in this +direction, we lately described Mr. Dumont's atmospheric turbine. In +speaking of this apparatus we stated that aerial motors generally stop +or are destroyed in high winds. Recently, Mr. Sanderson has +communicated to us the result of some experiments that he has been +making for years back by means of an apparatus which he styles a +pantanemone. + +The engraving that we give of this machine shows merely a cabinet +model of it; and it goes without saying that it is simply designed to +exhibit the principle upon which its construction is based. + +[Illustration: THE PANTANEMONE.] + +Two plane surfaces in the form of semicircles are mounted at right +angles to each other upon a horizontal shaft, and at an angle of 45 deg. +with respect to the latter. It results from this that the apparatus +will operate (even without being set) whatever be the direction of the +wind, except when it blows perpendicularly upon the axle, thus +permitting (owing to the impossibility of reducing the surfaces) of +three-score days more work per year being obtained than can be with +other mills. Three distinct apparatus have been successively +constructed. The first of these has been running for nine years in the +vicinity of Poissy, where it lifts about 40,000 liters of water to a +height of 20 meters every 24 hours, in a wind of a velocity of from 7 +to 8 meters per second. The second raises about 150,000 liters of +water to the Villejuif reservoir, at a height of 10 meters, every 24 +hours, in a wind of from 5 to 6 meters. The third supplies the +laboratory of the Montsouris observatory. + +The first is not directible, the second may be directed by hand, and +the third is directed automatically. These three machines defied the +hurricane of the 26th of last January.--_La Nature._ + + * * * * * + + + + +RELVAS'S NEW LIFE-BOAT. + + +The Spanish and Portuguese papers have recently made known some +interesting experiments that have been made by Mr. Carlos Relvas with +a new life-boat which parts the waves with great facility and exhibits +remarkable stability. This boat, which is shown in front view in one +of the corners of our engraving, is T-shaped, and consists of a very +thin keel connected with the side-timbers by iron rods. Cushions of +cork and canvas are adapted to the upper part, and, when the boat is +on the sea, it has the appearance of an ordinary canoe, although, as +may be seen, it differs essentially therefrom in the submerged part. +When the sea is heavy, says Mr. Relvas, and the high waves are +tumbling over each other, they pass over my boat, and are powerless to +capsize it. My boat clears waves that others are obliged to recoil +before. It has the advantage of being able to move forward, whatever +be the fury of the sea, and is capable, besides, of approaching rocks +without any danger of its being broken. + +[Illustration: RELVAS'S NEW LIFE BOAT.] +A committee was appointed by the Portuguese government to examine this +new life-boat, and comparative experiments were made with it and an +ordinary life-boat at Porto on a very rough sea. Mr. Relvas's boat was +manned by eight rowers all provided with cork girdles, while the +government life-boat was manned by twelve rowers and a pilot, all +likewise wearing cork girdles. The chief of the maritime department, +an engineer of the Portuguese navy and a Portuguese deputy were +present at the trial in a pilot boat. The three boats proceeded to the +entrance of the bar, where the sea was roughest, and numerous +spectators collected upon the shore and wharfs followed their +evolutions from afar. + +The experiments began at half past three o'clock in the afternoon. The +two life-boats shot forward to seek the most furious waves, and were +seen from afar to surmount the billows and then suddenly disappear. It +was a spectacle as moving as it was curious. It was observed that Mr. +Relvas's boat cleft the waves, while the other floated upon their +surface like a nut-shell. After an hour's navigation the two boats +returned to their starting point. + +The official committee that presided over these experiments has again +found in this new boat decided advantages, and has pointed out to its +inventor a few slight modifications that will render it still more +efficient.--_La Nature._ + + * * * * * + + + + +EXPERIMENTS WITH DOUBLE-BARRELED GUNS AND RIFLES. + + +The series of experiments we are about to describe has recently been +made by Mr. Horatio Phillips, a practical gun maker of London. The +results will no doubt prove of interest to those concerned in the use +or manufacture of firearms. + +The reason that the two barrels of a shot gun or rifle will, if put +together parallel, throw their charges in diverging lines has never +yet been satisfactorily accounted for, although many plausible and +ingenious theories have been advanced for the purpose. The natural +supposition would be that this divergence resulted from the axes of +the barrels not being in the same vertical plane as the center line of +the stock. That this is not the true explanation of the fact, the +following experiment would tend to prove. + +[Illustration: EXPERIMENTS WITH DOUBLE-BARRELLED GUNS.] + +Fig. 1 represents a single barrel fitted with sights and firmly +attached to a heavy block of beech. This was placed on an ordinary +rifle rest, being fastened thereto by a pin at the corner, A, the +block and barrel being free to revolve upon the pin as a center. +Several shots were fired both with the pin in position and with it +removed, the barrel being carefully pointed at the target each time. +No practical difference in the accuracy of fire was discernible under +either condition. When the pin was holding the corner of the block, +the recoil caused the barrel to move from right to left in a circular +path; but when the pin was removed, so that the block was not attached +to the rest in any way, the recoil took place in a line with the axis +of the bore. It will be observed that the conditions which are present +when a double barreled gun is fired in the ordinary way from the +shoulder were in some respects much exaggerated in the apparatus, for +the pin was a distance of 3 in. laterally from the axis of the barrel, +whereas the center of resistance of the stock of a gun against the +shoulder would ordinarily be about one-sixth of this distance from the +axis of the barrel. This experiment would apparently tend to prove +that the recoil does not appreciably affect the path of the +projectile, as it would seem that the latter must clear the muzzle +before any considerable movement of the barrel takes place. + +With a view to obtain a further confirmation of the result of this +experiment, it was repeated in a different form by a number of shots +being fired from a "cross-eyed" rifle,[1] in which the sights were +fixed in the center of the rib. Very accurate shooting was obtained +with this arm. + + [Footnote 1: A cross-eyed rifle is one made with a crooked stock + for the purpose of shooting from the right shoulder, aim being + taken with the left eye.] + +A second theory, often broached, in order to account for the +divergence of the charge, is that the barrel which is not being fired, +by its _vis inertia_ in some way causes the shot to diverge. In order +to test this, Mr. Phillips took a single rifle and secured it near the +muzzle to a heavy block of metal, when the accuracy of the shooting +was in no way impaired. + +So far the experiments were of a negative character, and the next step +was made with a view to discover the actual cause of the divergence +referred to. A single barrel was now taken, to which a template was +fitted, in order to record its exact length. The barrel was then +subjected to a heavy internal hydrostatic pressure. Under this +treatment it expanded circumferentially and at the same time was +reduced in length. This, it was considered, gave a clew to the +solution of the problem. A pair of barrels was now taken and a +template fitted accurately to the side of the right-hand one. As the +template fitted the barrel when the latter was not subject to internal +pressure, upon such pressure being applied any alterations that might +ensue in the length or contour of the barrel could be duly noted. The +right-hand barrel was then subjected to internal hydrostatic pressure. +The result is shown in an exaggerated form in Fig. 2. It will be seen +that both barrels are bent into an arched form. This would be caused +by the barrel under pressure becoming extended circumferentially, and +thereby reduced in length, because the metal that is required to +supply the increased circumference is taken to some extent from the +length, although the substance of metal in the walls of the barrel by +its expansion contributes also to the increased diameter. A simple +illustration of this effect is supplied by subjecting an India-rubber +tube to internal pressure. Supposing the material to be sufficiently +elastic and the pressure strong enough, the tube would ultimately +assume a spherical form. It is a well known fact that heavy barrels +with light charges give less divergence than light barrels with heavy +charges. + +After the above experiments it was hoped that, if a pair of barrels +were put together parallel and soldered only for a space of 3 in. at +the breech end, and were then coupled by two encircling rings joined +together as in Fig. 4, the left-hand ring only being soldered to the +barrel, very accurate shooting would be obtained. For, it was argued, +that by these means the barrel under fire would be able to contract +without affecting or being affected by the other barrel; that on the +right-hand, it will be seen by the illustration, was the one to slide +in its ring. + +A pair of able 0.500 bore express rifle barrels were accordingly +fitted in this way. Fig. 3 shows the arrangement with the rings in +position. Upon firing these barrels with ordinary express charges it +was found that the lines of fire from each barrel respectively crossed +each other, the bullet from the right-hand barrel striking the target +10 in. to the left of the bull's eye, while the left barrel placed its +projectile a similar distance in the opposite direction; or, as would +be technically said, the barrels crossed 20 in. at 100 yards, the +latter distance being the range at which the experiment was made. +These last results have been accounted for in the following manner: +The two barrels were rigidly joined for a space of 3 in., and for that +distance they would behave in a manner similar to that illustrated in +Fig. 2, and were they not coupled at the muzzles by the connecting +rings they would shoot very wide, the charges taking diverging +courses. When the connecting rings are fitted on, the barrel not being +fired will remain practically straight, and, as it is coupled to the +barrel being fired by the rings, the muzzle of the latter will be +restrained from pointing outward. + +The result will be as shown in an exaggerated manner by the dotted +lines on the right barrel in Fig. 3. + +It would appear from these experiments that when very accurate +shooting is required at long ranges with double-barreled rifles, they +should be mounted in a manner similar to that adopted in the +manufacture of the Nordenfelt machine gun, in which weapon the barrels +are fitted into a plate at the extreme breech end, the muzzles +projecting through holes bored to receive them in a metal plate. No +unequal expansion would then take place, and the barrels would be free +to become shorter independently of each other. We give the above +experiments on the authority of their author, who, we believe, has +taken great pains to render them as exhaustive as possible, so far as +they go.--_Engineering._ + + * * * * * + + + + +BALL TURNING MACHINE. + + +The distinguishing feature in the ball turning machine shown opposite +is that the tool is stationary, while the work revolves in two +directions simultaneously. In the case of an ordinary spherical +object, such as brass clack ball, the casting is made from a perfect +pattern having two small caps or shanks, in which the centers are also +marked to avoid centering by hand. It is fixed in the machine between +two centers carried on a face plate or chuck, with which they revolve. +One of these centers, when the machine is in motion, receives a +continuous rotary motion about its axis from a wormwheel, D. This is +driven by a worm, C, carried on a shaft at the back of the chuck, and +driven itself by a wormwheel, B, which gears with a screw which rides +loosely upon the mandrel, and is kept from rotating by a finger on the +headstock. This center, in its rotation, carries with it the ball, +which is thus slowly moved round an axis parallel to the face plate, +at the same time that it revolves about the axis of the mandrel, the +result being that the tool cuts upon the ball a scroll, of which each +convolution is approximately a circle, and lies in a plane parallel to +the line of centers. + +When the chuck is set for one size of ball, which may be done in a few +minutes, any quantity of that diameter may be turned without further +adjustment. A roughing cut for a 2 in. ball may be done in one minute, +and a finishing cut leaving the ball quite bright in the same time. +The two paps are cut off within one-sixteenth of an inch and then +broken off, and the ball finished in the usual way. On account of the +work being geometrically true, the finishing by the ferrule tool is +done in one quarter of the time usually required. + +[Illustration: IMPROVED BALL TURNING MACHINE.] + +The chuck may be applied to an ordinary lathe or may be combined with +a special machine tool, as show in our illustration. In the latter +case everything is arranged in the most handy way for rapid working, +and six brass balls of 2 in. in diameter can be turned and finished in +an hour. The machine is specially adapted for turning ball valves for +pumps, pulsometers, and the like, and in the larger sizes for turning +governor balls and spherical nuts for armor plates, and is +manufactured by Messrs. Wilkinson and Lister, of Bradford Road Iron +Works, Keighley.--_Engineering._ + + * * * * * + + + + +COOLING APPARATUS FOR INJECTION WATER. + + +It often happens in towns and where manufactories are crowded +together, that the supply of water for condensing purposes is very +small, and consequently that it attains an inconveniently high +temperature under unfavorable conditions of weather, resulting in the +deterioration of the vacuum and a consequent increase in the +consumption of fuel. To remedy or to diminish this difficulty, Messrs. +Boase and Miller, of London, have brought out the water cooler +illustrated above. This consists, says _Engineering_, of a revolving +basket of wire gauze surrounding an inner stationary vessel pierced +with numerous small holes, through which the heated water discharged +by the air pump finds its way into the basket, to be thrown out in the +form of fine spray to a distance of 20 ft. at each side. The drops are +received in the tank or pond, and in their rapid passage through the +air are sufficiently cooled to be again injected into the condenser. + +The illustration shows a cooler having a basket three feet in +diameter, revolving at 300 revolutions per minute, and discharging +into a tank 40 ft. square. It requires 3 to 4 indicated horse-power to +drive it, and will cool 300 gallons per minute. The following decrease +of temperature has been observed in actual practice: Water entering at +95 deg. fell 20 deg. in temperature; water entering at 100 deg. to 110 +deg. fell 25 deg.; and water entering at 110 deg. to 120 deg. fell 30 +deg. The machine with which these trials were made was so placed that +the top of the basket was four ft. from the surface of the water in +the pond. With a greater elevation, as shown in the engraving, better +results can be obtained. + +[Illustration: IMPROVED WATER COOLING APPARATUS.] + +The advantages claimed for the cooler are that by its means the +temperature of the injection water can be reduced, the cost and size +of cooling ponds can be diminished, and condensing engines can be +employed where hitherto they have not been possible. The apparatus has +been for two years in operation at several large factories, and there +is every reason to believe that its use will extend, as it supplies a +real want in a very simple and ingenious manner. Messrs. Duncan +Brothers, of Dundee and 32 Queen Victoria Street, E.C., are the +manufacturers. + + * * * * * + + + + +CORRUGATED DISK PULLEYS. + + +This is a pulley recently introduced by Messrs. J. and E. Hall, of +Dartford Eng. With the exception of the boss, which is cast, it is +composed entirely of steel or sheet iron. In place of the usual arms a +continuous web of corrugated sheet metal connects the boss to the rim; +this web is attached to the boss by means of Spence's metal. Inside +the rim, which is flanged inward, a double hoop iron ring is fixed for +strengthening purposes. The advantageous disposition of metal obtained +by means of the corrugated web enables the pulley to be made of a +given strength with less weight of material, and from this cause and +also on account of being accurately balanced these pulleys are well +adapted for high speeds. + +[Illustration] + + * * * * * + +[KANSAS CITY REVIEW.] + + + + +EARLY HISTORY OF THE TELEGRAPH. + + +Although the electric telegraph is, comparatively speaking, a recent +invention, yet methods of communication at a distance, by means of +signals, have probably existed in all ages and in all nations. There +is reason to believe that among the Greeks a system of telegraphy was +in use, as the burning of Troy was certainly known in Greece very soon +after it happened, and before any person had returned from Troy. +Polybius names the different instruments used by the ancients for +communicating information--"pyrsia," because the signals were always +made by means of fire lights. At first they communicated information +of events in an imperfect manner, but a new method was invented by +Cleoxenus, which was much improved by Polybius, as he himself informs +us, and which may be described as follows: + +Take the letters of the alphabet and arrange them on a board in five +columns, each column containing five letters; then the man who signals +would hold up with his left hand a number of torches which would +represent the number of the column from which the letter is to be +taken, and with his right hand a number of torches that will represent +the particular letter in that column that is to be taken. It is thus +easy to understand how the letters of a short sentence are +communicated from station to station as far as required. This is the +pyrsia or telegraph of Polybius. + +It seems that the Romans had a method of telegraphing in their walled +cities, either by a hollow formed in the masonry, or by a tube fixed +thereto so as to confine the sound, in order to convey information to +any part they liked. This method of communicating is in the present +age frequently employed in the well known speaking tubes. It does not +appear that the moderns had thought of such a thing as a telegraph +until 1661, when the Marquis of Worcester, in his "Century of +Inventions," affirmed that he had discovered a method by which a man +could hold discourse with his correspondent as far as they could +reach, by night as well as by day; he did not, however, describe this +invention. + +Dr. Hooke delivered a discourse before the Royal Society in 1684, +showing how to communicate at great distances. In this discourse he +asserts the possibility of conveying intelligence from one place to +another at a distance of 120 miles as rapidly as a man can write what +he would have sent. He takes to his aid the then recent invention of +the telescope, and explains how characters exposed at one station on +the top of one hill may be made visible to the next station on the top +of the next hill. He invented twenty-four simple characters, each +formed of a combination of three deal boards, each character +representing a letter by the use of cords; these characters were +pushed from behind a screen and exposed, and then withdrawn behind the +screen again. It was not, however, until the French revolution that +the telegraph was applied to practical purposes; but about the end of +1703 telegraphic communication was established between Paris and the +frontiers, and shortly afterward telegraphs were introduced into +England. + +The history of the invention and introduction of the electric +telegraph by Prof. Morse is one of inexhaustible interest, and every +incident relating to it is worthy of preservation. The incidents +described below will be found of special interest. The article is from +the pen of the late Judge Neilson Poe, and was the last paper written +by him. He prepared it during his recent illness, the letter embodied +in it from Mr. Latrobe being of course obtained at the time of its +date. It is as follows: + +On the 5th of April, 1843, when the monthly meeting of the directors +of the Baltimore & Ohio Railroad Company was about to adjourn, the +President, the Hon. Louis McLane, rose with a paper in his hand which +he said he had almost overlooked, and which the Secretary would read. +It proved to be an application from Prof. Morse for the privilege of +laying the wires of his electric telegraph along the line of the +railroad between Baltimore and Washington, and was accompanied by a +communication from B.H. Latrobe, Esq., Chief Engineer, recommending +the project as worthy of encouragement. + +On motion of John Spear Nicholas, seconded by the Hon. John P. +Kennedy, the following resolution was then considered: + +_Resolved_, "That the President be authorized to afford Mr. Morse such +facilities as may be requisite to give his invention a proper trial +upon the Washington road, provided in his opinion and in that of the +engineer it can be done without injury to the road and without +embarrassment to the operations of the company, and provided Mr. Morse +will concede to the company the use of the telegraph upon the road +without expense, and reserving to the company the right of +discontinuing the use if, _upon experiment_, it should prove _in any +manner injurious_." + +"Whatever," said Mr. McLane, "may be our individual opinions as to the +feasibility of Mr. Morse's invention, it seems to me that it is our +duty to concede to him the privilege he asks, and to lend him all the +aid in our power, especially as the resolution carefully protects the +company against all present or future injury to its works, and secures +us the right of requiring its removal at any time." + +[In view of the fact that no railroad can now be run safely without +the aid of the telegraph, the cautious care with which the right to +remove it if it should become a nuisance was reserved, strikes one at +this day as nearly ludicrous.] + +A short pause ensued, and the assent of the company was about to be +assumed, when one of the older directors, famed for the vigilance with +which he watched even the most trivial measure, begged to be heard. + +He admitted that the rights and interests of the work were all +carefully guarded by the terms of the resolution, and that the company +was not called upon to lay out any of its means for the promotion of +the scheme. But notwithstanding all this, he did not feel, as a +conscientious man, that he could, without further examination, give +his vote for the resolution. He knew that this idea of Mr. Morse, +however plausible it might appear to theorists and dreamers, and +so-called men of science, was regarded by all practical people as +destined, like many other similar projects, to certain failure, and +must consequently result in loss and possibly ruin to Mr. Morse. For +one, he felt conscientiously scrupulous in giving a vote which would +aid or tempt a visionary enthusiast to ruin himself. + +Fortunately, the views of this cautious, practical man did not +prevail. A few words from the mover of the resolution, Mr. Nicholas, +who still lives to behold the wonders he helped to create, and from +Mr. Kennedy, without whose aid the appropriation would not have passed +the House of Representatives, relieved the other directors from all +fear of contributing to Mr. Morse's ruin, and the resolution was +adopted. Of the President and thirty directors who took part in this +transaction, only three, Samuel W. Smith, John Spear Nicholas, and the +writer, survive. Under it Morse at once entered upon that test of his +invention whose fruits are now enjoyed by the people of all the +continents. + +It was not, however, until the spring of 1844 that he had his line and +its appointments in such a condition as to allow the transmission of +messages between the two cities, and it was in May of that year that +the incident occurred which has chiefly led to the writing of this +paper. + + +MR. LATROBE'S RECOLLECTIONS. + +MY DEAR MR. POE: Agreeably to my promise, this morning I put +on paper my recollection of the introduction of the magnetic telegraph +between Baltimore and Washington. I was counsel of the Baltimore & +Ohio Railroad Co. at the time, and calling on Mr. Louis McLane, the +President, on some professional matter, was asked in the course of +conversation whether I knew anything about an electric telegraph which +the inventor, who had obtained an appropriation from Congress, wanted +to lay down on the Washington branch of the road. He said he expected +Mr. Morse, the inventor, to call on him, when he would introduce me to +him, and would be glad if I took an opportunity to go over the subject +with him and afterward let him, Mr. McLane, know what I thought about +it. While we were yet speaking, Mr. Morse made his appearance, and +when Mr. McLane introduced me he referred to the fact that, as I had +been educated at West Point, I might the more readily understand the +scientific bearings of Mr. Morse's invention. The President's office +being no place for prolonged conversation, it was agreed that Mr. +Morse should take tea at my dwelling, when we would go over the whole +subject. We met accordingly, and it was late in the night before we +parted. Mr. Morse went over the history of his invention from the +beginning with an interest and enthusiasm that had survived the +wearying toil of an application to Congress, and with the aid of +diagrams drawn on the instant made me master of the matter, and wrote +for me the telegraphic alphabet which is still in use over the world. +Not a small part of what Mr. Morse said on this occasion had reference +to the future of his invention, its influence upon communities and +individuals, and I remember regarding as the wild speculations of an +active imagination what he prophesied in this connection, and which I +have lived to see even more than realized. Nor was his conversation +confined to his invention. A distinguished artist, an educated +gentleman, an observant traveler, it was delightful to hear him talk, +and at this late day I recall few more pleasant evenings than the only +one I passed in his company. + +Of course, my first visit the next morning was to Mr. McLane to make +my report. By this time I had become almost as enthusiastic as Mr. +Morse himself, and repeated what had passed between us. I soon saw +that Mr. McLane was becoming as eager for the construction of the line +to Washington as Mr. Morse could desire. He entered warmly into the +spirit of the thing, and laughed heartily, if not incredulously, when +I told him that although he had been Minister to England, Secretary of +State, and Secretary of the Treasury, his name would be forgotten, +while that of Morse would never cease to be remembered with gratitude +and praise. We then considered the question as to the right of the +company to permit the line to be laid in the bed of the road--the plan +of construction at that time being to bury in a trench some eight or +ten inches deep a half inch leaden tube containing the wrapped wire +that was to form the electric circuit. About this there was, in my +opinion, no doubt, and it was not long after that the work of +construction commenced. I met Mr. Morse from time to time while he +lived, and often recurred to the evening's discussion at my house in +Baltimore. + +The above is the substance of what I have more than once related to +other persons. I hope you will persist in your design of putting on +paper your own very interesting recollections in this connection, and +if what I have contributed of mine is of service to you, I shall be +much pleased. + + Most truly yours, + JOHN H.B. LATROBE. +March 3, 1881. + + * * * * * + + + + +THE KRAVOGL ELECTRIC MOTOR. + + +At the origin of every science, of whatever nature it may be, there is +always a fruitless period, of greater or less length, characterized by +the warfare of a few superior minds against general apathy. The finest +discoveries pass unperceived, so to speak, since they cannot cross the +limits of a narrow circle; and it often happens that they fall into +oblivion before they have been seriously judged. Meanwhile, a slow +progress is imperceptibly made, and, in measure as theoretical +principles more clearly disengage themselves, a few industrial +applications spring up and have the effect of awakening curiosity. An +impulse is thus given, and from this moment a movement in advance goes +on increasing at a headlong pace from day to day. + +With electricity this period has been of comparatively short duration, +since scarcely a century and a half separate us from the first +experiments made in this line of research. Now that it has truly taken +its place in a rank with the other sciences, we like to go back to the +hesitations of the first hour, and trace, step by step, the history of +the progress made, so as to assign to each one that portion of the +merit that belongs to him in the common work. When we thus cast a +retrospective glance we find ourselves in the presence of one strange +fact, and that is the simultaneousness of discoveries. That an +absolutely original idea, fertile in practical consequences, should +rise at a given moment in a fine brain is well; we admire the +discovery, and, in spite of us, a little surprise mingles with our +admiration. But is it not a truly curious thing that _several_ +individuals should have had at nearly the same time that idea that was +so astonishing in one? This, however, is a fact that the history of +electrical inventions offers more than one example of. No one ignores +the fact that the invention of the telephone gave rise to a notorious +lawsuit, two inventors having had this ingenious apparatus patented on +the same day and at nearly the same hour. This is one example among a +thousand. In the history of dynamo-electric machines it is an equally +delicate matter to fix upon the one to whom belongs the honor of +having first clearly conceived the possibility of engendering +continuous currents. + +We do not wish to take up this debate nor to go over the history of +the question again. Every one knows that the first continuous current +electric generator whose form was practical is due to Zenobius Gramme, +and dates back to July, 1871, an epoch at which appeared a memoir +(entitled "Note upon a magneto-electric machine that produces +continuous currents") that was read to the Academy of Sciences by Mr. +Jamin. Ten years previous, Pacinotti had had a glimpse of the +phenomenon, and of its practical realization, but was unfortunately +unable to appreciate the importance of his discovery and the benefit +that might be reaped from it. It is of slight consequence whether +Gramme knew of this experiment or not, for the glory that attaches to +his name could not be diminished for all that. But an interesting fact +that we propose to dwell upon now has recently been brought to light +in an electrical review published at Vienna.[1] It results from +documents whose authenticity cannot be doubted that, as far back as +1867, Mr. L. Pfaundler, a professor at Innsbruck, very clearly +announced the reversibility of a magneto-electric motor constructed by +Kravogl, a mechanician of the same place, and that he succeeded some +time before Gramme in obtaining continuous currents. + + [Footnote 1: _Zeitschrift des Electrotechnischen Vereines_ in + _Wien_, July, 1883.] + +The Kravogl motor that figured at the Universal Exhibition of 1867 is +but little known, and it is now very difficult to obtain drawings of +it. What is certain is that this motor is an application of the +properties of the solenoid, and, from this standpoint, resembles the +Bessolo motor that was patented in 1855. We may figure the apparatus +to our mind very well if we suppose that in the Gramme ring a half and +almost two-thirds of the core are removed, and the spirals are movable +around the said core. If a current be sent into a portion of the +spirals only, and in such a way that only half of the core be exposed, +the latter will move with respect to the bobbin or the bobbin with +respect to the core, according as we suppose the solenoid or the +bobbin fixed. In the first case we have a Bessolo motor, and in the +second a Kravogl one. + +In order to obtain a continuous motion it is only necessary to allow +the current to circulate successively in the different portions of the +solenoid. It is difficult to keep the core in place, since it is +unreachable, being placed in the interior of the bobbin. Kravogl +solved this difficulty by constructing a hollow core into which he +poured melted lead. This heavy piece, mounted upon rollers, assumed a +position of equilibrium that resulted from its weight, from friction, +and from magnetic attraction. But for a current of given intensity +this position, once reached, did not vary, and so necessitated a +simple adjustment of the rubbers. Under such circumstances, with a +somewhat large number of sections, the polarity of the core was nearly +constant. The spirals as a whole were attached to a soft iron armature +that had the effect of closing up the lines of forces and forming a +shell, so to speak. + +Like Bessolo, Kravogl never thought of making anything but a motor, +and did not perceive that his machine was reversible. It results from +some correspondence between Dr. A. Von Waltenhofen and Mr. L. +Pfaundler at this epoch that the latter clearly saw the possibility of +utilizing this motor as a current generator. Under date of November 9, +1867, he wrote, in speaking of the Kravogl motor, which had just been +taken to Innsbruck in order to send it to Paris. "I regret that I +shall not be able to see it any more, for I should have liked to try +to make it act in an opposite direction, that is to say, to produce a +current or an electric light by means of mechanical work." A little +more than two years later these experiments were carried out on a +larger motor constructed by Kravogl in 1869, and Mr. Pfaundler was +enabled to write as follows: "Upon running the machine by hand we +obtain a current whose energy is that of one Bunsen element." This +letter is dated February 11, 1870, that is to say, it is a year +anterior to the note of Gramme. + +[Illustration: FIG. 1.] + +In the presence of the historic interest that attaches to the +question, we do not think it will be out of place to reproduce here +the considerations that guided Prof. Pfaundler in the researches that +led him to convert the Kravogl motor into a dynamo-electric machine. +Let us consider two magnetized bars, _db_ and _bd'_, placed end to end +and surrounded by a cylindrical armature forming a shell, this +armature being likewise supposed to be a permanent magnet and to +present poles of contrary direction opposite the poles of the bars. +For the sake of greater simplicity this shell is represented by a part +only in the figure, _s n n s_. If, into a magnetic field thus +formed, we pass a spiral from left to right, the spiral will be +traversed by a current whose direction will change according to the +way in which the moving is done. It is only necessary to apply Lenz's +law to see that a reversal of the currents will occur at the points, +_a_ and _c_, the direction of the current being represented by arrows +in the figure. If we suppose a continual displacement of the spirals +from left to right, we shall collect a continuous current by placing +two rubbers at _a_ and _c_. Either the core or the shell may be +replaced by a piece of soft iron. In such a case this piece will move +with the spiral and keep its poles that are developed by induction +fixed in space. From this, in order to reach a dynamo-electric machine +it is necessary to try to develop the energy of the magnetic field by +the action of the current itself. If we suppose the core to be of soft +iron, and make a closer study of the action of the current as regards +the polarity that occurs under the influence of the poles, _s_, _n_, +_s_, we shall see that from _d_ to _a_ and from _b_ to _c_ the current +is contrary, while that from _a_ to _b_ and from _c_ to _d'_ it is +favorable to the development of such polarity. In short, with a spiral +moving from _d_ to _d'_ the resulting effect is _nil_, a fact, +moreover, that is self-evident. Under such circumstances, if we +suppose the shell, as well as the core, to be of soft iron, we shall +obtain a feeble current due to the presence of remanent magnetism; but +this magnetism will not be able to continue increasing under the +influence of the current. To solve this difficulty two means present +themselves: (1) to cause a, favorable magnetic current and act upon +the armature, and (2) to suppress such portions of the current in the +spirals as are injurious in effect. The first solution was thought of +by Gramme in 1871, and is represented diagramatically in Fig. 2. The +second is due to Prof. Pfaundler, and dates back to 1870. The core is +cut through the center (Fig. 3), and the portion to the right is +suppressed; the current is interrupted between _da_ and _cd'_, and is +closed only between _a_ and _c_ (_v_, Fig. 1). It results from this +arrangement that, under the action of the current, the polarity due to +remanent magnetism does nothing but increase. It suffices then for but +little remanent magnetism to prime the machine; the polarity of the +shell continues to increase, and the energy of the magnetic field, and +consequently of the current, has for a limit only the saturation of +the soft iron. If, now, we curve the core, the spirals, and the +armature into a circle, we have a Gramme or a Pfaundler machine, +according as we consider Fig. 2 or Fig. 3. + +[Illustration: FIG. 2.] + +[Illustration: FIG. 3.] + +This latter apparatus has in this case the form shown in Fig. 4. + +[Illustration: FIG. 4.] + +The spiral, _s m b_, is movable, and the core, N _o s_, is kept in a +position of equilibrium by virtue of its weight, and is provided with +rollers. For the sake of greater clearness, the front part of the +armature is supposed to be removed. The current does not circulate in +the spirals to the right of the diameter, W O, which latter is not +absolutely vertical. The position of the rubbers and armature is +regulated once for all. We do not know just what were the means +devised by Kravogl to suppress the current in the spheres to the +right. At all events, it is probable that the system has grown old +since Gramme invented his collector. In the application of the Kravogl +motor to the generation of continuous currents, Professor Pfaundler +now proposes to ingeniously utilize the Gramme collector. In such a +case the arrangement shown in Fig. 5 would be adopted. Let us suppose +an ordinary collector having as many plates as there are sections in +the ring, these plates being connected as usual with the entrance and +exit wires of the sections. The diametrically opposite touches that +are in the line, W O, are divided, and one of the halves is connected +at the entrance, _c a'_ (Fig. 4), with the corresponding section, +while the other communicates with the exit, _c' a_, of the neighboring +section. Each of these halves is prolonged by a piece of metal bent +into the form of an arc of a circle and embracing a little less than a +semi-circumference. Between these prolongations there is an insulating +part. In the rotary motion of the spiral, at least one of the touches +is always outside of the arc comprised between the brushes, R. In +order to secure a continuity of the circuit in the effective arc, W S_ o_, +it is only necessary to arrange a rubber, M, in such a way as to +establish a communication between the two parts of the divided touch +as soon as this latter enters the arc under consideration. + +In order to produce a current in the direction of the arrows shown in +Fig. 4, the spiral and axle must revolve from right to left. In this +case the rubber, M, occupies the position shown in the same figure, +the brushes embracing an arc of a little less than 180 deg.. As soon as +the lower touch comes in contact with the brush, R, when the +revolution is being effected from left to right, the rubber, M, +establishes a communication between the two halves that have until now +been isolated, and the current is no longer interrupted. The second +touch during this time is at any point whatever of the arc, W N _o_, +and the spirals corresponding to the latter arc outside of the +circuit. In short, thanks to the rubber, M, we have an ordinary Gramme +collector in that portion of the circuit comprised between the +brushes, and a collector with a breakage of the circuit in the portion +to the right. + +[Illustration: FIG. 5.] + +This type of machine is entirely theoretical. In the apparatus used +for Prof. Pfaundler's experiments in 1870, the armature revolved with +the solenoid. The core and armature were of soft iron, and the core +was arranged in a manner analogous to the preceding, and remained in +place under the action of its weight, and the shell, forming a +complete circle, revolved with poles fixed in space. + +Practically, the machine that we have just described would prove +inconvenient to realize, and would present serious inconveniences. In +the first place, it seems to us quite difficult to transmit the motion +of the solenoid to the axle, supposing the former to revolve within +the armature. In the second place, considerable friction would surely +occur between the spirals and core, and the axle, being submitted to a +lateral stress, would be placed in a poor condition for work. It is +even allowable to doubt whether such a type could be practically got +up. At all events, no trial has as yet been made of it. + +Compared with the Gramme machine, from an absolutely theoretical point +of view, the Pfaundler apparatus presents undoubted advantages. A +theoretically perfect dynamo electric machine would be one in which +there was a complete reciprocity between the magnetizing action of the +current and the inductive action of the magnetic field. Now, such is +not the case in the Gramme machine. In this apparatus the soft iron +core is at the same time a magnet through favorable induction and a +disadvantageous electro-magnet. This double polarization is only +remedied to a certain extent by the adjustment of the brushes. In the +Pfaundler machine, on the contrary, the electro-magnetism and +magnetism through induction act in the same direction, and concur in +effecting a polarization that favors the production of the current. +Looked at it in this light, the latter machine more nearly approaches +the type of perfection than does that of Gramme. + +But we must not forget that such qualities are purely theoretical. In +practice the best machine is that in which the copper is best +utilized, that is to say, that which with a given weight of this metal +furnishes the most work. Now, this is certainly not the case in the +Pfaundler machine, for here half or more than half of the ring is +inert--a defect which is apparent at first sight. It results from this +that as soon as we propose to obtain an electromotive force, however +slight it be, we must get it with machines of large dimensions. Now, +it is permissible to believe that under such circumstances (taking +into consideration the complication of mechanical means that the +construction of such apparatus necessitates, and the great friction +that occurs) it would be impossible to obtain practical rotary +velocities. Comparing his machine with Gramme's, Prof. Pfaundler +expresses the idea that between them there is the same analogy as +there is between a constant pressure and an expansion engine. With +cylinders of equal diameters the work performed by the former of these +is greater than that done by the second, but in the latter the +expansive force of the steam is better utilized. This comparison seems +to us to be more ingenious than exact. Would it not be coming nearer +to the truth if we were to suppose a case of a hydraulic motor whose +performance continued diminishing with the height of the fall, and +would it not be advantageous under such circumstances to utilize only +a portion of the fall for the purpose of increasing the motor's +performance? + +This machine, however, as before stated, has never as yet been +constructed, so that experimental data relative to its mode of working +are wanting. It is especially interesting as regards its origin, which +dates back to an epoch at which researches on the dynamo electric +machine were at their heat. It is in its historical aspect that it is +proper to regard it, and it is from such a point of view that we have +deemed it well to say a few words about it in this place.--_La Lumiere +Electrique._ + + * * * * * + + + + +BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES. + + +We shall not attempt to pass in review the several apparatus that have +hitherto been devised for igniting blasts in mining operations, but +shall simply describe in this place a machine recently invented for +this purpose by Mr. Bornhardt, an engineer to the Grand Duke of +Brunswick. + +This apparatus (shown in the accompanying engravings) consists +essentially of two hard-rubber disks, A (Figs. 2 and 3), keyed to an +iron axle, and of two rubbers, B, that are formed of skin and are held +against the disks by small springs, R; motion is communicated to the +axle, _a_, by means of a pair of gearings, _a_ and _b_, and a crank, +_f_. + +[Illustration: BORNHARDT'S ELECTRIC MACHINE FOR BLASTING IN MINES.] + +Each disk revolves between two metallic rings, _c_, provided with +points that attract and collect in Leyden jars, D, the electricity +produced by the friction. For discharging the condensers there is +employed a manipulator formed of a rod, mm, which can be acted upon, +from the exterior, by means of a button, _k_. Upon bringing the ball, +_m_, of the rod in contact with the ball, _p_, of the condenser, the +lever (which then takes the position shown by the dotted line) +continues to remain in connection with a small ring, _q_, through a +special spring. Another ring, _t_, is connected in the same way with +the external armature of the condenser. Upon connecting the rings, _p_ +and _t_, by a wire to which cartridges are attached, any number of the +latter may be ignited. + +The parts that we have just enumerated are inclosed in a tin box +covered with a wooden casing, P. Between the two there is inserted a +sheet of hard rubber in order to prevent a loss of electricity; the +whole is held in place by strong springs. + +In order to show the normal state of the condenser, a scale consisting +of 15 metallic buttons to give the dimensions of the sparks, is +arranged at X. This scale is capable of being connected with the +rings, _q_ and _t_, by means of chains; when the spark obtained after 15 +or 20 revolutions considerably exceeds the intervals of the scale, it +is a sure thing that the machine is in a proper state. + +In order to prepare the apparatus for carriage, the winch is taken off +and placed in the compartment, _m_, which is closed by means of a +door, Q. + +Figs. 5 and 6 show the arrangement of the dynamite cartridges and +wires in the blast hole. Figs. 7 to 10 show different arrangements of +the igniting wires. Figs. 11 and 12 give the general arrangement for +igniting a number of cartridges simultaneously by means of the +electric machine. Fig. 13 shows the arrangement where powder is +employed. Fig. 14 shows the arrangement of a horizontal +hole.--_Annales Industrielles._ + + * * * * * + + + + +IMPROVED ELECTRIC FIRE ALARM. + + +The object of this apparatus is to close an electric circuit when the +temperature of a room rises above a certain point. Many devices have +been invented for effecting this object, each of which have their own +advantages or disadvantages. The invention of Mr. Pritchett enables +the required result to be obtained in a very satisfactory manner. The +apparatus consists (as shown by the figure) of a long glass vessel +containing air; connected to this vessel there is a glass tube filled +with mercury. The whole is mounted on a metal cradle, which turns on +pivots. According to the position which the glass vessel and its +adjuncts occupy in the cradle (this position being adjustable by means +of a thumb-screw, seen at the upper part of the cradle), so will the +same have a tendency to rock longitudinally over to one side or the +other. Now, if we suppose the position to be such that the right hand +end of the glass vessel is depressed, and the left hand end raised, +then if the vessel becomes subjected to an elevation of temperature, +the air inside the same will become expanded, and the mercury column +in the tube will be driven over to the left, and will rise in the +turned up end of the tube. This will cause the left hand branch of the +glass vessel, and its attachments, to become increased in weight, +while the right hand branch will become proportionally lighter; the +consequence of this will be that the vessel and its cradle will cant +over, and by falling on an electrical contact will close a circuit and +sound an alarm. It is obvious that the apparatus is equally well +adapted for indicating a diminution as well as an increase of +temperature, for if the electrical contact be placed under the right +hand portion of the cradle, and the latter be adjusted so that in its +normal position its left hand portion is depressed, then when the +glass vessel becomes cooled, the air in it will contract, and the +mercury will fall in the turned-up portion of the tube before referred +to, and will rise in the limb connected to the vessel, consequently +the cradle and glass vessel will cant over in the reverse way to that +which it did in the first case. + +Owing to the surface which the glass vessel exposes, the air inside +quickly responds to any external change of temperature, consequently +the apparatus is very sensitive. Another important feature is the fact +that the cradle and vessel in canting over acquires a certain +momentum, and thus the contact made becomes very certain. + +[Illustration: PRITCHETT'S ELECTRIC FIRE ALARM.] + +Mr. Pritchett proposes that his apparatus shall give external evidence +outside the house by ringing a gong, and by dropping a semaphore arm +released by an electromagnet. He also proposes (as has often been +suggested) that a water supply shall be automatically turned +on.--_Electrical Review._ + + * * * * * + + + + +A STANDARD THERMOPILE. + + +Dr. G. Gore, F.R.S., has invented an improved thermopile for +measuring small electromotive forces. It consists of about 300 pairs +of horizontal, slender, parallel wires of iron and German silver, the +former being covered with cotton. They are mounted on a wooden frame. +About 11/2 in. of the opposite ends of the wires are bent downward to a +vertical position to enable them to dip into liquids at different +temperatures contained in long narrow troughs; the liquids being +non-conductors, such as melted paraffin for the hot junctions, and the +non-volatile petroleum, known as thin machinery oil. The electromotive +force obtained varies with the temperature; a pile of 295 pairs having +a resistance of 95.6 ohms at 16 deg. Cent. gave with a difference of +temperature of 100 deg. Cent. an electromotive force of 0.7729 volts, +or with 130 deg. Cent. an electromotive force of 1.005 volt. Each +element, therefore, equaled 0.0000262 volt for each degree Cent. +difference of temperature. On having been verified with a standard +voltaic cell the apparatus becomes itself a standard, especially for +small electromotive forces. It is capable of measuring the 1/34861 +part of a volt. For higher electromotive forces than a volt, several +of these piles would have to be connected in series. The fractional +electromotive force is obtained by means of a sliding contact which +cuts out so many pairs as is required. + + * * * * * + + + + +TELEPHONIC TRANSMISSION WITHOUT RECEIVERS. + + +The annual meeting of the French Society of Physics, the success of +which is continually increasing, took place this year in the salons of +the Observatory, which were kindly placed at the Society's disposal by +Admiral Mouchez. + +There were three consecutive sessions, the one of Tuesday, April 15, +being set apart for the members of the Association, the one of the +16th for the invited guests of Admiral Mouchez, and that of the 17th +for the invited guests of the Society. The salons were partially +lighted by the Siemens differential arc, continuous current lamps, and +partially by the Swan incandescent lamp supplied by a distributing +machine that permitted of the lamps being lighted and extinguished at +will without changing the normal operation of all the rest. Many +apparatus figured at this exhibition, but we shall on the present +occasion merely call attention to those that presented a certain +character of novelty or of originality. + +Among the apparatus that we shall reserve a description of for the +present was Messrs. Richard Bros.' registering thermometer designed +for the Concarneau laboratory, an instrument which, when sunk at one +mile from the coast, and to a depth of 40 meters, will give a diagram +of the temperature of the ocean at that depth; and Mr. Hospitalier's +continuous electrical indicators, designed for making known from a +distance such mechanical or physical phenomena as velocities, levels, +temperatures, pressures, etc. + +Among the most important of the apparatus exhibited we must reckon Mr. +Cailletet's devices for liquefying gases, and those of Mr. Mascart for +determining the ohm. The results obtained by Mr. Mascart (which have +been submitted to the Committee on Unities of the Congress of +Electricians now in session at Paris), are sensibly concordant with +those obtained independently in England by Lord Rayleigh. Everything +leads to the hope, then, that a rapid and definite solution will be +given of this important question of electric unities, and that nothing +further will prevent the international development of the C.G.S. +system. + +Mr. Jules Duboscq made a number of very successful projections, and we +particularly remarked the peculiar experiment made in conjunction with +Mr. Parinaud, that gave in projection two like spectra produced by the +same prism, and which, through superposition, were capable of +increasing the intensity of the colors, or, on the contrary, of +reconstituting white light. + +Among the optical applications we may cite Mr. Leon Laurent's +apparatus for controlling plane, parallel, perpendicular, and oblique +surfaces, and magic mirrors obtained with an ordinary light; Mr. S.P. +Thompson's apparatus for demonstrating the propagation of +electro-magnetic waves in ether (according to Maxwell's theory), as +well as some new polarizing prisms; and a mode of lighting the +microscope (presented by Mr. Yvon), that was quite analogous to the +one employed more than a year ago by Dr. Van Heurck, director of the +Botanical Garden of Anvers. + +Acoustics were represented by an electro-magnetic brake siren of Mr. +Bourbouze; Konig's apparatus for the synthesis of sounds; and Mr. S.P. +Thompson's cymatograph--a pendulum apparatus for demonstrating the +phenomena of beats. + +It was electricity again that occupied the largest space in the +programme of the session. + +Apparatus for teaching are assuming greater and greater importance +every day, and the exhibit of Mr. Ducretet included a large number of +the most interesting of these. The house of Breguet exhibited on a +reduced scale the magnificent experiments of Gaston Plante, wherein +320 leaden wire secondary elements charged for quantity with 3 Daniell +elements, and afterward coupled for tension, served to charge a +rheostatic machine formed of 50 condensers coupled for quantity. These +latter, coupled anew for tension, furnished upon being discharged a +spark due to a difference of potential of about 32,000 volts that +presented all the characters of the spark produced by induction coils +on the machines so improperly called "static." Finally, we may cite +the apparatus arranged by Mr. S.P. Thompson for studying the +development of currents in magneto-electric machines. The inventor +studies the influence of the forms of the inductors and armatures of +machines by means of an arrangement that allows him to change the +rings or armatures at will and to take out the induced bobbins in +order to sound every part of the magnetic field. Upon giving the +armature an angular motion limited by two stops, there develops a +certain quantity of electricity that may be measured by causing it to +traverse an appropriate ballistic galvanometer. Messrs. Deprez and +D'Arsonval's galvanometer answers very well for this purpose, and its +aperiodicity, which causes it quickly to return to zero as soon as the +induced current ceases, permits of a large number of readings being +taken within a very short space of time. + +Measuring apparatus were represented by a new and very elegant +arrangement of Sir William Thomson's reflecting galvanometers, due to +Mr. J. Carpentier. The mounting adopted by Mr. Carpentier permits of +an easy removal of the bobbins and of an instantaneous substitution +therefor. The galvanometric part, composed of the needles and mirror, +therefore remains entirely free, thus allowing of its being verified, +and making it convenient to attach the silken fiber. Mr. Carpentier +has, moreover, adopted for all the minor apparatus a transparent +celluloid scale which simplifies them, facilitates observations, and +renders the use of reflection almost industrial. + +We shall complete our enumeration of the measuring apparatus by citing +Ducretet's non-oscillating galvanometer, Sir William Thomson's +amperemeters, voltameters, ohmmeters, and mhosmeters, constructed and +exhibited by Breguet, and a new aperiodic galvanoscope of Mr. Maiche. +Mr. Baudot exhibited the recent improvements that he has made in his +multiplex printing telegraph, and M. Boudet of Paris showed a new +system of telephone transmission by submarine cables. + +[Illustration: FIG. 1.--DIAGRAM EXHIBITING THE ARRANGEMENT FOR +TELEPHONIC TRANSMISSIONS WITHOUT A RECEIVER.] + +Finally, we shall conclude our enumeration by referring to the +curiosities. The house of Siemens exhibited a miniature electric +railway actuated by a new model of Reynier accumulators; M. Maiche +operated a system of musical telephonic auditions that differed only +in detail from those instituted by Mr. Ader at the exhibition of 1881; +and Mr. Hospitalier presented a new form of an experiment devised by +Mr. Giltay, consisting of a telephonic transmission of sounds without +the use of receivers. Mr. Giltay's experiment is nothing but Mr. +Dunand's speaking condenser without the condenser. A glance at Fig. 1 +will show how things are arranged for the experiment. The transmitting +system comprises two distinct circuits, viz.: (1) one formed of a +pile, P, of 2 or 3 Leclanche elements, or of 1 or 2 small sized +accumulators, an Ader microphane transmitter, M, and the inducting +wire of a small induction coil, B; and (2) the other formed of the +induced wire of the coil, B, of a pile, P', of 10 or 12 Leclanche +elements, and of a line whose extremities terminate at R, in two +ordinary electro-medical handles. With this arrangement the experiment +performed is as follows: When any one speaks or sings in front of the +transmitter, T, while two persons, A and B, each having one hand +gloved, are holding the handles in the ungloved hand, it is only +necessary for A to place his gloved hand upon B's ear, or for the +latter to place his hand upon A's, or for each to place his hand on +the other's ear simultaneously, in order that A or B, or A and B +simultaneously, may hear a voice issuing from the glove. Under these +circumstances, Mr. Giltay's experiment is explained like Dunand's +speaking condenser--the hand of A and the ear of B here constituting +the armature of an elementary condenser in which the glove performs +the role of dielectric. + +Upon repeating this experiment at the laboratory of the School of +Physics and Industrial Chemistry of Paris, it has been found that the +glove maybe replaced by a sheet of plain or paraffined paper. In this +case, when two persons are holding the handles, and have their ears +applied, one against the other, if a sheet of paper be interposed, +airs or words will be heard to proceed therefrom. Finally, it has been +found possible to entirely suppress the paper, or dielectric, and to +hear directly, by simply interposing the auditor or auditors in the +circuit. One of the most curious forms of the experiment is the one +shown in Fig. 2. Here a third person, C, hears the hands of A and B +speak when a circuit is formed by means of three persons, A, B, and C, +the two former, A and B, each holding one of the wires of the circuit +and applying his free hand to the ear of C. Although the experiment is +one that requires entire silence, and could not on that account be +performed at the laboratory, a sort of telephonic chain can be formed +in which five or six persons may hear at the same time. A, putting his +hand on the ear of B, the latter putting his to that of C, and so on +up to the last person, who closes the circuit by grasping one of the +handles, the other one being held by A. + +[Illustration: EXPERIMENT ON TELEPHONIC TRANSMISSION WITHOUT +RECEIVING APPARATUS.] + +It is difficult in the present state of science to explain very +clearly how these telephonic transmissions are effected without a +receiver. All that we can conclude from it so far is that the ear is +an instrument of incomparable delicacy and of exquisite sensitiveness, +since it perceives vibrations in which the energy developer, +particularly in the telephonic chain, is exceedingly feeble. + +Without any desire to seek an application for an experiment that is +simply curious, we yet believe that there is here a phenomenon of a +nature to be studied by physicists. Discoveries in telephony and +microphony have certainly opened up to science, as regards both theory +and practice, new horizons that still promise other surprises for the +future. But to return to the observatory: The success obtained by the +exhibition of the French Society of Physics shows that these reunions +respond to a genuine need--that of instructing in and popularizing +science. While warmly congratulating the organizers of these meetings, +we may express a wish that the good example set by the Society of +Physics may be followed by other societies. We are convinced in +advance that an equal success awaits them.--_La Nature._ + + * * * * * + + + + +ON THE ARRANGEMENT OF GROUND CONDUCTORS. + + +In telegraphy, as well as in the question of lightning rods, attention +has been but incidentally paid to the improvement of ground +conductors, and this point has not been the object of that careful +study that has been bestowed upon the establishment of aerial lines. +It is only recently that the interest created by lightning rods has +given rise to new forms of conductors differing from those formerly +used. The publications of the Prussian Academy of Sciences of from +1876 to 1880 contain some information of special importance in regard +to this. It is stated therein that the effect of ground conductors may +be notably increased by the division of the earth plates and the use +of metallic rods, without necessitating a greater output of material. +These facts, however, have not as yet been put to profit in practice +for the reason, perhaps, that the considerations, which have remained +general, have not at once permitted of obtaining forms what could be +employed with perfect knowledge of the results. This is what led Mr. +Ulbricht, of Dresden, to make calculations for a few forms of +conductors, and to test their approximate values. The results of these +researches are printed in the _Elektrotechnischen Zeitschrift_ for +1883 (p. 18). + +[Illustration] + +The equations found show, in the first place, that there exist three +means of obtaining a considerable effect, as regards the ground +conductor, with a slight expenditure of material: The cylindrical +electrode may be drawn out into the form of a bar or wire; the plate +may be rendered narrow, and elongated in the form of a ribbon; and, +besides, the annular plate may be enlarged in lessening the metallic +surface. + +Finally, a short, open cylinder with a vertical axis may be formed by +curving a narrow plate or ribbon. It is not necessary to see the +formula to recognize the fact that this cylinder must behave like a +ribbon and a flat ring. The radius increasing, and the surface +remaining constant, the resistance of the earth here likewise +approaches zero. + +As the resistance of the earth is inversely proportional to the +diameter of the plates, the zero resistance can also be reached by +dividing a plate _ad infinitum_. As the parts of the plate may be +brought quite close to each other without perceptibly interfering with +the action, a _network_ has finally been reached by a division carried +very far, yet limited, and by connecting the parts with one another by +conducting cylinders. + +If we seek to determine what forms of ground conductors are efficient +and economical under given conditions, we shall have to begin by +informing ourselves as to the choice of material to be used for the +electrode, and shall then have to ascertain whether putting it in the +ground will or will not necessitate much outlay. The most suitable +material is copper, which may be used with advantage, in that it lasts +pretty well underground, and that the facility which it may be worked +permits of easily giving it more appropriate forms than those that can +be obtained with cast iron, which is of itself less costly. + +If the burying in the ground requires little or no labor, as when +there exist ponds, rivers, and wells, or subterranean strata of water +near the surface of the earth, elongated forms of conductors will be +employed, such as the solid or hollow cylinder, the wire, the ribbon, +the narrow ring, and the network. Plates approaching a square or +circular shape are not advantageous. But if the ground has to be dug +deeply in order to sink the conductor, the form of the electrode must +be more condensed, and selected in such a way that the necessary +action may be obtained with a minimum output of copper and labor. For +great depths, and when the ground will permit of boring, an elongated +and narrow cylinder will be used. Such a system, however, can only be +employed when the cylinder is surrounded by spring water, since, +without that, an intimate contact with earth that is only moist, +cannot be obtained with certainty. In earth that is only moist and for +moderate depths, preference may be given to an electrode laid down +flat. The digging necessary in this case is onerous, it is true, but +it permits of very accurately determining the state of the earth +beneath and of obtaining a very perfect adherence of the electrode +therewith. Two forms, the annular ribbon or the flat ring and the +network, present themselves, according to calculations, as a +substitute for copper plates, which are so expensive; and these forms +are satisfactory on condition that the labor of digging be not notably +increased. These forms should always have a diameter a little greater +than that of the plate. The flat ring and the network, however, offer +one weak point, which they possess in common with the plate, and that +is, their dimensions cannot be easily adapted to the nature of the +ground met with without a notable increase in the expense. Now, if the +ground should offer a conductivity less than what was anticipated, and +it were desired to increase the plate, say by one-third, it would be +impossible to do so as a consequence of the closed form. + +One important advantage is realized in this respect by combining the +ring and the network in the form of a reticulated ring having a +diameter of from 1 to 11/2 meters. On cutting this ring at a given place +and according to a certain radius we obtain the reticulated ribbon +shown in the accompanying figure. The thickness of the wires is 2.5 +mm., and their weight is 0.475 kilo. per meter. L, L, and L are the +points at which the conducting cable is soldered. A reticulated ribbon +of copper can be made in advance of any length whatever, and, +according to local exigencies, it may be easily curved and given the +form of a flat or cylindrical ring of varying width. Even though the +ribbon has already been cut for a ring of given diameter, it may be +still further enlarged by drawing it out and leaving a bit of the ring +open, so as to thus obtain a nearly corresponding diminution in the +resistance. Such a resistance may be still further diminished by +rendering the ring higher, that is to say, by employing an annular +cylindrical form. + +After assuring himself, by experiments on a small scale, that +calculation and observation gave concordant results for the flat ring, +the author made an experiment on a larger scale with the annular +network. For practical reasons he employed for this purpose a copper +wire 2.5 mm. in diameter, which may be expected to last as long as one +of iron plate 2 mm. in thickness. Calculation showed that in a ribbon +160 mm. wide, meshes 40 mm. in breadth were advantageous and favorable +as regards rigidity. A reticulated ribbon like this, 4 meters in +length, was made and formed into a flat ring having an external +diameter of 1.42 m. and an internal one of 1.10 m. The resistance of +this ring was found to be W = 0.3485 (1/_k_), and that of a plate one +meter square, W0 = 0.368 (1/_k_). + +As the conductivity of the earth is very variable, and as we cannot +have an absolute guarantee that the ramming will be uniform, it seemed +proper to make the measurements of the resistance by fixing the plate +and the ring in succession to the lower surface of a small raft, in +such a way that the contact with the water should correspond as well +as possible to the suppositions made for the calculation. As a second +ground conductor, a system of water pipes was used, and, after this, a +lightning rod conductor, etc. + +Repeated and varied experiments gave, for the calculation of the +values of the resistances, equations so concordant that the following +results may be considered very approximate. + +The square plate had a resistance of 35.5 Siemens units, and the +reticulated ring one of 32.5. From the first figure we deduce k = +1/91.12, that is to say, the specific conductivity of river-water is +1:91120000. Calculation, then, gives as the resistance of the earth in +Siemens units: + + Calculated. Observed. + Square plate. 33.5 33.5 + Annular ring. 31.76 32.5 + +These figures prove the accuracy of the calculations that had been +made in an approximate way. + +The experiments were performed upon the Elba, above Dresden. Other +experiments still had reference to the influence of immersion. In +order to diminish polarization, only instantaneous currents from the +measuring pile were employed. It was to be supposed that the current +of water through which the bubbles of gas were removed from the +electrodes would not have permitted of a notable resistance of +polarization. Later measurements, made upon a ribbon buried, like the +plates, in the earth, gave likewise most favorable results. + +As a result of these experiments, the State railways of Saxony have, +in such cases as were practicable, introduced the annular network of +copper. There are some manufacturers, too, who seem desirous of +adopting this system, although it has hardly emerged from the period +of experiment. The pecuniary advantages that will result from an +application of it ought, it would seem, to dispel a large proportion +of the criticisms directed against the erection of lightning rods, +from the standpoint of expense, and contribute to extend an +arrangement which may be considered as a very happy one. + +If we compare the square plate with the equivalent annular network, +constructed as above indicated, and which should possess, according to +the author an external diameter of 1.26 m. and of 3.45 m., we find +that: + + The square plate, 1 mm. thick weighs 8.9 kilos. + " 2 " " " 17.8 " + The annular network " 1.64 " + +The cost of reticulated ribbon per meter amounts to about 4.4 francs, +supposing it to be arranged as shown in the cut. + +As term of comparison, we may admit that the following forms are +nearly the equivalent of a horizontal, unburied plate one meter +square. + + Length. Diameter. + Vertical cylinder buried 1.40 m. 0.13 m. + " " " 1.80 m. 0.06 m. + Vertical bar " 2.60 m. 0.013 m. + Horizontal bar " 5.20 m. 0.013 m. + +Horizontal flat ring 1.32 m. in external diameter, and 1.08 m. +internal. + +Horizontal network 1.01 m. square, and having meshes of the same size +as those of the reticulated ribbon. + +Horizontal reticulated ribbon 3 m. in length and of the structure +described. + +Horizontal annular ring 1.26 m. in external diameter, 0.94 m. +internal. + +In conclusion, let us meet an objection that might be made to the +accuracy of the hypotheses that serve as a base to the preceding +calculations, in cases where ground plates for lightning rods and not +for telegraphs are concerned. Between the two ground plates of a +telegraph line there is generally a distance such that the curves of +the current undergo no deviation in the vicinity of one of the +electrodes (the only part important for integrations) through the +influence of the other. But it might be admitted that such would prove +the case with a lightning rod in a storm, at the time of the passage +of the fluid into the earth. The ground plate here is one of the +electrodes, and the other is replaced by the surface of the earth +strongly charged to a great distance under the storm clouds. If we +suppose (what may be admitted in a good lightning rod) that there no +longer occurs any spark from the point downward, the curves of the +current, in starting perpendicularly from the ground plate, would be +obliged to leave their rectilinear trajectory and strike the surface +of the earth at right angles. When the electricity flows through a +plane surface into an infinite body, it is only when such surface +presents a very great development that the respective potentials +decrease very slowly in the vicinity of the said surface. No notable +modification occurs, then, in the curves of equal potential, in the +vicinity of the ground plate through the action of this extended +charge, nor consequently any modification in the curves of the +current; but the electricity which spreads has but a short distance to +travel in order to overcome the most important resistances. + +The calculations of resistances given above have, then, the same value +for discharges of atmospheric electricity.--_Bull. du Musee de +l'Industrie._ + + * * * * * + + + + +ON ELECTROLYSIS. + +By H. SCHUCHT. + + +Concerning the separations which take place at the positive pole, the +composition of the peroxides, and the manner of their determination, +relatively little has been done. + +If solutions of the salts of lead, thallium, silver, bismuth, nickel, +and cobalt are decomposed by the current between platinum electrodes, +metal is deposited at the negative, and oxide at the positive +electrode. Manganese is precipitated only as peroxide. The formation +of peroxide is, of course, effected by the ozone found in the +electrolytic oxygen at the positive pole; the oxide existing in +solution is brought to a higher degree of oxidation, and is separated +out. Its formation may be decreased or entirely prevented by the +addition of readily oxidizible bodies, such as organic acids, lactose, +glycerine, and preferably by an excess of oxalic acid; but only until +the organic matter is transformed into carbonic acid. In this manner +Classen separates other metals from manganese in order to prevent the +saline solutions from being retained by the peroxide. + +With solutions of silver, bismuth, nickel, and cobalt, it is often +practicable to prevent the separation of oxide by giving the current a +greater resistance--increasing the distance between the electrodes. + +The proportion between the quantities of metal and of peroxide +deposited is not constant, and even if we disregard the concentration +of the solution, the strength of the current and secondary influences +(action of nascent hydrogen) is different in acid and in alkaline +solutions. In acid solutions much peroxide is formed; in alkaline +liquids, little or none. The reason of the difference is that ozone is +evolved principally in acid solutions, but appears in small quantities +only in alkaline liquids, or under certain circumstances not at all. +The quantity of peroxide deposited depends also on the temperature of +the saline solution; at ordinary temperatures the author obtained more +peroxide--the solution, the time, and the strength of current being +equal--than from a heated liquid. The cause is that ozone is destroyed +by heat and converted into ordinary oxygen. With the exception of lead +and thallium the quantity of metal deposited from an acid solution is +always greater than that of the peroxide. + +_Lead._--Luckow has shown that from acid solutions--no matter what may +be the acid--lead is deposited at the anode as a mixture of anhydrous +and hydrated peroxide of variable composition. Only very strongly acid +solutions let all their lead fall down as peroxide; the precipitation +is rapid immediately on closing the circuit, and complete separation +is effected only in presence of at least 10 per cent. of free nitric +acid. As the current becomes stronger with the increase of free acid, +there is deposited upon the first compact layer a new stratum of +loosely adhering peroxide. + +In presence of small quantities of other metals which are thrown down +by the current in the metallic state, such as copper, mercury, etc., +peroxide alone is deposited from a solution of lead containing small +quantities only of free nitric acid. + +The lead peroxide deposited is at first light brown or dark red, and +becomes constantly darker and finally taking a velvet-black. As its +stratification upon the platinum is unequal, it forms beautifully +colored rings. + +Experiments show that the quantity of peroxide deposited depends on +the nature of the solution and the strength of the current. In case of +very feeble currents and slight acidity, its quantity is so small that +it does not need to be taken into consideration. If the lead solution +is very dilute scarcely any current is observed, lead solutions _per +se_ being very bad conductors of electricity. + +Faintly acid concentrated lead solutions give loose peroxide along +with much spongy metallic lead. Free alkali decreases the separation +of peroxide; feebly alkaline solutions, concentrated and dilute, yield +relatively much peroxide along with metallic lead, while strongly +alkaline solutions deposit no peroxide. + +Dried lead peroxide is so sparingly hygroscopic that it may be weighed +as such; its weight remains constant upon the balance for a long time. +In order to apply the peroxide for quantitative determinations, a +large surface must be exposed to action. As positive electrode a +platinum capsule is convenient, and a platinum disk as negative pole. +The capsule shape is necessary because the peroxide when deposited in +large quantities adheres only partially, and falls in part in thin +loose scales. It is necessary to siphon off the nitric solution, +since, like all peroxides, that of lead is not absolutely insoluble in +nitric acid. The methods of Riche and May give results which are +always too high, since portions of saline solution are retained by the +spongy deposit and can be but very imperfectly removed by washing. +This is especially the case in presence of free alkali. + +The author has proceeded as follows: The lead peroxide is dried in the +capsule, and there is passed over it pure dry gaseous sulphurous acid +in a strong current from a rather narrow delivery tube. Lead sulphate +is formed with evolution of heat; it is let cool under the exsiccator, +and weighed as such. Or he ignites the peroxide along with finely +pulverized ammonium sulphite; the mass must have a pure white color. +After the conclusion of the reaction it is ignited for about 20 +minutes. The results are too high. The proportion of actual lead +peroxide in the deposit ranges from 94 to 94.76 per cent. The peroxide +precipitated from a nitric solution may, under certain circumstances, +be anhydrous. This result is due to the secondary influences at the +positive pole, where the free acid gradually withdraws water from the +peroxide. + +The peroxide thrown down from alkaline solutions retains alkali so +obstinately that it cannot be removed by washing; the peroxide plays +here the part of an acid. The lead nitrate mechanically inclosed in +the peroxide is resolved by ignition into oxide, hyponitric acid, and +oxygen; this small proportion of lead oxide does not exert an +important influence on the final result. The quantity of matter +mechanically inclosed is relatively high, as in the precipitation of +much lead peroxide there is relatively more saline matter occluded +than when a few centigrammes are deposited. The peroxide incloses also +more foreign matter if it is thrown down upon a small surface than if +it is deposited in a thin layer over a broad surface. From numerous +analyses the author concludes that in presence of much free nitric +acid the proportion of water is increased; with free alkali the +reverse holds good. + +_Thallium_ behaves similarly to lead. From a nitric acid solution it +is thrown down, according to the proportion of free acid, either as +sesquioxide only or in small quantities as silvery, metallic leaflets; +from alkaline solutions it is deposited as sesquioxide and metal, the +latter of a lead-gray color. Thallium solutions conduct the electric +current badly. Thallium oxide resembles lead peroxide in color; at a +strong heat it melts, becomes darker, and is converted into peroxide, +in which state it can be weighed. + +_Silver._--All solutions of silver salts, except the nitrate, and +those containing a very large quantity of free nitric acid or +nitrates, deposit electrolytically merely metallic silver. In the +above mentioned exceptional cases there is formed a small quantity of +peroxide which adheres to the anode as a blackish-gray deposit. The +greatest quantity of peroxide is obtained on employing a concentrated, +strongly acid solution of the nitrate, and a strong current. If the +solution is very dilute we obtain no peroxide, or mere traces which +disappear again toward the end of the process. The peroxide is +deposited at first in small, dark, shining octahedral crystals; +subsequently, in an amorphous state. At 110 deg. it evolves oxygen +suddenly, and is converted into metallic silver. It dissolves in +ammonia with a violent escape of nitrogen. In nitric acid it dissolves +without decomposition and with a red color. + +The author uses a galvanic current for reducing silver residues, +consisting of sulphocyanide. The salt is mixed with sulphuric acid in +a roomy platinum capsule, and a fine platinum wire gauze is used as +positive electrode. + +_Bismuth._--The current resolves bismuth solutions into metal and +bismutic acid. The latter is deposited at the positive pole, and in +thin layers appears of a golden-yellow, but in thick strata is darker, +approaching to red. Its formation is very gradual, and in time it +disappears again, owing to secondary actions of the current. On +ignition it becomes lemon yellow, and transitorily darker, even brown, +and passes into the sexquioxide. + +_Nickel and Cobalt._--On the electrolysis of the ammonical solution +the sesquioxide appears at the positive pole. Its formation is +prevented by an excess of ammonia. The author never obtains more than +31/2 per cent. of the quantity of the metal. The sesquioxides dissolve +in ammonia without escape of nitrogen, and are usually anhydrous. + +_Manganese._--Manganese is the only metal which is precipitated only +as peroxide. It is deposited at once on closing the circuit, and is at +first brown, then black and shining. Organic acids, ferrous oxide, +chromic oxide, ammonium salts, etc., prevent the formation of peroxide +and the red color produced by permanganic acid. In very dilute +strongly acid nitric solutions there is formed only permanganic acid, +which according to Riche is plainly visible in solutions containing +1/1000000 grm. manganese. On electrolyzing a manganiferous solution of +copper nitrate, red permanganic acid appeared in a stratum floating +above the platinum disk coated with brown peroxide. No manganese +peroxide was deposited. The peroxide adheres firmly to the platinum +when the proportion of free acid is small, not exceeding 3 per cent., +and the current is not too strong. If the action of the current is +prolonged after the peroxide is thrown down, it falls off in laminae. +According to Riche, in a nitric solution the manganese is deposited as +peroxide, also at the negative pole. This formation is not directly +due to the current, but is a precipitate occasioned by the production +of ammonia by the reduction of nitric acid. To determine the manganese +in peroxide electrolytically precipitated, it is heated to bright +redness in the platinum capsule until the weight becomes constant. The +results are too high. + +_Selenium and Tellurium._--Both these bodies are readily and +completely reduced by the current either in acid or alkaline +solutions. Selenium is thrown down at first of a fine brownish red, +which gradually becomes darker. The deposit of tellurium is of a +bluish black color. If the current is feeble, the deposit of selenium +is moderately compact; that of tellurium is always loose, and it often +floats on the liquid. A strong current precipitates both as powders. +The positive pole is coated during electrolysis with a film of a dark +color in case of selenium, but of a lemon yellow with tellurium. As in +case of arsenic and antimony, the hydrogen evolved at the negative +pole combines with the reduced substances, forming hydrogen, selenide, +or telluride, which remain in part in solution in the liquid. The +reduced metal separates out at the anode in a friable +condition.--_Zeitschrift fur Analytische Chemie, and Chemical News._ + + * * * * * + + + + +THE ELECTRO-CHEMICAL EQUIVALENT OF SILVER. + + + +A very careful and important determination of the electrochemical +equivalent of silver has been made at the observatory of the Physical +Institute of Wuerzbourg, and the results are that an ampere current +flowing for a second, or a coulomb of electricity deposits 1.1183 +milligrammes of silver or 0.3281 milligramme of copper, and decomposes +0.09328 milligramme of water, a result agreeing closely with that of +Lord Rayleigh recently communicated to the Physical Society. An ampere +therefore deposits 4.0259 grammes of silver per hour; Kohlrausch's +value is 4.0824, a value hitherto accepted universally. This value is +so useful in measuring electric currents with accuracy, and free from +the disturbances of magnetism, etc., that it is eminently satisfactory +to find the German value agree with that of Lord Rayleigh, which will +probably be adopted by English electricians. + + * * * * * + + + + +A NEW STANDARD LIGHT. + + +Herr Hefner-Alteneck has suggested a new standard light for +photometric purposes, which promises to be very simple and effective +in operation. The light is produced by an open flame of amyl-acetate +burning from a wick of cotton fiber which fills a tube of German +silver 1 in. long and 316 mils. internal diameter; the external +diameter being 324 mils. The flame is 1.58 in. high from top to +bottom; and it should be lighted at least ten minutes before using the +light for testing. A cylindrical glass chimney surrounds it to ward +off air currents. About 2 per cent. of the light is absorbed by the +glass. The power of the flame is that of a standard English candle; +and experiments have shown that amyl acetate, which besides is not +expensive, is the best fuel for steadiness and brilliance. Neither the +substitution of commercial amyl-acetate for pure nor the use of a wick +of cotton thread for loose cotton fiber alters the illuminating power; +but the wick should be trimmed square across the mouth of the tube, +for if it project and droop the illuminating power is increased. + + * * * * * + +[NATURE.] + + + + +DR. FEUSSNER'S NEW POLARIZING PRISM. + + +In a recent number of the _Zeitschrift fur Instrumentenkunde_ (iv., +42-50, February, 1884), Dr. K. Feussner of Karlsruhe has given a +detailed description of a polarizing prism lately devised by him, +which presents several points of novelty, and for which certain +advantages are claimed. The paper also contains an account, although +not an exhaustive one, of the various polarizing prisms which have +from time to time been constructed by means of different combinations +of Iceland spar. The literature of this subject is scattered and +somewhat difficult of access, and moreover only a small part of it has +hitherto been translated into English; and it would appear therefore +that a brief abstract of the paper may not be without service to those +among the readers of _Nature_ who may be unacquainted with the +original memoirs, or who may not have the necessary references at +hand. + +Following the order adopted by Dr. Feussner, the subject may be +divided into two parts: + + +I.--OLDER FORMS OF POLARIZING PRISMS. + +In comparing the various forms of polarizing prisms, the main points +which need attention are--the angular extent of the field of view, the +direction of the emergent polarized ray, whether it is shifted to one +side of, or remains symmetrical to the long axis of the prism; the +proportion which the length of the prism bears to its breadth; and +lastly, the position of the terminal faces, whether perpendicular or +inclined to the long axis. These requirements are fulfilled in +different degrees by the following methods of construction: + +[Illustration: Fig. 1., Fig. 2., and Fig. 3.] + +1. _The Nicol Prism_ (_Edin. New Phil. Journal_, 1828, vi., 83).--This +(Fig. 1), as is well known, is constructed from a rhombohedron of +Iceland spar, the length of which must be fully three times as great +as the width. The end faces are cut off in such a manner that the +angle of 72 deg. which they originally form with the lateral edge of the +rhombohedron is reduced to 68 deg.. The prism is then cut in two in a +plane perpendicular to the new end surfaces, the section being carried +obliquely from one obtuse corner of the prism to the other, in the +direction of its length. The surfaces of this section, after having +been carefully polished, are cemented together again by means of +Canada balsam. A ray of light, on entering the prism, is separated by +the double refraction of the calc-spar into an ordinary and an +extraordinary ray; the former undergoes total reflection at the layer +of balsam at an incidence which allows the extraordinary ray to be +transmitted; the latter, therefore, passes through unchanged. This +principle of obtaining a single polarized ray by means of total +reflection of the other is common to all the forms of prism now to be +described. + +Dr. Feussner gives a mathematical analysis of the paths taken by the +two polarized rays within the Nicol prism, and finds that the emergent +extraordinary ray can include an angular field of 29 deg., but that this +extreme value holds good only for rays incident upon that portion of +the end surface which is near to the obtuse corner, and that from +thence it gradually decreases until the field includes an angle of +only about half the previous amount. He finds, moreover, that, +although of course the ray emerges parallel to its direction of +incidence, yet that the zone of polarized light is shifted to one side +of the central line. Also that the great length of the Nicol--3.28 +times its breadth--is not only an inconvenience, but owing to the +large pieces of spar thus required for its construction, prisms of any +but small size become very expensive. To this it may be added that +there is a considerable loss of light by reflection from the first +surface, owing to its inclined position in regard to the long axis of +the prism. + +[Illustration: Fig. 4., Fig. 5., and Fig. 6.] + +It is with the view of obviating these defects that the modifications +represented in Figs. 2 to 6 have been devised. + +2. _The Shortened Nicol Prism_.--This arrangement of the Nicol prism +is constructed by Dr. Steeg and Reuter of Homburg v.d.H. For the sake +of facility of manufacture, the end surfaces are cleavage planes, and +the oblique cut, instead of being perpendicular, makes with these an +angle of about 84 deg.. By this alteration the prism becomes shorter, and +is now only 2.83 times its breadth; but if Canada balsam is still used +as the cement, the field will occupy a very unsymmetrical position in +regard to the long axis. If balsam of copaiba is made use of, the +index of refraction of which is 1.50, a symmetrical field of about 24 deg. +will be obtained. A prism of this kind has also been designed by Prof. +B. Hasert of Eisenach (_Pogg. Ann._, cxiii., 189), but its performance +appears to be inferior to the above. + +3. _The Nicol Prism with Perpendicular Ends._--The terminal surfaces +in this prism are perpendicular to the long axis, and the sectional +cut makes with them an angle of about 75 deg.. The length of the prism is +3.75 times its breadth, and if the cement has an index of refraction +of 1.525, the field is symmetrically disposed, and includes an angle +of 27 deg.. Prisms of this kind have been manufactured by Dr. Steeg, Mr. +C.D. Ahrens, and others. + +4. _The Foucault Prism_ (_Comptes Rendus_, 1857, xlv., 238).--This +construction differs from all those hitherto mentioned, in that a film +of air is employed between the two cut surfaces as the totally +reflecting medium instead of a layer of cement. The two halves of the +prism are kept in position, without touching each other, by means of +the mounting. The length of the prism is in this way much reduced, and +amounts to only 1.528 times its breadth. The end surfaces are cleavage +planes, and the sectional cut makes with them an angle of 59 deg.. The +field, however, includes not more than about 8 deg., so that this prism +can be used only in the case of nearly parallel rays; and in addition +to this the pictures which may be seen through it are to some extent +veiled and indistinct, owing to repeated internal reflection. + +5. _The Hartnack Prism_ (_Ann. de Ch. et de Physique_, ser. iv., vii., +181).--This form of prism was devised in 1866 by MM. Hartnack and +Prazmowiski; the original memoir is a valuable one; a translation of +it, with some additions, has lately been published (_Journ. of the R. +Microscopical Soc._, June, 1883, 428). It is considered by Dr. +Feussner to be the most perfect prism capable of being prepared from +calc-spar. The ends of the prism are perpendicular to its length; the +section carried through it is in a plane perpendicular to the +principal axis of the crystal. The cementing medium is linseed oil, +the index of refraction of which is 1.485. This form of prism is +certainly not so well known in this country as it deserves to be; a +very excellent one, supplied to the present writer by Dr. Steeg is of +rectangular form throughout, the terminal surfaces are 19 x 15 mm., +and the length 41 mm. The lateral shifting of the field is scarcely +perceptible, the prism is perfectly colorless and transparent, and its +performance is far superior to that of the ordinary Nicol. The field +of view afforded by this construction depends upon the cementing +substance used, and also upon the inclination of the sectional cut in +regard to the end of the prism; it may vary from 20 deg. to 41 deg.. If the +utmost extent of field is not required, the prism may be shortened by +lessening the angle of the section, at the expense, however, of +interfering with the symmetrical disposition of the field. + +6. _The Glan Prism_ (Carl's "Repertorium," xvi., 570, and xvii., +195).--This is a modification of the Foucault, and in a similar manner +includes a film of air between the sectional surfaces. The end +surfaces and also the cut carried through the prism are parallel to +the principal axis of the calc-spar. The ends are normal to the +length, and the field includes about 8 deg.. This prism is very short, and +may indeed be even shorter than it is broad. It is subject to the same +defect as that mentioned in the case of the Foucault, although perhaps +not quite to the same extent. + + +II.--THE NEW POLARIZING PRISM. + +This prism differs very considerably from the preceding forms, and +consists of a thin plate of a doubly refracting crystal cemented +between two wedge-shaped pieces of glass, the terminal faces of which +are normal to the length. The external form of the prism may thus be +similar to the Hartnack, the calc-spar being replaced by glass. The +indices of refraction of the glass and of the cementing medium should +correspond with the greater index of refraction of the crystal, and +the directions of greatest and least elasticity in the latter must +stand in a plane perpendicular to the direction of the section. One of +the advantages claimed for the new prism is that, it dispenses with +the large and valuable pieces of spar hitherto found necessary; a +further advantage being that other crystalline substances may be used +in this prism instead of calc-spar. The latter advantage, however, +occurs only when the difference between the indices of refraction for +the ordinary and extraordinary rays in the particular crystal made use +of is greater than in calc-spar. When this is the case, the field +becomes enlarged, and the length of the prism is reduced. + +[Illustration: Fig. 7.] + +The substance which Dr. Feussner has employed as being most suitable +for the separating crystal plate is nitrate of soda (_natronsalpeter_), +in which the above-mentioned values are [omega] = 1.587 and [eta] = +1.336. It crystallizes in similar form to calcite, and in both cases +thin plates obtained by cleavage may be used. + +As the cementing substance for the nitrate of soda, a mixture of gum +dammar with monobromonaphthalene was used, which afforded an index of +refraction of 1.58. In the case of thin plates of calcite, a solid +cementing substance of sufficiently high refractive power was not +available, and a fluid medium was therefore employed. For this purpose +the whole prism was inclosed in a short glass tube with airtight ends, +which was filled with monobromonaphthalene. In an experimental prism a +mixture of balsam of tolu was made use of, giving a cement with an +index of refraction of 1.62, but the low refractive power resulted in +a very considerable reduction of the field. The extent and disposition +of the field may be varied by altering the inclination at which the +crystal lamina is inserted (Fig. 7), and thereby reducing the length +of the prism, as in the case of the Hartnack. + +In order to obviate the effects of reflection from the internal side +surfaces if the prism, the wedge-shaped blocks of glass of which it is +built up may be made much broader than would otherwise be necessary; +the edges of this extra width are cut obliquely and suitably +blackened. + +The accompanying diagram (Fig. 8) represents a prism of cylindrical +external form constructed in this manner, the lower surface being that +of the incident light. In this the field amounts to 30 deg., and the +breadth is about double the length. + +[Illustration: Fig. 8.] + +Dr. Feussner remarks that a prism similar in some respects to his new +arrangement was devised in 1869 by M. Jamin (_Comptes Rendus_, +lxviii., 221), who used a thin plate of calc-spar inclosed in a cell +filled with bisulphide of carbon; and also by Dr. Zenker, who replaced +the liquid in M. Jamin's construction by wedges of flint glass. + +Among others, the carefully considered modifications of the Nicol +prism which have recently been devised by Prof. S.P. Thompson (_Phil. +Mag._, November, 1881, 349, and _Jour. R. Micros. Soc._, August, 1883, +575), and by Mr. R.T. Glazebrook (_Phil. Mag._, May, 1883, 352), do +not appear to have been known to Dr. Feussner. + +The following tabular view of different forms of polarizing prisms is +taken from the conclusion of Dr. Feussner's paper: + + ---------------------------------------+------+---------+------+------ + | |Inclina- |Ratio | + | |tion of | of | + | |section |length| + | |in regard| to | + | |to long |clear | + |Field.|axis. |width.|Fig. + ---------------------------------------+------+---------+------+------ + I. THE OLD POLARISING PRISMS. | deg. | deg. | | + 1. Nicol's prism. | 29 | 22 | 3.28 | 1 + 2. Shortened Nicol prism-- | | | | + a. Cemented with Canada balsam.| 13 | 25 | 2.83 | 2 + b. Cemented with copaiba " | 24 | 25 | 2.83 | 2 + 3. Nicol with perpendicular ends-- | | | | + a. With Canada balsam. | 20 | 15 | 3.73 | 3 + b. With cement of index of | | | | + refraction of 1.525. | 27 | 15 | 3.73 | 3 + 4. Foucault's prism. | 8 | 40 | 1.528| 4 + 5. Hartnack's prism-- | | | | + a. Original form. | 35 | 15.9 | 3.51 |5 _a b_ + b. With largest field. | 41.9 | 13.9 | 4.04 |5 _a a_ + c. With field of 30 deg.. | 30 | 17.4 | 3.19 |5 _a c_ + d. With field of 20 deg.. | 20 | 20.3 | 2.70 |5 _a d_ + 6. Glan's prism. | 7.9 | 50.3 | 0.831| 6 + | | | | + II. THE NEW POLARISING PRISM. | | | | + 1. With calc-spar: largest field. | 44 | 13.2 | 4.26 |5 _a a_ + 2. " field of 30 deg.. | 30 | 17.4 | 3.19 |5 _a c_ + 3. " field of 20 deg.. | 20 | 20.3 | 2.70 |5 _a d_ + 4. With nitrate of soda: | | | | + " largest field. | 54 | 16.7 | 3.53 |7 _a a_ + 5. " field of 30 deg.. | 30 | 24 | 2.25 |7 _a b_ + 6. " field of 20 deg.. | 20 | 27 | 1.96 |7 _a c_ + ---------------------------------------+------+---------+------+------ + +As an analyzing prism of about 6 mm. clear width, and 13.5 mm. long, +the new prism is stated by its inventor to be of the most essential +service, and it would certainly appear that the arrangement is rather +better adapted for small prisms than for those of considerable size. +Any means by which a beam of polarized light of large diameter--say 3 +to 31/2 inches--could be obtained with all the convenience of a Nicol +would be a real advance, for spar of sufficient size and purity for +such a purpose has become so scarce and therefore so valuable that +large prisms are difficult to procure at all. So far as an analyzer is +concerned, the experience of the writer of this notice would lead to +the opinion that improvements are to be looked for rather in the way +of the discovery of an artificial crystal which absorbs one of the +polarized rays than by further modifications depending upon total +reflection. The researches of Dr. Herapath on iodosulphate of quinine +(_Phil. Mag._, March, 1852, 161, and November, 1853, 346) are in this +direction; but crystals of the so-called herapathite require great +manipulative skill for their production. If these could be readily +obtained of sufficient size, they would be invaluable as analyzers. + +This opinion is supported by the existence of an inconvenience which +attends every form of analyzing prism. It is frequently, and +especially in projecting apparatus, required to be placed at the focus +of a system of lenses, so that the rays may cross in the interior of +the prism. This is an unfavorable position for a prismatic analyzer, +and in the case of a powerful beam of light, such as that from the +electric arc, the crossing of the rays within the prism is not +unattended with danger to the cementing substance, and to the surfaces +in contact with it. + +PHILIP R. SLEEMAN. + + * * * * * + + + + +ZIRCON. + +By F. STOLBA. + + +Finely ground zircon is quickly rendered soluble if fused with a +mixture of potassium borofluoride and potassium carbonate. The author +takes two parts of the former to three of the latter, and prepares an +intimate, finely divided mixture, which is kept ready for use. + +Of this mixture four parts are taken to one of zircon, thoroughly +mixed, and melted in a platinum crucible at a red heat. The mass fuses +readily, froths at first and gives off bubbles of gas, and flows then +quietly, forming a very fluid melt. If the zircon is finely ground, 15 +minutes are sufficient for this operation. The loss of weight is 16 +per cent., and is not notably increased on prolonged fusion. It +corresponds approximately to the weight of the carbonic anhydride +present in the potassium carbonate. + +As pungent vapors are given off during fusion, the operation should be +conducted under a draught hood. The activity of the mixture in +attacking zircon appears from the following experiment: Two zircon +crystals, each weighing 1/2 grm., were introduced into the melted +mixture and subjected to prolonged heat. In a short time they +decreased perceptibly in size; each of them broke up into two +fragments, and within an hour they were entirely dissolved. The melted +mass is poured upon a dry metal plate, and when congealed is thrown +into water. It is at once intersected with a number of fissures, which +facilitate pulverization. This process is the more necessary as the +unbroken mass is very slowly attacked by water even on prolonged +boiling. The powder is boiled in a large quantity of water so as to +remove everything soluble. There is obtained a faintly alkaline +solution and a sediment insoluble in water. From the filtrate alkalies +throw down zirconium hydroxide, free from iron. + +The portion insoluble in water is readily dissolved in hydrofluoric +acid, and is converted into zircon potassium fluoride. The chief bulk +of the zirconium is found in the aqueous solution in the state of +double fluorides. The platinum crucible is not in the least attacked +during melting. On the contrary, dirty platinum crucibles may be +advantageously cleaned by melting in them a little of the above +mentioned mixture. + +If finely divided zircon is boiled for a long time with caustic lye, +it is perceptibly attacked. It is very probable that in this manner +zircon might be entirely dissolved under a pressure of 10 atmospheres. + +Potassium borofluoride may be readily prepared from cryolite. +Crucibles of nickel seem especially well adapted for the fusion of +zircon in caustic alkalies.--_Ber. Boehm. Gesell. Wissenschaft; +Chem. News_. + + * * * * * + + + + +A PROCESS FOR MAKING WROUGHT IRON DIRECT FROM THE ORE.[1] + + [Footnote 1: A paper read at the Cincinnati Meeting of the + American Institute of Mining Engineers, by Willard P. Ward, A.M., + M.E., February, 1884.] + + +The numerous direct processes which have been patented and brought +before the iron masters of the world, differ materially from that now +introduced by Mr. Wilson. After a careful examination of his process, +I am convinced that Mr. Wilson has succeeded in producing good blooms +from iron ore, and I think that I am able to point out theoretically +the chief reasons of the success of his method. + +Without going deeply into the history of the metal, I may mention the +well known fact that wrought iron was extensively used in almost all +quarters of the globe, before pig or cast iron was ever produced. +Without entering into the details of the processes by which this +wrought iron was made, it suffices for my present purpose to say that +they were crude, wasteful, and expensive, so that they can be employed +to-day only in a very few localities favored with good and cheap ore, +fuel, and labor. + +The construction of larger furnaces and the employment of higher +temperatures led to the production of a highly carbonized, fusible +metal, without any special design on the part of the manufacturers in +producing it. This pig iron, however, could be used only for a few +purposes for which metallic iron was needed; but it was produced +cheaply and with little loss of metal, and the attempt to decarbonize +this product and bring it into a state in which it could be hammered +and welded was soon successfully made. This process of decarbonization, +or some modification of it, has successfully held the field against +all so-called, direct processes up to the present time. Why? Because +the old fashioned bloomeries and Catalan forges could produce blooms +only at a high cost, and because the new processes introduced failed +to turn out good blooms. Those produced were invariably "red short," +that is, they contained unreduced oxide of iron, which prevented the +contact of the metallic particles, and rendered the welding together +of these particles to form a solid bloom impossible. + +The process of puddling cast iron, and transforming it by +decarbonization into wrought iron, has, as everybody knows, been in +successful practical operation for many years, and the direct process +referred to so closely resembles this, that a short description of the +theory of puddling is not out of place here. + +The material operated on in puddling is iron containing from 21/2 to 4 +per cent. of carbon. During the first stage of the process this iron +is melted down to a fluid bath in the bottom of a reverberatory +furnace. Then the oxidation of the carbon contained in the iron +commences, and at the same time a fluid, basic cinder, or slag, is +produced, which covers a portion of the surface of the metal bath, and +prevents too hasty oxidation. This slag results from the union of +oxides of iron with the sand adhering to the pigs, and the silica +resulting from the oxidation of the silicon contained in the iron. + +This cinder now plays a very important part in the process. It takes +up the oxides of iron formed by the contact of the oxidizing flame +with the exposed portion of the metal bath, and at the same time the +carbon of the iron, coming in contact with the under surface of the +cinder covering, where it is protected from oxidizing influences, +reduces these oxides from the cinder and restores them to the bath in +metallic form. This alternate oxidation of exposed metal, and its +reduction by the carbon of the cast iron, continues till the carbon is +nearly exhausted, when the iron assumes a pasty condition, or "comes +to nature," as the puddlers call this change. The charge is then +worked up into balls, and removed for treatment in the squeezer, and +then hammered or rolled. In the Wilson process the conditions which we +have noted in the puddling operation are very closely approximated. +Iron ore reduced to a coarse sand is mixed with the proper proportion +of charcoal or coke dust, and the mixture fed into upright retorts +placed in the chimney of the puddling furnace. By exposure for 24 +hours to the heat of the waste gases from the furnace, in the presence +of solid carbon, a considerable portion of the oxygen of the ore is +removed, but little or no metallic iron is formed. The ore is then +drawn from the deoxidizer into the rear or second hearth of the +puddling furnace, situated below it, where it is exposed for 20 +minutes to a much higher temperature than that of the deoxidizer. Here +the presence of the solid carbon, mixed with the ore, prevents any +oxidizing action, and the temperature of the mass is raised to a point +at which the cinder begins to form. Then the charge is carried forward +by the workmen to the front hearth, in which the temperature of a +puddling furnace prevails. Here the cinder melts, and at the same +time the solid carbon reacts on the oxygen remaining combined with the +ore, and forms metallic iron; but by this time the molten cinder is +present to prevent undue oxidation of the metal formed, and solid +carbon is still present in the mixture to play the same role, of +reducing protoxide of iron from the cinder, as the carbon of the cast +iron does in the ordinary puddling process. I have said that the cast +iron used as the material for puddling contains about 3 per cent. of +carbon; but in this process sufficient carbon is added to effect the +reduction of the ore to a metallic state, and leave enough in the mass +to play the part of the carbon of the cast iron when the metallic +stage has been reached. + +It would be interesting to compare the Wilson with the numerous other +direct processes to which allusion has already been made, but there +have been so many of them, and the data concerning them are so +incomplete, that this is impossible. Two processes, however, the Blair +and the Siemens, have attracted sufficient attention, and are +sufficiently modern to deserve notice. In the Blair process a metallic +iron sponge was made from the ore in a closed retort, this sponge +cooled down in receptacles from which the air was excluded, to the +temperature of the atmosphere, then charged into a puddling furnace +and heated for working. In this way (and the same plan essentially has +been followed by other inventors), the metallic iron, in the finest +possible state of subdivision, is subjected to the more or less +oxidizing influences of the flame, without liquid slag to save it from +oxidation, and with no carbon present to again reduce the iron oxides +from the cinder after it is formed. The loss of metal is consequently +very large, but oxides of iron being left in the metal the blooms are +invariably "red short." + +In the Siemens process pieces of ore of the size of beans or peas, +mixed with lime or other fluxing material, form the charge, which is +introduced into a rotating furnace; and when this charge has become +heated to a bright-red heat, small coal of uniform size is added in +sufficient quantity to effect the reduction of the ore. + +The size of the pieces of the material employed prevents the intimate +mixture of the particles of iron with the particles of carbon, and +hence we would, on theoretical grounds, anticipate just what practice +has proved, viz., that the reduction is incomplete, and the resulting +metal being charged with oxides is red-short. In practice, blooms made +by this process have been so red-short that they could not be hammered +at all. + +It would be impracticable in this process to employ ore and carbon in +as fine particles as Wilson does, as a very large portion of the +charge would be carried off by the draught, and a sticking of the +material to the sides of the rotating furnace could scarcely be +avoided. I do not imagine that a division of the material into +anything like the supposed size of molecules is necessary; we know +that the graphitic carbon in the pig-iron employed in puddling is not +so finely divided, but it is much smaller particles than bean or pea +size, and by approximating the size of the graphite particles in pig +iron, Wilson has succeeded in obtaining good results. + +If we examine the utilization of the heat developed by the combustion +of a given quantity of coal in this process, and compare it with the +result of the combustion of an equivalent amount of fuel in a blast +furnace, we shall soon see the theoretical economy of the process. The +coal is burned on the grate of the puddling-furnace, to carbonic acid, +and the flame is more fully utilized than in an ordinary +puddling-furnace, for besides the ordinary hearth there is the second +or rear hearth, where additional heat is taken up, and then the +products of combustion are further utilized in heating the retorts in +which the ore is partly reduced. After this the heat is still further +utilized by passing it under the boilers for the generation of steam, +and the heat lost in the gases, when they finally escape, is very +small. In a blast furnace the carbon is at first burned only to +carbonic oxide, and the products of combustion issue mainly in this +form from the top of the furnace. Then a portion of the heat resulting +from the subsequent burning of these gases is pretty well utilized in +making steam to supply the power required about the works, but the +rest of the gas can only be utilized for heating the blast, and here +there is an enormous waste, the amount of heat returned to the furnace +by the heated blast being very small in proportion to the amount +generated by the burning of that portion of carbonic oxide expended in +heating it, and the gases escape from both the hot-blast and the +boilers at a high temperature. + +In the direct process under consideration the fuel burned is more +completely utilized than in the puddling process, to which the cast +iron from the blast furnace is subjected to convert it into wrought +iron. + +The economy claimed for this process, over the blast furnace and +puddling practice for the production of wrought iron, is that nearly +all the fuel used in the puddling operation is saved, and that with +about the same amount of fuel used in the blast furnace to produce a +ton of pig iron, a ton of wrought iron blooms can be made. I had no +opportunity of weighing the charges of ore and coal used, but I saw +the process in actual operation at Rockaway, N.J. The iron produced +was hammered up into good solid blooms, containing but little cinder. +The muck-bar made from the blooms was fibrous in fracture, and showed +every appearance of good iron. I am informed by the manager of the +Sanderson Brothers' steel works, at Syracuse, N.Y., that they +purchased blooms made by the Wilson process in 1881-1882, that _none_ +of them showed red-shortness, and that they discontinued their use +only on account of the injurious action of the titanium they contained +on the melting pots. These blooms were made from magnetic sands from +the Long Island and Connecticut coasts. + +[Illustration: NEW PROCESS FOR MAKING WROUGHT IRON FROM THE ORE.] + +The drawing given shows the construction of the furnace employed. I +quote from the published description: + + "The upper part, or deoxidizer, is supported on a strong + mantel plate resting on four cast iron columns. + + "The retorts and flues are made entirely of fire-brick, from + special patterns. The outside is protected by a wrought iron + jacket made of No. 14 iron. The puddling furnace is of the + ordinary construction, except in the working bottom, which is + made longer to accommodate two charges of ore, and thus + utilize more of the waste heat in reducing the ore to metallic + iron. + + "The operation of the furnace is as follows: The pulverized + ore is mixed with 20 per cent. of pulverized charcoal or coke, + and is fed into an elevator which discharges into the hopper + on the deoxidizer leading into the retorts marked C. These + retorts are proportioned so that they will hold ore enough to + run the puddling furnace 24 hours, the time required for + perfect deoxidation. After the retorts are filled, a fire is + started in the furnace, and the products of combustion pass up + through the main flue, or well, B, where they are deflected by + the arch, and pass out through suitable openings, as indicated + by arrows, into the down-takes marked E, and out through an + annular flue, where they are passed under a boiler. + + "It will be noticed that the ore is exposed to the waste heat + on three sides of the retorts, and owing to the great surface + so exposed, the ore is very thoroughly deoxidized, and reduced + in the retorts before it is introduced into the puddling + furnace for final reduction. The curved cast iron pipes marked + D are provided with slides, and are for the purpose of + introducing the deoxidized ore into the second bottom of the + furnace. As before stated, the furnace is intended to + accommodate two charges of ore, and as fast as it is balled up + and taken out of the working bottom, the charge remaining in + the second bottom is worked up in the place occupied by the + first charge, and a _new_ charge is introduced. As fast as the + ore is drawn out from the retorts the elevator supplies a new + lot, so that the retorts are always filled, thus making the + process continuous." + +The temperature of the charge in the deoxidizer is from 800 deg. to 1,000 deg. +F.--_Amer. Engineer._ + + * * * * * + + + + +SOME REMARKS ON THE DETERMINATION OF HARDNESS IN WATERS. + +By HERBERT JACKSON. + + +Having had occasion some short time ago to examine a hard water which +owed half its hardness to salts of magnesium, I noticed that the soap +test, applied in the usual way, gave a result which differed very much +from that obtained by the quantitative estimation of calcium and +magnesium. A perfectly normal lather was obtained when soap had been +added in quantities sufficient to neutralize 14 deg. of hardness, whereas +the water contained salts of calcium and magnesium equivalent, on +Clark's scale, to a hardness of 27 deg.. + +Although I was aware that similar observations had been made before, I +thought that it might be useful to determine the conditions under +which the soap test could not be depended upon for reliable results. + +I found with waters containing calcium or magnesium alone that, +whenever salts of either of these metals were in solution in +quantities sufficient to give 23 deg. of hardness on Clark's scale, no +dependence could be placed upon the results given by the soap test. In +the case of waters containing salts of both calcium and magnesium, I +found that if the salts of the latter metal were in solution in +quantities sufficient to give more than 10 deg. of hardness, no evidence +could be obtained of their presence so long as the salts of calcium in +the same water exceeded 6 deg.; in such a case a perfect and permanent +lather was produced when soap had been added equivalent to 7 deg. of +hardness. + +If any water be diluted so as to reduce the proportions of the salts +of calcium and magnesium below those stated above, perfectly reliable +results will of course be obtained. + +Instead of dilution I found that heating the water to about 70 deg. C. was +sufficient to cause a complete reaction between the soap and the salts +of calcium and magnesium, even if these were present in far larger +quantities than any given here. + +The experiments so far had all been made with a solution of Castile +soap of the strength suggested by Mr. Wanklyn in his book on "Water +Analysis." My attention was next directed to the use of any one of the +compounds of which such a soap is composed. I commenced with sodium +oleate, and found that by employing this substance in a moderately +pure condition, perfectly reliable results could be obtained in very +hard waters without the trouble of either diluting or heating. I was +unable to try sodium stearate directly because of the slight +solubility of this substance in cold water or dilute alcohol; but I +found that a mixture of sodium oleate and stearate behaved in exactly +the same manner as the Castile soap. + +I am not prepared at present to state the exact reaction which takes +place between salts of calcium and magnesium and a compound soap +containing sodium oleate and stearate. I publish these results because +I have not noticed anywhere the fact that some waters show a greater +hardness with soap when their temperatures approach the boiling point +than they do at the average temperature of the air, it being, I +believe, the ordinary impression that cold water wastes more soap than +hot water before a good and useful lather can be obtained, whereas +with very many waters the case is quite the reverse. Neither am I +aware at present whether it is well known that the use of sodium +oleate unmixed with sodium stearate dispenses with the process of +dilution even in very hard waters.--_Chem. News._ + + * * * * * + + + + +THE DENSITY AND PRESSURE OF DETONATING GAS MIXTURES. + + +MM. Berthelot and Vielle have recently been studying the influence of +the density of detonating gaseous mixtures upon the pressure +developed. The measure of pressure developed by the same gaseous +system, taken under two initial states of different density to which +the same quantity of heat is communicated, is an important matter in +thermodynamics. If the pressures vary in the same ratio as the +densities, we may conclude, independently of all special hypotheses on +the laws of gases, first, that the specific heat of the system is +independent of its density (that is to say, of its initial pressure), +and depends only on the absolute temperature, whatever that may mean; +and secondly, that the relative variation of the pressure at constant +volume, produced by the introduction of a determinate quantity of +heat, is also independent of the pressure, and a function only of the +temperature. Lastly, the pressure itself will vary proportionally with +the absolute temperature, as defined by the theory of a perfect gas, +and will serve to determine it. MM. Berthelot and Vielle operated with +a bomb, at first kept at ordinary temperatures in the air, and +afterward heated in an oil bath to 153 deg. Cent. They also employed +isomeric mixtures of the gases; methylic ether, cyanogen, hydrogen, +acetylene, and other gases were experimented upon, and the general +conclusions are as follows: 1. The same quantity of heat being +furnished to a gaseous system, the pressure of the system varies +proportionally to the density of the system. 2. The specific heat of +the gas is sensibly independent of the density as well toward very +high temperatures as about deg. Cent. This is all true for densities +near to those that the gas possesses cold under normal pressure, and +which varied in the experiment to double the original value. 3. The +pressure increases with the quantity of heat furnished to the same +system. 4. The apparent specific heat increases parallel with this +quantity of heat. These conclusions are independent of all hypotheses +on the nature and laws of gases, and were simply drawn from the +experiments in question. + + * * * * * + + + + +TURKISH BATHS FOR HORSES. + + +The Turkish bath has become an established institution in this +country; men of all classes now use it for sanitary as well as +remedial purposes. Athletes of various descriptions find it invaluable +in "training," and all the distinguished jockeys and light weights +keep themselves in condition by its use. + +It was thought probable that what was good for man might also be good +for the horse, and the fact has been proved. Messrs. Pickford, the +eminent carriers, in their hospital for horses at Finchley, have had a +bath in operation over eleven years, and find the horses derive great +benefit from its use. The bath is put in operation three days a week, +and is administered to over twenty horses in this time. The value of +the bath having been thus proved, it is rather strange that it has not +been more generally adopted by the large carrying firms. However, the +Great Northern Railway Company at their new hospital for horses at +Totteridge, are erecting a very complete Turkish bath. It consists of +three rooms. First, a large wash room or grooming room, from which is +entered the first hot room, or tepidarium, from 140 deg. to 150 deg. Fahr.; +from this room, the horse, after being thoroughly acclimated, can, if +necessary, pass to the hottest room, or calidarium, from 160 deg. to 170 deg. +Fahr., and without any turning round can pass on into the grooming and +washing room again. This last room is slightly heated from the two +other rooms, and in each are stocks in which the animal can he +fastened if required. The heating is done most economically by +Constantine's convoluted stove, and thorough ventilation is secured +from the large volume of hot air constantly supplied, which passes +through the baths, and as it becomes vitiated is drawn off by +specially designed outlets. The wash room is supplied with hot and +cold water, which can, of course, be mixed to any required +temperature.--_Building News._ + +[Illustration] + + || + |+-------------------------------------------------------+ + |+-------------------++---__-------____------------__---+| + || ||FOUL AIR FOUL AIR FOUL AIR|| + || || || + || || || + || || ============== || + || / / || + || / / 1ST HOT ROOM || + || / / || + || / / ============== || + || || || + / =======+ || || + / || || CURTAIN|| + WASHING ROOM|| |+=========================== =|| + \ || || || + \ =======+ || || + || || || + || \ \ ============== || + || \ \ || + || \ \ 2ND HOT ROOM || FRESH + || \ \ || / AIR + || || ============== ||== + || || +======|| | + || || | WARM || | + || ||FOUL AIR FOUL AIR| AIR || | + |+-------------------++---__--+===+---------__----------+|== + |+----------------------------|_|_|---------------------+| + || | ||||| | || + || | ||||| | || + || |============ S T O K E R Y || + || || || + || || || + || |+-----------------------------------|| + +-------------------------------------+ + + + * * * * * + + + + +MIRYACHIT, A NEWLY DESCRIBED DISEASE OF THE NERVOUS SYSTEM, AND +ITS ANALOGUES.[1] + + [Footnote 1: Read before the New York Neurological Society, + February 5, 1884.] + +By WILLIAM A. HAMMOND, M.D., Surgeon-General, U.S. Army (Retired +List); Professor of Diseases of the Mind and Nervous System in the New +York Post-Graduate Medical School and Hospital. + + +In a very interesting account of a journey from the Pacific Ocean +through Asia to the United States, by Lieutenant B.H. Buckingham and +Ensigns George C. Foulk and Walter McLean,[2] United States navy, I +find an affection of the nervous system described which, on account of +its remarkable characteristics, as well as by reason of certain known +analogies, I think should be brought to the special notice of the +medical profession. I quote from the work referred to, the following +account of this disease. The party is on the Ussuri River not far from +its junction with the Amur in Eastern Siberia: "While we were walking +on the bank here we observed our messmate, the captain of the general +staff (of the Russian army), approach the steward of the boat +suddenly, and, without any apparent reason or remark, clap his hands +before his face; instantly the steward clapped _his_ hands in the same +manner, put on an angry look, and passed on. The incident was somewhat +curious, as it involved a degree of familiarity with the steward +hardly to have been expected. After this we observed a number of queer +performances of the steward, and finally comprehended the situation. +It seemed that he was afflicted with a peculiar mental or nervous +disease, which forced him to imitate everything suddenly presented to +his senses. Thus, when the captain slapped the paddle-box suddenly in +the presence of the steward, the latter instantly gave it a similar +thump; or, if any noise were made suddenly, he seemed compelled +against his will to imitate it instantly, and with remarkable +accuracy. To annoy him, some of the passengers imitated pigs grunting, +or called out absurd names; others clapped their hands and shouted, +jumped, or threw their hats on the deck suddenly, and the poor +steward, suddenly startled, would echo them all precisely, and +sometimes several consecutively. Frequently he would expostulate, +begging people not to startle him, and again would grow furiously +angry, but even in the midst of his passion he would helplessly +imitate some ridiculous shout or motion directed at him by his +pitiless tormenters. Frequently he shut himself up in his pantry, +which was without windows, and locked the door, but even there he +could be heard answering the grunts, shouts, or pounds on the bulkhead +outside. He was a man of middle age, fair physique, rather intelligent +in facial expression, and without the slightest indication in +appearance of his disability. As we descended the bank to go on board +the steamer, some one gave a loud shout and threw his cap on the +ground; looking about for the steward, for the shout was evidently +made for his benefit, we saw him violently throw his cap, with a +shout, into a chicken-coop, into which he was about to put the result +of his foraging expedition among the houses of the stanitza. + + [Footnote 2: "Observations upon the Korean Coast, Japanese-Korean + Ports, and Siberia, made during a journey from the Asiatic + Station to the United States, through Siberia to Europe, June 3 + to September 8, 1882." Published by the United States Navy + Department, Washington, 1883, pp. 51.] + +"We afterward witnessed an incident which illustrated the extent of +his disability. The captain of the steamer, running up to him, +suddenly clapping his hands at the same time, accidentally slipped and +fell hard on the deck; without having been touched by the captain, the +steward instantly clapped his bands and shouted, and then, in +powerless imitation, he too fell as hard and almost precisely in the +same manner and position as the captain. In speaking of the steward's +disorder, the captain of the general staff stated that it was not +uncommon in Siberia; that he had seen a number of cases of it, and +that it was commonest about Yakutsk, where the winter cold is extreme. +Both sexes were subject to it, but men much less than women. It was +known to Russians by the name of 'miryachit'". + +So far as I am aware--and I have looked carefully through several +books of travel in Siberia--no account of this curious disease has +been hitherto published. + +The description given by the naval officers at once, however, brings +to mind the remarks made by the late Dr. George M. Beard, before the +meeting of the American Neurological Association in 1880, relative to +the "Jumpers" or "Jumping Frenchmen" of Maine and northern New +Hampshire.[3] + + [Footnote 3: "Journal of Nervous and Mental Diseases," vol. vii., + 1880, p. 487.] + +In June, 1880, Dr. Beard visited Moosehead Lake, found the "Jumpers," +and experimented with them. He ascertained that whatever order was +given them was at once obeyed. Thus, one of the jumpers who was +sitting in a chair with a knife in his hand was told to throw it, and +he threw it quickly, so that it stuck in a beam opposite; at the same +time he repeated the order to throw it with a cry of alarm not unlike +that of hysteria or epilepsy. He also threw away his pipe, which he +was filling with tobacco, when he was slapped upon the shoulder. Two +jumpers standing near each other were told to strike, and they struck +each other very forcibly. One jumper, when standing by a window, was +suddenly commanded by a person on the other side of the window to +jump, and he jumped up half a foot from the floor, repeating the +order. When the commands are uttered in a quick, loud voice, the +jumper repeats the order. When told to strike he strikes, when told to +throw he throws whatever he may happen to have in his hand. Dr. Beard +tried this power of repetition with the first part of the first line +of Virgil's "AEneid" and the first part of the first line of Homer's +"Iliad," and out-of-the-way words of the English language with which +the jumper could not be familiar, and he repeated or echoed the sound +of the word as it came to him in a quick, sharp voice, at the same +time he jumped, or struck, or threw, or raised his shoulders, or made +some other violent muscular motion. They could not help repeating the +word or sound that came from the person that ordered them, any more +than they could help striking, dropping, throwing, jumping, or +starting; all of these phenomena were indeed but parts of the general +condition known as jumping. It was not necessary that the sound should +come from a human being; any sudden or unexpected noise, as the +explosion of a gun or pistol, the falling of a window, or the slamming +of a door--provided it was unexpected and loud enough--would cause +these jumpers to exhibit some one or all of these phenomena. One of +these jumpers came very near cutting his throat, while shaving, on +hearing a door slam. They had been known to strike their fists against a +red-hot stove, to jump into the fire and into water. They could not +help striking their best friend if near them when ordered. The noise +of a steam whistle was especially obnoxious to them. One of these +jumpers, when taking some bromide of sodium in a tumbler, was told to +throw it, and he dashed the tumbler upon the floor. It was dangerous +to startle them in any way when they had an ax or an knife in their +hands. All of the jumpers agreed that it tired them to be jumped, and +they dreaded it, but they were constantly annoyed by their companions. + +From this description it will at once, I think, be perceived that +there are striking analogies between "miryachit" and this disorder of +the "Jumping Frenchmen" of Maine. Indeed, it appears to me that, if +the two affections were carefully studied, it would be found that they +were identical, or that, at any rate, the phenomena of the one could +readily be developed into those of the others. It is not stated that +the subjects of miryachit do what they are told to do. They require an +example to reach their brains through the sense of sight or that of +hearing, whereas the "Jumpers" do not apparently perform an act which +is executed before them, but they require a command. It seems, +however, that a "Jumper" starts whenever any sudden noise reaches his +ears. + +In both classes of cases a suggestion of some kind is required, and +then the act takes place independently of the will. There is another +analogous condition known by the Germans as _Schlaftrunkenheit_, and +to English and American neurologists as somnolentia, or +sleep-drunkenness. In this state an individual, on being suddenly +awakened, commits some incongruous act of violence, ofttimes a murder. +Sometimes this appears to be excited by a dream, but in others no such +cause could be discovered. + +Thus, a sentry fell asleep during his watch, and, being suddenly +aroused by the officer in command, attacked the latter with his sword, +and would have killed him but for the interposition of the bystanders. +The result of the medical examination was that the act was +involuntary, being the result of a violent confusion of mind +consequent upon the sudden awaking from a profound sleep. Other cases +are cited by Wharton and Stille in their work on medical +jurisprudence, by Hoffbauer, and by myself in "Sleep and its +Derangements." + +The following cases among others have occurred in my own experience: + +A gentleman was roused one night by his wife, who heard the +street-door bell ring. He got up, and, without paying attention to +what she said, dragged the sheets off of the bed, tore them hurriedly +into strips, and proceeded to tie the pieces together. She finally +succeeded in bringing him to himself, when he said he had thought the +house was on fire, and he was providing means for their escape. He did +not recollect having had any dream of the kind, but was under the +impression that the idea had occurred to him at the instant of his +awaking. + +Another was suddenly aroused from a sound sleep by the slamming of a +window-shutter by the wind. He sprang instantly from his bed, and, +seizing a chair that was near, hurled it with all his strength against +the window. The noise of the breaking of glass fully awakened him. He +explained that he imagined some one was trying to get into the room +and had let his pistol fall on the floor, thereby producing the noise +which had startled him. + +In another case a man dreamed that he heard a voice telling him to +jump out of the window. He at once arose, threw open the sash, and +jumped to the ground below, fortunately only a distance of about ten +feet, so that he was not injured beyond receiving a violent shock. +Such a case as this appears to me to be very similar to those +described by Dr. Beard in all its essential aspects. + +A few years ago I had a gentleman under my charge who would attempt to +execute any order given him while he was asleep by a person +whispering into his ear. Thus, if told in this way to shout, he +shouted as loud as he could; if ordered to get up, he at once jumped +from the bed; if directed to repeat certain words, he said them, and +so on. + +I am not able to give any certain explanation of the phenomena of +miryachit or of the "Jumpers," or of certain of those cases of +sleep-drunkenness which seem to be of like character. But they all +appear to be due to the fact a motor impulse is excited by perceptions +without the necessary concurrence of the volition of the individual to +cause the discharge. They are, therefore, analogous to reflex actions, +and especially to certain epileptic paroxysms due to reflex +irritations. It would seem as though the nerve cells were very much in +the condition of a package of dynamite or nitro glycerin, in which a +very slight impression is sufficient to effect a discharge of nerve +force. They differ, however, from the epileptic paroxysm in the fact +that the discharge is consonant with the perception--which is in these +cases an irritation--and is hence an apparently logical act, whereas +in epilepsy the discharge is more violent, is illogical, and does not +cease with the cessation of the irritation. + +Certainly the whole subject is of sufficient importance to demand the +careful study of competent observers. + + * * * * * + + + + +THE GUM DISEASE IN TREES.[1] + + [Footnote 1: Communicated to the _Medical Times_ by Sir James Paget.] + + +An essay by Dr. Beijerinck, on the contagion of the gum disease in +plants, lately published by the Royal Academy of Sciences at +Amsterdam, contains some useful facts. The gum disease (_gummosis, +gum-flux)_ is only too well known to all who grow peaches, apricots, +plums, cherries, or other stone fruits. A similar disease produces gum +arabic, gum tragacanth, and probably many resins and gum resins. It +shows itself openly in the exudation of thick and sticky or hard and +dry lumps of gum, which cling on branches of any of these trees where +they have been cracked or wounded through the bark. Dr. Beijerinck was +induced to make experimental inoculations of the gum disease by +suspicions that, like some others observed in plants, it was due to +bacteria. He ascertained that it is in a high degree contagious, and +can easily be produced by inserting the gum under the edge of a wound +through the bark of any of the trees above named. The observation that +heated or long boiled pieces of gum lose their contagious property +made it most probable that a living organism was concerned in the +contagions; and he then found that only those pieces of the gum +conveyed contagion in which, whether with or without bacteria, there +were spores of a relatively highly organized fungus, belonging to the +class of Ascomycetes; and that these spores, inserted by themselves +under the bark, produced the same pathological changes as did the +pieces of gum. The fungus thus detected, was examined by Professor +Oudemans, who ascertained it to be a new species of Coryneum, and has +named it _Coryneum Beijerincki_. The inoculation experiments are best +made by means of incisions through the bark of young branches of +healthy peach trees or cherry trees, and by slightly raising the cut +edge of the bark and putting under it little bits of gum from a +diseased tree of the same kind. In nearly every instance these wounds +become the seats of acute gum disease, while similar wounds in the +same or other branches of the same tree, into which no gum is +inserted, remain healthy, unless, by chance, gum be washed into them +during rain. The inoculation fails only when the inserted pieces of +gum contain no Coryneum. By similar inoculations similar diseases can +be produced in plum, almond, and apricot trees, and with the gum of +any one of these trees any other can be infected; but of many other +substances which Beijerinck tried, not one produced any similar +disease. The inoculation with the gum is commonly followed by the +death of more or less of the adjacent structures; first of the bark, +then of the wood. Small branches or leaf stalks thus infected in +winter, or in many places at the same time, may be completely killed; +but, in the more instructive experiments the first symptom of the gum +disease is the appearance of a beautiful red color around the wound. +It comes out in spots like those which often appear spontaneously on +the green young branches of peach trees that have the gum disease; and +in these spots it is usual to find Coryneum stromata or mycelium +filaments. The color is due to the formation of a red pigment in one +or more of the layers of the cells of the bark. But in its further +progress the disease extends beyond the parts at which the Coryneum or +any structures derived from it can be found; and this extension, +Beijerinck believes, is due to the production of a fluid of the nature +of a ferment, produced by the Coryneum, and penetrating the adjacent +structures. This, acting on the cell walls, the starch granules, and +other constituents of the cells, transforms them into gum, and even +changes into gum the Coryneum itself, reminding the observer of the +self-digestion of a stomach. + +In the cells of the cambium, the same fluid penetrating unites with +the protoplasm, and so alters it that the cells produced from it form, +not good normal wood, but a morbid parenchymatous structure. The cells +of this parenchyma, well known among the features of gum disease, are +cubical or polyhedral, thin walled, and rich in protoplasm. This, in +its turn, is transformed into gum, such as fills the gum channels and +other cavities found in wood, and sometimes regarded as gum glands. +And from this also the new ferment fluid constantly produced, and +tracking along the tissues of the branches, conveys the Coryneum +infection beyond the places in which its mycelium can be found. + + * * * * * + + + + +DRINKSTONE PARK. + + +Drinkstone has long been distinguished on account of the successful +cultivation of remarkable plants. It lies some eight miles southeast +from Bury St. Edmund's, and is the seat of T.H. Powell, Esq. The +mansion or hall is a large old-fashioned edifice, a large portion of +its south front being covered by a magnificent specimen of the +Magnolia grandiflora, not less than 40 feet in height, while other +portions of its walls are covered with the finest varieties of +climbing roses and other suitable plants. The surrounding country, +although somewhat flat, is well wooded, and the soil is a rich loam +upon a substratum of gravel, and is consequently admirably suited to +the development of the finer kinds of coniferous and other ornamental +trees and shrubs, so that the park and grounds contain a fine and well +selected assortment of such plants. + +[Illustration: THE SNOWFLAKE, LEUCOJUM VERNUM, AT DRINKSTONE +PARK.] + +Coniferous trees are sometimes considered as out of place in park +scenery; this, however, does not hold good at Drinkstone, where Mr. +Powell has been displayed excellent taste in the way of improving the +landscape and creating a really charming effect by so skillfully +blending the dressed grounds with the rich greensward of the park +that it is not easy to tell where the one terminates or the other +commences. + +The park, which covers some 200 acres, including a fine lake over +eight acres in extent, contains also various large groups or clumps of +such species as the Sequoia gigantea, Taxodium sempervirens, Cedres +deodora, Picea douglasii, Pinsapo, etc., interspersed with groups of +ornamental deciduous trees, producing a warm and very pleasing effect +at all seasons of the year. Among species which are conspicuous in the +grounds are fine, well-grown examples of Araucaria imbricata, some 30 +feet high; Cedrus deodara, 60 feet in height; Abies pinsapo, 40 feet; +and fine specimens of Abies grandis, A. nobilis, and A. nordmanniana, +etc., together with Abies albertiana or mertensiana, a fine, +free-growing species; also Libocedrus gigantea, Thuiopsis borealis, +Thuia lobbii, Juniperus recurva, Taxas adpressa, fine plants; with +fine golden yews and equally fine examples of the various kinds of +variegated hollies, etc. + +[Illustration: ODONTOGLOSSUM ROSSI MAJOR VAR. RUBESCENS, AT DRINKSTONE +PARK.] + +Particular attention is here paid to early spring flowers. Drinkstone +is also celebrated as a fruit growing establishment, more particularly +as regards the grape vine; the weight and quality of the crops of +grapes which are annually produced here are very remarkable.--_The +Gardeners' Chronicle._ + + * * * * * + + + + +ON THE CHANGES WHICH TAKE PLACE IN THE CONVERSION OF HAY INTO +ENSILAGE. + +By FREDK. JAS. LLOYD, F.C.S., Lecturer on Agriculture, King's +College. + + +The recently published number of the _Royal Agricultural Society's +Journal_ contains some information upon the subject of silage which +appears to me of considerable interest to those chemists who are at +present investigating the changes which take place in the conversion +of grass into silage. The data[1] are, so far as I know, unique, and +though the analytical work is not my own, yet it is that of an +agricultural chemist, Mr. A. Smetham, of Liverpool, whose work I know +from personal experience to be thoroughly careful and reliable. I have +therefore no hesitation in basing my remarks upon it. + + [Footnote 1: _Royal Agricultural Society's Journal_, vol. xx., + part i., pp. 175 and 380.] + +We have here for the first time an accurate account of the quantity of +grass put into a silo, of the quantity of silage taken out, and of the +exact composition both of the grass and resulting silage. I desire +merely to place myself in the position of, so to speak, a "chemical +accountant." + +The ensilage has been analyzed at three depths, or rather in three +layers, the first being 1 foot, the second 1 ft. to 1 ft. 6 in., and +the third 1 ft. 6 in. to 2 ft. from the bottom of the silo. By +doubling the figures of the bottom layer analysis, adding these to the +second and third layer analysis, and dividing by 4, we obtain a fair +representation of the average composition of the silage taken +throughout the silo, for by so doing we obtain the average of the +analyses of each 6-inch layer of silage. The results of the analyses +are as follows, calculated on the dry matter. The moisture was +practically the same, being 70.48 per cent, in the grass and 72.97 in +the silage. + + + _Composition of Grass and Silage (dried at 100 deg.C.)._ + + Grass. Ensilage. + Fat (ether extract) 2.80 5.38 + Soluble albuminous compounds 3.06 5.98 + Insoluble albuminous compounds 6.94 3.77 + Mucilage, sugar, and extractives, etc. 11.65 4.98 + Digestible fiber 36.24 33.37 + Indigestible woody fiber 32.33 31.79 + ------- ------- + 93.02 85.27 + Soluble mineral matters 5.24 12.62 + Insoluble mineral matters 1.74 2.11 + ------- ------- + 100.00 100.00 + +The striking difference in the mineral matter of the grass and silage +I will merely draw attention to; it is not due to the salt added to +the silage. I may say, however, that other analysts and I myself have +found similar striking differences. For instance, Prof. Kinch[2] +found in grass 8.50 per cent. mineral matter, in silage 10.10 per +cent., which, as be points out, is equivalent, to a "loss of about 18 +per cent. of combustible constituents"--a loss which we have no proof +of having taken place. In Mr. Smetham's sample the loss would have to +be 50 per cent., which did not occur, and in fact is not possible. +What is the explanation? + + [Footnote 2: _Journ. Chem. Society_, March, 1884, p. 124.] + +I am, however, considering now the organic constituents. Calculating +the percentages of these in the grass and silage, we obtain the +following figures: + + _Percentage Composition of Organic Compounds._ + + Grass. Ensilage. + Fat (ether extract) 3.01 6.31 + Soluble albuminous compounds 8.29} {7.01 + }10.75 11.43{ + Insoluble " " 7.46} {4.42 + + Mucilage, sugar, and extractives 12.52 5.84 + Digestible fiber 38.96 39.14 + Indigestible woody fiber 34.76 37.28 + ------- ------- + 100.00 100.00 + +The difference in the total nitrogen in the grass and silage is equal +to 0.68 per cent. of albuminoids. Practically it is a matter of +impossibility that the nitrogen could have increased in the silo, and +it will be a very safe premise upon which to base any further +calculations that the total amount of nitrogen in the silage was +identical with that in the grass. There may have been a loss, but +that is not yet proved. Arguing then upon the first hypothesis, it is +evident that 100 parts of the organic matters of silage represent more +than 100 parts of the organic matter of grass, and by the equation we +obtain 10.75:11.43 :: 100:106 approximately. If now we calculate the +composition of 106 parts organic matter of grass, it will represent +exactly the organic matter which has gone to form 100 parts of that +present in silage. + +The following table gives these results, and also the loss or gain in +the various constitutents arising from the conversion into silage: + + _Organic Matter_. + + In 106 pts. In 100 pts. Loss or + Grass. Silage. Gain. + +Fat (ether extract) 3.19 6.31 +3.12 +Soluble albuminous compounds 3.49 7.01 +3.52 +Insoluble " " 7.91 4.42 -3.49 +Mucilage 13.27 5.84 -7.43 +Digestible Fiber 41.30 39.14 -2.16 +Indigestible woody fiber 36.84 37.28 +0.44 + ------- ------- + 106.00 100.00 + +These calculations show, provided my reasoning be correct, that the +chief changes which take place are in the albuminous compounds, which +has already been pointed out by Professors Voelcker, Kinch, and +others; and in the starch, gum, mucilage, sugar, and those numerous +bodies termed extractives, which was to be expected. But they show +most conclusively that the "decrease in the amount of indigestible +fiber and increase in digestible" so much spoken of is, so far as our +present very imperfect methods of analyzing these compounds permit us +to judge, a myth; and I have not yet found any sufficient evidence to +support this statement. A loss, then, of 6 parts of organic matter out +of every 106 parts put into the silo has in this instance taken place, +due chiefly to the decomposition of starch, sugar, and mucilage, etc. +And as the grass contained 70 parts of water when put into the silo, +the total loss would only be 1.7 per cent. of the total weight. This +theoretical deduction was found by practical experience correct, for +Mr. Smith, agent to Lord Egerton, upon whose estate this silage was +made, in his report to Mr. Jenkins says the "actual weight out of the +silo corresponds exactly with the weight we put into the same." + +In my judgment these figures are of interest to the agricultural +chemist for many reasons. First, they will clear the ground for future +workers and eliminate from their researches what would have greatly +complicated them--changes in the cellulose bodies. + +Secondly, they are of interest because our present methods of +distinguishing between and estimating digestible and indigestible +fiber is most rough, and probably inaccurate, and may not in the least +represent the power of an animal--say a cow--to digest these various +substances; and most of us know that when a new method of analysis +becomes a necessity, a new method is generally discovered. Lastly, +they are of interest to the agriculturist, for they point out, I +believe for the first time, the exact amount of loss which grass--or +at least one sample--has undergone in conversion into silage, and also +that much of the nitrogenous matter is changed, and so far as we know +at present, lost its nutritive value. This, however, is only comparing +silage with grass. What is wanted is to compare silage with hay--both +made out of the same grass. Then, and then only, will it be possible +to sum up the relative advantages or disadvantages of the two methods +of preserving grass as food for cattle.--_Chem. News_. + + * * * * * + + + + +THE ILLUMINATING POWER OF ETHYLENE. + + +Dr. Percy Frankland has obtained results which may be thus briefly +summarized: (1.) That pure ethylene, when burnt at the rate of 5 cubic +feet per hour from a Referee's Argand burner, emits a light of 68.5 +standard candles. (2.) That the illuminating power of equal volumes of +mixtures of ethylene with either hydrogen carbonic oxide or +marsh-gas is less than that of pure ethylene. (3.) That when the +proportion of ethylene in such mixtures is above 63 per cent. the +illuminating power of the mixture is but slightly affected by the +nature of the diluent. When, on the other hand, the proportion of +ethylene in such mixtures is low, the illuminating power of the +mixture is considerably the highest when marsh-gas is the diluent, and +the lowest when the ethylene is mixed with carbonic oxide. (4.) That +if 5 cubic feet of ethylene be uniformly consumed irrespectively of +the composition of the mixture, the calculated illuminating power is +in every case equal to or actually greater than that of pure ethylene +until a certain degree of dilution is attained. This intrinsic +luminosity of ethylene remains almost constant when the latter is +diluted with carbonic oxide, until the ethylene forms only 40 per +cent. of the mixture, after which it rapidly diminishes to zero when +the ethylene forms only 20 per cent. of the mixture. When the ethylene +is diluted with hydrogen, its intrinsic luminosity rises to 81 candles +when the ethylene constitutes 30 per cent. of the mixture, after which +it rapidly falls to zero when the ethylene amounts to only 10 per +cent. In the case of mixtures of ethylene and marsh-gas, the intrinsic +luminosity of the former is augmented with increasing rapidity as the +proportion of marsh gas rises, the intrinsic luminosity of ethylene, +in a mixture containing 10 per cent. of the latter, being between 170 +and 180 candles. + + * * * * * + + + + +DIFFRACTION PHENOMENA DURING TOTAL SOLAR ECLIPSES.[1] + + [Footnote 1: A paper read before the American Astronomical + Society, May 5, 1884.] + +By G.D. Hiscox. + + +The reality of the sun's corona having been cast in doubt by a leading +observer of the last total eclipse, who, from the erratic display +observed in the spectroscope, has declared it a subjective phenomenon +of diffraction, has led me to an examination and inquiry as to the +bearing of an obscurely considered and heretofore only casually +observed phenomenon seen to take place during total solar eclipses. +This phenomenon, it seems to me, ought to account for, and will +possibly satisfy, the spectroscopic conditions observed just before, +during, and after totality; which has probably led to the epithet used +by some leading observers--"the fickle corona." The peculiar +phenomenon observed in the spectroscope, the flickering bands or lines +of the solar spectrum flashing upon and across the coronal spectrum, +has caused no little speculation among observers. + +The diffraction or interference bands projected by the passage of a +strong beam of light by a solid body, as discovered long since by +Grimaldi, and investigated later by Newton, Fresnel, and Fraunhofer, +are explained and illustrated in our text books; but the grand display +of this phenomenon in a total solar eclipse, where the sun is the +source of light and the moon the intercepting body, has as yet +received but little attention from observers, and is not mentioned to +my knowledge in our text books. + +In the instructions issued from the United States Naval Observatory +and the Signal Office at Washington for the observation of the eclipse +of July 29, 1878, attention was casually directed to this phenomenon, +and a few of the observers at Pike's Peak, Central City, Denver, and +other places have given lucid and interesting descriptions of the +flight of the diffraction bands as seen coursing over the face of the +earth at the speed of the moon's shadow, at the apparent enormous +velocity of thirty-three miles per minute, or fifty times the speed of +a fast railway train. + +From a known optical illusion derived from interference or fits of +perception, as illustrated in quick moving shadows, this great speed +was not realized to the eye, as the observed motion of these shadows +was apparently far less rapid than their reality. + +The ultra or diffraction bands outside of the shadow were distinctly +seen and described by Mr. J.E. Keeler at Central City, both before and +after totality. He estimates the shadow bands at 8 inches wide and 4 +feet apart. + +Professor E.S. Holden, also at Central City, estimated the dark bands +as about 3 feet apart, and variable. + +From estimates which he obtained from other observers of his party, +the distances between the bands varied from 6 to l1/2 feet, but so +quickly did they pass that they baffled all attempts to count even the +number that passed in one second. + +He observed the time of continuance of their passage from west to east +as forty-eight seconds, which indicates a width of 33 miles of +diffraction bands stretching outward from the edge of the shadow to +the number of many thousands. + +Mr. G.W. Hill, at Denver, a little to the north of the central track +of the shadow, observed the infra or bands within the shadow, alluding +to the fact that they must be moving at the same rate as the shadow, +although their apparent motion was much slower, or like the shadows of +flying clouds. He attributes the discrepancy to optical illusion. + +At Virginia City the _colors_ of the _ultra_ bands were observed, and +estimated at five seconds' duration from the edge of the shadow, which +is equal to about 4 miles in width. These are known to be the +strongest color bands in the diffraction spectrum, which accounts for +their being generally observed. + +Mr. W.H. Bush, observing at Central City, in a communication to Prof. +Holden alludes to the brilliancy of the colors of these bands as seen +through small clouds floating near the sun's place during totality, +and of the rapid change of their rainbow colors as observed dashing +across the clouds with the rapidity of thought. + +All of these bands, both ultra and infra, as seen in optical +experiments, are colored in reverse order, being from violet to red +for each band outward and inward from the edge of the shadow. + +It is very probable that the velocity of the passage of all the bands +during a total eclipse very much modifies the distinctness of the +colors or possibly obliterates them by optically blending so as to +produce the dull white and black bands which occupied so large a +portion of this grand panorama. + +The phenomenon of these faint colored bands, with the observed light +and dark shadows, may be attributed to one or all of the following +causes: + +1. A change in the direction of a small portion of the sun's light +passing by the solid body of the moon, it being deflected outward by +repulsion or reflection from its surface, and other portions being +deflected inward after passing the body by mutual repulsion of its own +elements toward a _light vacuum_ or space devoid of the element of +vibration. + +2. The colored spectral bands being the direct result of the property +of interference, or the want of correspondence of the wave lengths due +to divergence; the same phenomenon being also observed in convergent +light. This is practically illustrated in the hazy definition of the +reduced aperture of telescopes, and its peculiarities shown in the +spectral rings within and beyond the focus. + +3. Chromatic dispersion by our atmosphere, together with selective +absorption, also by our atmosphere and its vapors, have been suggested +as causes in this curious and complicated phenomena. + +In none of the reports descriptive of the phenomena of polarization of +the corona is there the slightest allusion to the influence that the +diffraction bands may possibly have in modifying or producing the +various conditions of polarization observed; although these +observations have been made and commented upon during the past +twenty-five years. + +Investigations now in progress of the modifying relation of the +phenomenon of diffraction in its effect upon not only the physical +aspect of the corona, but also in some strange spectroscopic anomalies +that have been observed near the sun at other times than during a +total solar eclipse, will, it is hoped, result in a fuller +interpretation of the physical nature of one of the grandest elements +of creation--_light_; let there be more of it. + + * * * * * + + +A CATALOGUE containing brief notices of many important scientific +papers heretofore published in the SUPPLEMENT, may be had gratis at +this office. + + * * * * * + + +The Scientific American Supplement. + +PUBLISHED WEEKLY. + +Terms of Subscription, $5 a Year. + +Sent by mail, postage prepaid, to subscribers in any part of the +United States or Canada. 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